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21. 发明申请

US20090045473A1 Devices having horizontally-disposed nanofabric articles and methods of making the same 有权
公开(公告)号：US20090045473A1
公开(公告)日：2009-02-19
申请号：US11999228
申请日：2007-12-04
申请人： Venkatachalam C. Jaiprakash , Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
发明人： Venkatachalam C. Jaiprakash , Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
IPC分类号： H01L29/84
CPC分类号： G11C13/025 , B81B2203/0338 , B81B2203/04 , B81C1/00142 , B81C2201/0109 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/22 , G11C11/56 , G11C23/00 , G11C2213/16 , G11C2213/77 , G11C2213/81 , H01H1/0094 , H01L21/76838 , H01L51/0048 , H01L2221/1094 , Y10S977/724 , Y10S977/734 , Y10S977/742
摘要： New devices having horizontally-disposed nanofabric articles and methods of making same are described. A discrete electro-mechanical device includes a structure having an electrically-conductive trace. A defined patch of nanotube fabric is disposed in spaced relation to the trace; and the defined patch of nanotube fabric is electromechanically deflectable between a first and second state. In the first state, the nanotube article is in spaced relation relative to the trace, and in the second state the nanotube article is in contact with the trace. A low resistance signal path is in electrical communication with the defined patch of nanofabric. Under certain embodiments, the structure includes a defined gap into which the electrically conductive trace is disposed. The defined gap has a defined width, and the defined patch of nanotube fabric spans the gap and has a longitudinal extent that is slightly longer than the defined width of the gap.

22. 发明授权

US08217490B2 Nonvolatile nanotube diodes and nonvolatile nanotube blocks and systems using same and methods of making same 有权
标题翻译：非挥发性纳米管二极管和非易失性纳米管块及使用其的系统及其制造方法
公开(公告)号：US08217490B2
公开(公告)日：2012-07-10
申请号：US11835856
申请日：2007-08-08
申请人： Claude L. Bertin , Thomas Rueckes , X. M. Henry Huang , Ramesh Sivarajan , Eliodor G. Ghenciu , Steven L. Konsek , Mitchell Meinhold , Jonathan W. Ward , Darren K. Brock
发明人： Claude L. Bertin , Thomas Rueckes , X. M. Henry Huang , Ramesh Sivarajan , Eliodor G. Ghenciu , Steven L. Konsek , Mitchell Meinhold , Jonathan W. Ward , Darren K. Brock
IPC分类号： G11C11/56 , G11C5/00 , H01L29/00
CPC分类号： H01L27/1021 , B82Y10/00 , G11C13/025 , G11C2213/19 , G11C2213/71 , G11C2213/72 , H01L21/8221 , H01L27/0688 , H01L27/1203 , Y10S977/943
摘要： Under one aspect, a non-volatile nanotube switch includes a first terminal; a nanotube block including a multilayer nanotube fabric, at least a portion of which is positioned over and in contact with at least a portion of the first terminal; a second terminal, at least a portion of which is positioned over and in contact with at least a portion of the nanotube block, wherein the nanotube block is constructed and arranged to prevent direct physical and electrical contact between the first and second terminals; and control circuitry capable of applying electrical stimulus to the first and second terminals. The nanotube block can switch between a plurality of electronic states in response to a plurality of electrical stimuli applied by the control circuitry to the first and second terminals. For each different electronic state, the nanotube block provides an electrical pathway of different resistance between the first and second terminals.
摘要翻译：在一个方面，非挥发性纳米管开关包括第一端子; 纳米管块，其包括多层纳米管织物，其至少一部分位于所述第一端子的至少一部分上方并与其接触; 第二端子，其至少一部分定位在所述纳米管块的至少一部分上方并与所述纳米管块的至少一部分接触，其中所述纳米管块被构造和布置成防止所述第一和第二端子之间的直接物理和电接触; 以及能够向第一和第二终端施加电刺激的控制电路。响应于由控制电路施加到第一和第二端子的多个电刺激，纳米管块可以在多个电子状态之间切换。对于每个不同的电子状态，纳米管块提供在第一和第二端子之间具有不同电阻的电路径。

