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21. 发明授权

US4778830A Polyester polyols liquid at room temperature and their preparation and use in preparing plastics by polyisocyanate addition polymerization 失效
标题翻译：聚酯多元醇液体在室温下及其制备和用途通过多异氰酸酯加成聚合制备塑料
公开(公告)号：US4778830A
公开(公告)日：1988-10-18
申请号：US127270
申请日：1987-12-01
申请人： Joachim Streu , Matthias Marx , Peter Weyland , Dietrich Scherzer , Wolfgang Straehle
发明人： Joachim Streu , Matthias Marx , Peter Weyland , Dietrich Scherzer , Wolfgang Straehle
IPC分类号： C08G18/42 , C08G18/46 , C08G63/16 , C08G18/14
CPC分类号： C08G18/4615 , C08G18/42 , C08G18/4238 , C08G63/16
摘要： Disclosed are polyester polyols liquid at 25.degree. C., having an average functionality of from 2 to 3, a hydroxyl number of from 25 to 400, an acid number smaller than 10 and a viscosity at 25.degree. C. of from 200 to 10,000 mPas, which contain in bonded form units having at least one of the structures--O--CH.sub.2 --CH(CH.sub.3)--CH.sub.2 --CH.sub.2 --CH.sub.2 --O--,--O--CH.sub.2 --CH(C.sub.2 H.sub.5)--CH.sub.2 --CH.sub.2 --O--,--OC--CH(CH.sub.3)--CH.sub.2 --CH.sub.2 --CO--and--OC--CH(C.sub.2 H.sub.5)--CH.sub.2 --CO--which are prepared by the polycondensation or transesterification of 2-methyl-1,5-pentanediol, 2-ethyl-1,4-butanediol, 2-methyl-glutaric acid and/or 2-ethyl succinic acid or their derivatives, optionally while using other organic polycarboxylic acids and multivalent aliphatic alcohols and are useful for preparing non-cellular or cellular polyurethane plastics or polyurethane-polyurea plastics.
摘要翻译：公开了在25℃下的平均官能度为2至3，羟基数为25至400，酸值小于10，25℃下的粘度为200至10,000mPas的聚酯多元醇液体（CH 3）-CH 2 -CH 2 -CH 2 -O - ， - O-CH 2 -CH（C 2 H 5）-CH 2 -CH 2 -O-的结构中至少一个具有键合形式的单元， -OC-CH（CH 3）-CH 2 -CH 2 -CO-和-OC-CH（C 2 H 5）-CH 2 -CO-，它们是通过2-甲基-1,5-戊二醇，2-乙基-2-甲基-1,5-戊二醇的缩聚或酯交换制备的， 1,4-丁二醇，2-甲基 - 戊二酸和/或2-乙基琥珀酸或其衍生物，任选地同时使用其它有机多元羧酸和多价脂族醇，并且可用于制备非细胞或细胞聚氨酯塑料或聚氨酯 - 聚脲塑料。

22. 发明申请

US20120142887A1 CROSSLINKED POLYAMIDES 审中-公开
标题翻译：交联聚氨酯
公开(公告)号：US20120142887A1
公开(公告)日：2012-06-07
申请号：US13308707
申请日：2011-12-01
申请人： Philippe Desbois , Dietrich Scherzer , Andreas Wollny , Andreas Radtke
发明人： Philippe Desbois , Dietrich Scherzer , Andreas Wollny , Andreas Radtke
IPC分类号： C08G69/16
CPC分类号： C08G69/18
摘要： A process for crosslinking polyamides by reacting a compound of the general formula R1R2C═CR3—X in which R1, R2 and R3 are each independently hydrogen or an organic radical with a lactam A at a temperature of (−30) to 150° C., and then reacting with a lactam B, a catalyst and an activator at a temperature of 40 to 240° C.
摘要翻译：通过使通式为R 1 R 2 C = CR 3 -X的化合物（其中R 1，R 2和R 3各自独立地为氢或有机基团）与内酰胺A在（-30）至150℃的温度下反应来交联聚酰胺的方法。然后在40〜240℃的温度下与内酰胺B，催化剂和活化剂反应。

