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21. 发明授权

US4248753A Michael adducts of polymeric materials useful in coating applications 失效
标题翻译：用于涂料应用的聚合物材料的迈克尔加合物
公开(公告)号：US4248753A
公开(公告)日：1981-02-03
申请号：US937386
申请日：1978-08-28
申请人： Stephen L. Buchwalter , Joseph F. Bosso , Roger M. Christenson
发明人： Stephen L. Buchwalter , Joseph F. Bosso , Roger M. Christenson
IPC分类号： C08F8/32 , C08F283/00 , C08F283/06 , C08G18/67 , C09D5/44 , C09D161/06 , C09D163/10 , C09D201/02 , C25D13/06 , C08L75/12 , C08L63/02
CPC分类号： C09D161/06 , C08G18/6705 , C09D163/10 , C09D5/4434 , Y10S524/901 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529
摘要： Resinous compositions which are the Michael adducts of primary and/or secondary amines and polymers containing alpha, beta-ethylenically unsaturated moieties in conjugation with carbonyl moieties are disclosed. The compositions are depositable on substrates to form films. The films are amenable to oxidative and aminoplast cures and cure with light color. The compositions are desirable for use in cationic electrodeposition.
摘要翻译：公开了作为初级和/或仲胺的迈克尔加合物和含有α，β-烯键式不饱和部分与羰基部分缀合的聚合物的树脂组合物。组合物可沉积在基材上以形成薄膜。这些胶片适合于氧化和氨基塑料固化并用浅色固化。组合物用于阳离子电沉积中是理想的。

22. 发明授权

US4065416A Water-based coatings with reduced solvent or water popping and sagging 失效
标题翻译：水性涂料具有减少溶剂或水的流失和流挂
公开(公告)号：US4065416A
公开(公告)日：1977-12-27
申请号：US618584
申请日：1975-10-01
申请人： Roger M. Christenson , Clarence E. Evjen
发明人： Roger M. Christenson , Clarence E. Evjen
IPC分类号： C09D133/24 , C08L33/02
CPC分类号： C09D133/24
摘要： This invention relates to a water-based coating composition in which solvent or water popping and sagging are eliminated or substantially reduced. The composition comprises a thermosetting, film-forming organic binder dispersed in an aqueous medium containing from 60 to 100 parts by weight of water and from 0 to 40 parts by weight of a volatile organic solvent. The organic binder is formulated from (a) an acid-containing interpolymer adapted to be dissolved or dispersed in water with the aid of a base and (b) a water-soluble or water-dispersible polyether polyol or polyester polyol having a molecular weight of at least 300. The interpolymer consists essentially of the interpolymerization product of an N-alkoxyalkyl-substituted amide, an alpha, beta-ethylenically unsaturated carboxylic acid, and at least one other monomer containing a ##STR1## In addition to the elimination of, or substantial reduction in solvent or water popping and sagging of the composition, films formed from the compositions exhibit good properties, such as hardness, water resistance, salt spray resistance and stain resistance.
摘要翻译：本发明涉及一种水性涂料组合物，其中消除或显着降低了溶剂或水的流失和流挂。该组合物包含分散在含有60至100重量份水和0至40重量份挥发性有机溶剂的水性介质中的热固性成膜有机粘合剂。有机粘合剂由（a）适于通过碱溶解或分散于水中的含酸共聚体配制，和（b）水溶性或水分散性聚醚多元醇或分子量为至少为300.互聚物基本上由N-烷氧基烷基取代的酰胺，α，β-烯键式不饱和羧酸和至少一种其它含有的单体的共聚产物组成，

23. 发明授权

US4029621A Reaction products of a polyepoxide with a thiol having a group hydroyzable to carboxyl, and aqueous solubilized products 失效
标题翻译：聚环氧化物与具有可水解羧基的硫醇的反应产物和水溶性产物
公开(公告)号：US4029621A
公开(公告)日：1977-06-14
申请号：US680935
申请日：1976-04-28
申请人： Marvis E. Hartman , Thomas R. Hockswender , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Marvis E. Hartman , Thomas R. Hockswender , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C08G59/14 , C08G59/42 , C08G59/66 , C08G59/16
CPC分类号： C08G59/66 , C08G59/1483 , C08G59/4207
摘要： Aqueous coating compositions which may be applied by conventional coating techniques as well as by electrodeposition are provided by reacting an epoxy-containing organic material with a compound containing a mercaptan group and at least one group hydrolyzable to a carboxyl group. Examples of such hydrolyzable groups include ester groups, amide groups and nitrile groups. The resultant product is then hydrolyzed and solubilized using hydrolyzing agents such as aqueous alkali metal hydroxides and aqueous solutions of various amines.
摘要翻译：可以通过常规涂布技术和电沉积施用的水性涂料组合物通过使含环氧基的有机材料与含有硫醇基团的化合物和至少一个可水解成羧基的基团反应来提供。这些可水解基团的实例包括酯基，酰胺基和腈基。然后使用水解剂如碱金属氢氧化物水溶液和各种胺的水溶液将所得产物水解和溶解。