23. 发明申请

US20100327247A1 METHOD AND SYSTEM OF USING NANOTUBE FABRICS AS JOULE HEATING ELEMENTS FOR MEMORIES AND OTHER APPLICATIONS 有权
标题翻译：使用纳米管织物作为记忆元件和其他应用的加热元件的方法和系统
公开(公告)号：US20100327247A1
公开(公告)日：2010-12-30
申请号：US12066053
申请日：2006-09-06
申请人： Jonathan W. Ward , Thomas Rueckes , Mitchell Meinhold , Brent M. Segal
发明人： Jonathan W. Ward , Thomas Rueckes , Mitchell Meinhold , Brent M. Segal
IPC分类号： H01L45/00 , H01L21/02 , H05B1/00
CPC分类号： H01L45/1286 , B82Y10/00 , G11C13/0004 , G11C13/025 , G11C2213/81 , H01L27/2436 , H01L45/06 , H01L45/1226 , H01L45/1233 , H01L45/144
摘要： Methods and systems of using nanotube elements as joule heating elements for memories and other applications. Under one aspect, a method includes providing an electrical stimulus, regulated by a drive circuit, through a nanotube element in order to heat an adjacent article. Further, a detection circuit electrically gauges the state of the article. The article heated by the nanotube element is, in preferred embodiments, a phase changing material, hi memory applications, the invention may be used as a small-scale CRAM capable of employing small amounts of current to induce rapid, large temperature changes in a chalcogenide material. Under various embodiments of the disclosed invention, the nanotube element is composed of a non-woven nanotube fabric which is either suspended from supports and positioned adjacent to the phase change material or is disposed on a substrate and in direct contact with the phase change material. A plurality of designs using various geometric orientations of nanotube fabrics, phase change materials, and drive and detection circuitry is disclosed. Additionally, methods of fabricating nanotube heat emitters are disclosed.
摘要翻译：使用纳米管元件作为焦耳加热元件用于存储器和其他应用的方法和系统。在一个方面，一种方法包括通过纳米管元件提供由驱动电路调节的电刺激，以加热邻近的物品。此外，检测电路电测量物品的状态。在优选实施例中，由纳米管元件加热的物品是相变材料。在记忆应用中，本发明可以用作能够使用少量电流以在硫族化物中快速，大的温度变化的小规模CRAM 材料。在所公开的发明的各种实施例中，纳米管元件由无纺布纳米管织物组成，该无纺布纳米管织物从支撑物悬挂并且邻近相变材料定位，或者设置在基底上并与相变材料直接接触。公开了使用纳米管织物，相变材料以及驱动和检测电路的各种几何取向的多个设计。另外，公开了制造纳米管热发射体的方法。

