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21. 发明授权

US4992400A Cracking catalyst for hydrocarbon charges comprising an offretite, a zeolite and a matrix 失效
标题翻译：用于烃装料的裂化催化剂包括异位素，沸石和基质
公开(公告)号：US4992400A
公开(公告)日：1991-02-12
申请号：US154258
申请日：1988-02-10
申请人： Christian Marcilly , Jean-Marie Deves , Francis Raatz
发明人： Christian Marcilly , Jean-Marie Deves , Francis Raatz
IPC分类号： B01J29/06 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/50 , B01J29/80 , C10G11/04 , C10G11/05
CPC分类号： C10G11/05 , B01J29/80 , B01J2229/16 , B01J2229/26 , B01J2229/42 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/50
摘要： The cracking catalyst of the invention contains:(a) 20-95% by weight of at least one matrix, selected from the group consisting of alumina, silica, magnesia, clay, titanium oxide, zirconia, combinations of at least two of these compounds and alumina-boron oxide combinations,(b) 1-60% by weight of at least one zeolite of open structure whose main dodecagonal channels have openings of at least 7 Angstroms, said zeolite of open structure being selected from the group formed of X, Y, L, omega and beta zeolites,(c) 0.5-60% by weight of at least one offretite whose main dodecagonal channels have openings smaller than 7 Angstroms and which have a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio from about 15 to about 500, the crystalline parameters a and c of elementary mesh ranging respectively from 1.285 to 1.315 nm for a and from 0.748 to 0.757 nm for c and have a potassium content lower than 1.5% by weight.
摘要翻译：本发明的裂化催化剂包含：（a）20-95重量％的至少一种选自氧化铝，二氧化硅，氧化镁，粘土，氧化钛，氧化锆，这些化合物中的至少两种的组合的基质和氧化铝 - 氧化硼组合，（b）1-60重量％的至少一种开口结构的沸石，其主要十二边形通道具有至少7埃的开口，所述开放结构的沸石选自由X， Y，L，ω和β沸石，（c）0.5-60％重量的至少一种其主要十二边形通道的开口小于7埃，并且具有约15至约500的SiO 2 / Al 2 O 3摩尔比，基本网格的结晶参数a和c分别为1.85〜1.315nm，c为0.748〜0.757nm，钾含量低于1.5重量％。

22. 发明授权

US07160436B2 Method for two-step hydrocracking of hydrocarbon feedstocks 有权
标题翻译：碳氢化合物原料两步加氢裂化方法
公开(公告)号：US07160436B2
公开(公告)日：2007-01-09
申请号：US10343218
申请日：2001-07-26
申请人： Eric Benazzi , Jean-Marie Deves , Pierre Marion , Christophe Gueret , Alain Billon , Patrick Bourges
发明人： Eric Benazzi , Jean-Marie Deves , Pierre Marion , Christophe Gueret , Alain Billon , Patrick Bourges
IPC分类号： C10G65/12 , C10G37/02
CPC分类号： C10G47/20 , C10G65/12 , C10G2300/207 , C10G2300/301 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： An improved hydrocracking process of hydrocarbon charges, in two stages with an intermediate separation, in which the second-stage of hydrocracking is carried out in the presence of an added nitrogen content which is greater than 150 ppm by weight, preferably about 500 ppm by weight, and preferably in the presence of a Y zeolite catalyst, produces high yields of middle distillate.
摘要翻译：改进的烃电荷的加氢裂化方法，分两个阶段进行中间分离，其中第二阶段的加氢裂化在加入的氮含量大于150重量ppm，优选约500重量ppm的条件下进行，并且优选在Y沸石催化剂的存在下，产生高产率的中间馏分。

23. 发明授权

US06558625B1 Distribution device for automatic catalyst evaluation multi-reactors 有权
标题翻译：自动催化剂评估多反应器配电装置
公开(公告)号：US06558625B1
公开(公告)日：2003-05-06
申请号：US09604732
申请日：2000-06-28
申请人： Jean-Marie Deves , Jean-Yves Bernhard , Bernard Chatelain , Pierre Toutant , José Brandely , Corinne Guitton
发明人： Jean-Marie Deves , Jean-Yves Bernhard , Bernard Chatelain , Pierre Toutant , José Brandely , Corinne Guitton
IPC分类号： G01N3112
CPC分类号： G01N31/10 , B01J4/008 , B01J2219/00351 , B01J2219/00409 , B01J2219/00585 , B01J2219/00686 , B01J2219/00704 , B01J2219/00745 , B01J2219/0075 , C40B40/18 , G01N1/26
摘要： The present invention relates to a distribution device intended for a gaseous effluent produced by a chemical reaction, comprising at least two inlet ways and two outlet ways. This device comprises at least one closed-loop line divided into four sections by four controlled sealing elements, and each one of said four ways communicates with a single section so that the inlet ways are connected to two opposite sections and said outlet ways are connected to the other two sections.
摘要翻译：本发明涉及一种用于通过化学反应产生的气态流出物的分配装置，其包括至少两个入口通道和两个出口通道。该装置包括由四个受控的密封元件分成四个部分的至少一个闭环线，并且所述四个方向中的每一个与单个部分连通，使得入口通路连接到两个相对的部分，并且所述出口连接到另外两个部分。

