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21. 发明授权

US4846994A Use of graft polymers based on polyalkylene oxides as grayness inhibitors in the wash and aftertreatment of textile material containing synthetic fibers 失效
标题翻译：在含有合成纤维的纺织材料的洗涤和后处理中使用基于聚环氧烷作为灰色抑制剂的接枝聚合物
公开(公告)号：US4846994A
公开(公告)日：1989-07-11
申请号：US175175
申请日：1988-03-31
申请人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
发明人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
IPC分类号： C08F283/10 , C11D3/00 , C11D3/37 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/224 , D06M15/53
CPC分类号： C11D3/3788 , C08F283/10 , C11D3/0036
摘要： A detergent containing as grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers graft polymers obtainable by grafting(a) polyalkylene oxides which have a number average molecular weight of from 300 to 100,000 and are based on ethylene oxide, propylene oxide and/or butylene oxide, with(b) at least one vinyl ester derived from a saturated monocarboxylic acid containing 3 to 6 carbon atoms, a methyl or ethyl ester of (meth)acrylic acid and optionally mixtures of at least one of the monomers mentioned and up to 95% by weight of vinyl acetate in a weight ratio (a):(b) of from 1:02 to 1:10.
摘要翻译：在含有合成纤维的纺织材料的洗涤和后处理中含有灰色抑制剂的洗涤剂，其可通过接枝（a）数均分子量为300至100,000的聚环氧烷并且基于环氧乙烷，环氧丙烷和/ 或环氧丁烷与（b）至少一种衍生自含有3-6个碳原子的饱和一元羧酸的乙烯基酯，（甲基）丙烯酸的甲酯或乙酯和至少一种所提及的单体的混合物至95重量％的重量比（a）：（b）为1:02至1:10的乙酸乙烯酯。

22. 发明授权

US4725655A Preparation of copolymers of monoethylenically unsaturated mono- and dicarboxylic acids and anhydrides 失效
公开(公告)号：US4725655A
公开(公告)日：1988-02-16
申请号：US919583
申请日：1986-10-16
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C08F2/00 , C08F2/10 , C08F8/00 , C08F8/12 , C08F8/44 , C08F20/00 , C08F20/02 , C08F120/04 , C08F220/04 , C08F222/02 , C08F220/06 , C08F222/04
CPC分类号： C08F220/04 , C08F222/02
摘要： Copolymers which contain, as copolymerized monomer units, monoethylenically unsaturated mono- and dicarboxylic acids are prepared by a process in which(a) from 10 to 60% by weight of a monoethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms, its salt and/or, if appropriate, its anhydride,(b) from 90 to 40% by weight of a monothylenically unsaturated monocarboxylic acid of 3 to 10 carbon atoms and/or its salt and(c) from 0 to 20% by weight of another, carboxyl-free monoethylenically unsaturated monomer which is copolymerizable with (a) and (b),the percentages being based on the sum of the monomers, are polymerized in the presence of from 0.5 to 5% by weight of a water-soluble free-radical-forming initiator in an aqueous medium at from 60.degree. to 150.degree. C., and, if appropriate, their anhydride groups are hydrolyzed, the monomers (a) and (b) being employed in a form such that from 20 to 80% of their amount is neutralized during the polymerization reaction, wherein the copolymerization is carried out continuously in a reactor cascade comprising several reactors, and an aqueous solution of a pre-prepared copolymer of (a), (b) and, if appropriate, (c) is initially introduced into all the reactors and heated to the required reaction temperature, the total amount of unneutralized or partially neutralized (a), not less than 40% by weight of unneutralized or partially neutralized (b), where relevant, all or some of (c), and some or all of the amount of initiator required for polymerization, with or without the amount of neutralizing agent required for the neutralization according to the definition, are metered into the first reactor, the remaining amount of unneutralized or neutralized (b) and, where relevant, (c), and any remaining amount of initiator and neutralizing agent which may be required are introduced into the second reactor or are distributed over the second reactor and the downstream reactors, and the reactants are allowed to react together during a residence time of from 0.5 to 8 hours. The above copolymers can be used as incrustation inhibitors or for scaling inhibition.