24. 发明授权

US4615779A Cationic coating compositions for electrodeposition over rough steel 失效
公开(公告)号：US4615779A
公开(公告)日：1986-10-07
申请号：US698993
申请日：1985-02-07
申请人： Gregory J. McCollum , Roger L. Scriven , Roger M. Christenson , George W. Mauer , Robert R. Zwack
发明人： Gregory J. McCollum , Roger L. Scriven , Roger M. Christenson , George W. Mauer , Robert R. Zwack
IPC分类号： C08G18/08 , C08G18/64 , C08G18/80 , C09D5/44 , C25D13/06
CPC分类号： C08G18/0814 , C08G18/643 , C08G18/8064 , C09D5/4453 , Y10T428/31529
摘要： A method of cationic electrodeposition, electrocoated articles and novel electrocoating compositions are disclosed. The compositions comprise a cationic resin containing blocked isocyanate functionality and are capable of being electrodeposited over rough steel and producing extremely smooth films upon curing.

25. 发明授权

US4591518A Acrylic functional urethane alkyd resin coating compositions 失效
标题翻译：丙烯酸官能氨基甲酸酯醇酸树脂涂料组合物
公开(公告)号：US4591518A
公开(公告)日：1986-05-27
申请号：US639874
申请日：1984-08-13
申请人： William J. Schillinger , J. Alden Erikson , Rostyslaw Dowbenko , Roger M. Christenson
发明人： William J. Schillinger , J. Alden Erikson , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C09D175/14 , C08G18/42 , C08G18/81 , C09D175/16 , B05D3/02 , C08F20/00 , C08G63/76
CPC分类号： C09D175/16 , C08G18/4288 , C08G18/8108 , C08G18/8158
摘要： An air oxidizable coating composition is disclosed comprising an ungelled urethane modified alkyd resin containing pendant polymerizable unsaturated groups attached to the alkyd through urethane linkages. The ungelled urethane modified alkyd is the reaction product of components comprising a hydroxyl containing, air oxidizable alkyd resin having an oil length of between about 20 percent and about 70 percent and an isocyanate-functional ethylenically unsaturated compound. Also disclosed are a process for coating the substrate with the coating composition and certain ungelled urethane modified alkyd resins.
摘要翻译：公开了一种空气可氧化涂料组合物，其包含含有通过氨基甲酸酯键连接到醇酸树脂上的侧基聚合不饱和基团的未凝胶化的聚氨酯改性醇酸树脂。未凝胶化的氨基甲酸酯改性醇酸树脂是包含具有约20％至约70％的油长度的含羟基的可空气可氧化醇酸树脂和异氰酸酯官能的烯属不饱和化合物的组分的反应产物。还公开了用涂料组合物和某些未凝胶化的氨基甲酸酯改性醇酸树脂涂覆基材的方法。

26. 发明授权

US4560717A Cationic electrodepositable compositions containing formaldehyde scavenger 失效
公开(公告)号：US4560717A
公开(公告)日：1985-12-24
申请号：US627587
申请日：1984-07-03
申请人： Roger M. Christenson , Joseph T. Valko , Joseph E. Plasynski , Roger L. Scriven
发明人： Roger M. Christenson , Joseph T. Valko , Joseph E. Plasynski , Roger L. Scriven
IPC分类号： C09D5/44 , C25D13/06 , C25D13/10 , C08K5/21
CPC分类号： C09D5/4492
摘要： Formaldehyde-containing cationic electrodepositable compositions to which are added a formaldehyde scavenger are disclosed. Also disclosed are the use of these compositions in a method of cationic electrodeposition. Free formaldehyde in cationic compositions can lower the pH of the compositions making them more corrosive to the metal parts such as ferrous metal tanks and attending piping and pumps in contact with such compositions. The presence of the formaldehyde scavenger in such compositions stabilizes the pH.

