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1. 发明授权

US4552935A Heat-curable epoxy resin mixtures containing imide compounds and condensation products of phenols, amines and aldehydes or ketones 失效
标题翻译：含有酰亚胺化合物和酚类，胺类和醛类或酮类的缩合产物的热固性环氧树脂混合物
公开(公告)号：US4552935A
公开(公告)日：1985-11-12
申请号：US568845
申请日：1984-01-06
申请人： Theobald Haug , Friedrich Stockinger
发明人： Theobald Haug , Friedrich Stockinger
IPC分类号： C08G59/00 , C08G14/06 , C08G59/40 , C08G59/56 , C08G59/62 , C08L63/00 , C08L61/00 , C08G8/32
CPC分类号： C08G59/623 , C08G14/06 , C08G59/4042 , C08L63/00
摘要： Heat-curable mixtures containing (a) epoxy compounds having on average more than one 1,2-epoxy group per molecule, (b) monoimides or polyimides of specific unsaturated dicarboxylic acids of the formula I ##STR1## wherein A is an x-valent aromatic or aliphatic radical, R.sup.1 is hydrogen or methyl, and x is 1, 2 or 3, and (c) products of condensing specific phenols, specific amines and aldehydes or ketones in an acid medium.The novel curable mixtures have a long shelf life and give rise to moulded materials which are highly resistant to chemicals and resistant to boiling water.
摘要翻译：包含（a）每分子平均具有多于一个1,2-环氧基的环氧化合物的热固化性混合物，（b）式I的特定不饱和二羧酸的单酰亚胺或聚酰亚胺其中A是 x价芳族或脂族基，R1是氢或甲基，x是1,2或3，和（c）在酸性介质中缩合特异性酚，特定胺和醛或酮的产物。新型可固化混合物具有长的保存期限，并产生耐化学品和耐沸水的成型材料。

2. 发明授权

US4503285A Flexible base materials, their preparation and their use for printed circuits 失效
标题翻译：柔性基材，其制备方法及其在印刷电路中的应用
公开(公告)号：US4503285A
公开(公告)日：1985-03-05
申请号：US612996
申请日：1984-05-21
申请人： Roland Darms , Theobald Haug , Harry Beyeler
发明人： Roland Darms , Theobald Haug , Harry Beyeler
IPC分类号： H05K1/03 , H05K1/00
CPC分类号： H05K1/0346 , Y10T428/31681 , Y10T428/31721 , Y10T428/31725
摘要： Flexible base materials consisting of a metal foil and a film, firmly adhering thereto without an interlayer, of a polyamide/polyimide block copolymer of the formula I, or of a polyamide/polyimide copolymer prepared from a polyamide acid block of the formula IVa or Va and a dicarboxylic acid dichloride of the formula XI and a diamine of the formula XII.The individual symbols are defined in claim 1.The base materials according to the invention are suitable for the preparation of flexible printed circuits.
摘要翻译：由金属箔和膜组成的柔性基材，其中没有中间层牢固地粘附在其上，具有式I的聚酰胺/聚酰亚胺嵌段共聚物或由式IVa或Va的聚酰胺酸嵌段制备的聚酰胺/聚酰亚胺共聚物和式XI的二羧酸二氯化物和式XII的二胺。各个符号在权利要求1中限定。根据本发明的基础材料适用于制备柔性印刷电路。

