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21. 发明授权

US5468257A Process for dying leather with pigments and cationic binders 失效
标题翻译：用颜料和阳离子粘合剂染色皮革的方法
公开(公告)号：US5468257A
公开(公告)日：1995-11-21
申请号：US169567
申请日：1993-12-17
申请人： Joachim Probst , Fritz Novotny , Harro Traubel , Ludger Heiliger
发明人： Joachim Probst , Fritz Novotny , Harro Traubel , Ludger Heiliger
IPC分类号： C08F220/18 , B01F17/00 , C08F20/10 , C08F20/52 , C08F220/28 , C08F220/56 , C09B67/20 , C09B67/46 , C09D17/00 , C14C11/00 , D06P1/52 , D06P3/32
CPC分类号： B01F17/005 , C08F220/28 , C09B67/006 , D06P1/5257 , D06P3/32
摘要： Specific cationic polymers having hydrophobic side chains are highly suitable as binders for pigments for the dyeing of leather.
摘要翻译：具有疏水侧链的特定阳离子聚合物非常适合作为用于染色皮革的颜料的粘合剂。

22. 发明授权

US5336711A Binder composition and its use for the production of coating or sealing compositions 失效
标题翻译：粘合剂组合物及其用于生产涂料或密封组合物的用途
公开(公告)号：US5336711A
公开(公告)日：1994-08-09
申请号：US973366
申请日：1992-11-09
申请人： Volker Schneider , Harald Blum , Werner Kubitza , Joachim Probst
发明人： Volker Schneider , Harald Blum , Werner Kubitza , Joachim Probst
IPC分类号： C08G18/08 , C08G18/42 , C08G18/63 , C08G18/70 , C09D151/00 , C09D151/08 , C09D175/04 , C09D175/06 , C09J151/08 , C09J175/04 , C09J175/06 , C09K3/10 , H01L23/29 , H01L23/31 , C08L67/00
CPC分类号： C08G18/4288 , C08G18/0823 , C08G18/631 , C08G18/635 , C08G18/638 , C08G18/706 , C09D175/06 , C09J175/06
摘要： The present invention relates to an aqueous binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containing at least one polyester resin having carboxylate and hydroxyl groups and grafted with vinyl monomers andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.s and contains at least one organic polyisocyanate,wherein the binder composition has an NCO/OH equivalent ratio of 0.5:1 to 5:1, based on the isocyanate groups of component B) and the alcoholic hydroxyl groups of component A).The present invention also relates to a process for the production of a coating or sealing composition containing this aqueous binder composition.
摘要翻译：本发明涉及一种水性粘合剂组合物，其包含A）含有至少一种具有羧酸酯和羟基并与乙烯基单体接枝的聚酯树脂的水可稀释有机多元醇组分的水溶液或分散体，以及B）乳化的多异氰酸酯组分在水溶液或分散体A）中，在23℃下的粘度为50至10,000mPa.s，并含有至少一种有机多异氰酸酯，其中粘合剂组合物的NCO / OH当量比为0.5:1至5:1。 1，基于组分B）的异氰酸酯基团和组分A）的醇羟基。本发明还涉及一种生产包含该含水粘合剂组合物的涂料或密封组合物的方法。