23. 发明授权

US4914167A Polymeric organic acids, their preparation and their use in detergents and cleansers 失效
标题翻译：聚合有机酸，它们的制备及其在洗涤剂和清洁剂中的应用
公开(公告)号：US4914167A
公开(公告)日：1990-04-03
申请号：US752013
申请日：1985-07-08
申请人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
发明人： Juergen Hambrecht , Heinrich Hartmann , Walter Denzinger , Albert Hettche , Wolfgang Trieselt , Rolf Schneider
IPC分类号： C08F2/02 , C08F220/04 , C11D3/37
CPC分类号： C11D3/3761 , C08F220/04
摘要： Organic polyacids are prepared from monomeric monofunctional acids, such as acrylic acid or methacrylic acid and monomers without an acid group, with or without dicarboxylic acids or their anhydrides, by continuous free radical mass copolymerization under superatmospheric pressure at from 200.degree. to 400.degree. C., followed, if desired, by neutralization of the polyacids obtained. The polyacids obtained by the novel process are useful as phosphate substitutes and scale inhibitors in detergents and cleansers.
摘要翻译：有机多元酸通过在200-400℃的超大气压下连续自由基基团共聚，由单体单官能酸例如丙烯酸或甲基丙烯酸和无酸基的单体制备，含或不含二羧酸或其酸酐。，如果需要，通过中和获得的多元酸。通过该方法获得的多酸可用作洗涤剂和清洁剂中的磷酸盐替代物和防垢剂。

24. 发明授权

US4849126A Use of graft polymers based on polyesters, polyester urethanes and polyester amides as grayness inhibitors in detergents 失效
标题翻译：使用基于聚酯，聚酯氨酯和聚酯酰胺的接枝聚合物作为洗涤剂中的灰色抑制剂
公开(公告)号：US4849126A
公开(公告)日：1989-07-18
申请号：US179414
申请日：1988-04-08
申请人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
发明人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
IPC分类号： C08F283/00 , C08F283/02 , C08F283/04 , C11D3/00 , C11D3/37 , D06M15/507 , D06M15/59
CPC分类号： C11D3/0036 , C08F283/006 , C08F283/02 , C08F283/04 , C11D3/3788
摘要： Detergents contain graft polymers obtainable by grafting(a) polycondensates based on polyesters, polyester urethanes and polyester amides and having in each case a number average molecular weight from 500 to 100,000 with(b) from 0.2 to 10 parts by weight, based on 1 part by weight of the polycondensates, of vinyl esters of saturated C.sub.1 - to C.sub.6 -carboxylic acids, acrylic and/or methacrylic esters of saturated monohydric alcohols containing 1 to 4 carbon atoms.
摘要翻译：洗涤剂含有可通过接枝（a）基于聚酯，聚酯氨酯和聚酯酰胺的缩聚物而获得的接枝聚合物，并且在每种情况下其数均分子量为500至100,000，（b）为0.2至10重量份，基于1份的缩聚物，饱和C 1 -C 6羧酸的乙烯基酯，含有1至4个碳原子的饱和一元醇的丙烯酸和/或甲基丙烯酸酯。