3. 发明授权

US4424336A Meat-curable mixture, which are stable on storage, of epoxide resin, 3-aminocrotonic acid derivatives and maleimide compound 失效
标题翻译：对于环氧树脂，3-氨基巴豆酸衍生物和马来酰亚胺化合物，其在贮存时稳定的可固化混合物
公开(公告)号：US4424336A
公开(公告)日：1984-01-03
申请号：US418875
申请日：1982-09-16
申请人： Theobald Haug
发明人： Theobald Haug
IPC分类号： C08G59/00 , C08G59/40 , C08G59/52 , C08G59/54
CPC分类号： C08G59/52 , C08G59/4014 , C08G59/54
摘要： Heat-curable mixtures of one or more epoxide compounds, which, on average, have more than one epoxide group in the molecule, and one or more .beta.-aminocrotonic acid derivatives, such as .beta.-aminocrotononitrile, .beta.-aminocrotonamide or .beta.-aminocrotonic acid esters, and also, if desired, a polyamine or polycarboxylic acid anhydride or a malenimide. The novel curable mixtures are distinguished by outstanding stability on storage, can be processed easily and give moulded materials with good mechanical properties.
摘要翻译：一种或多种环氧化合物的热固化混合物，其平均在分子中具有多于一个的环氧基团，以及一种或多种β-氨基巴豆酸衍生物，例如β-氨基巴豆腈，β-氨基巴豆酰胺或β-氨基巴豆酸酯，如果需要，还可以使用多胺或多羧酸酐或马来酰亚胺。新型可固化混合物的特征在于在储存时具有突出的稳定性，可以容易地加工，并赋予具有良好机械性能的模制材料。

4. 发明授权

US4360655A Heat-curable mixtures, which are stable on storage, of epoxide compounds .beta.-aminocrotonic acid derivatives and polyamine 失效
标题翻译：环氧化合物β-氨基巴豆酸衍生物和多胺的储存稳定的可热固化混合物
公开(公告)号：US4360655A
公开(公告)日：1982-11-23
申请号：US268922
申请日：1981-06-01
申请人： Theobald Haug
发明人： Theobald Haug
IPC分类号： C08G59/00 , C08G59/40 , C08G59/52 , C08G59/54
CPC分类号： C08G59/52 , C08G59/4014 , C08G59/54
摘要： Heat-curable mixtures of one or more epoxide compounds, which, on average, have more than one epoxide group in the molecule, and one or more .beta.-aminocrotonic acid derivatives, such as .beta.-aminocrotononitrile, .beta.-aminocrotonamide or .beta.-aminocrotonic acid esters, and also, if desired, a polyamine or polycarboxylic acid anhydride or a maleimide. The novel curable mixtures are distinguished by outstanding stability on storage, can be processed easily and give moulded materials with good mechanical properties.
摘要翻译：一种或多种环氧化合物的热固化混合物，其平均在分子中具有多于一个的环氧基团，以及一种或多种β-氨基巴豆酸衍生物，例如β-氨基巴豆腈，β-氨基巴豆酰胺或β-氨基巴豆酸酯，如果需要，还可以使用聚胺或多元羧酸酐或马来酰亚胺。新型可固化混合物的特征在于在储存时具有突出的稳定性，可以容易地加工，并赋予具有良好机械性能的模制材料。

5. 发明授权

US4065433A Process for the manufacture of polyaddition products containing imide groups 失效
标题翻译：制备含酰亚胺基团的加聚产物的方法
公开(公告)号：US4065433A
公开(公告)日：1977-12-27
申请号：US534104
申请日：1974-12-18
申请人： Albrecht Muller , Theobald Haug , Alfred Renner
发明人： Albrecht Muller , Theobald Haug , Alfred Renner
IPC分类号： C08G73/00 , C07F9/553 , C08G65/00 , C08G65/34 , C08G73/12 , C08G73/16
CPC分类号： C07F9/5537 , C08G73/12 , C08G73/125 , C08G73/127
摘要： According to the invention, polyaddition products containing imide groups are manufactured by reacting certain polyimides (preferably maleimides) with polyhydric alcohols in the presence of basic compounds. The preferred embodiment (E) relates to the use of catalysts as basic compounds. In particular, amines and alkali metal compounds can be used. A further embodiment (F) relates to the use of primary polyamines as basic compounds. In the latter case, the polyamine participates in the polyaddition mechanism, that is to say the molecules are incorporated into the polyaddition products. In this latter case, catalysts can also be used additionally.
摘要翻译：根据本发明，通过在碱性化合物的存在下使某些聚酰亚胺（优选马来酰亚胺）与多元醇反应制备含酰亚胺基团的加聚产物。优选的实施方案（E）涉及催化剂作为碱性化合物的用途。特别地，可以使用胺和碱金属化合物。另一个实施方案（F）涉及使用初级多胺作为碱性化合物。在后一种情况下，多胺参与加聚机理，也就是说分子被加入到加成产物中。在后一种情况下，也可以另外使用催化剂。

