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21. 发明授权

US06727335B2 Polymeric phosphinic acids and salts thereof 失效
标题翻译：聚合次膦酸及其盐
公开(公告)号：US06727335B2
公开(公告)日：2004-04-27
申请号：US10417692
申请日：2003-04-17
申请人： Martin Sicken , Norbert Weferling , Hans-Peter Schmitz
发明人： Martin Sicken , Norbert Weferling , Hans-Peter Schmitz
IPC分类号： C08F13002
CPC分类号： C07F9/305 , C07F9/485
摘要： The invention relates to polymeric phosphinic acids and their salts of the formula (I) in which X is hydrogen or a 1/m metal of valency m, R1 and R2 are identical or different and are hydrogen, a carboxyl group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having 1 to 10 carbon atoms, phenyl, benzyl or alkyl-substituted aromatics, R3 and R4 are identical or different and are hydrogen or a vinyl group of the formula (VI) —CR1═CHR2 (VI) in which R1 and R2 have the abovementioned meaning, and {overscore (u)} is the average number of monomer units. The invention also relates to a process for the preparation of the abovementioned compounds and their use.
摘要翻译：本发明涉及式（I）的聚合物次膦酸及其盐，其中X是氢或1价金属的价态m，R 1和R 2相同或不同，为氢，羧基，羧酸衍生物，具有1-10个碳原子的未取代或取代的烷基，苯基，苄基或烷基取代的芳族化合物，R 3和R 4相同或不同，为氢或式（Ⅵ）的乙烯基，其中R 1和R 2具有上述意思和{超核（u是单体单元的平均数）。本发明还涉及制备上述化合物的方法及其用途。

22. 发明授权

US06600067B2 Process for preparing ethylenediphosphonic acids 失效
标题翻译：制备乙二膦酸的方法
公开(公告)号：US06600067B2
公开(公告)日：2003-07-29
申请号：US10025712
申请日：2001-12-19
申请人： Martin Sicken , Hans-Peter Schmitz
发明人： Martin Sicken , Hans-Peter Schmitz
IPC分类号： C07F938
CPC分类号： C07F9/3839
摘要： The invention relates to a process for preparing ethylenediphosphonic acids of the formula I, where R1 and R2 may be identical or different and are hydrogen, a carboxy group, a carboxylic acid derivative, an unsubstituted or substituted alkyl group having from 1 to 10 carbon atoms, phenyl, benzyl, or alkyl-substituted aromatic systems, which comprises reacting phosphorous acid (H3PO3) directly with alkynes.
摘要翻译：本发明涉及一种制备式I的亚乙基二膦酸的方法，其中R 1和R 2可以相同或不同，为氢，羧基，羧酸衍生物，未取代或取代的具有1-10个碳原子的烷基，苯基，苄基或烷基取代的芳族体系，其包括使亚磷酸（H 3 PO 3）直接与炔反应。

23. 发明授权

US06420598B1 Process for preparing alkylphosphonic acids 有权
标题翻译：制备烷基膦酸的方法
公开(公告)号：US06420598B1
公开(公告)日：2002-07-16
申请号：US09591712
申请日：2000-06-12
申请人： Norbert Weferling , Martin Sicken , Hans-Peter Schmitz
发明人： Norbert Weferling , Martin Sicken , Hans-Peter Schmitz
IPC分类号： C07F930
CPC分类号： C07F9/3808
摘要： The present invention relates to a process for the preparation of alkylphosphonic acids, which comprises reacting phosphorous acid (H3PO3) with short-chain olefins, and to the use of the products prepared by this process.
摘要翻译：本发明涉及一种制备烷基膦酸的方法，其包括使亚磷酸（H 3 PO 3）与短链烯烃反应，以及使用通过该方法制备的产物。

24. 发明授权

US5973194A Process for preparing dialkylphosphinate salts 有权
标题翻译：制备二烷基次膦酸盐的方法
公开(公告)号：US5973194A
公开(公告)日：1999-10-26
申请号：US198542
申请日：1998-11-24
申请人： Norbert Weferling , Hans-Peter Schmitz , Gunter Kolbe
发明人： Norbert Weferling , Hans-Peter Schmitz , Gunter Kolbe
IPC分类号： C01B25/163 , C07B61/00 , C07F9/30
CPC分类号： C07F9/30
摘要： The invention relates to a process for preparing dialkylphosphinate salts, which comprisesa) reacting elemental yellow phosphorus with alkyl halides in the presence of alkali metal hydroxide or alkaline earth metal hydroxide to form a mixture which comprises as main constituents the salts of alkylphosphonous, phosphorous and hypophosphorous acids,b) adjusting the mixture to a pH below 7 and then reacting the mixture with olefins in the presence of a free-radical initiator andc) reacting the dialkylphosphinic acids obtained according to b) and/or alkali metal salts thereof with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K to give the metal dialkylphosphinate salts.The invention likewise relates to the use of the metal dialkylphosphinate salts prepared by the process according to the invention to prepare flame retardants.
摘要翻译：本发明涉及一种制备二烷基次膦酸盐的方法，该方法包括：a）在碱金属氢氧化物或碱土金属氢氧化物存在下使元素黄磷与烷基卤化物反应形成一种混合物，该混合物包含烷基亚磷酸，磷和次磷酸，b）将混合物调节至低于7的pH，然后在自由基引发剂存在下使该混合物与烯烃反应，和c）将根据b）获得的二烷基次膦酸与/或其碱金属盐与金属反应 Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K的化合物，得到二烷基次膦酸金属盐。本发明同样涉及通过本发明方法制备的二烷基次膦酸金属盐制备阻燃剂的用途。

