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    • 21. 发明授权
    • Ethylene-propylene-diene rubber, elastomer composition and vulcanized
rubber thereof
    • 乙烯 - 丙烯 - 二烯橡胶,弹性体组合物及其硫化橡胶
    • US5710218A
    • 1998-01-20
    • US430259
    • 1995-04-28
    • Hidenari NakahamaTakashi Mishima
    • Hidenari NakahamaTakashi Mishima
    • B60C1/00C08J3/215C08K3/06C08L23/16C08L47/00
    • B60C1/0016B60C1/0025C08J3/215C08K3/06C08L23/16C08J2323/16C08L2205/02C08L2205/025
    • The invention provides ethylene-propylene-diene rubbers capable of imparting excellent heat resistance, weather resistance and dynamic fatigue resistance to vulcanized rubbers made therefrom. The ethylene-propylene-diene rubbers have sulfur dispersed therein at a temperature of 90.degree. to 160.degree. C. prior to the addition of vulcanization accelerators or other rubber additives. The ethylene-propylene-diene rubbers contain (A) 90 to 40% by weight of a high-molecular weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the rubber dispersed therein at a temperature of 90.degree. to 160.degree. C. prior to the addition of a vulcanization accelerator or other rubber additive. The vulcanized rubbers are particularly suitable for use as automobile components which require dynamic fatigue resistance such as muffler hangers, belts, rubber vibration insulators, engine mounts, tire treads for pneumatic tires, sidewalls for pneumatic tires and white sidewalls.
    • 本发明提供能够赋予由其制成的硫化橡胶优异的耐热性,耐候性和动态耐疲劳性的乙烯 - 丙烯 - 二烯橡胶。 在加入硫化促进剂或其它橡胶添加剂之前,乙烯 - 丙烯 - 二烯橡胶在90℃至160℃的温度下分散有硫。 乙烯 - 丙烯 - 二烯橡胶含有(A)90〜40重量%的乙烯含量为60〜82摩尔%,特性粘度(η)为3.0〜3.0的高分子量乙烯 - 丙烯 - 二烯共聚物橡胶 在135℃下在萘烷中测得的5.0dl / g,碘值为8〜35,(B)10〜60重量%的乙烯含量低的乙烯 - 丙烯 - 二烯共聚物橡胶 60〜82摩尔%,在135℃下在十氢萘中测定的特性粘度(η)为0.15〜0.8dl / g,碘值为8〜35,(C)0.1〜5份的硫 在加入硫化促进剂或其它橡胶添加剂之前,基于100重量份在90℃至160℃的温度下分散的橡胶。 硫化橡胶特别适用于需要动态抗疲劳性的汽车部件,例如消声器吊架,皮带,橡胶振动绝缘子,发动机支架,用于充气轮胎的轮胎胎面,充气轮胎的侧壁和白色侧壁。
    • 22. 发明授权
    • Process for preparing ethylene-.alpha.-olefin-nonconjugated polyene
random copolymer
    • 制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法
    • US5696214A
    • 1997-12-09
    • US575678
    • 1995-12-19
    • Toshihiro SaganeToshiyuki TsutsuiMasaaki KawasakiKeiji OkadaHidenari NakahamaTetsuo Tojo
    • Toshihiro SaganeToshiyuki TsutsuiMasaaki KawasakiKeiji OkadaHidenari NakahamaTetsuo Tojo
    • C08F4/64C08F4/659C08F4/6592C08F210/18C08L23/16C08F236/20
    • C08F210/18C08L23/16C08F4/65912C08F4/65927C08L2312/00Y10S526/943
    • Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
    • 公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法,包括(a)乙烯,(b)3个或更多个碳原子的α-烯烃和(c)非共轭多烯在 含有特定茂金属化合物的茂金属催化剂。 通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性:(i)共聚物含有衍生自乙烯(a)的单元和衍生自3个或更多个碳原子的(b)的α-烯烃的单元 摩尔比为40/60〜95/5 [(a)/(b)],(ii)碘值为1〜50,(iii)特性粘度(η)大于0.1dl / g以下 (iv)13 C-NMR光谱中的Tαβ与Tαα的强度比D(Tαβ/Tαα)不大于0.5,(v)B值为 1.00至1.50,(vi)玻璃化转变温度Tg不高于-50℃,(vii)上述定义的共聚物的特性粘度(η)与特性粘度(η)的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔%(eta)/(η)空白的直链乙烯 - 丙烯共聚物大于0.9。 还公开了含有无规共聚物的可硫化橡胶组合物。 乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度,耐候性,耐臭氧性,加工性,低温柔韧性和耐热性都优异。
    • 24. 发明授权
    • Process oil composition, oil-extended elastomer containing the same and olefin-based thermoplastic elastomer composition
    • 加工油组合物,含有它的含油弹性体和烯烃类热塑性弹性体组合物
