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21. 发明授权

US5516853A Process for the production of water-dilutable binders and their use in coating compositions 失效
标题翻译：用于生产水可稀释粘合剂的方法及其在涂料组合物中的用途
公开(公告)号：US5516853A
公开(公告)日：1996-05-14
申请号：US424923
申请日：1995-04-19
申请人： Volker Schneider , Eberhard Arning , Harald Blum , Christian Wamprecht
发明人： Volker Schneider , Eberhard Arning , Harald Blum , Christian Wamprecht
IPC分类号： C08F8/08 , C08F8/14 , C08F8/42 , C08F8/44 , C08F220/04 , C08F220/10 , C08F220/14 , C08F222/04 , C09D133/04 , C09D133/12
CPC分类号： C08F8/14 , C08F2800/20
摘要： The present invention relates to a process for the production of oxidatively crosslinkable, water-dilutable binders bya) forming a copolymer having intramolecular carboxylic anhydride groups by copolymerizing anhydride-functional compounds, other olefinically unsaturated monomers and 5 to 50% by weight, based on the weight of the olefinically unsaturated monomers used for the production of the copolymers a), of monomers which cannot be homopolymerized under the reaction conditions,b) subsequently reacting by ring-opening esterification at least 50% of the anhydride groups present in the copolymer with one or more unsaturated monohydric alcohols,c) reacting by ring-opening esterification up to 50% of the anhydride groups with monohydric saturated alcohols having a molecular weight of 32 to 200 either before, during or after step b),d) optionally reacting 1 to 70% of the carboxyl groups formed in steps b) and c) with organic epoxide compounds ande) neutralizing at least a portion of the carboxyl groups formed in steps b) and c).The present invention also relates to the binders obtained by this process and to their use in water-dilutable lacquers and coating compositions.
摘要翻译：本发明涉及通过以下方式制备可氧化交联的水可稀释粘合剂的方法：a）通过以下方式形成具有分子内羧酸酐基团的共聚物：通过将酐官能化合物，其它烯属不饱和单体和5-50重量％用于生产共聚物a）的烯属不饱和单体的重量，在反应条件下不能均聚的单体，b）随后通过开环酯化反应使共聚物中存在的至少50％的酸酐基团与一种或多种不饱和一元醇，c）在步骤b）之前，期间或之后，通过开环酯化至多50％酸酐基与分子量为32至200的一元饱和醇反应，d）任选地使1 至70％的步骤b）和c）中形成的羧基与有机环氧化合物反应，e）中和至少一部分在步骤b）和c）中形成的羧基。本发明还涉及通过该方法获得的粘合剂及其在水可稀释漆和涂料组合物中的用途。

22. 发明授权

US06458898B1 Two-component polyurethane coating compositions containing polyester polyols as a binder component 失效
标题翻译：含有聚酯多元醇作为粘合剂组分的双组分聚氨酯涂料组合物
公开(公告)号：US06458898B1
公开(公告)日：2002-10-01
申请号：US08329109
申请日：1994-10-25
申请人： Christian Wamprecht , Michael Sonntag
发明人： Christian Wamprecht , Michael Sonntag
IPC分类号： B32B2740
CPC分类号： C09D175/14 , C08G18/68 , C08G18/686 , Y10T428/31551 , Y10T428/31605
摘要： Two-component polyurethane coating compositions containing wherein the binder contains polyisocyanates and certain polyester polyols having hydroxyl numbers of 80 to 250 prepared from a) polyol mixtures and b) aliphatic unsaturated dicarboxylic acids and, optionally, aliphatic saturated dicarboxylic acids, and their use for the production of coatings on plastic moldings such as those used in automobile construction.
摘要翻译：双组分聚氨酯涂料组合物，其中粘合剂含有多异氰酸酯和由a）多元醇混合物和b）脂族不饱和二羧酸和任选的脂族饱和二羧酸制备的羟基数为80至250的某些聚酯多元醇及其用于在塑料模制品上生产涂料，如汽车制造中使用的涂料。