24. 发明授权

US08587989B2 NRAM arrays with nanotube blocks, nanotube traces, and nanotube planes and methods of making same 有权
标题翻译：具有纳米管块的NRAM阵列，纳米管迹线和纳米管平面及其制造方法
公开(公告)号：US08587989B2
公开(公告)日：2013-11-19
申请号：US12486602
申请日：2009-06-17
申请人： H. Montgomery Manning , Thomas Rueckes , Claude L. Bertin , Jonathan W. Ward , Garo Derderian
发明人： H. Montgomery Manning , Thomas Rueckes , Claude L. Bertin , Jonathan W. Ward , Garo Derderian
IPC分类号： G11C13/00
CPC分类号： G11C13/025 , B82Y10/00 , H01L27/2409 , H01L27/2436 , H01L27/2463 , H01L27/2472 , H01L45/04 , H01L45/1233 , H01L45/149 , H01L45/1675
摘要： NRAM arrays with nanotube blocks, traces and planes, and methods of making the same are disclosed. In some embodiments, a nanotube memory array includes a nanotube fabric layer disposed in electrical communication with first and second conductor layers. A memory operation circuit including a circuit for generating and applying a select signal on first and second conductor layers to induce a change in the resistance of the nanotube fabric layer between the first and second conductor layers is provided. At least two adjacent memory cells are formed in at least two selected cross sections of the nanotube fabric and conductor layers such that each memory cell is uniquely addressable and programmable. For each cell, a change in resistance corresponds to a change in an informational state of the memory cell. Some embodiments include bit lines, word lines, and reference lines. In some embodiments, 6F2 memory cell density is achieved.
摘要翻译：公开了具有纳米管块，轨迹和平面的NRAM阵列及其制造方法。在一些实施例中，纳米管存储器阵列包括布置成与第一和第二导体层电连通的纳米管织物层。一种存储器操作电路，包括用于在第一和第二导体层上产生和施加选择信号以引起第一和第二导体层之间的纳米管织物层的电阻变化的电路。至少两个相邻的存储单元形成在纳米管织物和导体层的至少两个选定的横截面中，使得每个存储单元是唯一可寻址和可编程的。对于每个单元，电阻变化对应于存储单元的信息状态的变化。一些实施例包括位线，字线和参考线。在一些实施例中，实现6F2存储单元密度。

25. 发明申请

US20100051880A1 AQUEOUS CARBON NANOTUBE APPLICATOR LIQUIDS AND METHODS FOR PRODUCING APPLICATOR LIQUIDS THEREOF 有权
标题翻译：水性碳纳米管应用液体及其生产应用液体的方法
公开(公告)号：US20100051880A1
公开(公告)日：2010-03-04
申请号：US12612445
申请日：2009-11-04
申请人： Eliodor G. Ghenciu , Tzong-Ru T. Han , Ramesh SIVARAJAN , Thomas Rueckes , Rahul Sen , Brent M. Segal , Jonathan W. Ward
发明人： Eliodor G. Ghenciu , Tzong-Ru T. Han , Ramesh SIVARAJAN , Thomas Rueckes , Rahul Sen , Brent M. Segal , Jonathan W. Ward
IPC分类号： H01B1/04
CPC分类号： D06M11/64 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/17 , C01B2202/02 , C01B2202/28 , D06M10/02 , D06M11/50 , D06M11/55 , D06M2101/40 , H01L51/0003 , H01L51/0048 , Y10S977/746 , Y10S977/845
摘要： Certain applicator liquids and method of making the applicator liquids are described. The applicator liquids can be used to form nanotube films or fabrics of controlled properties. An applicator liquid for preparation of a nanotube film or fabric includes a controlled concentration of nanotubes dispersed in a liquid medium containing water. The controlled concentration is sufficient to form a nanotube fabric or film of preselected density and uniformity.
摘要翻译：描述了一些施用液体和制备涂抹液的方法。施用液体可用于形成具有受控特性的纳米管膜或织物。用于制备纳米管膜或织物的涂布液包括分散在含水液体介质中的受控浓度的纳米管。受控浓度足以形成预选密度和均匀性的纳米管织物或薄膜。