25. 发明授权

US5398801A Product conveying apparatus 失效
标题翻译：产品输送设备
公开(公告)号：US5398801A
公开(公告)日：1995-03-21
申请号：US945115
申请日：1992-09-14
申请人： Manfred Langen , Hans-Peter Schmitz , Udo Teich
发明人： Manfred Langen , Hans-Peter Schmitz , Udo Teich
IPC分类号： B65G47/30 , B65G47/248 , B65G47/38 , B65G47/52 , B65G47/74 , B65G47/94 , B65H67/06 , B65G47/24
CPC分类号： B65G47/248 , B65H67/064 , B65H67/068 , B65H2701/31
摘要： A conveying apparatus for supporting an article such as a product carrier during its conveyance is disclosed. The conveying apparatus includes a transferring track segment and a receiving track segment which are positioned laterally side by side, and with the transferring track segment being progressively inclined from a horizontal orientation to a laterally tilted orientation, and with the receiving track segment being progressively inclined from a laterally tilted orientation to a horizontal orientation. As result, the article being conveyed is rotated about a longitudinal axis and transferred to the receiving track segment. The apparatus finds particular utility in a yarn spinning plant, wherein yarn packages may be conveyed in a horizontal orientation and then rotated to a vertical orientation to facilitate packaging.
摘要翻译：公开了一种用于在输送过程中支撑诸如商品载体的物品的输送装置。输送装置包括横向并排定位的转印轨道段和接收轨道段，并且转印轨道段从水平方向逐渐倾斜到横向倾斜的方向，并且接收轨道段从向水平方向的横向倾斜取向。结果，所传送的物品围绕纵向轴线旋转并被传送到接收轨道段。该设备在纱线纺纱设备中具有特别的用途，其中纱线包装可以以水平方向输送，然后旋转到垂直取向以便于包装。

26. 发明授权

US5287895A Equipment for transporting and handling weft-yarn stock bobbins 失效
标题翻译：纬纱线轴的运输和处理设备
公开(公告)号：US5287895A
公开(公告)日：1994-02-22
申请号：US871522
申请日：1992-04-20
申请人： Tonny Raaijmakers , Gregor Gebald , Manfred Langen , Helmut Bungter , Hans-Peter Schmitz
发明人： Tonny Raaijmakers , Gregor Gebald , Manfred Langen , Helmut Bungter , Hans-Peter Schmitz
IPC分类号： B65H67/06 , D03D51/00 , D03J1/04 , D03J1/12 , D03D47/00
CPC分类号： D03J1/04 , B65H67/064 , B65H2701/31 , Y10S414/121
摘要： An equipment for transporting, handling and feeding stock bobbins to a loom having a preparation station (5) for the charging of bobbin holders (12) with stock bobbins (4) and a transport loop (7) for transporting these bobbin holders (12) towards looms. The looms are arranged in groups and for returning bobbin holders (12') containing empty bobbin tubes towards the preparation station (5), as well as at least one storage section (7c) branching off the transport loop (7) for receiving a number of the bobbin holders (12, 12') which corresponds with the need of bobbins at the time by at least one of the groups of looms (1a, 1b, . . . 1n). For the exchange of the bobbin holders (12' or 12 respectively) on the looms a loading mechanism (18) is provided which is mounted on a secondary transport mechanism (10) which may be moved independently of the transport loop (7) towards a number of groups of looms (1a, 1b, . . . 1n) and is intended for temporarily receiving the bobbin holders (12, 12') which may be fed from and returned to the storage section (7c). Through this execution a simple clearly arranged method of construction of the equipment is achieved, which makes possible a loading of the looms with stock bobbins to match the needs, which may be automated in a simple manner.
摘要翻译：一种用于将织物运送，处理和喂料的设备，该织机具有一个准备工位（5），用于对具有坯料筒管（4）的筒管架（12）和用于运送这些筒管架（12）的输送回路（7）对织机所述织机被分组布置，并且用于将含有空筒管的所述筒管架（12'）朝向所述准备台（5）以及至少一个分支出所述输送回路（7）的存储部分（7c）用于接收数字通过至少一个织机组（1a，1b，...，1n）与筒管的时间对应的筒管架（12,12'）。为了在梭织机上更换筒管架（12'或12），提供了一个装载机构（18），该装载机构（18）安装在辅助传送机构（10）上，辅助传送机构（10）可独立于传送环（7）而朝向织机组（1a，1b，...）的组织数目，用于临时接收可以从存储部分（7c）馈送并返回到储存部分（7c）的筒管架（12,12'）。通过这种执行，实现了一种简单明确的设备构造方法，这使得可以将织机与库管筒一起装载以满足需要，这可以以简单的方式自动化。