23. 发明授权

US4645817A Preparation of hydroxyl group-containing alkoxylation products of organic carboxylic acids 失效
标题翻译：有机羧酸的含羟基烷氧基化产物的制备
公开(公告)号：US4645817A
公开(公告)日：1987-02-24
申请号：US722567
申请日：1985-04-11
申请人： Joachim Probst , Michael Sonntag , Roland Richter , Hanns P. Muller
发明人： Joachim Probst , Michael Sonntag , Roland Richter , Hanns P. Muller
IPC分类号： C08G18/00 , C07B31/00 , C07B41/12 , C07C67/00 , C08F8/00 , C08G18/42 , C08G18/48 , C08G18/62 , C08G65/10 , C08G65/26 , C08G18/80 , C08F20/62 , C08G18/16 , C08G63/42
CPC分类号： C08G65/2645 , C08F8/00 , C08G18/6258 , C08G65/105 , C08G65/2615 , C08G65/2669
摘要： The present invention relates to a process for the preparation of alkoxylation products of organic carboxylic acids containing alcoholic hydroxyl groups by the reaction of any organic compounds containing at least one carboxyl group with alkylene oxides in an alkoxylation reaction in the presence of catalysts, characterized in that the catalysts used are phase transfer catalysts selected from the group consisting of(a) tetraalkylammonium or tetraalkylphosphonium halides in which the sum of carbon atoms of the alkyl groups is at least 8,(b) basic alkali metal compounds converted into complexes with crown ethers and(c) complexes of (i) basic alkali metal compounds and (ii) acyclic organic compounds containing at least 5 alkylene oxide units of the formula --R--O-- (R=C.sub.1 -C.sub.4 -alkylene) in the form of one or more polyether chains having at least 3 alkylene oxide units, said compounds having a molecular weight of at least 238 and containing a total of at least 40% by weight of alkylene oxide units of the type indicated in polyether chains having at least 3 alkylene oxide units.The present invention also relates to the use of these alkoxylation products for the production of polyurethanes by reaction with organic polyisocyanates.
摘要翻译：本发明涉及一种在催化剂存在下通过烷氧基化反应中含有至少一个羧基的任何有机化合物与烯化氧的反应来制备含醇羟基的有机羧酸的烷氧基化产物的方法，其特征在于：所使用的催化剂是选自（a）四烷基铵或四烷基鏻卤化物的相转移催化剂，其中烷基的碳原子总数至少为8，（b）碱基碱金属化合物与冠醚转化为络合物，（c）碱性碱金属化合物和（ii）含有至少5个式-RO-（R = C 1 -C 4 - 亚烷基）的氧化烯单元的一种或多种聚醚链形式的无环有机化合物的络合物具有至少3个烯化氧单元，所述化合物的分子量至少为238，并且含有至少40重量％的环氧烷烃具有至少3个氧化烯单元的聚醚链中所示类型的单元。本发明还涉及这些烷氧基化产物通过与有机多异氰酸酯反应生产聚氨酯的用途。

24. 发明授权

US4434269A Cationic sizing agent for paper and a process for the preparation thereof 失效
标题翻译：用于纸张的阳离子上胶剂及其制备方法
公开(公告)号：US4434269A
公开(公告)日：1984-02-28
申请号：US344991
申请日：1982-02-02
申请人： Joachim Probst , G/u/ nter Kolb , Peter Mummenhoff , Heinz B/a/ umgen
发明人： Joachim Probst , G/u/ nter Kolb , Peter Mummenhoff , Heinz B/a/ umgen
IPC分类号： C08F20/00 , C08F2/24 , C08F2/28 , C08F20/34 , C08F20/44 , C08F220/06 , C08F220/42 , C08F257/02 , D21H17/34 , D21H17/35 , D21H17/37 , D21H17/43 , D21H17/45 , D21H19/20 , D21H21/16 , C08L79/00
CPC分类号： D21H17/455 , C08F2/28 , C08F220/06 , C08F220/42 , C08F257/02 , D21H17/35 , D21H17/37 , D21H17/43 , D21H21/16 , Y10T428/31906
摘要： Cationic sizing agents for paper in the form of an aqueous colloid-disperse solution having average particle diameters of from 15 to 200 nm are obtained by dissolving a water-soluble cationic, chemically uniformaly composed terpolymer compound of:(a) from 7 to 40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate,(b) from 45 to 80% by weight of styrene, and(c) from 4 to 40% by weight of acrylonitrilein an aqueous medium, the total of components (a) to (c) always amounting to 100% by weight and at least 10% of the N,N-dimethylamino groups of the terpolymer being quaternized and the rest being protonated, and by emulsifying, in the presence of from 10 to 70% by weight, based on the following monomer mixture, of this emulsifier,(d) acrylonitrile or methacrylonitrile in quantities of from 5 to 95% by weight, with(e) C.sub.1 -C.sub.12 -alkyl esters of acrylic acid and/or of methacrylic acid in quantities of from 5 to 95% by weight,the total of components (d) and (e) amounting to 100% by weight, and by subjecting the emulsion thus obtained to a radically initiated emulsion polymerization process at temperatures of from 20.degree. to 150.degree. C.
摘要翻译：通过将（a）的水溶性阳离子化学均匀构成的三元共聚物化合物溶解为7〜40重量％，得到平均粒径为15〜200nm的水分胶体分散溶液形式的纸的阳离子上浆剂，重量的丙烯酸N，N-二甲基氨基乙酯和/或甲基丙烯酸酯，（b）45-80％（重量）苯乙烯，和（c）4-40％重量的丙烯腈在水性介质中的组分（ a）至（c）总计为100重量％，并且至少10％的三元共聚物的N，N-二甲基氨基被季铵化，其余的被质子化，并且在10-70％（d）丙烯腈或甲基丙烯腈，其量为5-95重量％，（e）丙烯酸和/或甲基丙烯酸的C 12 -C 12烷基酯（d）和（e）的总量为1至5重量％ 00重量％，并且通过使所得乳液在20℃至150℃的温度下进行自由基引发的乳液聚合反应。