25. 发明授权

US4746456A Detergents containing graft copolymers of polyalkylene oxides and vinyl acetate as antiredeposition inhibitors 失效
标题翻译：含有聚环氧烷和乙酸乙烯酯的接枝共聚物的洗涤剂作为抗再沉积抑制剂
公开(公告)号：US4746456A
公开(公告)日：1988-05-24
申请号：US914267
申请日：1986-10-02
申请人： Alexander Kud , Guenther Schulz , Wolfgang Trieselt , Heinrich Hartmann
发明人： Alexander Kud , Guenther Schulz , Wolfgang Trieselt , Heinrich Hartmann
IPC分类号： D06L1/12 , C11D3/00 , C11D3/37 , D06M13/02 , D06M13/224 , D06M15/53 , D06M101/00 , D06M101/16
CPC分类号： C11D3/3788 , C11D3/0036
摘要： Detergents contain added graft copolymers which have an antiredeposition action and are obtainable by grafting polyalkylene oxides having a number average molecular weight of from 2000 to 100,000 with vinyl acetate in a weight ratio of from 1:0.2 to 1:10, and up to 15% of whose acetate groups may be hydrolyzed.
摘要翻译：洗涤剂含有添加的接枝共聚物，其具有抗再沉积作用，可通过用乙酸乙烯酯以1:0.2至1:10的重量比和至多15重量％的重量比接枝数均分子量为2000至100,000的聚环氧烷，其乙酸酯基团可被水解。

26. 发明授权

US4702858A Washing agents containing, as additives, carboxyl-containing copolymers which are neutralized or amidated with amines 失效
标题翻译：作为添加剂含有用胺中和或酰胺化的含羧基共聚物的洗涤剂
公开(公告)号：US4702858A
公开(公告)日：1987-10-27
申请号：US888957
申请日：1986-07-24
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Erhard Klahr , Albert Hettche
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Erhard Klahr , Albert Hettche
IPC分类号： C08F8/32 , C08F8/44 , C11D3/37
CPC分类号： C11D3/3761 , C11D3/3769
摘要： Washing agents contain, as additives for inhibiting redeposition and promoting the primary washing action, homopolymers of acrylic acid and of methacrylic acid, copolymers of acrylic acid and methacrylic acid and copolymers which contain, as essential components,(a) an ethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms and(b) acrylic acid, methacrylic acid and/or hydroxy-C.sub.2 -C.sub.6 -alkyl esters of ethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units,where the homo- and copolymers in the form of the free acids have a weight average molecular weight of from 5000 to 500,000 in the neutralized or amidated form, the carboxyl groups of the homo- and copolymers in each case being partially or completely neutralized with amines of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl or R.sup.1 --O--CH.sub.2 --(CH.sub.2).sub.n --, n is from 1 to 3, R.sup.1 is C.sub.1 -C.sub.18 -alkyl, R.sup.2 and R.sup.3 are each H or C.sub.1 -C.sub.18 -alkyl and/or from 5 to 50% of the said carboxyl groups being in the form of amides derived from primary and secondary amines of the formula I.
摘要翻译：洗涤剂含有作为抑制再沉积和促进初次洗涤作用的添加剂，丙烯酸和甲基丙烯酸的均聚物，丙烯酸和甲基丙烯酸的共聚物以及含有作为必要成分的（a）烯属不饱和二羧酸 4至6个碳原子，和（b）丙烯酸，甲基丙烯酸和/或烯属不饱和C 3 -C 6 - 羧酸的羟基-C 2 -C 6烷基酯作为共聚单元，其中以自由基形式存在的均聚物和共聚物酸的中和或酰胺化形式的重均分子量为5000至500,000，每种情况下的均聚物和共聚物的羧基用式“IMAGE”的胺部分或完全中和，其中R为C8-C18 - 烷基或R 1 -O-CH 2 - （CH 2）n - ，n为1至3，R 1为C 1 -C 18烷基，R 2和R 3各自为H或C 1 -C 18 - 烷基和/或5至50％的所述羧基为衍生自原料的酰胺形式芳胺和仲胺。