23. 发明申请

US20110201728A1 COPOLYERS HAVING LONG-CHAIN ACRYLATES 有权
标题翻译：具有长链丙烯酸酯的共聚物
公开(公告)号：US20110201728A1
公开(公告)日：2011-08-18
申请号：US13123990
申请日：2009-10-02
申请人： Motonori Yamamoto , Ulrike Licht , Dietrich Scherzer
发明人： Motonori Yamamoto , Ulrike Licht , Dietrich Scherzer
IPC分类号： C08L3/00 , C08F224/00 , C08L33/10 , C08L75/00
CPC分类号： C08F220/18 , C08F220/32 , C08L3/02 , C08L2666/04
摘要： The present invention relates to copolymers obtainable by free-radical polymerization of i) 10% to 90% by weight, based on the total weight of components i to iv, of at least one monomer selected from the group consisting of a C8-C30 alkyl (meth)acrylate, C8-C30 vinyl ester, C8-C30 vinyl ether, C8-C30 olefin, and triglyceride of unsaturated C8-C30 carboxylic acids; ii) 0.5% to 70% by weight, based on the total weight of components i to iv, of a double-bond-containing monomer having at least one epoxide, isocyanate, carbodiimide, silane, β-dicarbonyl, oxazoline, or anhydride group; iii) 0% to 75% by weight, based on the total weight of components i to iv, of one or more monomers selected from the group consisting of vinylaromatic, C1-C7-alkyl (meth)acrylate, ethylenically unsaturated acetophenone derivative or benzophenone derivative, C1-C7 vinyl ester, C1-C7 vinyl ether, ethylenically unsaturated nitrile, ethylenically unsaturated amide, vinyl halide, C2-C7 olefin, cyclic lactam, and mixtures of these monomers; and iv) 0% to 10% by weight, based on the total weight of components i to iv, of a free-radically polymerizable monomer with carboxylic acid, sulfonic acid or phosphonic acid groups or salts thereof. The invention further relates to polymer mixtures comprising these copolymers and also to the use of the copolymers as chain extenders, compatibilizers and/or hydrolysis stabilizers, to produce paper and cardboard, for surface finishing in the paper, textile, and leather industries, and in adhesives.
摘要翻译：本发明涉及可通过自由基聚合获得的共聚物，i）10至90重量％，基于组分i至iv的总重量，至少一种选自下组的单体：C 8 -C 30烷基（甲基）丙烯酸酯，C8-C30乙烯基酯，C8-C30乙烯基醚，C8-C30烯烃和不饱和C8-C30羧酸的甘油三酯; ii）基于i至iv组分的含有至少一种环氧化物，异氰酸酯，碳二亚胺，硅烷，二羰基，恶唑啉或酸酐的含双键的单体的总重量的0.5重量％至70重量％组; iii）0至75重量％，基于组分i至iv的总重量，选自乙烯基芳族化合物，（甲基）丙烯酸C 1 -C 7烷基酯，烯属不饱和苯乙酮衍生物或二苯甲酮的一种或多种单体衍生物，C1-C7乙烯基酯，C1-C7乙烯基醚，烯键式不饱和腈，烯属不饱和酰胺，卤代乙烯基，C 2 -C 7烯烃，环状内酰胺和这些单体的混合物; 和iv）基于组分i至iv的具有羧酸，磺酸或膦酸基团的可自由基聚合的单体或其盐的0重量％至10重量％。本发明还涉及包含这些共聚物的聚合物混合物，并且还涉及使用共聚物作为增链剂，增容剂和/或水解稳定剂来生产纸和纸板，用于纸，纺织和皮革工业中的表面处理，以及粘合剂。

24. 发明申请

US20080194741A1 Flowable Thermoplastic Materials With Halogen-Free Flame Protection 有权
标题翻译：可流动的热塑性材料与无卤素火焰保护
公开(公告)号：US20080194741A1
公开(公告)日：2008-08-14
申请号：US11576646
申请日：2005-10-06
申请人： Jochen Engelmann , Bernd Bruchmann , Andreas Eipper , Jean-Francois Stumbe , Carsten Weiss , Dietrich Scherzer , Michaela Liese , Mark Volkel
发明人： Jochen Engelmann , Bernd Bruchmann , Andreas Eipper , Jean-Francois Stumbe , Carsten Weiss , Dietrich Scherzer , Michaela Liese , Mark Volkel
IPC分类号： C08K5/5333 , C08K5/3492
CPC分类号： C08L67/00 , C08K5/0066 , C08K5/49 , C08L67/02 , C08L69/00 , C08L101/005 , C08L2666/02 , C08L2666/18
摘要： Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polymer, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of a halogen-free flame retardant, selected from the group of the phosphorus-containing or nitrogen-containing compounds, or of the P—N condensates, or a mixture of these, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.
摘要翻译：热塑性模塑组合物，其包含A）10至98重量％的至少一种热塑性聚合物，B）0.01至50重量％的B1）至少一种高度支化或超支化聚碳酸酯，其OH值为1至600 mg KOH / g聚碳酸酯（根据DIN 53240第2部分）或B2）至少一种高度支化或超支化的A x B B y Y y型聚酯，其中x为至少1.1和y为至少2.1，或这些的混合物，C）1至40重量％的无卤阻燃剂，选自含磷或含氮化合物，或 PN缩合物，或它们的混合物，D）0至60重量％的其它添加剂，其中组分A）至D）的重量百分比的总和为100％。

