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21. 发明授权

US07105689B2 Compound suitable for use as a catalyst or for producing a catalyst system derived from a bis-phosphorinane 有权
标题翻译：适合用作催化剂的化合物或用于生产衍生自双 - 磷杂烷的催化剂体系的化合物
公开(公告)号：US07105689B2
公开(公告)日：2006-09-12
申请号：US10467232
申请日：2002-01-26
申请人： Michael Slany , Martin Schäfer , Michael Röper
发明人： Michael Slany , Martin Schäfer , Michael Röper
IPC分类号： C07F17/02
CPC分类号： B01J31/2433 , B01J2231/321 , B01J2531/80 , B01J2531/822 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C67/38 , C07C253/30 , C07F9/65683 , C07C69/44 , C07C69/24 , C07C255/19
摘要： A compound of formula (I) suitable as a catalyst or for the preparation of a catalyst system: L1-X-L2 (I) is provided, in which X is a lower alkylene group, an arylene group or an alkarylene group;L1 is in which Y1 is oxygen, sulfur or N—R17,R11, R12, R13, R14, R15, R16 and R17 independently of one another being hydrogen, alkyl or aryl; andL2 is in which Y2 is oxygen, sulfur or N—R27,R21, R22, R23, R24, R25, R26 and R27 independently of one another being hydrogen, alkyl or aryl,it being possible for L1 and L2 to be identical or different.
摘要翻译：适合作为催化剂或用于制备催化剂体系的式（I）化合物：<？in-line-formula description =“In-line formula”end =“lead”？> L 1 > -XL <2>（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>，其中X是低级亚烷基，亚芳基基团或亚烷基; L 1其中Y 1是氧，硫或NR 17，R 11，R 11， 12，R 13，R 14，R 15，R 16和R 16， 17彼此独立地为氢，烷基或芳基; 和L 2其中Y 2是氧，硫或NR 27，R 21，R SUP， > 22，R 23，R 24，R 25，R 26和R SUP > 27个彼此独立地为氢，烷基或芳基，L 1和L 2可以相同或不同。

22. 发明授权

US06723882B2 Preparation of dialkyl ketones 失效
标题翻译：二烷基酮的制备
公开(公告)号：US06723882B2
公开(公告)日：2004-04-20
申请号：US10197447
申请日：2002-07-18
申请人： Michael Slany , Martin Schäfer , Michael Röper
发明人： Michael Slany , Martin Schäfer , Michael Röper
IPC分类号： C07C4549
CPC分类号： C07C45/50 , B01J31/24 , B01J31/28 , C07C49/04
摘要： Dialkyl ketones are prepared by reductive carbonylation of &agr;-olefins by means of carbon monoxide and hydrogen in the presence of a catalyst system comprising (a) palladium or a palladium compound; (b) a phosphine; (c) a protic acid having a pKa of ≦4.5, measured in aqueous solution at 25° C.; and (d) a solubilizable carboxamide.
摘要翻译：通过一氧化碳和氢气在包含（a）钯或钯化合物的催化剂体系的存在下，通过还原羰基化α-烯烃制备二烷基酮;（b）膦;（c）具有pKa的质子酸 <= 4.5，在25℃的水溶液中测量。和（d）可溶性羧酰胺。

23. 发明授权

US06353141B1 Functionalized cyclopentene-derived oligomer mixtures, their preparation and their use 失效
标题翻译：官能化的环戊烯衍生的低聚物混合物，其制备及其用途
公开(公告)号：US06353141B1
公开(公告)日：2002-03-05
申请号：US09331419
申请日：1999-06-21
申请人： Edgar Zeller , Gerhard Schulz , Bernhard Geissler , Michael Röper , Guido Voit
发明人： Edgar Zeller , Gerhard Schulz , Bernhard Geissler , Michael Röper , Guido Voit
IPC分类号： C07C4500
CPC分类号： C07C209/26 , C07C29/16 , C07C45/50 , C07C51/145 , C07C47/02
摘要： Functionalized cyclopentene-derived oligomer mixtures are prepared by reacting oligomer mixtures which contain ethyleneic double bonds in one or more reaction steps starting from cyclopentene-derived oligomer mixtures of the formula I R1R2C═[═CH—(CH2)3—CH═]n═CR3R4 (I) where n is an integer from 1 to 15, and R1, R2, R3 and R4 are, independently of one another, hydrogen or alkyl, and are used as described.
摘要翻译：官能化的环戊烯衍生的低聚物混合物通过在一个或多个反应步骤中含有乙烯双键的低聚物混合物反应来制备，所述混合物起始于式Iwheren为1至15的整数的环戊烯衍生的低聚物混合物，R1，R2，R3和R4为，彼此独立地是氢或烷基，并按照所述使用。

