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    • 21. 发明授权
    • Heat-curable mixtures based on polyimides and
poly-.beta.-iminocrotononitriles
    • 基于聚酰亚胺和聚-β-亚胺基腈的热固化混合物
    • US4247672A
    • 1981-01-27
    • US58223
    • 1979-07-16
    • Theobald HaugJurg Kiefer
    • Theobald HaugJurg Kiefer
    • C08F20/00C08F20/52C08F26/00C08G73/12C08F22/40
    • C08G73/12
    • Heat-curable mixtures which are stable on storage and consist of (a) poly-imides of specific unsaturated dicarboxylic acids of the general formula I ##STR1## in which A is a x-valent organic radical having at least 2 and not more than 30 carbon atoms, Z is a radical of the formulae ##STR2## and x is the number 2 or 3, and (b) poly-(.beta.-iminocrotononitriles) of the formula II, III and/or IV ##STR3## in which Y is a m-valent organic radical having at least 2 and at most 30 carbon atoms, R' is a hydrogen atom or an alkyl having 1 to 6 carbon atoms, cycloalkyl having 5 or 6 carbon atoms or aryl having 6 to 10 carbon atoms, R is an aliphatic or aromatic radical having not more than 30 carbon atoms, E, together with the two nitrogen atoms, is a five-membered or six-membered ring, m is 2 or 3 and n is 1 or 2, are suitable for the production of moulded materials, preferably by casting the resin mixture or by laminating or bonding substrates.
    • 在存储时稳定的由以下组成的可热固化的混合物:(a)通式I 的特定不饱和二羧酸的聚酰亚胺,其中A是具有至少2并且不大于30的x价有机基团 碳原子,Z是式“IMAGE”的基团,x是数字2或3,和(b)式II,III和/或IV的多 - (β-亚氨基加成蒙尼酮) IMAGE>其中Y是具有至少2个且至多30个碳原子的m价有机基团,R'是氢原子或具有1至6个碳原子的烷基,具有5或6个碳原子的环烷基或具有6个 至10个碳原子,R为不大于30个碳原子的脂族或芳族基团,E与两个氮原子一起为五元或六元环,m为2或3,n为1或 2,适用于模制材料的生产,优选通过浇铸树脂混合物或通过层压或粘结基材。