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    • 22. 发明授权
    • Silicon polyethers and a method of producing the same
    • 硅聚醚及其制备方法
    • US08198361B2
    • 2012-06-12
    • US12694636
    • 2010-01-27
    • Benjamin FalkKalman KoczoAntonio Palumbo
    • Benjamin FalkKalman KoczoAntonio Palumbo
    • C08L83/00C08L83/04C07F7/02
    • C08G65/336C07F7/081C07F7/0838
    • The present invention provides a non-crosslinked silicon polyether composition comprising at least one compound with the following formula; [(R1O)(C2H4O)a(C3H6O)b(C4H8O)c]dR2(R3)e wherein R1 is a monovalent radical defined as MgMAhMBiMHjMEkDlDHmDEnToTHpTEqQr M=R4R5R6SiO1/2; MA=R7R8R9SiR10; MB=[(R11R12R13Si)sR14]tSi(R15)u(R16)vR17 MH=R18Si(R19)(R20)O1/2; ME=R21R22RESiO1/2; D=R23R24SiO2/2; DH=R25Si(R26)O2/2; DE=R27RESiO2/2; T=R28SiO3/2; TH=R29SiO3/2; TE=RESiO2/2; and Q=SiO4/2; R2 and R14 are polyvalent linear or branched; R3 is —(C2H4O)(C3H6O)b(C4H8O)c—R30 or R1; R30 is a monovalent saturated; R4, R5, R6, R7, R8, R9, R11, R12, R13, R15, R16, R19, R20, R21, R22, R23, R24, R26, R27, and, R28 are monovalent hydrocarbon radicals having from 1 to about 10 carbons; R10, R17, R18, R25 and R29 are divalent hydrocarbon radicals having 1 to about 25 carbons; RE is —R32—(C2H4O)a(C3H6O)b(C4H8O)c—R33; R32 is a divalent hydrocarbon radical having 1 to about 60 carbons; R33 is a monovalent hydrocarbon radical having 1 to about 20 carbons; h is 0 or 1 subject to the limitation if h is 1 then g+i+j+k+l+m+n+o+p+q+r=0; subscript d is 1
    • 本发明提供一种非交联硅聚醚组合物,其包含至少一种具有下式的化合物: [(R1O)(C2H4O)a(C3H6O)b(C4H8O)c] dR2(R3)e其中R1是定义为MgMAhMBiMHjMEkD1DHmDEnToTHpTEqQrM = R4R5R6SiO1 / 2的一价基团; MA = R7R8R9SiR10; MB = [(R11R12R13Si)sR14] tSi(R15)u(R16)vR17 MH = R18Si(R19)(R20)O1 / 2; ME = R21R22RESiO1 / 2; D = R23R24SiO2 / 2; DH = R25Si(R26)O2 / 2; DE = R27RESiO2 / 2; T = R28SiO3 / 2; TH = R29SiO3 / 2; TE = RESiO2 / 2; 和Q = SiO4 / 2; R2和R14是多价直链或支链的; R3是 - (C2H4O)(C3H6O)b(C4H8O)c-R30或R1; R30是一价饱和的; R4,R5,R6,R7,R8,R9,R11,R12,R13,R15,R16,R19,R20,R21,R22,R23,R24,R26,R27和R28均为1〜 10个碳; R 10,R 17,R 18,R 25和R 29是具有1至约25个碳的二价烃基; RE为-R32-(C2H4O)a(C3H6O)b(C4H8O)c-R33; R32是具有1至约60个碳的二价烃基; R33是具有1至约20个碳的一价烃基; h为0或1,如果h为1,则g + i + j + k + l + m + n + o + p + q + r = 0; 下标d是1
    • 25. 发明申请
    • Method for demulsifying
    • 破乳方法
    • US20070299143A1
    • 2007-12-27
    • US11472727
    • 2006-06-22
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • B01D17/05C09K3/00
    • B01D17/047C08G77/46C10G33/04C10L1/285
    • The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.