24. 发明授权

US06252117B1 Preparation of phosphabenzene compounds 失效
标题翻译：膦酸化合物的制备
公开(公告)号：US06252117B1
公开(公告)日：2001-06-26
申请号：US09525064
申请日：2000-03-14
申请人： Thomas Mackewitz , Michael Röper , Bernhard Breit
发明人： Thomas Mackewitz , Michael Röper , Bernhard Breit
IPC分类号： C07F950
CPC分类号： C07F9/6568
摘要： Phosphabenzene compounds of the formulae I and II where R1 to R6 are identical or different and are, for example, hydrogen, are prepared by reacting corresponding pyrylium salts with PH3 in the presence or absence of a solvent or diluent. The pyrylium salts are combined with PH3 at above 0° C. and reacted at a temperature in the range from 0° C. to 200° C. and a pressure above 1 bar without addition of an acid catalyst or a base.
摘要翻译：在存在或不存在溶剂或稀释剂的情况下，通过使相应的吡喃鎓盐与PH 3反应来制备其中R 1至R 6相同或不同且为例如氢的式I和II的亚膦酸化合物。吡喃鎓盐与0℃下的PH 3结合，在0℃至200℃的温度和1巴以上的温度下反应，不加酸催化剂或碱。

25. 发明申请

US20060252938A1 Process for the separation of palladium catalyst from crude reaction mixtures of aryl acetic acids obtained by carbonylation 审中-公开
标题翻译：从羰基化得到的芳基乙酸粗反应混合物中分离钯催化剂的方法
公开(公告)号：US20060252938A1
公开(公告)日：2006-11-09
申请号：US10554247
申请日：2004-04-16
申请人： Xavier Sava , Michael Röper , Colin Orgill , John Cooper
发明人： Xavier Sava , Michael Röper , Colin Orgill , John Cooper
IPC分类号： B01J38/00 , C07C51/00 , C07D263/52 , C07D209/82
CPC分类号： C07C51/47 , B01J31/4038 , C22B3/24 , C22B11/048 , Y02P10/214 , Y02P10/234 , Y02P20/584 , C07C57/30 , C07C59/64
摘要： A process for the separation of palladium from solvent-free at room temperature solid crude reaction mixtures comprising aryl acetic acids of the general formula (I), wherein Z means phenyl, napht-2-yl, 9H-fluoren-2-yl, substituted carbazol-2-yl, benzoxazol-5-yl, either of which can be substituted with H, C1-C8-alkyl optionally cyclic and optionally substituted with —F or —Cl, C6-C10-aryl optionally substituted with F or Cl OR4, COR5, F, —Cl; optionally substituted pyrrolyl or dehydropyrrolyl or 1-oxo-1,3-dehydro-isoindol 2-yl; R1 means H or C1-C4-alkyl; R2, R3, R4, R5 mean independently of each other H, C1-C8 alkyl, C6-C10-aryl optionally substituted with —F or Cl, or thiophenyl; which crude mixture is obtained by palladium catalyzed carbonylation, by adsorption of the palladium on solid adsorbents, characterized in that the adsorption is carried out in the absence of a reducing agent for palladium and at a temperature, where the crude reaction mixture is molten.
摘要翻译：一种在室温下将钯从无溶剂中分离的方法，包括通式（I）的芳基乙酸的固体粗反应混合物，其中Z表示苯基，萘-2-基，9H-芴-2-基，取代的咔唑-2-基，苯并恶唑-5-基，其中任一个可以被H，C 1 -C 8 - 烷基取代，任选地环状且任选地被-F 或-Cl，C 6 -C 10 - 芳基，其任选被F或Cl取代或OR 4，COR 5，，F，-Cl; 任选取代的吡咯基或脱氢吡咯基或1-氧代-1,3-脱氢 - 异吲哚-2-基; R 1表示H或C 1 -C 4 - 烷基; R 2，R 3，R 4，R 5和它们彼此独立地表示H，C 1， C 1 -C 6烷基，任选被-F或Cl取代的C 6 -C 10 - 芳基或噻吩基; 通过钯在固体吸附剂上吸附，通过钯催化羰基化获得粗混合物，其特征在于，在不存在钯还原剂和在粗反应混合物熔融的温度下进行吸附。