25. 发明申请

US20070164466A1 Method for producing filler-containing foam slabs 审中-公开
标题翻译：生产含填料的泡沫板的方法
公开(公告)号：US20070164466A1
公开(公告)日：2007-07-19
申请号：US10589617
申请日：2005-02-16
申请人： Dietrich Scherzer , Rudiger Bluhm , Franz-Josef Dietzen , Swen Ruck
发明人： Dietrich Scherzer , Rudiger Bluhm , Franz-Josef Dietzen , Swen Ruck
IPC分类号： B29C44/20
CPC分类号： C08J9/0066 , C08J9/0085 , C08J2201/03 , C08J2201/038 , C08J2325/04 , C08J2361/02 , C08J2379/08 , C08J2381/06
摘要： Process for production of foam webs or foam sheets, these webs or sheets being based on a polymer selected from polysulfones, polyetherimides, polyether ketones, and styrene polymers, via extrusion of a melt which comprises the polymer and a blowing agent, and then foaming of this melt, which comprises a process in which the melt also comprises from 1 to 50% by weight, based on the polymer, of a filler selected from A) a fibrous filler A, B) a particulate, non-graphite filler B, and mixtures of these.
摘要翻译：通过挤出包含聚合物和发泡剂的熔体，这些纤维网或片材基于选自聚砜，聚醚酰亚胺，聚醚酮和苯乙烯聚合物的聚合物，生产泡沫网或泡沫片的方法，然后发泡该熔体包括其中熔体还包含基于聚合物的1至50重量％的填料，所述填料选自A）纤维填料A，B）颗粒状非石墨填料B和这些的混合物。

26. 发明授权

US6007752A Production of sheet-like polyurethane moldings 失效
标题翻译：生产片状聚氨酯模塑制品
公开(公告)号：US6007752A
公开(公告)日：1999-12-28
申请号：US851106
申请日：1997-05-05
申请人： Dietrich Scherzer , Ludwig Jung , Bernd Bruchmann , Hans Renz
发明人： Dietrich Scherzer , Ludwig Jung , Bernd Bruchmann , Hans Renz
IPC分类号： C08J5/18 , C08G18/32 , C08G18/79 , C08J5/04 , D06M15/564 , B29C67/00 , C08G18/10
CPC分类号： D06M15/564 , C08G18/3203 , C08G18/3256 , C08G18/798
摘要： Sheet-like polyurethane moldings are produced by impregnation of porous sheets with a prepolymer containing free isocyanate groups and reversibly blocked isocyanate-reactive groups or containing free isocyanate-reactive groups and reversibly blocked isocyanate groups, and subsequent reaction of the prepolymers in a heated mold.
摘要翻译：片状聚氨酯模制品是通过用含有游离异氰酸酯基团和可逆封闭的异氰酸酯反应性基团或含有游离异氰酸酯反应性基团和可逆封闭的异氰酸酯基团的预聚物浸渍多孔片材以及随后在加热模具中预反应物的反应来制备的。

