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    • 13. 发明授权
    • Process for the hydrometallurgical and electrochemical treatment of the
active mass of exhausted lead batteries, to obtain electrolytic lead
and elemental sulphur
    • 用于湿法冶金和电化学处理废气铅电池活性物质的方法,以获得电解铅和元素硫
    • US5630931A
    • 1997-05-20
    • US591717
    • 1996-01-25
    • Adilson C. Manequini
    • Adilson C. Manequini
    • B09B3/00C01B17/06C01B17/24C01B17/26C22B7/00C22B13/00C25C1/18H01M10/54C25D5/06
    • C25C1/18C22B13/045H01M10/54Y02P10/212Y02W30/84
    • A hydrometallurgical and electrochemical process for treating exhausted lead batteries, in particular the active mass and the electrolyte, is described having as products electrolytically obtained lead and elemental sulphur. The active mass (paste) obtained from the mechanical processing of the exhausted batteries, consisting mainly of lead sulphate and dioxide, is dispersed in a dilute H.sub.2 SO.sub.4 solution and then reacted with an Na.sub.2 S solution to convert all the lead compounds present into insoluble lead sulphide and sodium sulphate. After filtration, the sodium sulphate solution is evaporated to obtain the anhydrous salt. From this, by thermal reduction with carbon, the Na.sub.2 S is reformed for use in treating further paste. The lead sulphide obtained in this manner is leached with an electrolyte based on ferric fluoborate, which oxidizes the sulphide to elemental sulphur and solubilizes the lead in the form of fluoborate. After filtering the residue containing the elemental sulphur, the lead fluoborate solution is electrolyzed in a diaphragm cell to obtain electrolytic lead in the cathodic compartment and regenerate the ferric fluoborate in the anodic compartment for use in leaching further sulphide.
    • 描述了用于处理排出的铅电池,特别是活性物质和电解质的湿法冶金和电化学方法,其具有电解获得的铅和元素硫的产物。 由主要由硫酸铅和二氧化硫组成的排出的电池的机械加工得到的活性物质(糊状物)分散在稀的H 2 SO 4溶液中,然后与Na 2 S溶液反应,将所有的铅化合物转化为不溶的硫化铅, 硫酸钠。 过滤后,蒸发硫酸钠溶液,得到无水盐。 由此,通过用碳热还原,将Na 2 S重整以用于处理另外的糊状物。 以这种方式获得的硫化铅用基于氟硼酸盐的电解质浸出,其将硫化物氧化成元素硫并以氟硼酸盐的形式溶解铅。 在过滤含有元素硫的残余物之后,将荧光氟化铅溶液在隔膜电池中电解以在阴极室中获得电解铅,并在阳极室中再生氟硼酸盐以用于浸出另外的硫化物。
    • 16. 发明授权
    • Method and apparatus for continuously galvanizing flat workpieces, and
especially printed circuit boards
    • 连续镀锌扁平工件,特别是印刷电路板的方法和装置
    • US4800001A
    • 1989-01-24
    • US8738
    • 1987-01-30
    • Rudi OttHeribert Reith
    • Rudi OttHeribert Reith
    • C25D5/06H05K3/24C25D7/00C25D17/12C25D17/28
    • H05K3/241C25D5/06
    • Printed circuit boards can be continuously electroplated by passing them through a pair of rollers (7) forming cathodic rollers, which are spring-pressed towards each other, the rollers being driven, for example at the circumferential speed of about 1/2 meter per minute. The rollers form a transport arrangement for the printed circuit board, while providing electrical connection to conductive tracks thereon. Closely downstream of the cathodic rollers are a pair of anodic rollers, made, for example, of titanium with a covering of platinum or iridium, over which a felt sleeve is placed, on which felt sleeve an electrolyte, including sulfuric acid and copper is sprayed. The anodic rollers, connected to a positive terminal, are spaced from the surface of the printed circuit board to leave a surface gap between the rollers and the printed circuit board of about 0.1 mm. Copper is electrolytically deposited, for example, at the current density of about 15 A/dm.sup.2, which is about six times of the density of immersion bath galvanizing, thus permitting deposition of about 32 micrometers copper in 10 minutes rather than 60 minutes in an immersion bath. A plurality of cathodic roller pairs (7) and anodic roller pairs (8) are combined in a single housing to form a module, for example of 10 pairs each, requiring for ten modules 7 meters of length of plane floor space for continuous processing.
