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    • 21. 发明申请
    • Method for manufacturing magnesium borohydride
    • 镁硼氢化物的制造方法
    • US20070140944A1
    • 2007-06-21
    • US11305914
    • 2005-12-19
    • Grigorii SoloveichikJi-Cheng Zhao
    • Grigorii SoloveichikJi-Cheng Zhao
    • C01B35/00
    • C01B6/21
    • Disclosed herein is a method comprising reacting a metal borohydride with a metal chloride composition that comprises magnesium chloride in a solvent to form a reaction mixture; wherein either the metal borohydride, the metal chloride composition or both the metal borohydride and the metal chloride composition are soluble in the solvent and a formed metal chloride is insoluble in the solvent; removing the solvent from the reaction mixture to produce a borohydride complex; treating the borohydride complex to obtain magnesium borohydride; extracting magnesium borohydride solvate; and desolvating the magnesium borohydride solvate to form magnesium borohydride.
    • 本文公开了一种方法,其包括使金属硼氢化物与金属氯化物组合物反应,所述金属氯化物组合物在溶剂中包含氯化镁以形成反应混合物; 其中金属硼氢化物,金属氯化物组合物或金属硼氢化物和金属氯化物组合物都可溶于溶剂中,形成的金属氯化物不溶于溶剂; 从反应混合物中除去溶剂以产生硼氢化物络合物; 处理硼氢化物复合物得到硼氢化镁; 提取硼氢化镁溶剂合物; 并将硼氢化镁溶剂化物脱醇形成硼氢化镁。
    • 23. 发明授权
    • Niobium-silicide based composities resistant to high temperature oxidation
    • 铌硅基复合材料耐高温氧化
    • US06913655B2
    • 2005-07-05
    • US10263527
    • 2002-10-03
    • Melvin Robert JacksonBernard Patrick BewlayJi-Cheng Zhao
    • Melvin Robert JacksonBernard Patrick BewlayJi-Cheng Zhao
    • C22C27/02C22C29/18F01D5/28
    • C22C29/18C22C27/02F01D5/28F05D2200/11Y02T50/672
    • A niobium-silicide refractory metal intermetallic composite adapted for use in a turbine component. The niobium-silicide refractory metal intermetallic composite comprises: between about 19 atomic percent and about 24 atomic percent titanium; between about 1 atomic percent and about 5 atomic percent hafnium; between about 16 atomic percent and about 22 atomic percent silicon; between about 7 atomic percent and about 14 atomic percent chromium; from about 1.5 atomic percent to about 3 atomic percent tin; and a balance of niobium. The niobium silicide refractory intermetallic composite contains a tetragonal phase, which comprises a volume fraction from 0.35 to 0.5 of the niobium silicide refractory intermetallic composite, and a hexagonal M3Si5 silicide phase (wherein M is at least one of Nb and Hf) which comprises a volume fraction comprises less than 0.25 of the niobium silicide refractory intermetallic composite. A ratio of the sum of atomic percentages of niobium and tantalum present in said niobium silicide refractory intermetallic composite to the sum of atomic percentages of titanium and of hafnium present in said niobium silicide refractory intermetallic composite has a value from 1.5 to 2.0.
    • 适用于涡轮机部件的铌硅化物耐火金属金属间复合材料。 所述铌 - 硅化物难熔金属金属间复合物包括:约19原子%至约24原子%的钛; 约1原子%至约5原子%的铪; 介于约16原子%和约22原子%之间的硅; 约7原子%至约14原子%的铬; 从约1.5原子%至约3原子%的锡; 和铌的平衡。 所述铌硅化物难熔金属间复合材料包含四方相,其包含硅化铌耐火金属间复合材料的0.35至0.5的体积分数和六方晶系的N 3 Si 5 Si 5 Si 包括体积分数的相(其中M是Nb和Hf中的至少一种)包括小于0.25的硅化铌耐火金属间复合材料。 所述铌硅化物难熔金属间化合物中存在的铌和钽的原子百分比之和与存在于所述铌硅化物耐火金属间复合材料中的钛和铪的原子百分比之和的比值为1.5至2.0。
    • 26. 发明授权
    • Niobium-silicide based composites resistant to low temperature pesting
    • 铌 - 硅化物基复合材料耐低温虫害
    • US06419765B1
    • 2002-07-16
    • US09735769
    • 2000-12-13
    • Melvin Robert JacksonBernard Patrick BewlayJi-Cheng Zhao
    • Melvin Robert JacksonBernard Patrick BewlayJi-Cheng Zhao
    • C22C2702
    • C22F1/18C22C27/02
    • A niobium-silicide refractory metal intermetallic composite having enhanced material characteristics, such as oxidation resistance, creep resistance, and toughness, and turbine components made therefrom. The composite comprises between about 14 atomic percent and about 26 atomic percent titanium; between about 1 atomic percent and about 4 atomic percent hafnium; up to about 6 atomic percent tantalum; between about 12 atomic percent and about 22 atomic percent silicon; up to about 5 atomic percent germanium; up to about 4 atomic percent boron; between about 7 atomic percent and about 14 atomic percent chromium; up to about 3 atomic percent iron; up to about 2 atomic percent aluminum; between about 1 atomic percent and about 3 atomic percent tin; up to about 2 atomic percent tungsten; up to about 2 atomic percent molybdenum; and a balance of niobium, wherein a ratio of a sum of atomic percentages of niobium and tantalum present in said niobium silicide refractory intermetallic composite to a sum of atomic percentages of titanium and hafnium present in said niobium silicide refractory intermetallic composite has a value between about 1.4 and about 2.2 (i.e.,1.4
    • 具有提高材料特性如耐氧化性,抗蠕变性和韧性的铌 - 硅化物耐火金属金属间复合物和由其制成的涡轮部件。 复合材料包含约14原子%至约26原子%的钛; 约1原子%至约4原子%的铪; 高达约6原子%的钽; 约12原子%和约22原子%之间的硅; 高达约5原子%的锗; 高达约4原子%的硼; 约7原子%至约14原子%的铬; 高达约3原子%铁; 高达约2原子%的铝; 在约1原子%和约3原子%之间的锡; 高达约2原子%的钨; 高达约2原子%的钼; 和铌的余量,其中存在于所述铌硅化物难熔金属间复合材料中的铌和钽的原子百分比之和与存在于所述铌硅化物耐火金属间复合材料中的钛和铪的原子百分比之和的比值在约 1.4和约2.2(即1.4 <(Nb + Ta):Ti + Hf)<2.2)。