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21. 发明授权

US4559159A Copolymers, their preparation and their use as assistants in detergents and cleansing agents 失效
标题翻译：共聚物，它们的制备及其作为洗涤剂和清洁剂助剂的用途
公开(公告)号：US4559159A
公开(公告)日：1985-12-17
申请号：US580806
申请日：1984-02-16
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Richard Mueller , Paul Diessel , Albert Hettche
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Richard Mueller , Paul Diessel , Albert Hettche
IPC分类号： C08F8/00 , C08F8/14 , C08F220/04 , C11D3/37 , D06L1/12 , D06M13/02 , D06M13/188 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/402 , D06M15/263 , C08F220/06 , D06L3/02
CPC分类号： C08F220/04 , C08F8/14 , C11D3/3757 , C11D3/3769 , C11D3/3773
摘要： Water-soluble copolymers which consist of from 40 to 90% by weight of one or more ethylenically unsaturated monocarboxylic acids of 3 to 5 carbon atoms, from 60 to 10% by weight of one or more ethylenically unsaturated dicarboxylic acids of 4 to 8 carbon atoms and/or of the corresponding dicarboxylic acid anhydride and, if required, not more than 15% by weight, based on the total weight of the carboxyl-containing monomers, of one or more carboxyl-free monomers, and which are esterified with from 2 to 60% by weight, based on the total weight of the carboxyl-containing monomers, of one or more compounds which contain a terminal hydroxyl group and one or more alkylene oxide groups of 2 to 4 carbon atoms, the preparation of such water-soluble copolymers and their use as assistants in detergents, cleansing and dishwashing agents.
摘要翻译：由40至90重量％的含有3-5个碳原子的一种或多种烯属不饱和一元羧酸组成的水溶性共聚物，60至10重量％的一种或多种4-8个碳原子的烯键式不饱和二羧酸和/或相应的二羧酸酐，并且如果需要，不超过15重量％，基于含羧基单体的总重量，一种或多种无羧基单体，并且用2 至60重量％，基于含羧基单体的总重量，一种或多种含有末端羟基和一个或多个2至4个碳原子的氧化烯基团的化合物，制备这种水溶性共聚物及其用作洗涤剂，清洁剂和餐具洗涤剂中的助剂。

22. 发明授权

US4451582A Preparation of insoluble, only slightly swellable polymers of basic vinyl-heterocyclic compounds 失效
标题翻译：制备碱性乙烯基 - 杂环化合物的不溶性，仅略微溶胀的聚合物
公开(公告)号：US4451582A
公开(公告)日：1984-05-29
申请号：US472242
申请日：1983-03-04
申请人： Walter Denzinger , Hans-Helmut Goertz , Axel Sanner , Heinrich Hartmann
发明人： Walter Denzinger , Hans-Helmut Goertz , Axel Sanner , Heinrich Hartmann
IPC分类号： B01D15/00 , B01J20/26 , B01J31/00 , B01J31/06 , B01J31/08 , B01J31/16 , B01J39/20 , B01J41/14 , C08F2/00 , C08F26/00 , C08F26/06 , C08F269/00 , C12N11/08 , C08F126/06 , C08F8/10 , C08F226/06
CPC分类号： C12N11/08 , B01J20/26 , B01J31/003 , B01J31/06 , B01J31/08 , B01J31/1658 , B01J39/20 , C08F26/06 , B01J2231/321 , B01J2531/16 , B01J2531/824 , B01J31/181
摘要： A process for the preparation of insoluble, only slightly swellable, granular polymers of basic vinyl-heterocyclic compounds and of their copolymers with up to 30% by weight of copolymerizable monomers and 0.1-10% by weight of crosslinking agent by exclusion of (atmospheric) oxygen from the mixture of monomer and crosslinking agent, without addition of any initiator or catalyst, and the use of the polymers obtained as ion exchangers, adsorbents and carriers for proteins.
摘要翻译：制备碱性乙烯基 - 杂环化合物的不溶性，仅略微溶胀的颗粒状聚合物及其共聚物与高达30重量％的可共聚单体和0.1-10重量％的交联剂的方法，排除（大气）来自单体和交联剂的混合物的氧，而不添加任何引发剂或催化剂，以及使用作为离子交换剂获得的聚合物，用于蛋白质的吸附剂和载体。