    • 本发明涉及一种用于分离油和水的乳液的方法,所述方法包括将破乳有效量的硅氧烷破乳剂掺入包含油相和水相的乳液中,所述硅氧烷破乳剂具有包含聚硅氧烷主链的分子结构 共价键合至少两个硅氧烷单元(i)一个或多个包含一个或多个独立地具有1-5个碳原子的氧化烯单元的环氧烷基团,和(ii)一种或多种含环氧乙烷和/或含氧杂环丁烷基团 其中所述环氧乙烷或氧杂环丁烷分别通过与能够开环环氧乙烷或氧杂环丁烷环的化学或基团反应而任意开环,并且其中基本上从硅氧烷破乳剂和乳液中排除固体填料。 本发明还涉及含有上述破乳剂和乳液的水相和油相的组合物。
    • 27. 发明授权
    • Clarifying agents for organomodified silicones
    • 有机改性硅氧烷的澄清剂
    • US08580285B2
    • 2013-11-12
    • US13156499
    • 2011-06-09
    • Benjamin FalkSigfredo Gonzalez
    • Benjamin FalkSigfredo Gonzalez
    • A61K8/06A61K8/02
    • C08L83/12A61K8/894A61K8/898A61K2800/10A61K2800/262A61Q19/00C08G77/388C08G77/46C08L83/08
    • There is provided herein a composition comprising a silicone copolymer of the general formula (I) MaMEcDdDEeTfTEgQh where M=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D=R6R7SiO2/2; DE=R8RESiO2/2; T=R9RESiO2/2; T=R9SiO3/2; TE=RESiO2/2; and Q=SiO4/2; where R1, R2, R3, R4, R5, R6, R7, R8, and R9 are each independently selected from the group of monovalent hydrocarbon radicals RE is a monovalent radical defined as: —R10O—(C2H4O)h(C3H6O)i(C4H8O)i—R11 or —R12 with the provision that the copolymer must contain at least one RE group; R10 is a linear or branched divalent hydrocarbon radical containing from 3 to about 10 carbon atoms; R11 is H or —C(═O)CH3 or a monovalent saturated or unsaturated hydrocarbon radical, optionally containing heteroatoms and hydroxyl groups, containing from 1 to about 30 carbon atoms; R12 is a hydrocarbon radical, containing from 2 to about 30 carbon atoms and at least 1 hydroxyl group, optionally containing heteroatoms; subscripts a, b, c, d, e, f, and g are 0 or positive subject to the limitation a+b+c+d+e+f+g
    • 本文提供了包含通式(I)MaMEcDdDEeTfTEgQh的硅氧烷共聚物的组合物,其中M = R1R2R3SiO1 / 2; ME = R4R5RESiO1 / 2; D = R6R7SiO2 / 2; DE = R8RESiO2 / 2; T = R9RESiO2 / 2; T = R9SiO3 / 2; TE = RESiO2 / 2; 和Q = SiO4 / 2; 其中R 1,R 2,R 3,R 4,R 5,R 6,R 7,R 8和R 9各自独立地选自一价烃基RE中的一价基团,定义如下:-R10O-(C 2 H 4 O)h(C 3 H 6 O) C4H8O)i-R11或-R12,条件是共聚物必须含有至少一个RE基团; R 10是含有3至约10个碳原子的直链或支链二价烃基; R 11是H或-C(= O)CH 3或任选含有1至约30个碳原子的杂原子和羟基的一价饱和或不饱和烃基; R 12是含有2至约30个碳原子和至少1个羟基,任选地含有杂原子的烃基; 下标a,b,c,d,e,f和g分别为0或正,受限于a + b + c + d + e + f + g <1000; 下标h,i和j为0或正数,受限于h + i + j小于100; 和b)有机油。
    • 29. 发明授权
    • Method for demulsifying
    • 破乳方法
    • US07745501B2
    • 2010-06-29
    • US11472727
    • 2006-06-22
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • Kalman KoczoSabine Isabelle AzouaniBenjamin Falk
    • B01D17/05C10G33/04
    • B01D17/047C08G77/46C10G33/04C10L1/285
    • The invention relates to a method for separating emulsions of oil and water, the method comprising incorporating a demulsifying-effective amount of a silicone demulsifier into an emulsion comprising an oil phase and an aqueous phase, the silicone demulsifier having a molecular structure comprising a polysiloxane backbone of at least two siloxane units covalently bound to (i) one or more alkylene oxide groups comprising one or more alkylene oxide units independently having one to five carbon atoms, and (ii) one or more oxirane-containing and/or oxetane-containing groups, wherein said oxirane or oxetane is optionally ring-opened by reaction with a chemical or group capable of ring-opening an oxirane or oxetane ring, respectively, and wherein a solid filler is substantially excluded from the silicone demulsifier and emulsion. The invention also relates to compositions containing the above-described demulsifier and the water and oil phases of an emulsion.
