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    • 13. 发明授权
    • Method of preparation of crosslinked hydrophilic resins
    • 交联亲水树脂的制备方法
    • US5506324A
    • 1996-04-09
    • US251826
    • 1994-05-31
    • Herbert GartnerRoswitha PetriPhilippe Trijasson, deceased
    • Herbert GartnerRoswitha PetriPhilippe Trijasson, deceased
    • A61L15/60C08F8/00C08F8/14C08F20/02C08G65/332
    • A61L15/60C08F8/14C08G65/3322C08F2810/20
    • The invention is crosslinked carboxyl containing hydrophilic resin crosslinked by a compound corresponding to formula 1,R.sup.1 --(O(CH(R.sup.3)CH(R.sup.3)O).sub.y --C(O)--R.sup.2).sub.xwherein: R.sup.1 is independently is each occurrence a C.sub.2-10 straight or branched chain alkyl moiety; R.sup.2 is independently is each occurrence a C.sub.2-10 straight or branched chain alkenyl moiety; R.sup.3 is independently in each occurrence hydrogen or methyl; x is independently in each occurrence 2 or greater where x is 2; y is independently in each occurrence 3 to 8, and where x is 3 or greater, y is independently in each occurrence 2 to 7.In another embodiment, the invention is a process for the preparation of crosslinked hydrophilic resins which comprises A) contacting one or more ethylenically unsaturated carboxylic acids, acid arthydrides, and optionally one or more known comonomers with a crosslinking compound of formula 1 in an aqueous medium, optionally in the presence of a free radical or redox catalyst system, under conditions such that a crosslinked hydrophilic resin is prepared. Optionally, the properties of the crosslinked hydrophilic resin are enhanced by heating the crosslinked hydrophilic resin under conditions such that the crosslinked hydrophilic resin exhibits a centrifuge capacity 25 (g/g) or greater, an absorption under load of 25 g/g or greater, and a ratio of absorption under load to centrifuge capacity of 0.6 or greater.
    • 本发明是通过对应于式1的化合物R1-(O(CH(R3)CH(R3)O)yC(O)-R2)x交联的交联的含羧基的亲水性树脂,其中:R1独立地为C2 -10直链或支链烷基部分; R2各自独立地出现C2-10直链或支链烯基部分; R3各自独立地为氢或甲基; x在每次出现时独立为2或更大,其中x为2; 在每次出现的情况下,y独立地为3至8,并且其中x为3或更大,y在每次出现时独立地为2-7。在另一个实施方案中,本发明是制备交联亲水性树脂的方法,其包括:A) 或更多的烯属不饱和羧酸,酸亚硫酸酯,以及任选的一种或多种已知的共聚单体,其中在水性介质中,任选地,在自由基或氧化还原催化剂体系的存在下,使交联的亲水树脂 准备好了 任选地,通过在交联的亲水性树脂显示离心机容量25(g / g)或更大,负载下的吸收为25g / g以上的条件下加热交联的亲水性树脂,可以提高交联亲水性树脂的性能, 负载下的吸收与离心机容量之比为0.6以上。