26. 发明授权

US06916954B2 Catalyst system and method for carbonylation 失效
标题翻译：催化剂体系和羰基化方法
公开(公告)号：US06916954B2
公开(公告)日：2005-07-12
申请号：US10381365
申请日：2001-09-25
申请人： Martin Schäfer , Michael Slany , Edgar Zeller , Michael Röper , Michael Schulz , Günther Grimm
发明人： Martin Schäfer , Michael Slany , Edgar Zeller , Michael Röper , Michael Schulz , Günther Grimm
IPC分类号： B01J31/24 , B01J31/16 , B01J31/28 , B01J35/00 , C07B61/00 , C07C51/14 , C07C53/122 , C07C67/38 , C07C51/10 , B01J31/00
CPC分类号： B01J31/2404 , B01J31/165 , B01J31/24 , B01J31/2419 , B01J31/28 , B01J35/0013 , B01J2231/321 , B01J2531/824 , C07C51/14 , C07C67/38 , C07C53/122
摘要： The invention relates to a catalyst system for carbonylating olefinically or acetylenically unsaturated compounds with carbon monoxide and a nucleophile compound, containing (a) palladium; (b) a phosphine and (c) a polymer containing nitrogen which is soluble in the reaction mixture, with the exception of polyvinyl polymers with aromatic radicals containing nitrogen on the polymer chain. The invention also relates to a method for carbonylation in the presence of one such catalyst system.
摘要翻译：本发明涉及用于将烯属或炔属不饱和化合物与一氧化碳和亲核化合物羰基化的催化剂体系，其中含有（a）钯; （b）膦和（c）含有可溶于反应混合物中的氮的聚合物，除了在聚合物链上具有含有氮的芳族基团的聚乙烯基聚合物。本发明还涉及在一种这样的催化剂体系存在下羰基化的方法。

27. 发明申请

US20110160504A1 PROCESS FOR PREPARING A C4-OLEFIN MIXTURE BY SELECTIVE HYDROGENATION AND METATHESIS PROCESS FOR USING THIS STREAM 有权
标题翻译：通过选择性氢化和使用本流程的METATHESIS过程制备C4-烯烃混合物的方法
公开(公告)号：US20110160504A1
公开(公告)日：2011-06-30
申请号：US13042142
申请日：2011-03-07
申请人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
发明人： Jürgen Stephan , Andreas Brodhagen , Markus Schubert , Frank Poplow , Michael Röper , Thomas Hill
IPC分类号： C07C5/05
CPC分类号： C07C11/08 , C07C6/04 , C07C2523/44 , C07C11/107 , C07C11/10
摘要： A C4-olefin mixture having a 1,3-butadiene content of from 100 to 500 ppm and a content of 1,2-dienes of less than 10 ppm is described. The present invention further provides a process for preparing this C4-olefin mixture and provides for its use in a metathesis reaction for preparing 2-pentene and/or 3-hexene.
摘要翻译：描述1,3-丁二烯含量为100-500ppm，1,2-二烯含量小于10ppm的C 4 - 烯烃混合物。本发明还提供了一种制备该C 4烯烃混合物的方法，并提供其在复分解反应中用于制备2-戊烯和/或3-己烯的用途。

28. 发明授权

US07074965B2 Diphosphine 失效
标题翻译：二膦
公开(公告)号：US07074965B2
公开(公告)日：2006-07-11
申请号：US10491419
申请日：2002-09-26
申请人： Xavier Sava , Michael Slany , Michael Röper
发明人： Xavier Sava , Michael Slany , Michael Röper
IPC分类号： C07F9/01
CPC分类号： B01J31/2485 , B01J2231/321 , B01J2531/824 , C07C67/38 , C07F9/65683 , C07F9/657163 , C07C69/533
摘要： A system comprising a diphosphine of the formula R1>P—(CH)n—PR2R3 where R1 is a divalent radical which together with the phosphorus atom to which it is linked forms an unsubstituted or substituted 2-phosphatricyclo[3.3.1.1{3,7}]decyl group or a derivative thereof in which one or more of the carbon atoms are replaced by heteroatoms, R2, R3 are each, independently of one another, a monovalent radical having from 1 to 20 atoms or together form a divalent radical having from 2 to 20 atoms, n is 4 or 5, and a mixture of such diphosphines, and palladium or a palladium compound is suitable as carbonylation catalyst for the carbonylation of a conjugated diene.
摘要翻译：一种包括式（Ⅳ）的二膦的体系，其中包含式？formulas formulas formulas formulas description end？？？>> >> >> >> >> >> >> >> >> >> >> >> <<<<<<<< β-in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1 与其连接的磷原子一起形成未取代或取代的2-磷酸三环[3.3.1.1 {3,7}]癸基或其衍生物的二价基团，其中一个或多个碳原子被杂原子取代，R 2，R 3，3彼此各自独立地为具有1至20个原子的一价基团或一起形成具有 2至20个原子，n为4或5，这些二膦和钯或钯化合物的混合物适合用作羰基化共轭二烯的羰基化催化剂。

