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    • 23. 发明授权
    • Boron or aluminum complexes
    • 硼或铝络合物
    • US08563761B2
    • 2013-10-22
    • US12736195
    • 2009-03-19
    • Michel ArmandJean-Marie TarasconNadir RechamSylvie GrugeonStephane LaruelleShanmukaraj Devaraj
    • Michel ArmandJean-Marie TarasconNadir RechamSylvie GrugeonStephane LaruelleShanmukaraj Devaraj
    • C07F5/06C07F5/02C01G49/02
    • C07F5/022C07F5/025C07F5/069H01M10/052H01M10/0567
    • The present invention relates to boron and aluminum complexes, to the preparation thereof, and to the use thereof for solubilizing ionic compounds. The complexes have one of the following formulae: in which D represents B or Al; R1 represents R, RF, NO2, CN, C(═O)OR, RSO2, or RFSO2; —X1—, —X2—, —X3— and X4 each represent a divalent group >C═O, >C═NC≡N, >C═C(C≡N)2, >CR2R3 or >SO2; —Y1—, —Y2— and —Y3— each represent a divalent group —O—, >N(C≡N), >N(CORF), >N(SO2R4), >NR4, >N(COR4) or >N(SO2RF); R, R2 and R3 each represent H, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, an oxaalkyl group or an alkenyl group; R4 represents an alkyl group, an aryl group, an alkylaryl group, a heteroaryl group, an arylalkyl group, an oxaalkyl group, an alkenyl group or an RFCH2— group; RF is a perfluoroalkyl group, a partially fluorinated alkyl group, or a partially or totally fluorinated phenyl group; each of the R′2 and R′3 groups represents R or F.
    • 本发明涉及硼和铝络合物,其制备方法及其用于增溶离子化合物的用途。 所述络合物具有下式之一:其中D表示B或Al; R1表示R,RF,NO2,CN,C(= O)OR,RSO2或RFSO2; -X1-,-X2-,-X3-和X4各自表示二价基团> C = O,> C = NC = N,> C = C(C = N)2,> CR2R3或> SO2; -Y2-,-Y2-和-Y3-各自表示二价基团-O - ,> N(C = N),> N(CORF),> N(SO 2 R 4),NR 4,N(COR 4) N(SO2RF); R,R 2和R 3各自表示H,烷基,芳基,烷基芳基,芳烷基,氧杂烷基或烯基; R4表示烷基,芳基,烷基芳基,杂芳基,芳基烷基,氧杂烷基,烯基或RFCH2-基团; RF是全氟烷基,部分氟化烷基或部分或全部氟化苯基; R'2和R'3各自表示R或F.
    • 24. 发明授权
    • Flexible, aqueous, controlled emission electrochemical cell
    • 柔性,水性,受控发射电化学电池
    • US07722986B2
    • 2010-05-25
    • US11793105
    • 2005-12-19
    • Valerie LucasLionel BeluzeMathieu MorcretteJean-Marie Tarascon
    • Valerie LucasLionel BeluzeMathieu MorcretteJean-Marie Tarascon
    • H01M10/36H01M4/00
    • G02F1/15
    • The invention concerns an electrochromic cell in thin films and aqueous electrolyte, with an emissivity that varies as a function of an applied control voltage. It is formed of the following flexible elements, superimposed and respectively in intimate contact: a first current collector (11) in electrically conducting material and intended to be connected to a first potential of the control voltage, a porous counter electrode (12) formed of a mixture of PVDF-HFP, PEO and a powder of a compound comprising complementary ions of an insertion material, a porous separator (13) formed of a mixture of PVDF-HFP and PEO, a second current collector (14) in electrically conducting material, intended to be connected to a second potential of the control voltage and capable of being traversed by ions, a porous electronic conduction layer (15) formed of a mixture of PVDF-HFP, PEO and a powder of an electrically conducting material, a porous active layer (16) formed of a mixture of PVDF-HFP, PEO and a powder of an insertion material.
    • 本发明涉及薄膜和含水电解质中的电致变色元件,发射率随施加的控制电压而变化。 它由以下柔性元件形成,叠加并分别紧密接触:导电材料中的第一集电体(11)并且旨在连接到控制电压的第一电位;多孔对电极(12)由 PVDF-HFP,PEO和包含插入材料的互补离子的化合物的粉末的混合物,由PVDF-HFP和PEO的混合物形成的多孔隔膜(13),导电材料中的第二集电体(14) ,旨在连接到控制电压的第二电位并能够被离子穿过;由PVDF-HFP,PEO和导电材料的粉末的混合物形成的多孔电子传导层(15),多孔 活性层(16)由PVDF-HFP,PEO和插入材料的粉末的混合物形成。