    • US08318846B2
    • 2012-11-27
    • US12085231
    • 2006-11-10
    • Yuichi ItoHidenari NakahamaKotaro Ichino
    • Yuichi ItoHidenari NakahamaKotaro Ichino
    • C08K5/01
    • C08L23/12C08L23/16C08L91/06C08L2666/02C08L2666/06
    • An object of the present invention is to provide an olefin-based thermoplastic elastomer composition that has both weatherability and flexibility at low temperatures, is excellent in fluidity, and causes no stickiness even in the use at high temperatures; a process oil composition for elastomers that serves as the raw material of the thermoplastic elastomer composition and contributes to the above characteristics; and an oil-extended elastomer containing the process oil composition.The process oil composition for elastomers of the present invention has a property that, when 20 parts by weight of the process oil composition for elastomers are blended with respect to 100 parts by weight of a propylene homopolymer, the melting point of the propylene homopolymer is lowered by 2 to 4.5° C. compared to that of the propylene homopolymer without blending. The process oil composition for elastomers is a mixture of a purified mineral oil and a synthetic oil obtained by polymerizing (an) olefinic monomer(s), wherein the ratio of the purified mineral oil to the synthetic oil is preferably 40/60 to 80/20.
    • 本发明的目的是提供一种在低温下具有耐候性和柔软性的烯烃类热塑性弹性体组合物,流动性优异,即使在高温下使用也不会发粘。 用作弹性体的工艺油组合物,其用作热塑性弹性体组合物的原料并有助于上述特性; 和含有该工艺油组合物的含油弹性体。 本发明的弹性体的加工油组合物具有如下特性:当相对于100重量份丙烯均聚物共混20重量份用于弹性体的工艺油组合物时,丙烯均聚物的熔点降低 与未共混的丙烯均聚物相比,为2〜4.5℃。 用于弹性体的工艺油组合物是纯化矿物​​油和通过聚合(a)烯烃单体获得的合成油的混合物,其中纯化矿物油与合成油的比例优选为40/60〜80 / 20。
    • 25. 发明授权
    • Vulcanized rubber molded product, method of producing the same, and use of the molded product
    • 硫化橡胶成型体及其制造方法以及成型品的使用
    • US07906560B2
    • 2011-03-15
    • US11889305
    • 2007-08-10
    • Hidenari NakahamaMikio HosoyaMasaaki Kawasaki
    • Hidenari NakahamaMikio HosoyaMasaaki Kawasaki
    • C08F8/00C08F8/34C08J9/36
    • C08J3/245C08F8/34C08J2321/00C08F210/18
    • The present invention provides a vulcanized foamed rubber molded product which has surface smoothness equal to or higher than that of a non-foamed vulcanized rubber molded product, has excellent mechanical strength properties, compression set resistance and abrasion resistance and a non-foamed vulcanized rubber molded product which is superior in surface smoothness to a conventional non-foamed vulcanized rubber molded product and has excellent compression set resistance, mechanical strength properties and abrasion resistance, as well as a method of producing the same. The molded product of the present invention is characterized in that the amount of sulfur atoms present in the surface thereof is at least 1.2 times as high as the amount of sulfur atoms present in a cut face obtained by cutting the surface to a depth of 1.0 mm in the vertical direction. The method of producing comprises allowing droplets or spray of a liquid containing an elementary substance consisting of a non-oxygen element in the group VI in the periodic table to adhere to the surface of a non-vulcanized rubber composition containing an elemental sulfur and/or a sulfur compound as a crosslinking agent, and then vulcanizing or vulcanizing and foaming the composition.