27. 发明授权

US4477618A Aminoplast curable coating compositions containing sulfonic acid esters as latent acid catalysts 失效
标题翻译：含有磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物
公开(公告)号：US4477618A
公开(公告)日：1984-10-16
申请号：US427402
申请日：1982-09-29
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson , Michael M. Chau , Wen-Hsuan Chang
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson , Michael M. Chau , Wen-Hsuan Chang
IPC分类号： C08F8/36 , C08K5/42 , C09D161/20
CPC分类号： C07C309/00 , C08K5/42 , C09D161/20
摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.
摘要翻译：能够进行酸催化交联的高固体，有机溶剂型可喷涂涂料组合物由含活性氢的树脂，在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成，以及催化量的磺酸的非离子酯。磺酸酯由以下结构式表示：其中：Z是选自氨基和有机基团的基团，所述有机基团通过碳原子连接到硫原子上; C3-C20环烷基; 并且R 1，R 2，R 3，R 4，R 5独立地为氢或有机基团。这些基团可以特别描述如下：R 1是氢，烷氧羰基，C 3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基; R2是氢，烷氧羰基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R3是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R4是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基，R5是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基。

28. 发明授权

US4337184A Urethane rheology modifiers substantially free of terminal hydrophobic groups and compositions containing same 失效
标题翻译：基本上不含末端疏水基团的聚氨酯流变改性剂和含有它们的组合物
公开(公告)号：US4337184A
公开(公告)日：1982-06-29
申请号：US220617
申请日：1980-12-29
申请人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C08G18/30 , C08G18/66 , C08G18/72 , C09D7/00 , C08K5/29
CPC分类号： C08G18/6677 , C08G18/302 , C08G18/6666 , C08G18/721 , C09D7/002 , C08L75/04
摘要： Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate and little or no water. The modifiers are characterized by having a branched structure and containing substantially no terminal hydrophobic groups.
摘要翻译：用于水基和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能材料，二异氰酸酯和少量或不含水的反应。改性剂的特征在于具有支链结构并且基本上不含末端疏水基团。

29. 发明授权

US4335829A Coated metal surfaces and method of coating metal surfaces with aqueous resinous dispersions of epoxy resins and acrylic polymers 失效
标题翻译：涂覆的金属表面和用环氧树脂和丙烯酸聚合物的水性树脂分散体涂覆金属表面的方法
公开(公告)号：US4335829A
公开(公告)日：1982-06-22
申请号：US964549
申请日：1978-11-29
申请人： Roger M. Christenson , Rudolf Maska , Rostyslaw Dowbenko , Thomas R. Hockswender
发明人： Roger M. Christenson , Rudolf Maska , Rostyslaw Dowbenko , Thomas R. Hockswender
IPC分类号： B65D8/04 , C08L63/00 , C09D133/02 , C09D133/26 , C09D157/10 , C09D157/12 , B65D8/00 , B05D3/02 , B32B15/08 , B32B27/38
CPC分类号： C09D157/10 , C09D133/02 , C09D133/26 , C09D157/12 , C08L63/00 , Y10T428/1355 , Y10T428/31529 , Y10T428/31692
摘要： An aqueous resinous dispersion and a method of coating employing the aqueous resinous dispersion are disclosed. The aqueous resinous dispersions are solubilized with base and comprise an acrylic polymer containing N-ethoxymethylacrylamide or methacrylamide moieties and an epoxy resin. The dispersion is useful for coating metal containers particularly as a coating for the interior of containers which are used for alcoholic beverages, for example, beer cans.
摘要翻译：公开了一种水性树脂分散体和使用该水性树脂分散体的涂布方法。水性树脂分散体用碱溶解并且包含含有N-乙氧基甲基丙烯酰胺或甲基丙烯酰胺部分的丙烯酸聚合物和环氧树脂。该分散体可用于涂覆金属容器，特别是用作用于酒精饮料（例如啤酒罐）的容器内部的涂层。

30. 发明授权

US4222911A Polyester diol extended uralkyd resin and coating compositions containing the same 失效
标题翻译：聚酯二醇延伸的uralkyd树脂和含有它的涂料组合物
公开(公告)号：US4222911A
公开(公告)日：1980-09-16
申请号：US931632
申请日：1978-08-07
申请人： Roger M. Christenson , J. Alden Erikson
发明人： Roger M. Christenson , J. Alden Erikson
IPC分类号： C08G18/42 , C09D3/52 , C09D3/66 , C09D3/72
CPC分类号： C08G18/4202 , C08G18/4288
摘要： Coating compositions containing polyester diol extended uralkyd resins form flexible coatings. Such uralkyd resins are prepared by reacting oil modified alkyd resin, polyester diol having a number average molecular weight in the range of from about 800 to about 4000, and diisocyanate.
摘要翻译：含有聚酯二醇的涂层组合物延伸的uralkyd树脂形成柔性涂层。这种uralkyd树脂通过使油改性醇酸树脂，数均分子量在约800至约4000的聚酯二醇和二异氰酸酯反应制备。

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