23. 发明授权

US06380308B1 High-solids binder compositions and their use 有权
标题翻译：高固体粘合剂组合物及其用途
公开(公告)号：US06380308B1
公开(公告)日：2002-04-30
申请号：US09711743
申请日：2000-11-13
申请人： Christian Wamprecht , Michael Sonntag , Holger Mundstock
发明人： Christian Wamprecht , Michael Sonntag , Holger Mundstock
IPC分类号： C08G1863
CPC分类号： C08L51/04 , C08F279/02 , C08G18/635 , C09D151/04 , C09D175/04 , Y10T428/31551
摘要： The invention relates to a binder composition containing A) 50-90 parts by wt. of OH-functional graft copolymer resins prepared from a) 0.1 to 10 parts by wt. of polybutadiene, b) 5 to 60 parts by wt. of an unsaturated aromatic monomer, c) 10 to 50 parts by wt. of a hydroxyalkyl ester of (meth)acrylic acid, d) 5 to 70 parts by wt. of a cycloaliphatic ester of (meth)acrylic acid, e) 5 to 50 parts by wt. of an aliphatic ester of (meth)acrylic acid, f) 0.1 to 5 parts by wt. of a mono-olifinically unsaturated mono- or dicarboxylic acid and/or maleic or fumaric acid half esters, B) 0.1 to 5 parts by wt. of a polyfunctional crosslinking agent.
摘要翻译：本发明涉及一种粘合剂组合物，其包含A）50-90重量份由以下制备的OH官能接枝共聚物树脂：0.1〜10重量份的聚丁二烯，b）5〜60重量份。的不饱和芳族单体，c）10至50重量份。的（甲基）丙烯酸的羟烷基酯，d）5〜70重量份。的（甲基）丙烯酸的脂环族酯，e）5〜50重量份的（甲基）丙烯酸的脂肪族酯，f）0.1〜5重量份。的单烯烃不饱和单羧酸和/或马来酸或富马酸半酯，B）0.1至5重量份。的多官能交联剂。

24. 发明授权

US6162891A Polyester polyols and their use in two-component polyurethane lacquers 失效
标题翻译：聚酯多元醇及其在双组分聚氨酯漆中的应用
公开(公告)号：US6162891A
公开(公告)日：2000-12-19
申请号：US352664
申请日：1994-12-09
申请人： Christian Wamprecht , Michael Sonntag , Jurgen Meixner
发明人： Christian Wamprecht , Michael Sonntag , Jurgen Meixner
IPC分类号： C08G18/68 , C08G18/78 , C08G63/52 , C09D175/14 , C08G18/42
CPC分类号： C09D175/14 , C08G18/68 , C08G18/7831 , C08G63/52
摘要： The present invention relates to polyester polyols having hydroxyl numbers of 175 to 520 which are the reaction products ofa) 50 to 60 mole % of a polyol component containing(i) 0 to 39 mole % of one or more dihydric aliphatic or cycloaliphatic alcohols having at least 2 carbon atoms other than neopentyl glycol,(ii) 20 to 59 mole % of neopentyl glycol and(iii) 41 to 80 mole % of one or more at least trihydric aliphatic alcohols containing at least 3 carbon atoms andb) 40 to 50 mole % of a dicarboxylic acid component containing(iv) 0 to 60 mole % of one or more aliphatic or cycloaliphatic, saturated or unsaturated dicarboxylic acids or their anhydrides having at least 2 carbon atoms other than fumaric acid, itaconic acid and maleic acid or their anhydrides and(v) 40 to 100 mole % of one or more of fumaric acid, itaconic acid, maleic acid or their anhydrides,wherein the percentages set forth in a) and b) each add up to 100.The present invention also relates to the use of these polyester polyols, optionally in admixture with other organic polyhydroxyl compounds, as a binder component for two-component polyurethane lacquers also containing lacquer polyisocyanates, more particularly for the production of lacquer coatings on large vehicles and in car repair lacquering.
摘要翻译：本发明涉及羟基数为175〜520的聚酯多元醇，其为a）50〜60摩尔％的多元醇成分的反应产物，所述多元醇成分含有（i）0〜39摩尔％的一种或多种二元脂肪族或脂环族醇，除新戊二醇以外的至少2个碳原子，（ii）20〜59摩尔％的新戊二醇和（iii）41〜80摩尔％的含有至少3个碳原子的一种以上至少三元脂肪醇，b）40〜 50摩尔％的含有（iv）0至60摩尔％的一种或多种脂族或脂环族饱和或不饱和二羧酸或其酸酐的二羧酸组分，其中除了富马酸，衣康酸和马来酸以外具有至少2个碳原子，或它们的酸酐和（v）40至100摩尔％的富马酸，衣康酸，马来酸或其酸酐中的一种或多种，其中a）和b）中列出的百分比各自加到100上。本发明还涉及使用这些p 醇酯多元醇，任选与其它有机多羟基化合物混合，作为也包含漆多异氰酸酯的双组分聚氨酯漆的粘合剂组分，更特别地用于在大型车辆和汽车修漆上生产漆涂料。