27. 发明授权

US5247969A Feeding and removing weft yarn stock bobbins to a loom bobbin frame 失效
标题翻译：喂养和移除纱线袜子BOBBIN框架
公开(公告)号：US5247969A
公开(公告)日：1993-09-28
申请号：US883599
申请日：1992-05-14
申请人： Tonny Raaijmakers , Antonius J. M. Hamer , Gregor Gebald , Manfred Langen , Helmut Bungter , Hans-Peter Schmitz
发明人： Tonny Raaijmakers , Antonius J. M. Hamer , Gregor Gebald , Manfred Langen , Helmut Bungter , Hans-Peter Schmitz
IPC分类号： D03J1/12 , B65H67/06 , D03D47/34 , D03J1/00
CPC分类号： D03J1/00 , B65H67/065 , D03D47/34 , B65H2701/31
摘要： A mechanism for feeding weft yarn stock bobbins to a loom includes a bobbin frame (3) for at least two stock bobbins (4) which may be fitted to bobbin holders (38) having longitudinal axes (L) which may be aligned on a common yarn guide member (6). The bobbin holders (38) are each formed on a bobbin carrier (10, 10') intended for receiving one of the stock bobbins (4) and able by means of a holder (30) of a charging mechanism to be fastened to the bobbin frame (3) and removed from the bobbin frame, the bobbin carrier having a yarn guide unit (45) for feeding the piece (A) at the start of the weft yarn (5) wound onto this stock bobbin (4) to the common yarn guide member (6). The yarn guide unit (45) is formed on a carrier part (44) able to swing between a normal position suitable for seizing the starting piece (A) and a deflected position in which in an operating position of the bobbin carrier (10, 10') predetermined on the bobbin frame (3) and aligned with the yarn guide member (6), the yarn guide unit (45) may be set in a definite yarn delivery position and may be brought together with the yarn guide member (6). A simplification of the charging process and delivery of the yarn is accordingly achievable.
摘要翻译：用于将织纬纱线喂入织机的机构包括用于至少两个坯料筒管（4）的梭骨架（3），其可以装配到具有纵向轴线（L）的筒管架（38）上，所述纵轴线（L）可以在公共纱线引导构件（6）。筒管架（38）各自形成在用于接收一个坯料筒管（4）的筒管架（10,10'）上，并且能够借助于紧固到筒管的充电机构的保持器（30）框架（3）从梭骨架上拆下，筒管架具有一个导丝单元（45），用于将卷绕在该卷轴（4）上的纬纱（5）的起始处的片（A）馈送到共同的纱线引导构件（6）。导丝单元（45）形成在能够在适合于抓住起始片（A）的正常位置和在所述筒管架（10,10）的操作位置之间摆动的托架部（44）上 '）预定在筒管架（3）上并与纱线引导构件（6）对准，导纱单元（45）可以设定在确定的纱线输送位置，并且可以与导纱构件（6）。因此可以实现纱线的充装过程和输送的简化。

28. 发明授权

US4453410A Method and apparatus for locating material defects in hollow bodies 失效
标题翻译：用于定位中空体材料缺陷的方法和装置
公开(公告)号：US4453410A
公开(公告)日：1984-06-12
申请号：US503642
申请日：1983-06-14
申请人： Hans-Peter Schmitz , Bernard Schleper
发明人： Hans-Peter Schmitz , Bernard Schleper
IPC分类号： G01N29/04 , G01N29/265 , G01N29/28 , G21C17/003
CPC分类号： G21C17/003 , G01N29/265 , G01N29/28 , G01N2291/048 , G01N2291/101 , G01N2291/2636
摘要： An ultrasonic probe is positioned within a hollow body such as a pipe for detecting possible flaws in the body wall. The probe is designed for rotational and longitudinal movement in said pipe and includes an ultrasonic transmitter/receiver mounted eccentrically within a liquid filled chamber of the probe, so that transmitted impulses strike the inner wall of the pipe at such an angle that the angle of refraction of the sound wave in the material of the wall is always less than 90.degree..
摘要翻译：超声波探头位于诸如管道的中空体内，用于检测体壁中的可能的缺陷。该探针设计用于在所述管道中旋转和纵向运动，并且包括偏心地安装在探针的液体填充室内的超声波发射器/接收器，使得传递的脉冲以与折射角度成一定角度撞击管道的内壁的声波在墙体材料中总是小于90°。

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