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    • 19. 发明授权
    • Method of treating fluoride contaminated wastes
    • 处理氟化物污染废物的方法
    • US4735784A
    • 1988-04-05
    • US884387
    • 1986-07-11
    • Phillip K. DavisVijay K. Kakaria
    • Phillip K. DavisVijay K. Kakaria
    • A62D3/00A62D3/20A62D3/34A62D3/35A62D101/22A62D101/45A62D101/49C01B7/19C01F7/50C03C14/00C01F1/00C01B33/08C04B33/08
    • A62D3/20C01B7/191C01F7/50C03C14/00A62D2101/45A62D2101/49A62D2203/10C03C2214/14
    • A process for treating solid substantially non-volatile wastes contaminated with a heat sensitive contaminant is disclosed. The wastes are heated to form a liquid slag. The liquid slag is held at elevated temperature until at least a portion of the contaminating components have either decomposed or evolved from the melt as a gas. The slag is subjected to cooling and the contaminating compounds are bound or encapsulated into a solid glassy slag. The process is particularly suitable for handling fluoride and cyanide contaminated aluminum smelting wastes such as spent potliner material. It is advantageous to add silica to such wastes. The residue from the slagging reaction is a glassy solid sodium metal silicate matrix such that the fluoride residues remaining in the wastes are encapsulated. The amount of silicate blended with the feed material is selected to substantially tie up all of the sodium remaining in the residue after slag melting and is typically 7.5 to 50 weight percent of the feed. The resulting solid, glassy slag material produced is not hazardous to health and is essentially inert to the environment.
    • 公开了一种处理受热敏污染物污染的固体基本上非挥发性废物的方法。 废物被加热以形成液体渣。 液体炉渣保持在升高的温度,直到至少一部分污染成分从熔体中分解或放出为气体。 炉渣被冷却,污染的化合物被结合或包封在固体玻璃状炉渣中。 该方法特别适用于处理氟化物和氰化物污染的铝冶炼废物,例如废瓷砖材料。 向这种废物中加入二氧化硅是有利的。 来自成渣反应的残留物是玻璃状固体金属硅酸钠基质,使残留在废物中的氟化物残留物被包封。 选择与进料材料混合的硅酸盐的量,以基本上将炉渣熔化后剩余的残余物中的所有钠基团结合,并且通常为进料的7.5至50重量%。 产生的固体,玻璃状渣物质对健康无害,对环境基本上是惰性的。