27. 发明授权

US5616624A Preparation of bead-form expandable styrene polymers having improved expandability 失效
标题翻译：制备具有改善的膨胀性的珠粒可发性苯乙烯聚合物
公开(公告)号：US5616624A
公开(公告)日：1997-04-01
申请号：US495594
申请日：1995-08-02
申请人： Michael Witt , Dietrich Scherzer , Klaus Hahn , Dieter Naegele
发明人： Michael Witt , Dietrich Scherzer , Klaus Hahn , Dieter Naegele
IPC分类号： C08F2/20 , C08F2/44 , C08J9/20 , C08K5/09 , C08J9/18
CPC分类号： C08J9/20 , C08K5/09 , C08J2325/04
摘要： A process for the preparation of bead-form expandable styrene polymers by polymerizing styrene, if desired in the presence of further comonomers, in aqueous suspension in the presence of organic molecular colloids as suspension stabilizers and conventional styrene-soluble polymerization catalysts and with addition of a blowing agent and, if desired, conventional additives in effective amounts, wherein the aqueous suspension contains at least one olefinically unsaturated carboxylic acid or a water-soluble salt thereof in an amount, based on the organic phase, of from 0.002 to 0.3% by weight of carboxylate anions.
摘要翻译： PCT No.PCT / EP94 / 00662 Sec。 371日期：1995年8月2日 102（e）日期1995年8月2日PCT 1994年3月5日PCT公布。第WO94 / 21719号公报日期1994年9月29日一种通过在有机分子胶体作为悬浮稳定剂和常规苯乙烯可溶性聚合催化剂存在下，在水悬浮液中，如果需要在其它共聚单体存在下聚合苯乙烯，制备珠粒形可发性苯乙烯聚合物的方法并且如果需要，加入有效量的常规添加剂，其中水悬浮液含有至少一种基于有机相的烯属不饱和羧酸或其水溶性盐为0.002 到0.3重量％的羧酸根阴离子。

28. 发明授权

US5494941A Preparation of chlorofluorocarbon-free flexible polyurethane foams using diphenylmethane diisocyanate-based polyisocyanate mixtures containing urethane groups, and modified polyisocyanate mixtures of the type 失效
标题翻译：使用含有氨基甲酸酯基团的二苯基甲烷二异氰酸酯基聚异氰酸酯混合物和类型的改性多异氰酸酯混合物制备不含氟氯化碳的柔性聚氨酯泡沫体
公开(公告)号：US5494941A
公开(公告)日：1996-02-27
申请号：US15746
申请日：1993-02-10
申请人： Heinz-Dieter Lutter , Bernd Bruchmann , Claudia Spang , Roland Minges , Dietrich Scherzer , Michael Lugmayr , Ruth Zschiesche
发明人： Heinz-Dieter Lutter , Bernd Bruchmann , Claudia Spang , Roland Minges , Dietrich Scherzer , Michael Lugmayr , Ruth Zschiesche
IPC分类号： C08G18/10 , C08G18/12 , C08G18/40 , C08G18/48 , C08G18/65 , C08G18/72 , C08G18/76 , C08G101/00 , C08J9/02 , C08G18/00
CPC分类号： C08G18/7664 , C08G18/12 , C08G18/409 , C08G18/4812 , C08G2101/0008 , C08G2101/0041 , C08G2101/0083
摘要： The invention relates to a process for the preparation of CFC-free, flexible polyurethane foams or molded foams by reactingA) liquid polyisocyanate mixtures containing bonded urethane groups and having a content of NCO groups of from 20 to 30% by weight, these mixtures themselves being prepared by reacting a mixture of diphenylmethane diisocyanates and polyphenyl-polymethylene polyisocyanates (crude diphenylmethane diisocyanate) with a polyether-polyol mixture, having a hydroxyl number of from 120 to 25, of at least one polyoxypropylene glycol and at least one trifunctional polyoxypropylene-polyoxyethylene glycol having a content of ethylene oxide units of from 90 to 10% by weight or by reacting 4,4'-diphenylmethane diisocyanate (diphenylmethyl diisocyanate) or an diphenylmethane diisocyanate isomer mixture with said polyether-polyol mixture to give an NCO-containing quasi-prepolymer and diluting this quasi-prepolymer with crude diphenylmethane diisocyanate, withB) relatively high-molecular-weight polyhydroxyl compounds.
摘要翻译：本发明涉及一种制备无CFC的柔性聚氨酯泡沫或模制泡沫的方法，其通过使A）含有键合的氨基甲酸酯基团的液体多异氰酸酯混合物并且具有20至30重量％的NCO基团的含量，这些混合物本身通过使二苯基甲烷二异氰酸酯和聚苯基多亚甲基多异氰酸酯（粗二苯基甲烷二异氰酸酯）与羟基数为120至25的聚醚 - 多元醇混合物的混合物与至少一种聚氧丙烯二醇和至少一种三官能聚氧丙烯 - 聚氧乙烯乙二醇的含量为90〜10重量％的环氧乙烷单元，或通过使4,4'-二苯基甲烷二异氰酸酯（二苯基甲基二异氰酸酯）或二苯基甲烷二异氰酸酯异构体混合物与所述聚醚 - 多元醇混合物反应，得到含NCO的准 - 预聚物，并用粗二苯基甲烷二异氰酸酯稀释该准预聚物，B）相对较高小重量多羟基化合物。