26. 发明授权

US07566478B2 Methods of making carbon nanotube films, layers, fabrics, ribbons, elements and articles 有权
标题翻译：制作碳纳米管薄膜，层，织物，丝带，元件和制品的方法
公开(公告)号：US07566478B2
公开(公告)日：2009-07-28
申请号：US10341005
申请日：2003-01-13
申请人： Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
发明人： Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
IPC分类号： C23C16/26 , B05D5/12 , B05D3/00
CPC分类号： B82Y40/00 , B82Y10/00 , B82Y30/00 , C01B32/162 , C01B2202/02 , C01B2202/22 , G11C13/025 , G11C23/00 , G11C2213/16 , G11C2213/81 , H01L21/76838 , H01L2221/1094 , Y10S977/843
摘要： Methods of Making Carbon Nanotube Films, Layers, Fabrics, Ribbons, Elements and Articles are disclosed. Carbon nanotube growth catalyst is applied on to a surface of a substrate. The substrate is subjected to a chemical vapor deposition of a carbon-containing gas to grow a non-woven fabric of carbon nanotubes. Portions of the non-woven fabric are selectively removed according to a defined pattern to create the article. A non-woven fabric of carbon nanotubes may be made by applying carbon nanotube growth catalyst on to a surface of a wafer substrate to create a dispersed monolayer of catalyst. The substrate is subjected to a chemical vapor deposition of a carbon-containing gas to grow a non-woven fabric of carbon nanotubes in contact and covering the surface of the wafer and in which the fabric is substantially uniform density.
摘要翻译：公开了制备碳纳米管薄膜，层，织物，丝带，元件和制品的方法。将碳纳米管生长催化剂施加到基材的表面上。对基板进行化学气相沉积的含碳气体以生长碳纳米管的无纺织物。根据限定的图案选择性地去除无纺织物的部分以产生制品。碳纳米管的无纺布可以通过将碳纳米管生长催化剂涂覆在晶片基板的表面上来制造催化剂的分散单层。对基板进行化学气相沉积的含碳气体，使碳纳米管的无纺织物接触并覆盖晶片的表面，其中织物的密度基本上均匀。

27. 发明授权

US07560136B2 Methods of using thin metal layers to make carbon nanotube films, layers, fabrics, ribbons, elements and articles 有权
标题翻译：使用薄金属层制造碳纳米管薄膜，层，织物，丝带，元件和制品的方法
公开(公告)号：US07560136B2
公开(公告)日：2009-07-14
申请号：US10341055
申请日：2003-01-13
申请人： Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
发明人： Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
IPC分类号： C23C16/22 , C23C16/00
CPC分类号： H01L21/3146 , B82Y10/00 , H01L29/43 , Y10S977/742 , Y10S977/75 , Y10S977/751
摘要： Methods of using thin metal layers to make Carbon Nanotube Films, Layers, Fabrics, Ribbons, Elements and Articles are disclosed. Carbon nanotube growth catalyst is applied on to a surface of a substrate, including one or more thin layers of metal. The substrate is subjected to a chemical vapor deposition of a carbon-containing gas to grow a non-woven fabric of carbon nanotubes. Portions of the non-woven fabric are selectively removed according to a defined pattern to create the article. A non-woven fabric of carbon nanotubes may be made by applying carbon nanotube growth catalyst on to a surface of a wafer substrate to create a dispersed monolayer of catalyst. The substrate is subjected to a chemical vapor deposition of a carbon-containing gas to grow a non-woven fabric of carbon nanotubes in contact and covering the surface of the wafer and in which the fabric is substantially uniform density.
摘要翻译：公开了使用薄金属层制造碳纳米管薄膜，层，织物，丝带，元件和制品的方法。将碳纳米管生长催化剂施加到基材的表面，包括一层或多层薄金属层。对基板进行化学气相沉积的含碳气体以生长碳纳米管的无纺织物。根据限定的图案选择性地去除无纺织物的部分以产生制品。碳纳米管的无纺布可以通过将碳纳米管生长催化剂涂覆在晶片基板的表面上来制造催化剂的分散单层。对基板进行化学气相沉积的含碳气体，使碳纳米管的无纺织物接触并覆盖晶片的表面，其中织物的密度基本上均匀。