24. 发明授权

US5968345A Process for the catalytic conversion of hydrocarbons into aromatic compounds using a catalyst containing alkali of alkaline-earth metals 失效
标题翻译：使用含有碱土金属碱的催化剂将烃催化转化成芳族化合物的方法
公开(公告)号：US5968345A
公开(公告)日：1999-10-19
申请号：US973406
申请日：1997-12-15
申请人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
发明人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
IPC分类号： B01J23/62 , B01J21/04 , B01J23/56 , B01J23/58 , B01J23/64 , B01J23/644 , B01J23/652 , B01J23/656 , B01J27/08 , B01J27/13 , C10G35/085 , C10G35/09
CPC分类号： B01J21/04 , B01J23/56 , B01J23/58 , B01J23/6567 , C10G35/085 , B01J23/62 , B01J23/6445 , B01J23/652 , B01J23/656 , B01J27/13
摘要： A process for the conversion of a hydrocarbon load containing paraffin, naphthene and aromatic hydrocarbons having 5 to 12 carbon atoms into aromatic compounds, which entails contacting the load with a catalyst under temperature and pressure conditions to produce the aromatic compounds, the catalyst containing:a matrix consisting of 0 to 100% by weight of .eta. transition alumina, the remaining weight percentage of the matrix, up to 100%, consisting of .gamma. transition alumina, andat least one doping metal selected from the group consisting of alkali metals and alkaline-earth metals,at least one halogen selected from the group consisting of fluorine, chlorine, bromine and iodine,at least one noble metal selected from the platinum group, andat least one promoter metal selected from the group consisting of tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese chromium, molybdenum and tungsten,the catalyst having previously been hydrothermally treated at a temperature of 300 to 1,000.degree. C. in a gaseous atmosphere containing steam, the atmosphere also containing chlorine in a molar content of greater than 0 but no more than 20%.
摘要翻译： PCT No.PCT / FR96 / 00915 Sec。 371 1997年12月15日第 102（e）日期1997年12月15日PCT Filted 1996年6月14日PCT公布。公开号WO97 / 00303 日本1997年1月3日将含有碳原子数为5〜12的烷烃，环烷烃和芳烃的烃负荷转化成芳香族化合物的方法，其需要使负载与催化剂在温度和压力条件下接触以产生芳族化合物，所述催化剂包含：由0-100重量％的η转变氧化铝组成的基体，所述基体的剩余重量百分比，至多100％，由γ转变氧化铝组成，以及至少一种掺杂金属，其选自碱金属和碱土金属，选自氟，氯，溴和碘的至少一种卤素，选自铂族的至少一种贵金属和选自锡的至少一种助催化剂金属，锗，铟，镓，铊，锑，铅，铼，锰铬，钼和钨，催化剂先前已被水热在含有蒸汽的气体气氛中，在300〜1000℃的温度下处理，气氛中还含有摩尔含量大于0但不大于20％的氯。

25. 发明授权

US5922639A Catalysts for use in hydrocarbon conversion reactions and containing one doping metal chosen from the group consisting of titanium, zirconium, hafnium, cobalt, nickel, zinc, the lanthanides and alkali and alkaline-earth metals 失效
标题翻译：用于烃转化反应并含有选自钛，锆，铪，钴，镍，锌，镧系元素和碱金属和碱土金属的一种掺杂金属的催化剂
公开(公告)号：US5922639A
公开(公告)日：1999-07-13
申请号：US973403
申请日：1997-12-15
申请人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
发明人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
IPC分类号： B01J23/56 , B01J23/58 , B01J23/63 , B01J27/13 , B01J27/138 , B01J37/02 , C10G35/09 , B01J27/06 , B01J27/125 , B01J27/135
CPC分类号： C10G35/09 , B01J23/56 , B01J23/58 , B01J23/63 , B01J27/13
摘要： The present invention relates to a catalyst comprising :a matrix consisting of a mixture of .eta. transition alumina, .gamma. transition alumina, andat least one doping metal chosen from the group made up of titanium, zirconium, hafnium, cobalt, nickel, zinc, the lanthanides, the alkali metals and alkaline-earth metals,at least one halogen chosen from the group made up of fluorine, chlorine, bromine and iodine,at least one noble metal from the platinum group, andat least one promoter metal chosen from the group made up of tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenum and tungsten.
摘要翻译： PCT No.PCT / FR96 / 00916 Sec。 371 1997年12月15日第 102（e）日期1997年12月15日PCT Filted 1996年6月14日PCT公布。公开号WO97 / 00304 日本1997年1月3日本发明涉及一种催化剂，其包含：由等离子体氧化铝，γ过渡氧化铝和至少一种掺杂金属的混合物组成的基体，所述掺杂金属选自钛，锆，铪，钴，镍，锌，镧系元素，碱金属和碱土金属，选自氟，氯，溴和碘的至少一种卤素，至少一种来自铂族的贵金属，以及至少一种助催化剂选自由锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼和钨组成的组中的金属。