25. 发明申请

US20130208724A1 Automated Adaption to Various Industrial Ethernet Protocols 审中-公开
标题翻译：自动适应各种工业以太网协议
公开(公告)号：US20130208724A1
公开(公告)日：2013-08-15
申请号：US13805881
申请日：2011-06-20
申请人： Marco Colucci , Joachim Probst , Jochen Stinus
发明人： Marco Colucci , Joachim Probst , Jochen Stinus
IPC分类号： H04L29/06
CPC分类号： H04L69/08 , H04L12/40169 , H04L12/403 , H04L12/413 , H04L41/0816 , H04L2012/40228 , H04L2012/4026
摘要： A method for configuring a field device that is connected to a field bus, wherein the field bus is designed for Industrial Ethernet Protocols, wherein the method comprises the following steps: analyzing a data packet transmitted on the field bus; determining an Industrial Ethernet Protocol being used in the data packet; and automatically activating a protocol stack suitable to determined Industrial Ethernet Protocol.
摘要翻译：一种用于配置连接到现场总线的现场设备的方法，其中所述现场总线被设计用于工业以太网协议，其中所述方法包括以下步骤：分析在现场总线上发送的数据分组; 确定在数据分组中使用的工业以太网协议; 并自动激活适合于确定的工业以太网协议的协议栈。

26. 发明授权

US06962953B2 Aqueous secondary dispersions 有权
标题翻译：水性二次分散体
公开(公告)号：US06962953B2
公开(公告)日：2005-11-08
申请号：US10174034
申请日：2002-06-18
申请人： Joachim Probst , Martin Melchiors , Wieland Hovestadt , Michael Sonntag , Burkhard Köhler , Bernhard Jansen
发明人： Joachim Probst , Martin Melchiors , Wieland Hovestadt , Michael Sonntag , Burkhard Köhler , Bernhard Jansen
IPC分类号： C08L53/00 , C09D153/00 , C08F2/00 , C08L33/14 , C08L47/10
CPC分类号： C08L53/00 , C09D153/00 , Y10T428/31855 , C08L2666/04 , C08L2666/02
摘要： The present invention relates to heat and storage stable vinyl polymer polyol secondary dispersions containing A) at least one vinyl polymer resin having functional groups selected from hydroxyl, carboxyl and/or sulfonic acid groups and dispersed in a water/solvent mixture in the presence of a neutralizing agent, and B) at least one amphiphilic polymer built up from a hydrophobic and a hydrophilic segment. The invention also relates to a process for the preparation of the vinyl polymer polyol secondary dispersions by preparing vinyl polymer resin A) by polymerizing a mixture of ethylenically unsaturated monomers a) in the presence of an initiator b) in a water/solvent mixture and adding at least one amphiphilic polymer B), then at least partly neutralizing and dispersing the resulting product, optionally after the addition of a further amount of water.
摘要翻译：本发明涉及储存稳定的乙烯基聚合物多元醇二次分散体，其包含A）至少一种具有选自羟基，羧基和/或磺酸基团的官能团的乙烯基聚合物树脂，并分散在水/溶剂混合物中中和剂，和B）由疏水和亲水链段构成的至少一种两亲性聚合物。本发明还涉及通过制备乙烯基聚合物多元醇二次分散体来制备乙烯基聚合物多元醇二次分散体的方法，其通过在引发剂b）存在下在水/溶剂混合物中聚合烯键式不饱和单体a）的混合物并加入至少一种两亲聚合物B），然后至少部分地中和和分散所得产物，任选地在加入另外量的水之后。