    • 本发明涉及一种用于分离油和水的乳液的方法,所述方法包括将破乳有效量的硅氧烷破乳剂掺入包含油相和水相的乳液中,所述硅氧烷破乳剂具有包含聚硅氧烷主链的分子结构 共价键合至少两个硅氧烷单元(i)一个或多个包含一个或多个独立地具有1-5个碳原子的氧化烯单元的环氧烷基团,和(ii)一种或多种含环氧乙烷和/或含氧杂环丁烷基团 其中所述环氧乙烷或氧杂环丁烷分别通过与能够开环环氧乙烷或氧杂环丁烷环的化学或基团反应而任意开环,并且其中基本上从硅氧烷破乳剂和乳液中排除固体填料。 本发明还涉及含有上述破乳剂和乳液的水相和油相的组合物。
    • 30. 发明申请
    • COPOLYMER OF EPOXY COMPOUNDS AND AMINO SILANES
    • 环氧化合物和氨基硅烷的共聚物
    • US20090118421A1
    • 2009-05-07
    • US12050543
    • 2008-03-18
    • Benjamin Falk
    • Benjamin Falk
    • C08L83/04C08G77/04
    • C08L83/04C07F7/1804C08C19/40C08F8/32C08F8/42C08G59/1477C08G59/4085C08G77/12C08G77/14C08G77/20C08G77/26C08G77/388C08G77/46C08G77/50C08G77/54C08G77/80C08L63/00C09D183/08D06M15/6436D06M15/65Y10T428/249921Y10T442/20
    • The present invention provides for a composition comprising the reaction product of a. an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and b. an amino silane having the formula: N(H)(R1)R2Si(OR3)3-a-b-c(OR4)a(R5Si(OR6)d(R7)e)bR8c with R1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R2 and R5 are independently selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R3, R6, R7, and R8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a, and c are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (a+b+c)≦3; the subscripts d and e are zero or positive and have a value ranging from 0 to 3 subject to the limitation that (d+e)≦3.
    • 本发明提供包含a的反应产物的组合物。 包含至少两个环氧乙烷或氧杂环丁烷基团的环氧乙烷或氧杂环丁烷化合物; 和b。 具有下式的氨基硅烷:<?in-line-formula description =“In-line formula”end =“lead”?> N(H)(R1)R2Si(OR3)3-abc(OR4)a(R5Si OR6)d(R7)e)bR8c <?在线公式描述=“在线公式”end =“tail”?>其中R 1选自H或含有1至20个的单价烃基 碳原子 R2和R5独立地选自氧或由1-60个碳组成的二价直链或支链烃基; R4是含有3〜200个碳原子的烃基; R 3,R 6,R 7和R 8,各自独立地选自具有1至200个碳原子的一价直链或支链烃基; 下标b为零或正数,值范围为0〜3; 下标a和c为零或正,并且具有范围从0到3的值,但受限于(a + b + c)<= 3; 下标d和e为零或正,并且具有范围从0到3的值,受限于(d + e)<= 3。