23. 发明授权

US06586534B1 Agglomerated particles of finely divided polymers which are water-soluble or capable of swelling in water and contain ammonium carboxylate groups 失效
标题翻译：精细分散的聚合物的聚集颗粒，其水溶性或能够在水中溶胀并含有羧酸铵基团
公开(公告)号：US06586534B1
公开(公告)日：2003-07-01
申请号：US08809710
申请日：1997-04-04
申请人： Martin Rübenacker , Reinhard Schneider , Jürgen Nieberle , Heinrich Hartmann , Walter Denzinger , Axel Kistenmacher
发明人： Martin Rübenacker , Reinhard Schneider , Jürgen Nieberle , Heinrich Hartmann , Walter Denzinger , Axel Kistenmacher
IPC分类号： C08F800
CPC分类号： C08F220/04 , C08F6/18
摘要： Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers containing ammonium carboxylate groups are prepared by azeotropic removal of water from water-in-oil emulsions of the water-soluble or water-swellable polymers which contain ammonium carboxylate groups in the presence of from 0.1 to 40% by weight, based on the polymers, of polyalkylene glycols which have an agglomerating effect and which are obtainable by an addition reaction of C2-C4-alkylene oxides with alcohols, phenols, amines or carboxylic acids and contain at least two polymerized alkylene oxide units and additionally of from 0.1 to 20% by weight, based on the polymers, of protective colloids which are obtainable by free radical copolymerization of C8-C40-monoolefins with monoethylenically unsaturated C4-C6-dicarboxylic anhydrides by a mass polymerization method at from 80 to 300° C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, and said agglomerated polymer particles are used as thickeners for textile pigment print pastes.
摘要翻译：通过共沸除去含有羧酸铵基团的水溶性或水溶胀性聚合物的水，从而将含有羧酸铵基团的细分散的水溶性或水溶胀性聚合物的聚集的聚合物颗粒共沸去除，基于聚合物，存在具有附聚效应的聚亚烷基二醇的0.1至40重量％，其可通过C 2 -C 4 - 烯化氧与醇，酚，胺或羧酸的加成反应获得并含有至少两个聚合的烯化氧单元，另外为基于聚合物的0.1至20重量％的保护胶体，其通过C8-C40-单烯烃与单烯属不饱和C4-C6-二羧酸酐通过质量自由基共聚获得在80〜300℃下进行聚合，得到分子量为500〜20,000g / mol的共聚物，所述聚集体聚合物颗粒用作纺织品颜料印刷浆料的增稠剂。

24. 发明授权

US06512055B2 Copolymers and their reaction products with amines as fuel and lubricant additives 有权
标题翻译：共聚物及其与胺的反应产物作为燃料和润滑剂添加剂
公开(公告)号：US06512055B2
公开(公告)日：2003-01-28
申请号：US09848281
申请日：2001-05-04
申请人： Wolfgang Günther , Knut Oppenländer , Walter Denzinger , Heinrich Hartmann , Helmut Mach , Harald Schwahn , Hans Peter Rath
发明人： Wolfgang Günther , Knut Oppenländer , Walter Denzinger , Heinrich Hartmann , Helmut Mach , Harald Schwahn , Hans Peter Rath
IPC分类号： C08F812
CPC分类号： C10M149/06 , C08F8/32 , C08F210/10 , C08F210/14 , C08F216/18 , C08F220/06 , C08F222/06 , C08F226/10 , C08F255/02 , C08F255/10 , C08F2220/1858 , C08F2220/1883 , C08F2220/1891 , C08F2800/10 , C10L1/221 , C10L1/236 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/04 , C10L10/18 , C10M2215/04 , C10M2215/042 , C10M2215/26 , C10M2217/00 , C10M2217/02 , C10M2217/024 , C10M2217/028 , C10M2217/04 , C10M2217/046 , C10M2217/06 , C08F2500/02 , C08F226/08 , C08F222/00
摘要： Copolymers I carrying functional groups and comprising a) 20-60 mol % of at least one monoethylenically unsaturated C4-C6-dicarboxylic acid or an anhydride thereof, b) 10-70 mol % of at least one oligomer of propene or of a branched 1-olefin of 4 to 10 carbon atoms, having an average molecular weight Mw of from 300 to 5000, and c) 1-50 mol % of at least one monoethylenically unsaturated compound which is copolymerizable with the monomers a) and b), a process for their preparation, oil-soluble reaction products obtainable therefrom by reaction with an amine and the use of said reaction products as additives for lubricants and fuels.
摘要翻译：携带官能团并包含a）20-60mol％的至少一种单烯属不饱和C4-C6-二羧酸或其酸酐的共聚物，b）10-70mol％的至少一种丙烯或支链1- 4〜10个碳原子的烯烃，平均分子量Mw为300〜5000，和c）1-50摩尔％的可与单体a）和b）共聚的至少一种单烯键式不饱和化合物，制备，通过与胺反应可得到的油溶性反应产物和使用所述反应产物作为润滑剂和燃料的添加剂。