29. 发明授权

US07064239B2 Preparation of 1,6-hexanediol 失效
标题翻译： 1,6-己二醇的制备
公开(公告)号：US07064239B2
公开(公告)日：2006-06-20
申请号：US10537829
申请日：2003-12-03
申请人： Rolf-Hartmuth Fischer , Thomas Krug , Andrea Haunert , Michael Röper , Tilman Sirch , Wolfram Stüer
发明人： Rolf-Hartmuth Fischer , Thomas Krug , Andrea Haunert , Michael Röper , Tilman Sirch , Wolfram Stüer
IPC分类号： C07C31/20 , C07C31/18
CPC分类号： C07C29/177 , C07C31/20
摘要： The present invention provides a process for preparing 1,6-hexanediol having a purity of ≧99.5% by weight by catalytically dimerizing acrylic esters and catalytically hydrogenating the hexenedioic diesters obtained in this way to 1,6-hexanediol by a) dimerizing C1- to C8-acrylic esters in the presence of at least one rhodium compound to give mixtures of predominantly 2- and 3-hexenedioic diesters, b) hydrogenating the resulting dimerizing effluent in the presence of chromium-free catalysts comprising predominantly copper as the hydrogenation component and c) purifying the crude 1,6-hexanediol obtained in this way by fractional distillation.
摘要翻译：本发明提供了一种通过催化二聚丙烯酸酯制备纯度> 99.5％（重量）的1,6-己二醇的方法，并将以这种方式获得的己二酸二酯催化氢化，在至少一种铑化合物的存在下加入到C 8 - 丙烯酸酯中，得到主要为2-和3-己烯二酸二酯的混合物，b）将得到的二聚流出物在主要含有铜作为氢化组分的无铬催化剂的存在下，和c）通过分馏纯化以这种方式得到的粗制1,6-己二醇。

30. 发明授权

US06963014B1 C13 alcohol mixture and functionalised C13 alcohol mixture 失效
标题翻译： C13醇混合物和官能化C13醇混合物
公开(公告)号：US06963014B1
公开(公告)日：2005-11-08
申请号：US10129980
申请日：2000-11-17
申请人： Edgar Zeller , Marc Walter , Wolfgang Richter , Klaus Diehl , Michael Röper , Jürgen Tropsch
发明人： Edgar Zeller , Marc Walter , Wolfgang Richter , Klaus Diehl , Michael Röper , Jürgen Tropsch
IPC分类号： B01F17/38 , C07B61/00 , C07C2/08 , C07C29/141 , C07C29/16 , C07C31/125 , C07C41/03 , C07C43/11 , C07C45/50 , C07F9/09 , C07F9/11 , C11D7/26 , C07C27/20 , C07C27/22 , C07C27/24 , C07C29/15
CPC分类号： C11D7/262 , C07C29/141 , C07C29/16 , C07C41/03 , C07C43/11 , C07C45/50 , C07F9/091 , C07F9/11 , C11D7/261 , C07C31/125 , C07C47/02
摘要： A process for preparing a C13-alcohol mixture comprises a) bringing a butene-containing C4-hydrocarbon stream containing less than 5% by weight, based on the butene fraction, of isobutene into contact with a nickel-containing heterogeneous catalyst at elevated temperature, b) isolating a C12-olefin fraction from the reaction mixture, c) hydroformylating the C12-olefin fraction by reaction with carbon monoxide and hydrogen in the presence of a cobalt catalyst and d) hydrogenating the product from c). The alcohol mixture is suitable for preparing surfactants by alkoxylation, glycosidation, sulfation, phosphation, alkoxylation and subsequent sulfation or alkoxylation and subsequent phosphation.
摘要翻译：制备C 13 - 醇混合物的方法包括a）将含有小于5％（重量）的含丁烯C 4 - 的异丁烯在升高的温度下与含镍的非均相催化剂接触，b）从反应混合物中分离出C 12 - 12α-烯烃部分，c）将C 12 - α-烯烃部分通过在一种钴催化剂存在下与一氧化碳和氢气反应，和d）从c）氢化产物。醇混合物适于通过烷氧基化，糖基化，硫酸化，磷酸化，烷氧基化和随后的硫酸化或烷氧基化和随后的磷酸化来制备表面活性剂。

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