6. 发明授权

US4963300A Process for the preparation of laminates 失效
标题翻译：制备层压板的方法
公开(公告)号：US4963300A
公开(公告)日：1990-10-16
申请号：US279747
申请日：1988-12-05
申请人： Kurt Meier , Theobald Haug , Wolfgang Scharf
发明人： Kurt Meier , Theobald Haug , Wolfgang Scharf
IPC分类号： C08J5/24 , C08G59/68 , H05K1/03
CPC分类号： C08G59/68 , H05K1/0326 , Y10T442/3577 , Y10T442/3585 , Y10T442/3691
摘要： A process for the preparation of a laminate including the steps(i) preparation of a layer by bringing into contact a fibrous substrate with a curable mixture containing an epoxy resin having on average at least two 1,2-epoxide groups per molecule or a mixture of these epoxy resins and a compound of the formula I ##STR1## or a mixture of these compounds, in which a and b are independent of one another 1 or 2, R.sup.1 is a .pi.-arene, R.sup.2 is a .pi.-arene or an indenyl- or cyclopentadienyl anion, X.sup.- is an anion [LQ.sub.m ].sup.- or an anion of a partly fluorinated or perfluorinated aliphatic or aromatic sulfonic acid, L is P, As or Sb, Q is fluorine or some of the Q substituents may also be hydroxyl groups, and m corresponds to a value which exceeds the valence of L by unity,(ii) preparation of a laminated sequence from at least two layered materials which are to be bonded together(iii) compression moulding of the said laminate sequence at elevated temperature.
摘要翻译：一种用于制备层压体的方法，包括以下步骤：（i）通过使纤维基材与含有每分子平均具有至少两个1,2-环氧基的环氧树脂或混合物的可固化混合物接触来制备层的这些环氧树脂和式I化合物[R1（FeIIR2）a] ab（+）ab。[X]（ - ）（I）或这些化合物的混合物，其中a和b彼此独立 1或2，R 1是一个仲芳基，R 2是一个或多个茚基 - 或环戊二烯阴离子，X-是阴离子[LQm] - 或部分氟化或全氟化的脂族或芳族磺酸的阴离子，L 是P，As或Sb，Q是氟或Q取代基中的一些也可以是羟基，m对应于超过L的化合价的一个数值，（ii）从至少两层分层要结合在一起的材料（iii）在升高的温度下对所述层压体序列进行压缩成型。

7. 发明授权

US5073438A Process for the preparation of laminates 失效
标题翻译：制备层压板的方法
公开(公告)号：US5073438A
公开(公告)日：1991-12-17
申请号：US572731
申请日：1990-08-23
申请人： Kurt Meier , Theobald Haug , Wolfgang Scharf
发明人： Kurt Meier , Theobald Haug , Wolfgang Scharf
IPC分类号： C08J5/24 , C08G59/68 , H05K1/03
CPC分类号： C08G59/68 , H05K1/0326 , Y10T442/3577 , Y10T442/3585 , Y10T442/3691
摘要： A laminate prepared by combining at least two layers wherein at least one of which is made of a fibrous material, an epoxy resin having on average at least two 1,2-epoxide groups per molecule or a mixture of these epoxy resins and a ferrocene derivative of the formula [R.sup.1 (Fe.sup.II R.sup.2).sub.a ].sup.ab+ ab.[X].sup.-, wherein a and b independently of one another are 1 or 2, R.sup.1 is a .pi.-arene, R.sup.2 is a .pi.-arene or an indenyl- or cyclopentadienyl anion, X.sup..crclbar. is an anion [LQ.sub.m ].sup..crclbar. or an anion of a partly fluorinated or perfluorinated aliphatic or aromatic sulfonic acid, L is P, As or Sb, Q is fluorine or some of the Q substituents may also be hydroxyl groups, and m corresponds to a value which exceeds the valence of L by unity, subjecting the layers to compression molding at such a temperature and pressure that a liquid resin matrix is present at the beginning of this step and an initial fall in the viscosity is produced so that entrained gases can escape from the layers and crosslinking the laminated layers to obtain a rapid rise in viscosity such that the resin which flows out does not bind the compression mold.