25. 发明授权

US06284716B1 Copolymers and their reaction products with amines as fuel and lubricant additives 失效
标题翻译：共聚物及其与胺的反应产物作为燃料和润滑剂添加剂
公开(公告)号：US06284716B1
公开(公告)日：2001-09-04
申请号：US08605073
申请日：1996-03-12
申请人： Wolfgang Günther , Knut Oppenländer , Walter Denzinger , Heinrich Hartmann , Helmut Mach , Harald Schwahn , Hans Peter Rath
发明人： Wolfgang Günther , Knut Oppenländer , Walter Denzinger , Heinrich Hartmann , Helmut Mach , Harald Schwahn , Hans Peter Rath
IPC分类号： C10M12963
CPC分类号： C10M149/06 , C08F8/32 , C08F210/10 , C08F210/14 , C08F216/18 , C08F220/06 , C08F222/06 , C08F226/10 , C08F255/02 , C08F255/10 , C08F2220/1858 , C08F2220/1883 , C08F2220/1891 , C08F2800/10 , C10L1/221 , C10L1/236 , C10L1/2364 , C10L1/2366 , C10L1/2368 , C10L1/238 , C10L1/2383 , C10L1/2387 , C10L10/04 , C10L10/18 , C10M2215/04 , C10M2215/042 , C10M2215/26 , C10M2217/00 , C10M2217/02 , C10M2217/024 , C10M2217/028 , C10M2217/04 , C10M2217/046 , C10M2217/06 , C08F2500/02 , C08F226/08 , C08F222/00
摘要： Copolymers I carrying functional groups and comprising a) 20-60 mol % of at least one monoethylenically unsaturated C4-C6-dicarboxylic acid or an anhydride thereof, b) 10-70 mol % of at least one oligomer of propene or of a branched 1-olefin of 4 to 10 carbon atoms, having an average molecular weight Mw of from 300 to 5000, and c) 1-50 mol % of at least one monoethylenically unsaturated compound which is copolymerizable with the monomers a) and b), a process for their preparation, oil-soluble reaction products obtainable therefrom by reaction with an amine and the use of said reaction products as additives for lubricants and fuels.
摘要翻译：携带官能团并包含a）20-60mol％的至少一种单烯属不饱和C4-C6-二羧酸或其酸酐的共聚物，b）10-70mol％的至少一种丙烯或支链1- 4〜10个碳原子的烯烃，平均分子量Mw为300〜5000，和c）1-50摩尔％的可与单体a）和b）共聚的至少一种单烯键式不饱和化合物，制备，通过与胺反应可得到的油溶性反应产物和使用所述反应产物作为润滑剂和燃料的添加剂。

26. 发明授权

US5425784A Polymeric tanning agents 失效
标题翻译：聚合鞣制剂
公开(公告)号：US5425784A
公开(公告)日：1995-06-20
申请号：US256054
申请日：1994-06-27
申请人： Walter Denzinger , Heinrich Hartmann , Brigitte Wegner
发明人： Walter Denzinger , Heinrich Hartmann , Brigitte Wegner
IPC分类号： C08F251/00 , C14C3/22
CPC分类号： C08F251/00 , C14C3/22
摘要： Water-soluble graft polymers of monosaccharides, oligosaccharides, polysaccharides and derivatives thereof, obtainable by free radical polymerization ofA) a monomer selected from, or a monomer mixture of,(a) from 20 to 100% by weight of acrylic acid or methacrylic acid or of a mixture thereof or of the alkali metal, alkaline earth metal or ammonium salts thereof,(b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers having at least 2 ethylenically unsaturated, nonconjugated double bonds in the molecule,in the presence ofB) monosaccharides, oligosaccharides, polysaccharides, oxidatively, hydrolyrically or enzymatically degraded polysaccharides, oxidized hydrolyrically degraded or oxidized enzymatically degraded polysaccharides, chemically modified mono-, oligo- or polysaccharides or a mixture of the stated compounds in a weight ratio A:B of from 95:5 to 20:80, are used as a tanning agent for the self-tanning, pretanning and simultaneous tanning of pelts and skins and for the retanning of leather and skin.
摘要翻译： PCT No.PCT / EP93 / 00061 Sec。 371日期1994年6月27日第 102（e）日期1994年6月27日PCT 1993年1月14日PCT PCT。公开号WO93 / 14227 日期：1993年7月22日。单糖，寡糖，多糖及其衍生物的水溶性接枝聚合物，可通过A）选自下列的单体或（a）20至100％的单体混合物丙烯酸或甲基丙烯酸或其混合物或其碱金属，碱土金属或铵盐的重量，（b）0至80重量％的可与单体（a）共聚的其它单烯属不饱和单体，和（c）在B）单糖，寡糖，多糖，氧化，水解或酶促降解的多糖的存在下，在分子中具有至少2个烯属不饱和的非共轭双键的0至5重量％的单体，氧化水解降解或氧化的酶促降解的多糖，化学修饰的单糖，寡糖或多糖或所述化合物的混合物，其重量比A:B为95:5至 20:80，被用作皮革和皮肤自鞣，预处理和同时鞣制皮革和皮肤的鞣制剂。