29. 发明授权

US5208368A Preparation of mixtures of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates of reduced iodine color number 失效
标题翻译：二氯甲烷二异氰酸酯和聚苯乙烯聚异氰酸酯的还原碘颜料数量的混合物的制备
公开(公告)号：US5208368A
公开(公告)日：1993-05-04
申请号：US723133
申请日：1991-06-28
申请人： Dietrich Scherzer , Roland Minges , Bernd Bruchmann , Wolfgang Heider , Willy van Pee , Peter Keller
发明人： Dietrich Scherzer , Roland Minges , Bernd Bruchmann , Wolfgang Heider , Willy van Pee , Peter Keller
IPC分类号： C07C263/10 , C07C263/18 , C07C263/20 , C07C265/14 , C08G18/76
CPC分类号： C07C263/18 , C08G18/3206 , C08G18/48 , C08G18/7664
摘要： Mixtures of diphenylmethane diisocyanates and polyphenylpolymethylene polyisocyanates (crude MDI) of reduced iodine color number are prepared by reacting the corresponding mixtures of diphenylmethanediamines and polyphenylpolymethylenepolyamines with phosgene in the presence of at least one inert organic solvent at elevated temperature, at least one monohydric or polyhydric polyoxyalkylene alcohol, preferably having a functionality of from 2 to 3, and advantageously having a hydroxyl number of from 20 to 1800, or mixtures thereof in an effective amount, expediently in an amount of from 0.1 to 10% by weight, based on the weight of the crude MDI, being introduced into the reaction mixture when the phosgenation is complete, the phosgene and the inert organic solvent then being removed, up to 5% by weight, based on the weight of crude MDI, of at least one phenol-based antioxidant and/or aryl phosphite being added, if desired to the reaction product, and the reaction mixture being heated.
摘要翻译：通过在至少一种惰性有机溶剂的存在下，在升高的温度下使相应的二苯基甲烷二胺和多苯基多亚甲基多胺与碳酰氯的混合物反应制备二苯基甲烷二异氰酸酯和聚苯基多亚甲基多异氰酸酯（粗MDI）的混合物，至少一种一元或多元聚氧化烯醇，优选具有2至3的官能度，有利地具有20至1800的羟值，或其有效量的混合物，有利的量为0.1至10重量％，基于当完成光气化时，将粗MDI加入到反应混合物中，然后除去光气和惰性有机溶剂至多5重量％，基于粗MDI的重量计至少一种酚类抗氧化剂和/或亚磷酸芳基酯，如果需要加入到反应产物中，并且反应混合物被加热。

30. 发明授权

US09139752B2 Process for producing polyamides via anionic polymerization 有权
标题翻译：通过阴离子聚合生产聚酰胺的方法
公开(公告)号：US09139752B2
公开(公告)日：2015-09-22
申请号：US13630462
申请日：2012-09-28
申请人： Philippe Desbois , Bernd Bruchmann , Dietrich Scherzer , Andreas Wollny , Andreas Radtke
发明人： Philippe Desbois , Bernd Bruchmann , Dietrich Scherzer , Andreas Wollny , Andreas Radtke
IPC分类号： C08G69/14 , C09D177/02 , C08G69/18 , C08G18/80 , C08G69/20
CPC分类号： C08G69/18 , C08G18/8074 , C08G69/20 , C08J2475/00 , C09D177/02
摘要： The present invention relates to a process for producing polyamides, preferably crosslinked polyamides, via anionic polymerization of lactams in the presence of an anionic catalyst and of a caprolactam-capped polyisocyanate, where said isocyanate comprises more than 3.5 capped isocyanate groups.
摘要翻译：本发明涉及通过在阴离子催化剂和己内酰胺封端的多异氰酸酯的存在下通过内酰胺的阴离子聚合制备聚酰胺，优选交联的聚酰胺的方法，其中所述异氰酸酯包含多于3.5个封端的异氰酸酯基团。

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