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21. 发明授权

US4704193A Covalently coupled cofactor modified electrodes and methods of synthesis and use 失效
标题翻译：共价偶联辅因子修饰的电极和合成和使用的方法
公开(公告)号：US4704193A
公开(公告)日：1987-11-03
申请号：US862951
申请日：1986-05-14
申请人： Mark L. Bowers , Mark A. Druy , Charles N. Durfor , H. Gilbert Smith , Sukant K. Tripathy , Barbara A. Yenser
发明人： Mark L. Bowers , Mark A. Druy , Charles N. Durfor , H. Gilbert Smith , Sukant K. Tripathy , Barbara A. Yenser
IPC分类号： C12Q1/00 , B01D59/40
CPC分类号： C12Q1/003 , Y10S435/814
摘要： An electrically and covalently coupled cofactor modified electrode for mediating the heterogeneous or homogeneous catalysis of a biochemical reaction by an enzyme. The electrode coating comprises an imidazoleflavin derivative covalently bonded to the electrode surface. Methods for preparation and use of the modified electrode are also presented.
摘要翻译：用于介导酶的生物化学反应的异质或均相催化的电和共价偶联的辅因子修饰电极。电极涂层包含共价键合到电极表面的咪唑黄素衍生物。还介绍了改性电极的制备和使用方法。

22. 发明授权

US4684434A Method for the preparation of thin large-area single crystals of diacetylenes and polydiacetylenes 失效
标题翻译：制备二乙炔和聚二乙炔的薄大面积单晶的方法
公开(公告)号：US4684434A
公开(公告)日：1987-08-04
申请号：US705587
申请日：1985-02-26
申请人： Mrinal K. Thakur , Sukant K. Tripathy , Daniel J. Sandman
发明人： Mrinal K. Thakur , Sukant K. Tripathy , Daniel J. Sandman
IPC分类号： C30B7/00
CPC分类号： C30B7/00 , C30B29/54 , C30B29/58 , C30B7/005 , Y10S117/919
摘要： A method for preparing thin large-area single crystals of diacetylene monomer represented by the formula:R--CX.tbd.C--C.tbd.C--R'wherein R and R' are side groups selected such that the diacetylene monomer is polymerizable by a 1,4-addition solid state reaction upon exposure to actinic radiation, is provided. The method involves forming a liquid layer containing pure diacetylene monomer between two opposed surfaces; applying pressure to the liquid layer disposed between the two opposed surfaces; and crystallizing the liquid layer disposed between the two opposed surfaces while the liquid layer is kept under constant pressure to form thin large-area single crystals of pure diacetylene monomer.A method for preparing thin large-area single crystals of polydiacetylene is also provided. The method involves forming a liquid layer containing diacetylene monomer represented by the formula:R--C.tbd.C--C.tbd.C--R'wherein R and R' are side groups selected such that the diacetylene monomer is polymerizable by a 1,4-addition solid state reaction upon exposure to actinic radiation in pure form between two opposed surfaces; applying pressure to the liquid layer disposed between the two opposed surfaces; crystallizing the liquid layer disposed between the two opposed surfaces while the liquid layer is kept under constant pressure to form thin large-area single crystals of pure diacetylene monomer; and exposing a surface of the thin large-area single crystal of diacetylene monomer to ultraviolet or gamma radiation to form thin large-area single crystals of polydiacetylene.
摘要翻译：制备由下列通式表示的双乙炔单体的薄的大面积单晶的方法：R-CX 3BOND CC 3BOND CR'其中R和R'是选择的侧基，使得乙炔单体可通过1,4-加成固体提供了暴露于光化辐射的状态反应。该方法包括在两个相对的表面之间形成含有纯双乙炔单体的液体层; 对设置在两个相对表面之间的液体层施加压力; 并且在液体层保持恒定压力的同时使设置在两个相对表面之间的液体层结晶，形成纯的乙炔单体的薄的大面积单晶。还提供了制备聚二乙炔薄的大面积单晶的方法。该方法包括形成含有由下式表示的乙炔单体的液体层：RC 3BOND CC 3BOND CR'，其中R和R'是选择的侧基，使得双乙炔单体可通过暴露于1,4-加成固相反应而可聚合在两个相对表面之间的纯粹形式的光化辐射; 对设置在两个相对表面之间的液体层施加压力; 在液体层保持恒定压力的同时使设置在两个相对表面之间的液体层结晶，形成纯的大面积纯双乙炔单体的单晶; 并将该乙炔单体的薄的大面积单晶的表面暴露于紫外线或γ射线以形成多个大面积的聚二乙炔的大面积单晶。