27. 发明授权

US5352729A Use of pigment formulations for the preparation of pastes, printing inks and coatings 失效
标题翻译：使用颜料配方制备糊剂，印刷油墨和涂料
公开(公告)号：US5352729A
公开(公告)日：1994-10-04
申请号：US973986
申请日：1992-11-09
申请人： Hermann Birkhofer , Walter Denzinger , Heinrich Hartmann , Juan A. G. Gomez , Paul Guenthert , Joachim Jesse , Robert Kreuzer , Knut Oppenlaender , Reinhard U. Roth , Benno Sens
发明人： Hermann Birkhofer , Walter Denzinger , Heinrich Hartmann , Juan A. G. Gomez , Paul Guenthert , Joachim Jesse , Robert Kreuzer , Knut Oppenlaender , Reinhard U. Roth , Benno Sens
IPC分类号： C09B67/08 , C09B67/20 , C09B67/46 , C09C3/10 , C09D7/00 , C09D11/037 , C08L35/08 , C08L33/02 , C08L23/20 , C08L23/24
CPC分类号： C09D11/037 , C09B67/0063 , C09B67/009 , C09D7/007 , Y10T428/2998
摘要： Pigment formulations containing(a) at least one finely divided pigment,(b) at least one copolymer obtainable by free radical polymerization of(.alpha..sub.1) C.sub.8 -C.sub.40 -monoolefins or(.alpha..sub.2) C.sub.8 -C.sub.40 -alkyl vinyl ethers or(.alpha..sub.3) a mixture of C.sub.8 -C.sub.40 -alkyl vinyl ethers and up to 50 mol % of C.sub.8 -C.sub.40 -monoolefins with(.beta.) monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids or C.sub.4 -C.sub.12 -dicarboxylic anhydridesand having a molecular weight of from 500 to 20,000 g/mol, some or all of whose carboxyl or anhydride groups may be reacted with ammnonia, amines, alcohols, amino- or hydroxycarboxylic acids or alkali metal or alkaline earth metal hydroxides, and(c) if required, further assistants conventionally used in pigment formulationsare used for the preparation of pastes, printing inks and coatings.
摘要翻译：含有（a）至少一种细分散颜料的颜料配方，（b）至少一种可通过（α1）C8-C40-单烯烃或（α2）C8-C40-烷基乙烯基醚的自由基聚合获得的共聚物或（α 3）C8-C40烷基乙烯基醚和高达50mol％的C8-C40-单烯烃与（β）单烯属不饱和C4-C12-二羧酸或C4-C12-二羧酸酐的混合物，其分子量为 500至20,000g / mol，其羧基或酸酐基团的一些或全部可与氨基，胺，醇，氨基或羟基羧酸或碱金属或碱土金属氢氧化物反应，和（c）如果需要，用于颜料配方中用于制备糊剂，印刷油墨和涂料。

28. 发明授权

US5266165A Paper sizing using copolymers of long-chain olefins and maleic anhydride in the form of the semiamides with morpholine 失效
标题翻译：使用长链烯烃和马来酸酐的共聚物以半自由基与吗啉的纸浆定型
公开(公告)号：US5266165A
公开(公告)日：1993-11-30
申请号：US955270
申请日：1992-10-01
申请人： Arnold DeClercq , Walter Denzinger , Norbert Greif , Heinrich Hartmann , Knut Oppenlaender , Ulrich Riebeling
发明人： Arnold DeClercq , Walter Denzinger , Norbert Greif , Heinrich Hartmann , Knut Oppenlaender , Ulrich Riebeling
IPC分类号： C08F8/32 , C08F8/44 , C08F10/00 , C08F210/00 , D21H17/16 , D21H19/16 , D21H17/45 , C08F8/30 , C08F222/06 , D21H21/16
CPC分类号： D21H17/16 , C08F8/44
摘要： Abstract of the Disclosure: Copolymers of (a) C.sub.12 - to C.sub.24 -monoolefins and (b) maleic anhydride or itaconic anhydride, having molecular weights of from 800 to 100,000 g/mol, in the form of partially or completely neutralized semiamides with morpholine, in aqueous solution or dispersion, can be used as sizes for paper.
摘要翻译：公开的摘要：（a）C12-至C24-单烯烃和（b）分子量为800至100,000g / mol的马来酸酐或衣康酸酐的共聚物为部分或完全中和的具有吗啉的半酰胺形式，在水溶液或分散体中，可用作纸张的尺寸。