8. 发明授权

US4782126A Polymers formed from allyl-substituted or methallyl-substituted, bicyclic, unsaturated dicarboxylic anhydrides 失效
标题翻译：由烯丙基取代或甲代烯丙基取代的双环不饱和二羧酸酐形成的聚合物
公开(公告)号：US4782126A
公开(公告)日：1988-11-01
申请号：US96991
申请日：1987-09-16
申请人： Alfred Renner , Theobald Haug , Bruno Schreiber
发明人： Alfred Renner , Theobald Haug , Bruno Schreiber
IPC分类号： C08F2/00 , C08F22/04 , C08F36/00 , C08F36/02 , C08L63/00 , C08F34/02 , C08F122/04 , C08F222/04
CPC分类号： C08F22/04 , C08L63/00
摘要： Polymers formed from anhydrides of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or methyl.The novel polymers are suitable for use as curing agents for polyepoxide compounds.
摘要翻译：由式I（I）的酸酐形成的聚合物，其中R 1和R 2彼此独立地是氢或甲基。新型聚合物适合用作聚环氧化物化合物的固化剂。

9. 发明授权

US4518748A Curable epoxy resin mixtures 失效
标题翻译：可固化环氧树脂混合物
公开(公告)号：US4518748A
公开(公告)日：1985-05-21
申请号：US568684
申请日：1984-01-06
申请人： Theobald Haug , Friedrich Stockinger
发明人： Theobald Haug , Friedrich Stockinger
IPC分类号： C08G59/00 , C08G14/06 , C08G59/62 , C08L63/00 , C08L63/02
CPC分类号： C08G59/623 , C08G14/06
摘要： Curable mixtures containing (a) epoxide compounds with on average more than one 1,2-epoxide group per molecule, (b) the condensates prepared from certain phenols, certain amines and aldehydes or ketones in an acid medium and, where relevant, (c) curing accelerators. The novel curable mixtures have a good storage stability and give shaped substances with outstanding resistance to chemicals.
摘要翻译：含有（a）每分子平均具有多于一个1,2-环氧基的环氧化合物的可固化混合物，（b）在酸性介质中由某些酚，某些胺和醛或酮制备的缩合物，）固化促进剂。新型可固化混合物具有良好的储存稳定性，并具有出色的抗化学药品的成型物质。

10. 发明授权

US4284752A Process for producing crosslinked unsaturated polymers by reaction of .beta . 失效
标题翻译：通过β-氨基巴豆酸酯，腈或酰胺与多异氰酸酯反应制备交联的不饱和聚合物的方法
公开(公告)号：US4284752A
公开(公告)日：1981-08-18
申请号：US147991
申请日：1980-05-08
申请人： Theobald Haug
发明人： Theobald Haug
IPC分类号： C08F299/00 , C08F290/00 , C08G18/00 , C08G18/67
CPC分类号： C08G18/678 , C08G18/675
摘要： Novel, crosslinked, unsaturated polymers which have properties better than those of known crosslinked, unsaturated polymers are produced by reaction of .beta.-aminocrotonic acid esters, nitriles or amides with polyisocyanates, at temperatures for example of between 50.degree. and 180.degree. C.
摘要翻译：具有优于已知交联的不饱和聚合物性能的新型交联的不饱和聚合物通过在例如50至180℃的温度下，通过β-氨基巴豆酸酯，腈或酰胺与多异氰酸酯的反应来制备。

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