27. 发明授权

US06528573B1 Aqueous two-component polyurethane systems with increased impact resistance and good stability properties, method for producing same and their use 失效
标题翻译：具有增加的耐冲击性和良好稳定性的水性双组分聚氨酯体系，其制备方法及其用途
公开(公告)号：US06528573B1
公开(公告)日：2003-03-04
申请号：US09868206
申请日：2001-06-13
申请人： Joachim Probst , Ulrich Biskup , Claus Kobusch
发明人： Joachim Probst , Ulrich Biskup , Claus Kobusch
IPC分类号： C08L7500
CPC分类号： C09D175/04 , C08F265/04 , C08F265/06 , C08G18/6254 , C08G18/706 , C09D151/003 , C08L2666/14 , C08L2666/02
摘要： This invention relates to aqueous two-component polyurethane systems, to a process for producing them, and to their use for the production of coatings having an enhanced impact strength and good resistance to solvents.
摘要翻译：本发明涉及水性双组分聚氨酯体系，其制备方法及其用于生产具有增强的冲击强度和良好的耐溶剂性的涂料的用途。

28. 发明授权

US5563207A Water-dispersible polyisocyanate compositions 失效
标题翻译：水分散性多异氰酸酯组合物
公开(公告)号：US5563207A
公开(公告)日：1996-10-08
申请号：US428753
申请日：1995-04-25
申请人： Martin Brahm , Wolfgang Kremer , Lutz Schmalstieg , Joachim Probst , Werner Kubitza
发明人： Martin Brahm , Wolfgang Kremer , Lutz Schmalstieg , Joachim Probst , Werner Kubitza
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/28 , C08G18/48 , C08G18/70 , C08G18/72 , C08G18/80 , C09D5/00 , C09D175/00 , C09D175/04 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/706 , C08G18/283 , C08G18/8064
摘要： Water-dispersible polyisocyanate compositions based on aliphatic and aromatic diisocyanates and having an NCO content, based on solids, of 6 to 21% by weight, a weight ratio of incorporated TDI units to incorporated HDI units of 6:1 to 0.1:1 and a content of ethylene oxide units, arranged within terminal polyether chains, of 5 to 40% by weight; a method for the preparation of these polyisocyanate compositions by reacting a polyisocyanate component with monovalent polyether alcohols containing ethylene oxide units at an NCO/OH equivalent ratio of 2:1 to 120:1; and aqueous coating compositions containing these polyisocyanate compositions and polyhydroxyl compounds as the binder.
摘要翻译：基于脂肪族和芳族二异氰酸酯并且基于固体的NCO含量为6〜21重量％，结合的TDI单元与加入的HDI单元的重量比为6:1至0.1:1的水分散性多异氰酸酯组合物和排列在末端聚醚链内的环氧乙烷单元的含量为5-40重量％; 通过使多异氰酸酯组分与NCO / OH当量比为2:1至120:1的含有环氧乙烷单元的单价聚醚醇反应来制备这些多异氰酸酯组合物的方法; 以及含有这些多异氰酸酯组合物和多羟基化合物作为粘合剂的水性涂料组合物。

29. 发明授权

US5552477A Coating compound, a process for its preparation and its use for the production of coatings 失效
标题翻译：涂料化合物，其制备方法及其在涂料生产中的应用
公开(公告)号：US5552477A
公开(公告)日：1996-09-03
申请号：US204183
申请日：1994-03-04
申请人： Rolf Dhein , Knud Reuter , Lothar B acker , Manfred Bock , Werner Kubitza , Joachim Probst
发明人： Rolf Dhein , Knud Reuter , Lothar B acker , Manfred Bock , Werner Kubitza , Joachim Probst
IPC分类号： C08G18/66 , C08G18/08 , C08G18/42 , C08G18/62 , C08G18/65 , C08G18/70 , C09D175/04 , C08L75/04 , C08L75/06
CPC分类号： C08G18/6511 , C08G18/0819 , C08G18/4288 , C08G18/6254 , C08G18/706
摘要： An aqueous two-component coating agent whose binder consists essentially of a combination of a) a polyol component present dissolved and/or dispersed in water comprising a1) at least one water-dilutable polymerisation resin or polycondensation resin with a molecular weight Mn of over 500 possessing hydroxyl groups and a2) a reactive diluent consisting of at least one water-soluble compound with a molecular weight Mn of under 500 capable of reacting with isocyanate groups and b) a polyisocyanate component with a viscosity at 23.degree. C. of from 50 to 10 000 mPa present emulsified in the aqueous solution or dispersion, a method for producing such coating agents wherein the said polyisocyanate component is emulsified in the said aqueous solution or dispersion with the optional incorporation of auxiliary substances and additives in the system prior to adding the polyisocyanate, and the use of the coating agents for the production of air-drying and/or heat-drying coatings.
摘要翻译： PCT No.PCT / EP92 / 01983 Sec。 371日期1994年3月4日 102（e）1994年3月4日PCT PCT 1992年8月28日PCT公布。公开号WO93 / 05087 日期1993年3月18日一种水性双组分涂布剂，其粘合剂基本上由以下组合组成：a）溶解和/或分散在水中的多元醇组分，其包含a1）至少一种水可稀释聚合树脂或缩聚树脂与分子重量Mn超过500具有羟基，和a2）由至少一种分子量为500以下的可与异氰酸酯基反应的水溶性化合物组成的反应性稀释剂，和b）在23℃下的粘度的多异氰酸酯组分在水溶液或分散体中乳化的50至10000立方厘米的方法，制备这种涂料的方法，其中所述多异氰酸酯组分在所述水溶液或分散体中乳化，并且可选地将辅助物质和添加剂并入系统中在加入多异氰酸酯之前，以及使用涂布剂来生产空气干燥和/或加热干燥涂层。