29. 发明授权

US5145559A Production of paper, board and cardboard 失效
标题翻译：生产纸张，纸板和卡片
公开(公告)号：US5145559A
公开(公告)日：1992-09-08
申请号：US641852
申请日：1991-01-16
申请人： Werner Auhorn , Friedrich Linhart , Primoz Lorencak , Michael Kroener , Norbert Sendhoff , Walter Denzinger , Heinrich Hartmann
发明人： Werner Auhorn , Friedrich Linhart , Primoz Lorencak , Michael Kroener , Norbert Sendhoff , Walter Denzinger , Heinrich Hartmann
IPC分类号： C08F8/12 , D21H17/34 , D21H17/36
CPC分类号： D21H17/34
摘要： Paper, board and cardboard are produced by draining a paper stock, containing undesirable substances, in the presence of hydrolyzed homo- and/or copolymers of N-vinylformamide having a degree of hydrolysis of not less than 60% and a cationic retention aid. According to the invention, faster drainage and improved retention are obtained compared with the use of known fixing agents.
摘要翻译：在水解度不低于60％的N-乙烯基甲酰胺和阳离子助留剂的水解均聚物和/或共聚物的存在下，通过排出含有不需要的物质的纸料来制造纸，纸板和纸板。根据本发明，与使用已知的固定剂相比，获得了更快的排水和改进的保留。

30. 发明授权

US5009805A Liquid detergent with copolymer additive 失效
标题翻译：液体洗涤剂与共聚添加剂
公开(公告)号：US5009805A
公开(公告)日：1991-04-23
申请号：US424084
申请日：1989-10-19
申请人： Johannes Perner , Paul Diessel , Heinrich Hartmann , Walter Denzinger , Alfred Oftring , Willibald Schoenleben
发明人： Johannes Perner , Paul Diessel , Heinrich Hartmann , Walter Denzinger , Alfred Oftring , Willibald Schoenleben
IPC分类号： C11D3/32 , C11D3/37
CPC分类号： C11D3/3773
摘要： Liquid detergent formulations contain as essential constituents a surfactant and 0.1-20% by weight of a copolymer which contains(a) 50-99 mol % of units of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, a half ester of a monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic acid, an ester of a monoethylenically unsaturated C.sub.3 -C.sub.8 -monocarboxylic acid, a C.sub.2 -C.sub.30 -olefin, styrene, a C.sub.1 -C.sub.3 -alkylstyrene, a C.sub.1 -C.sub.28 -alkyl vinyl ether, a vinyl ester of a saturated C.sub.1 -C.sub.8 -monocarboxylic acid or a mixture thereof and(b) 50-1 mol % of units of an amide of a monoethylenically unsaturated C.sub.3 -C.sub.8 -carboxylic acid where the amide groups have the structure ##STR1## where R.sup.1 is C.sub.8 -C.sub.28 -alkyl or preferably ##STR2## R.sup.3 and R.sup.4 are each H, CH.sub.3 or C.sub.2 H.sub.5, R is C.sub.1 -C.sub.28 -alkyl,n is from 2 to 100 andR.sup.2 is H or R.sup.1,and has a K value of from 8 to 200, or a salt thereof.
摘要翻译：液体洗涤剂配方含有表面活性剂和0.1-20重量％的共聚物，其含有（a）50-99摩尔％的单烯属不饱和C3-C8-单羧酸单元，单烯属不饱和C4-C8-二羧酸酸，单烯键式不饱和C4-C8-二羧酸的半酯，单烯属不饱和C3-C8-一元羧酸的酯，C2-C30-烯烃，苯乙烯，C1-C3-烷基苯乙烯，C1-C28- 烷基乙烯基醚，饱和C1-C8-一元羧酸的乙烯基酯或其混合物，和（b）50-1摩尔％的单烯属不饱和C 3 -C 8 - 羧酸的酰胺单元，其中酰胺基具有其中R 1为C 8 -C 28 - 烷基或优选R 3和R 4各自为H，CH 3或C 2 H 5，R为C 1 -C 28 - 烷基，n为2至100，R 2为H或R 1，并且的K值为8〜200，或其盐。

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