    • 本发明提供一种具有等于或高于非发泡硫化橡胶成型体的表面光滑度的硫化泡沫橡胶成型体,具有优异的机械强度特性,耐压缩变形性和耐磨性,以及非发泡硫化橡胶成型体 表面平滑度优于常规非发泡硫化橡胶成型体的产品,其耐压缩变形性,机械强度特性和耐磨性优异,以及其制造方法。 本发明的成型体的特征在于,其表面存在的硫原子的量为通过将表面切割成1.0mm深度而获得的切割面中存在的硫原子的量的至少1.2倍 在垂直方向。 制造方法包括允许含有元素周期表第Ⅵ族中由非氧元素组成的元素的液体的液滴或喷雾剂粘附到含有元素硫的非硫化橡胶组合物的表面和/或 硫化合物作为交联剂,然后硫化或硫化和发泡组合物。
    • 26. 发明申请
    • Vulcanized rubber molded product, method of producing the same, and use of the molded product
    • 硫化橡胶成型体及其制造方法以及成型品的使用
    • US20050080150A1
    • 2005-04-14
    • US10939456
    • 2004-09-14
    • Hidenari NakahamaMikio HosoyaMasaaki Kawasaki
    • Hidenari NakahamaMikio HosoyaMasaaki Kawasaki
    • C08F8/00C08F8/34C08J3/24C08J5/00C08J9/00C08K3/30C08L21/00C08L23/16
    • C08J3/245C08F8/34C08J2321/00C08F210/18
    • The present invention provides a vulcanized foamed rubber molded product which has surface smoothness equal to or higher than that of a non-foamed vulcanized rubber molded product, has excellent mechanical strength properties, compression set resistance and abrasion resistance and a non-foamed vulcanized rubber molded product which is superior in surface smoothness to a conventional non-foamed vulcanized rubber molded product and has excellent compression set resistance, mechanical strength properties and abrasion resistance, as well as a method of producing the same. The molded product of the present invention is characterized in that the amount of sulfur atoms present in the surface thereof is at least 1.2 times as high as the amount of sulfur atoms present in a cut face obtained by cutting the surface to a depth of 1.0 mm in the vertical direction. The method of producing comprises allowing droplets or spray of a liquid containing an elementary substance consisting of a non-oxygen element in the group VI in the periodic table to adhere to the surface of a non-vulcanized rubber composition containing an elemental sulfur and/or a sulfur compound as a crosslinking agent, and then vulcanizing or vulcanizing and foaming the composition.
    • 本发明提供一种具有等于或高于非发泡硫化橡胶成型体的表面光滑度的硫化泡沫橡胶成型体,具有优异的机械强度特性,耐压缩变形性和耐磨性,以及非发泡硫化橡胶成型体 表面平滑度优于常规非发泡硫化橡胶成型体的产品,其耐压缩变形性,机械强度特性和耐磨性优异,以及其制造方法。 本发明的成型体的特征在于,其表面存在的硫原子的量为通过将表面切割成1.0mm深度而获得的切割面中存在的硫原子的量的至少1.2倍 在垂直方向。 制造方法包括允许含有元素周期表第Ⅵ族中由非氧元素组成的元素的液体的液滴或喷雾剂粘附到含有元素硫的非硫化橡胶组合物的表面和/或 硫化合物作为交联剂,然后硫化或硫化和发泡组合物。