25. 发明授权

US06423816B1 Polyester polyols and their use as a binder component in two-component polyurethane coating compositions 失效
标题翻译：聚酯多元醇及其在双组分聚氨酯涂料组合物中作为粘合剂组分的用途
公开(公告)号：US06423816B1
公开(公告)日：2002-07-23
申请号：US08583167
申请日：1996-01-04
申请人： Christian Wamprecht , Michael Sonntag
发明人： Christian Wamprecht , Michael Sonntag
IPC分类号： C08G6312
CPC分类号： C09D175/14 , C08G18/68 , C08G63/52 , C09D167/06 , C08L2666/36
摘要： The present invention relates to polyester polyols having a hydroxyl number of 60 to 400, which are esterification products of a) an alcohol component containing one or more aliphatic or cycloaliphatic alcohols having at least 3 hydroxyl groups and 3 to 8 carbon atoms with b) a carboxylic acid component containing itaconic acid, maleic acid, their anhydrides and/or fumaric acid, provided that at least 10 mole % of either component a) or component b) is an aliphatic or cycloaliphatic, saturated or unsaturated monoalcohol or monocarboxylic acid having 1 to 18 carbon atoms. The present invention also relates to two-component polyurethane coating compositions containing these polyester polyols and lacquer polyisocyanates as the binder and to their use for coating substrates, in particular automotive substrates.
摘要翻译：本发明涉及羟基数为60〜400的聚酯多元醇，它们是a）含有一个或多个具有至少3个羟基和3至8个碳原子的脂族或脂环族醇的醇组分与b）羧酸的酯化产物含有衣康酸的组分，马来酸，它们的酸酐和/或富马酸，条件是至少10摩尔％的组分a）或组分b）是具有1至18个碳原子的脂族或脂环族饱和或不饱和的一元醇或一元羧酸原子本发明还涉及含有这些聚酯多元醇和漆多异氰酸酯作为粘合剂的双组分聚氨酯涂料组合物，以及它们用于涂覆基材，特别是汽车基材的用途。