27. 发明授权

US4698174A Additives for detergents and cleaning agents 失效
标题翻译：洗涤剂和清洁剂的添加剂
公开(公告)号：US4698174A
公开(公告)日：1987-10-06
申请号：US822610
申请日：1986-01-27
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/33 , C11D3/3761
摘要： Pulverulent and/or granular additives for pulverulent detergents and cleaning agents, consisting of(a) from 80 to 20% by weight of one or more copolymers comprising from 40 to 90% by weight of (meth)acrylic acid and from 60 to 10% by weight of maleic acid and/or one or more copolymers comprising from 10 to 45% by weight of (meth)acrylic acid, from 10 to 45% by weight of maleic acid and from 10 to 60% by weight of one or more hydroxyalkyl (meth)acrylates where hydroxyalkyl is of 2 to 6 carbon atoms, if appropriate in the form of a partially or completely neutralized water-soluble salt,(b) from 20 to 80% by weight of nitrilotriacetic acid or its mono-, di- or trisodium or mono-, di- or tripotassium salt and(c) from 0 to 20% by weight of one or more additives conventionally used for detergent and cleaning agent formulations, the use of these pulverulent and/or granular mixtures as additives for pulverulent and/or granular detergents and cleaning agents, and processes for the preparation of the said additives.
摘要翻译：用于粉状洗涤剂和清洁剂的粉末和/或颗粒添加剂由（a）80至20重量％的一种或多种共聚物组成，所述共聚物包含40至90重量％的（甲基）丙烯酸和60至10重量％的马来酸和/或一种或多种共聚物，其包含10至45重量％的（甲基）丙烯酸，10至45重量％的马来酸和10至60重量％的一种或多种羟烷基（甲基）丙烯酸酯，其中羟基烷基为2至6个碳原子，如果合适的话以部分或完全中和的水溶性盐的形式，（b）20至80重量％的次氮基三乙酸或其单 - 或三钠或单，二或三钾盐和（c）0至20重量％的常规用于洗涤剂和清洁剂配方的一种或多种添加剂，使用这些粉状和/或颗粒状混合物作为粉末状添加剂和/或颗粒状洗涤剂和清洁剂，以及制备方法 n的所述添加剂。

28. 发明授权

US4444561A Copolymers which contain basic groups and are used as antiredeposition agents in washing and after-treating textile goods containing synthetic fibers 失效
标题翻译：含有碱性基团并用作洗涤和后处理含有合成纤维的纺织品的抗再沉积剂的共聚物
公开(公告)号：US4444561A
公开(公告)日：1984-04-24
申请号：US467443
申请日：1983-02-17
申请人： Walter Denzinger , Wolfgang Trieselt , Johannes Perner , Heinrich Hartmann
发明人： Walter Denzinger , Wolfgang Trieselt , Johannes Perner , Heinrich Hartmann
IPC分类号： D06M15/333 , C11D3/00 , C11D3/37 , D06L1/12 , D06M15/327 , D06M15/39 , D06M101/00 , D06M101/16 , B08B3/04
CPC分类号： C11D3/3776 , C11D3/0036
摘要： Textile goods containing synthetic fibers are washed and after-treated by a process wherein, as an antiredeposition agent, a copolymer is employed which contains, as copolymerized monomers,(a) from 50 to 90% by weight of one or more vinyl esters of C.sub.1 -C.sub.4 aliphatic carboxylic acids,(b) from 5 to 35% by weight of one or more N-vinyllactams,(c) from 1 to 20% by weight of one or more monomers containing basic groups, or of salts or quaternization products of these monomers, and(d) from 0 to 20% by weight of one or more further monomers which are copolymerizable with monomers (a), (b) and (c) and are free from carboxyl and basic groups,the percentages in each case being based on the sum of the monomers, with the proviso that the percentages sum to 100.
摘要翻译：含有合成纤维的纺织品通过以下方法洗涤和后处理：其中，作为抗再沉积剂，使用含共聚单体的共聚物，（a）50至90重量％的一种或多种C1的乙烯基酯 -C4脂族羧酸，（b）5-35重量％的一种或多种N-乙烯基内酰胺，（c）1-20％重量的一种或多种含有碱性基团的单体，或其盐或季铵化产物这些单体，和（d）0至20重量％的一种或多种可与单体（a），（b）和（c）共聚的其它单体，并且不含羧基和碱基，每种情况下的百分数基于单体的总和，条件是百分比等于100。