23. 发明授权

US4647403A Ion implanted polydiacetylenes 失效
标题翻译：离子注入聚二乙炔
公开(公告)号：US4647403A
公开(公告)日：1987-03-03
申请号：US630484
申请日：1984-07-13
申请人： Boris S. Elman , Daniel J. Sandman , Sukant K. Tripathy , Mrinal K. Thakur
发明人： Boris S. Elman , Daniel J. Sandman , Sukant K. Tripathy , Mrinal K. Thakur
IPC分类号： C08F8/00 , C08L49/00 , H01B1/12 , H01L51/30 , H01B1/06
CPC分类号： H01B1/125 , C08F8/00 , C08L49/00 , H01L51/004
摘要： Ion implanted polydiacetylenes prepared by implanting ions into substituted polydiacetylenes at fluence levels from about 1.times.10.sup.13 ions/cm.sup.2 to about 1.times.10.sup.17 ions/cm.sup.2 are disclosed. Ion implanted polydiacetylenes exhibit electrical and/or optical properties which are different from those of untreated polydiacetylenes.
摘要翻译：公开了通过以约1×10 13离子/ cm 2至约1×10 17离子/ cm 2的注量水平将离子注入取代的聚二乙炔中制备的离子注入的聚二乙炔。离子注入的聚二乙炔表现出不同于未处理的聚二乙炔的电学和/或光学性质。

24. 发明授权

US07332297B2 Enzymatic polymerization 失效
标题翻译：酶聚合
公开(公告)号：US07332297B2
公开(公告)日：2008-02-19
申请号：US10390676
申请日：2003-03-14
申请人： Lynne A. Samuelson , Ferdinando Bruno , Susan Tripathy, legal representative , Ramaswamy Nagarajan , Jayant Kumar , Wei Liu
发明人： Sukant K. Tripathy
IPC分类号： C12P1/00 , C12P13/00 , C12P7/00 , C12N11/16 , C12N11/08 , C08G73/00
CPC分类号： C12P13/001 , C12P7/22 , Y10S435/817 , Y10S977/898
摘要： The invention relates to a novel method for enzymatic polymerization which includes (1) obtaining a reaction mixture including a monomer, a template, and an enzyme; and (2) incubating the reaction mixture for a time and under conditions sufficient for the monomer to align along the template and polymerize to form a polymer-template complex. The template can be a micelle, a borate-containing electrolyte, or lignin sulfonate. Such a complex possesses exceptional electrical and optical stability, water solubility, and processibility, and can be used in applications such as light-weight energy storage devices (e.g., rechargeable batteries), electrolytic capacitors, anti-static and anti-corrosive coatings for smart windows, and biological sensors.
摘要翻译：本发明涉及一种新型的聚合方法，其包括（1）获得包含单体，模板和酶的反应混合物; 和（2）将反应混合物温育一段时间并在足以使单体沿着模板排列的聚合物形成聚合物 - 模板复合物的条件下。模板可以是胶束，含硼酸盐的电解质或木质素磺酸盐。这种复合物具有优异的电气和光学稳定性，水溶性和加工性，并且可用于诸如轻量储能装置（例如可再充电电池），电解电容器，用于智能的防静电和抗腐蚀涂层窗户和生物传感器。

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