28. 发明授权

US07335395B2 Methods of using pre-formed nanotubes to make carbon nanotube films, layers, fabrics, ribbons, elements and articles 有权
标题翻译：使用预制纳米管制造碳纳米管薄膜，层，织物，丝带，元件和制品的方法
公开(公告)号：US07335395B2
公开(公告)日：2008-02-26
申请号：US10341054
申请日：2003-01-13
申请人： Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
发明人： Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
IPC分类号： B05D3/12
CPC分类号： B05D1/002 , B05D3/0254 , B82Y30/00 , C23C16/0281 , C23C16/26 , D04H1/4234 , D04H1/4242 , D04H1/4382 , D04H1/4391
摘要： Methods of Using Preformed Nanotubes to Make Carbon Nanotube Films, Layers, Fabrics, Ribbons, Elements and Articles are disclosed. To make various articles, certain embodiments provide a substrate. Preformed nanotubes are applied to a surface of the substrate to create a non-woven fabric of carbon nanotubes. Portions of the non-woven fabric are selectively removed according to a defined pattern to create the article. To make a nanofabric, a substrate is provided. Preformed nanotubes are applied to a surface of the substrate to create a non-woven fabric of carbon nanotubes wherein the non-woven fabric is substantially uniform density.
摘要翻译：公开了使用预制纳米管制备碳纳米管膜，层，织物，丝带，元件和制品的方法。为了制造各种制品，某些实施方案提供了基材。将预制的纳米管施加到基底的表面以产生碳纳米管的无纺织物。根据限定的图案选择性地去除无纺织物的部分以产生制品。为了制造纳米纤维，提供了基材。将预制的纳米管施加到基底的表面以产生碳纳米管的无纺织物，其中无纺织物具有基本均匀的密度。

29. 发明授权

US07304357B2 Devices having horizontally-disposed nanofabric articles and methods of making the same 有权
标题翻译：具有水平布置的纳米制品的装置及其制造方法
公开(公告)号：US07304357B2
公开(公告)日：2007-12-04
申请号：US11193795
申请日：2005-07-29
申请人： Venkatachalam C. Jaiprakash , Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
发明人： Venkatachalam C. Jaiprakash , Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
IPC分类号： H01L29/84
CPC分类号： G11C13/025 , B81B2203/0338 , B81B2203/04 , B81C1/00142 , B81C2201/0109 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/22 , G11C11/56 , G11C23/00 , G11C2213/16 , G11C2213/77 , G11C2213/81 , H01H1/0094 , H01L21/76838 , H01L51/0048 , H01L2221/1094 , Y10S977/724 , Y10S977/734 , Y10S977/742
摘要： New devices having horizontally-disposed nanofabric articles and methods of making same are described. A discrete electro-mechanical device includes a structure having an electrically-conductive trace. A defined patch of nanotube fabric is disposed in spaced relation to the trace; and the defined patch of nanotube fabric is electromechanically deflectable between a first and second state. In the first state, the nanotube article is in spaced relation relative to the trace, and in the second state the nanotube article is in contact with the trace. A low resistance signal path is in electrical communication with the defined patch of nanofabric. Under certain embodiments, the structure includes a defined gap into which the electrically conductive trace is disposed. The defined gap has a defined width, and the defined patch of nanotube fabric spans the gap and has a longitudinal extent that is slightly longer than the defined width of the gap. Under certain embodiments, a clamp is disposed at each of two ends of the nanotube fabric segment and disposed over at least a portion of the nanotube fabric segment substantially at the edges defining the gap. Under certain embodiments, the clamp is made of electrically-conductive material. Under certain embodiments, the contact between the nanotube patch and the trace is a non-volatile state. Under certain embodiments, the contact between the nanotube patch and the trace is a volatile state. Under certain embodiments, the at least one electrically conductive trace has an interface material to alter the attractive force between the nanotube fabric segment and the electrically conductive trace.
摘要翻译：描述了具有水平布置的纳米制品的新器件及其制造方法。分立的机电装置包括具有导电迹线的结构。定义的纳米管织物贴片与痕迹间隔开设置; 并且所述限定的纳米管织物片在第一和第二状态之间是机电偏转的。在第一状态下，纳米管制品相对于迹线具有间隔的关系，并且在第二状态下，纳米管制品与痕迹接触。低电阻信号路径与所定义的纳米片段电连通。在某些实施例中，该结构包括限定的导电迹线设置的间隙。限定的间隙具有限定的宽度，并且限定的纳米管织物片段跨过间隙并且具有比限定的间隙宽度稍长的纵向范围。在某些实施例中，夹具设置在纳米管织物片段的两端中的每一个处，并且在纳米管织物片段的至少一部分上大致位于限定间隙的边缘处。在某些实施例中，夹具由导电材料制成。在某些实施方案中，纳米管贴片和迹线之间的接触是非挥发性状态。在某些实施方案中，纳米管贴片和迹线之间的接触是挥发性状态。在某些实施例中，至少一个导电迹线具有界面材料，以改变纳米管织物片段和导电迹线之间的吸引力。