30. 发明授权

US5331039A Water-based binder composition and its use for the production of coating or sealing compositions 失效
标题翻译：水性粘合剂组合物及其用于生产涂料或密封组合物的用途
公开(公告)号：US5331039A
公开(公告)日：1994-07-19
申请号：US973368
申请日：1992-11-09
申请人： Harald Blum , Werner Kubitza , Joachim Probst , Michael Sonntag , Volker Schneider
发明人： Harald Blum , Werner Kubitza , Joachim Probst , Michael Sonntag , Volker Schneider
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/40 , C08G18/42 , C08G18/46 , C08G18/70 , C08L75/04 , C09D175/04 , C09D175/06 , C09J175/00 , C09J175/06 , H01L23/29 , H01L23/31 , C08L67/00
CPC分类号： C09D175/06 , C08G18/0819 , C08G18/10 , C08G18/4063 , C08G18/4202 , C08G18/706 , C08G2170/80
摘要： The present invention relates to a water-based binder composition containingA) an aqueous solution or dispersion of a water-dilutable organic polyol component containing a mixture of at least 5% by weight each of at least two hydroxy-functional polymers selected fromA1) polyester resins containing hydroxyl, urethane and carboxylate groups,A2) polyester resins containing hydroxyl and carboxylate groups, but no urethane or sulfonate groups,A3) polyester resins containing hydroxyl and sulfonate groups and, optionally, carboxylate groups and/or urethane groups,A4) polyacrylate resins containing hydroxyl, carboxylate and/or sulfonate groups,A5) acrylate-grafted polyester resins containing hydroxyl, carboxylate and/or sulfonate groups, andB) a polyisocyanate component which is emulsified in the aqueous solution or dispersion A), has a viscosity at 23.degree. C. of 50 to 10,000 mPa.s and contains at least one organic polyisocyanate,wherein the NCO:OH equivalent ratio, based on the isocyanate groups of component B) and the hydroxyl groups of the polyol component present in A), is 0.2:1 to 5:1.The present invention also relates to a process for the production of a coating or sealing composition containing this aqueous binder composition.
摘要翻译：本发明涉及水性粘合剂组合物，其包含A）水可稀释有机多元醇组分的水溶液或分散体，其含有至少5重量％的至少两种羟基官能聚合物的混合物，所述羟基官能聚合物选自A1）含有羟基，氨基甲酸酯和羧酸酯基团的聚酯树脂，A2）含有羟基和羧酸酯基团但不含氨基甲酸酯基或磺酸酯基团的聚酯树脂，A3）含有羟基和磺酸酯基团以及任选的羧酸酯基团和/或氨基甲酸酯基团的聚酯树脂，A4）含有羟基，羧酸酯和/或磺酸酯基的聚丙烯酸酯树脂，A5）含有羟基，羧酸酯和/或磺酸酯基团的丙烯酸酯接枝的聚酯树脂，和B）在水溶液或分散体A）中乳化的多异氰酸酯组分具有粘度在23℃下为50至10,000mPa.s并含有至少一种有机多异氰酸酯，其中NCO:OH当量比基于异氰酸酯组分B）的组分和A）中存在的多元醇组分的羟基为0.2:1至5:1。本发明还涉及一种生产包含该含水粘合剂组合物的涂料或密封组合物的方法。

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