26. 发明授权

US5969054A High solids polyurethane binder compositions containing grafted polyacrylate polyols 失效
标题翻译：含有接枝聚丙烯酸酯多元醇的高固含量聚氨酯粘合剂组合物
公开(公告)号：US5969054A
公开(公告)日：1999-10-19
申请号：US888520
申请日：1997-07-07
申请人： Christian Wamprecht , Michael Sonntag , Dieter Margotte
发明人： Christian Wamprecht , Michael Sonntag , Dieter Margotte
IPC分类号： C08L51/04 , C08F279/02 , C08G18/63 , C09D151/04 , C08F8/26 , C08F8/30 , C08F220/32 , C08G18/62
CPC分类号： C08G18/633 , C08F279/02 , C09D151/04
摘要： The present invention relates to binder compositions containingA) 40 to 95 parts by weight of OH-functional graft copolymer resins prepared by copolymerizinga) 0.1 to 10 parts by weight of polybutadienes containing at least 20% of 1,2-vinyl groups,b) 5 to 30 parts by weight of aliphatic .alpha.-olefins,c) 0.1 to 35 parts by weight of glycidyl esters of .alpha.-alkylalkane-monocarboxylic acids,d) 10 to 70 parts by weight of unsaturated, aromatic monomers,e) 5 to 60 parts by weight of hydroxyalkyl esters of acrylic and/or methacrylic acid having primary hydroxyl groups,f) 0 to 50 parts by weight of (cyclo)aliphatic esters of acrylic and/or methacrylic acid,g) 0.1 to 20 parts by weight of .alpha.,.beta.-mono-olefinically unsaturated monocarboxylic or dicarboxylic acids and/or maleic acid or fumaric acid semi-esters andh) 0 to 30 parts by weight of other copolymerizable compounds andB) 5 to 60 parts by weight of polyfunctional crosslinking resins,wherein 1 to 30% by weight of the OH groups of the component A) are secondary OH groups. The present invention also relates to the use of these binder compositions for vehicle coatings, in particular automotive refinish coatings and large vehicle coatings, for wood and furniture coatings, general industrial coatings, and for coatings that provide corrosion protection.
摘要翻译：本发明涉及粘合剂组合物，其含有A）40〜95重量份的OH-官能接枝共聚物树脂，其通过以下方法制备：a）将0.1至10重量份含有至少20％的1,2-乙烯基的聚丁二烯，b ）5〜30重量份脂肪族α-烯烃，c）0.1〜35重量份的α-烷基烷烃 - 一元羧酸的缩水甘油酯，d）10〜70重量份的不饱和芳族单体，e）5〜 60重量份具有伯羟基的丙烯酸和/或甲基丙烯酸的羟烷基酯，f）0至50重量份的丙烯酸和/或甲基丙烯酸的（环）脂族酯，g）0.1至20重量份的 α，β-单烯属不饱和单羧酸或二羧酸和/或马来酸或富马酸半酯，和h）0至30重量份的其它可共聚的化合物和B）5至60重量份的多官能交联树脂，其中1〜30重量％的O 组分A）的H基团是仲OH基团。本发明还涉及这些粘合剂组合物用于车辆涂料，特别是汽车修补涂料和大型车辆涂料，用于木材和家具涂料，一般工业涂料以及提供防腐蚀涂料的用途。

27. 发明授权

US5733973A High solids binder compositions containing OH-functional polyacrylate graft copolymers 失效
标题翻译：含有OH-官能的聚丙烯酸酯接枝共聚物的高固体粘合剂组合物
公开(公告)号：US5733973A
公开(公告)日：1998-03-31
申请号：US755878
申请日：1996-12-02
申请人： Christian Wamprecht , Michael Sonntag , Jurgen Schwindt , Dieter Margotte
发明人： Christian Wamprecht , Michael Sonntag , Jurgen Schwindt , Dieter Margotte
IPC分类号： C08F290/04 , C08F279/02 , C08L51/04 , C09D151/00 , C09D151/04 , C09D155/00 , C09D161/04 , C09D161/06 , C09D161/20 , C09D175/00 , C09D175/04 , C08G63/48
CPC分类号： C08F279/02 , C08L51/04
摘要： The present invention relates to binder compositions containing A) 40 to 95 parts by weight of OH-functional graft copolymer resins which are prepared by copolymerizing a mixture containing 0.1 to 10 parts by weight of at least one optionally functional polybutadiene having a molecular weight of 500 to 10,000 and having at least 20% by weight of side-chain 1,2-vinyl double bonds, and B) 5 to 60 parts by weight of a polyfunctional cross-linking resin selected from aminoplast resins and optionally blocked polyisocyanates, wherein the sum of the parts by weight of components A) and B) add up to 100, based on the weight of components A) and B). The present invention also relates to the use of the binder compositions according to the invention for lacquering vehicles, wood and furniture, and for preventing corrosion.
摘要翻译：本发明涉及粘合剂组合物，其包含A）40至95重量份的OH-官能的接枝共聚物树脂，其通过将含有0.1至10重量份的至少一种分子量为500的任意官能的聚丁二烯至10,000重量％，并且具有至少20重量％的侧链1,2-乙烯基双键，和B）5至60重量份选自氨基塑料树脂和任选的封端多异氰酸酯的多官能交联树脂，其中总和的组分A）和B）的重量份，基于组分A）和B）的重量加起来为100。本发明还涉及根据本发明的粘合剂组合物用于涂漆车辆，木材和家具以及用于防止腐蚀的用途。