29. 发明授权

US4904408A Use of graft polymers based on polyalkylene oxides as grayness inhibitors in the wash and aftertreatment of textile material containing synthetic fibers 失效
标题翻译：在含有合成纤维的纺织材料的洗涤和后处理中使用基于聚环氧烷作为灰色抑制剂的接枝聚合物
公开(公告)号：US4904408A
公开(公告)日：1990-02-27
申请号：US176333
申请日：1988-03-31
申请人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
发明人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
IPC分类号： C11D3/00 , C11D3/37 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/224 , D06M13/322 , D06M13/35 , D06M13/352 , D06M15/53
CPC分类号： C11D3/3788 , C11D3/0036
摘要： A detergent contains as a grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers a graft polymer obtainable by grafting(a) a polyalkylene oxide which has a number average molecular weight of from 300 to 100,000 and is based on ethylene oxide, propylene oxide and/or butylene oxide with(b) N-vinlypyrrolidone and(c) a vinyl ester derived from a saturated monocarboxylic acid containing from 1 to 6 carbon atoms and/or a methyl or ethyl ester of acrylic or methacrylic acid in a weight ratio (a):(b):(c) of from 1:0.3:1 to 1:5:30, the order of the addition of (b) and (c) in the graft copolymerization being immaterial and it being possible for up to 1 mole % of the grafted-on monomers (c) to be hydrolyzed.
摘要翻译：洗涤剂在含有合成纤维的纺织材料的洗涤和后处理中含有灰色抑制剂，该接枝聚合物可通过接枝（a）数均分子量为300至100,000并基于环氧乙烷，丙烯的聚环氧烷氧化物和/或环氧丁烷与（b）N-乙烯吡咯烷酮和（c）衍生自含有1至6个碳原子的饱和一元羧酸和/或丙烯酸或甲基丙烯酸的甲酯或乙酯的乙烯基酯的重量比（a）：（b）：（c）为1:0.3:1至1:5:30，接枝共聚中加入（b）和（c）的顺序是无关紧要的，至1摩尔％的被水解的接枝单体（c）。

30. 发明授权

US4846995A Use of graft polymers based on polyalkylene oxides as grayness inhibitors in the wash and aftertreatment of textile material containing syntheic fibers 失效
标题翻译：在含有合成纤维的纺织材料的洗涤和后处理中使用基于聚环氧烷作为灰色抑制剂的接枝聚合物
公开(公告)号：US4846995A
公开(公告)日：1989-07-11
申请号：US175190
申请日：1988-03-31
申请人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
发明人： Alexander Kud , Wolfgang Trieselt , Heinrich Hartmann
IPC分类号： C11D3/00 , C11D3/37 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/224 , D06M15/53
CPC分类号： C11D3/0036 , C11D3/3788
摘要： A detergent containing as grayness inhibitor in the wash and aftertreatment of textile material containing synthetic fibers graft polymers obtainable by grafting(a) a polyalkylene oxide which has a number average molecular weight of from 300 to 100,000, is based on ethylene oxide, propylene oxide and/or butylene oxide, and is end group capped at at least one end, with(b) at least on vinyl ester derived from a saturated monocarboxylic acid containing 1 to 6 carbon atoms and/or a methyl or ethyl ester of acrylic or methacrylic acid in a weight ratio (a):(b) of from 1:0.2 to 1:10.
摘要翻译：在含有合成纤维的纺织材料的洗涤和后处理中含有灰色抑制剂的洗涤剂可通过接枝（a）数均分子量为300至100,000的聚环氧烷获得的接枝聚合物，其基于环氧乙烷，环氧丙烷和和/或环氧丁烷，并且在至少一个末端封端，并且（b）至少在衍生自含有1至6个碳原子的饱和一元羧酸的乙烯酯和/或丙烯酸或甲基丙烯酸的甲酯或乙酯重量比（a）：（b）为1:0.2至1:10。

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