30. 发明授权

US07259410B2 Devices having horizontally-disposed nanofabric articles and methods of making the same 有权
标题翻译：具有水平布置的纳米制品的装置及其制造方法
公开(公告)号：US07259410B2
公开(公告)日：2007-08-21
申请号：US10776059
申请日：2004-02-11
申请人： Venkatachalam C. Jaiprakash , Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
发明人： Venkatachalam C. Jaiprakash , Jonathan W. Ward , Thomas Rueckes , Brent M. Segal
IPC分类号： H01L27/10
CPC分类号： G11C13/025 , B81B2203/0338 , B81B2203/04 , B81C1/00142 , B81C2201/0109 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/22 , G11C11/56 , G11C23/00 , G11C2213/16 , G11C2213/77 , G11C2213/81 , H01H1/0094 , H01L21/76838 , H01L51/0048 , H01L2221/1094 , Y10S977/724 , Y10S977/734 , Y10S977/742
摘要： New devices having horizontally-disposed nanofabric articles and methods of making same are described. A discrete electromechanical device includes a structure having an electrically-conductive trace. A defined patch of nanotube fabric is disposed in spaced relation to the trace; and the defined patch of nanotube fabric is electromechanically deflectable between a first and second state. In the first state, the nanotube article is in spaced relation relative to the trace, and in the second state the nanotube article is in contact with the trace. A low resistance signal path is in electrical communication with the defined patch of nanofabric. Under certain embodiments, the structure includes a defined gap into which the electrically conductive trace is disposed. The defined gap has a defined width, and the defined patch of nanotube fabric spans the gap and has a longitudinal extent that is slightly longer than the defined width of the gap. Under certain embodiments, a clamp is disposed at each of two ends of the nanotube fabric segment and disposed over at least a portion of the nanotube fabric segment substantially at the edges defining the gap. Under certain embodiments, the clamp is made of electrically-conductive material. Under certain embodiments, the contact between the nanotube patch and the trace is a non-volatile state. Under certain embodiments, the contact between the nanotube patch and the trace is a volatile state. Under certain embodiments, the at least one electrically conductive trace has an interface material to alter the attractive force between the nanotube fabric segment and the electrically conductive trace.
摘要翻译：描述了具有水平布置的纳米制品的新器件及其制造方法。分立的机电装置包括具有导电迹线的结构。定义的纳米管织物贴片与痕迹间隔开设置; 并且所述限定的纳米管织物片在第一和第二状态之间是机电偏转的。在第一状态下，纳米管制品相对于迹线具有间隔的关系，并且在第二状态下，纳米管制品与痕迹接触。低电阻信号路径与所定义的纳米片段电连通。在某些实施例中，该结构包括限定的导电迹线设置的间隙。限定的间隙具有限定的宽度，并且限定的纳米管织物片段跨过间隙并且具有比限定的间隙宽度稍长的纵向范围。在某些实施例中，夹具设置在纳米管织物片段的两端中的每一个处，并且在纳米管织物片段的至少一部分上大致位于限定间隙的边缘处。在某些实施例中，夹具由导电材料制成。在某些实施方案中，纳米管贴片和迹线之间的接触是非挥发性状态。在某些实施方案中，纳米管贴片和迹线之间的接触是挥发性状态。在某些实施例中，至少一个导电迹线具有界面材料，以改变纳米管织物片段和导电迹线之间的吸引力。

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