28. 发明授权

US09949869B2 Intrauterine system 有权
公开(公告)号：US09949869B2
公开(公告)日：2018-04-24
申请号：US13499701
申请日：2010-09-30
申请人： Taina Tjäder , Ulla Calvo Alonso , Pirjo Inki , Harri Jukarainen , Ilkka Jutila , Pirjo Kortesuo , Juha Lehtinen , Eeva Lukkari-Lax , Heikki Lyytikäinen , Joachim Moede , Hannu Nikander , Pirjo Sallinen , Faisal Shafiq , Wolfgang Kaufhold , Christian Wamprecht
发明人： Taina Tjäder , Ulla Calvo Alonso , Pirjo Inki , Harri Jukarainen , Ilkka Jutila , Pirjo Kortesuo , Juha Lehtinen , Eeva Lukkari-Lax , Heikki Lyytikäinen , Joachim Moede , Hannu Nikander , Pirjo Sallinen , Faisal Shafiq , Wolfgang Kaufhold , Christian Wamprecht
IPC分类号： A61F6/14 , A61K9/00
CPC分类号： A61F6/142 , A61K9/0039
摘要： The present invention relates to novel intrauterine systems and to methods for manufacturing these systems. An intrauterine system according to the invention comprises a reservoir and a continuous, closed and flexible frame. The frame comprises a thermoplastic polyurethane elastomer made of a polycarbonate diol, 1,6-hexamethylenediisocyanate, and a chain extender.

29. 发明申请

US20120007270A1 THERMOPLASTIC POLYURETHANES AND THEIR USE 有权
标题翻译：热塑性聚氨酯及其用途
公开(公告)号：US20120007270A1
公开(公告)日：2012-01-12
申请号：US13096612
申请日：2011-04-28
申请人： Faisal Shafiq , Christian Wamprecht , David Pucket
发明人： Faisal Shafiq , Christian Wamprecht , David Pucket
IPC分类号： D04H1/64 , B29C45/00 , C08G18/28
CPC分类号： C08G18/6607 , C08K3/36 , C08L75/04 , C08L83/06 , C08L83/00
摘要： This invention concerns thermoplastic polyurethane mouldings with improved surface resistance (resistance to writing and scratching) and very good technical processability as well as their use.
摘要翻译：本发明涉及具有改善的表面电阻（耐写入和划伤）和非常好的技术加工性及其用途的热塑性聚氨酯模制品。

30. 发明申请

US20110160310A1 TCB BASED HYDROPHILIC POLYURETHANE DISPERSIONS 审中-公开
标题翻译：基于TCB的水解聚氨酯分散体
公开(公告)号：US20110160310A1
公开(公告)日：2011-06-30
申请号：US13061338
申请日：2009-08-22
申请人： Jürgen Köcher , Christian Wamprecht
发明人： Jürgen Köcher , Christian Wamprecht
IPC分类号： A61K47/34 , C08L75/12 , A61P7/02
CPC分类号： A61L29/085 , A61L31/10 , A61L33/068 , C08G18/12 , C08G18/283 , C08G18/3212 , C08G18/44 , C08G18/664 , C08G18/755 , C08G18/758 , C08J3/07 , C08J2375/04 , C08J2375/08 , C09D175/06 , C08L75/04 , C08G18/3228
摘要： The present invention relates to a polyurethaneurea dispersion including a polyurethaneurea which is terminated with at least one polyethylene oxide- and polypropylene oxide-based copolymer unit, and includes a polycarbonate polyol-based unit of formula (I)
摘要翻译：本发明涉及包含聚氨酯脲的聚氨酯脲分散体，其用至少一种聚环氧乙烷和聚环氧丙烷基共聚物单元封端，并包括式（I）的基于聚碳酸酯多元醇的单元，

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