26. 发明授权

US5171556A Beta type zeolite and its preparation process 失效
标题翻译： β型沸石及其制备方法
公开(公告)号：US5171556A
公开(公告)日：1992-12-15
申请号：US743967
申请日：1991-08-12
申请人： Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Francis Raatz , Jean-Francois Joly , Jean-Marie Deves
发明人： Philippe Caullet , Jean-Louis Guth , Anne-Catherine Faust , Francis Raatz , Jean-Francois Joly , Jean-Marie Deves
IPC分类号： B01J29/70 , C01B39/48
CPC分类号： B01J29/7007 , C01B39/48 , B01J2229/26 , B01J2229/42
摘要： The object of the invention is a synthetic crystalline zeolite of the beta type characterized by:a) the following approximate general formula:M.sub.2/n O, Al.sub.2 O.sub.3, xSiO.sub.2where M represents a proton and/or a metallic cationn is the valence of Mx is a number ranging from 5 to 800,b) an X-ray diffraction diagram represented in table I of the description, andc) a fluorine content ranging from about 0.005 to 2.0% by weight, said zeolite having been furthermore synthetized in a fluoride medium.
摘要翻译：本发明的目的是一种β型合成结晶沸石，其特征在于：a）以下近似通式：M 2 / nO，Al 2 O 3，xSiO 2，其中M表示质子和/或金属阳离子n是M x的化合价是5〜800的数，b）说明书的表I所示的X射线衍射图，c）氟含量为0.005〜2.0重量％左右，所述沸石进一步在氟化物中合成中。

27. 发明授权

US5008000A Cracking catalyst for hydrocarbon charges comprising an offretite, a zeolite and a matrix 失效
标题翻译：用于烃装料的裂化催化剂包括异位素，沸石和基质
公开(公告)号：US5008000A
公开(公告)日：1991-04-16
申请号：US493601
申请日：1990-03-15
申请人： Christian Marcilly , Jean-Marie Deves , Francis Raatz
发明人： Christian Marcilly , Jean-Marie Deves , Francis Raatz
IPC分类号： B01J29/06 , B01J29/08 , B01J29/18 , B01J29/40 , B01J29/50 , B01J29/80 , C10G11/04 , C10G11/05
CPC分类号： C10G11/05 , B01J29/80 , B01J2229/16 , B01J2229/26 , B01J2229/42 , B01J29/084 , B01J29/18 , B01J29/40 , B01J29/50
摘要： The cracking catalyst of the invention contains:(a) 20-95% by weight of at least one matrix, selected from the group consisting of alumina, silica, magnesia, clay, titanium oxide, zirconia, combinations of at least two of these compounds and alumina-boron oxide combinations,(b) 1-60% by weight of at least one zeolite of open structure whose main dodecagonal channels have openings of at least 7 Angstroms, said zeolite of open structure being selected from the group formed of X, Y, L, omega and beta zeolites,(c) 0.5-60% by weight of at least one offretite whose main dodecagonal channels have openings smaller than 7 Angstroms and which have a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio from about 15 to about 500, the crystalline paramaters a and c of elementary mesh ranging respectively from 1.285 to 1.315 nm for a and from 0.748 to 0.757 nm for c and have a potassium content lower than 1.5% by weight.

28. 发明授权

US4923593A Cracking catalyst and catalytic cracking process 失效
标题翻译：裂化催化剂和催化裂化过程
公开(公告)号：US4923593A
公开(公告)日：1990-05-08
申请号：US299167
申请日：1989-01-19
申请人： Christian Marcilly , Jean-Marie Deves , Michel Bourgogne
发明人： Christian Marcilly , Jean-Marie Deves , Michel Bourgogne
IPC分类号： B01J29/50 , B01J29/70 , B01J29/80 , C10G11/05 , C10G11/18
CPC分类号： B01J29/80 , B01J29/50 , C10G11/05 , C10G11/18 , B01J29/70
摘要： The invention concerns a fluidized bed cracking process of a hydrocarbon charge, carried out in an extended, appreciably tubular and vertical reaction zone (1), the catalyst being introduced at the lower end of this extended zone by a piper (2), and the charge being introduced by at least one pipe (3) opening into the reaction zone at a level higher than the level at which the catalyst is admitted.The invention wherein, for example, part of the gasoline or part (3a) to an intermediate point between the catalyst and charge entry points, and wherein a specially adapted catalyst is used for this operating procedure. The invention also concerns the catalyst used in this way, a zeolite-based catalyst of the erionite family.
摘要翻译：本发明涉及在延伸的，明显管状和垂直的反应区（1）中进行的烃装料的流化床裂解过程，催化剂通过吹塑（2）在该延伸区的下端引入，电荷通过至少一个开口进入反应区的管（3）引入，其高于催化剂进入的水平。本发明其中例如汽油或部分（3a）到催化剂和进料点之间的中间点，并且其中特别适用的催化剂用于该操作过程。本发明还涉及以这种方式使用的催化剂，即一种基于沸石的催化剂。

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