    • 印刷电路板可以通过使它们通过形成阴极辊的一对辊(7)而连续电镀,所述辊形成阴极辊,所述辊彼此弹簧压紧,所述辊被驱动,例如以约1/2米/分钟的圆周速度 。 辊形成用于印刷电路板的输送装置,同时提供与其上的导电轨道的电连接。 阴极辊的紧密下游是一对阳极辊,例如由钛制成,具有铂或铱的覆盖物,在其上放置毡套,毛毡套上包括硫酸和铜的电解质被喷涂在其上 。 连接到正极端子的阳极辊与印刷电路板的表面间隔开,使辊和印刷电路板之间的表面间隙约为0.1mm。 铜以例如约15A / dm 2的电流密度进行电解沉积,约为浸浴镀锌密度的六倍,从而允许在10分钟内沉积约32微米的铜而不是60分钟沉积 浴。 多个阴极辊对(7)和阳极辊对(8)组合在单个壳体中以形成例如每对10对的模块,其需要十个模块,用于连续处理的7米长的平面占地空间。
    • 17. 发明授权
    • Partial plating device
    • 部分电镀装置
    • US4683045A
    • 1987-07-28
    • US924657
    • 1986-10-29
    • Yasuto MurataJunichi TezukaKenji Yamamoto
    • Yasuto MurataJunichi TezukaKenji Yamamoto
    • C25D5/02C25D5/06C25D17/00
    • C25D5/02
    • This is a plating device for partially electroplating connector terminals at the tip, the target portions to be plated being a pair of forked portions of each connector terminal that are opposing to each other. In this partial plating device, a plating solution supply member to be inserted between the pair of target portions in the connector terminals comprises a support member, anode, net member and winding means. The support member has a top portion substantially forming an arrowhead with slanted guide planes on both sides. An opening is provided at or near the tip of this top portion to allow seepage of the plating solution. The net member covers the top portion of the support at its tip as well as the surface in its vicinity, the net member being freely wound up in the direction intersecting the passage line by the winding means and forming a supply section for the plating solution at a location corresponding to said passage line. With this construction, minute target portions are contacted with the plating solution which seeps on the net member while preventing the net member from being worn at given locations.
    • 这是用于在尖端处部分地电镀连接器端子的电镀装置,被电镀的目标部分是彼此相对的每个连接器端子的一对叉形部分。 在该部分电镀装置中,插入在连接器端子的一对目标部分之间的电镀液供给部件包括支撑部件,阳极,网部件和卷绕装置。 支撑构件具有基本形成箭头的顶部,在两侧具有倾斜的引导平面。 在该顶部的尖端处或附近设置开口以允许电镀液的渗出。 网构件在其尖端处覆盖支撑件的顶部以及其附近的表面,网构件通过缠绕装置沿与通道线相交的方向自由地卷绕,并且形成用于电镀液的供应部分 对应于所述通道的位置。 利用这种结构,微小的目标部分与网状部件渗漏的电镀液接触,同时防止网状部件在给定的位置被磨损。
    • 19. 发明授权
    • Continuous contact plater method
    • 连续接触法
    • US4064019A
    • 1977-12-20
    • US666618
    • 1976-03-15
    • Charles D. Eidschun, Jr.
    • Charles D. Eidschun, Jr.
    • C25D5/02C25D5/06H05K3/24
    • H05K3/241C25D5/02C25D5/06
    • A continuous contact plater is disclosed having a pair of opposed belts for grasping and driving contact points through a pair of opposed jaws to be plated by contact on an anode roller, the same describing a helical trace on the roller. A metering roller is provided to adjustably determine the concentration of the plating fluid on the main roller, and a tray is positioned beneath the anode roller to the end that a porous sleeve on the anode roller constantly passes into the electro-plating solution in the tray. Adjustment means are provided to adjust the roller with regard to the contact points between the opposed belts, the latter being fixed with regard to the frame of the unit.
    • 公开了一种连续接触平板机,其具有一对相对的带,用于通过一对相对的夹爪抓握并驱动接触点,以通过阳极辊上的接触进行电镀,其中描述了辊上的螺旋迹线。 设置计量辊以可调节地确定主辊上的电镀液的浓度,并且托盘位于阳极辊下方,使得阳极辊上的多孔套管不断地进入托盘中的电镀溶液 。 提供调整装置以相对于相对的带之间的接触点来调整辊,后者相对于单元的框架是固定的。
    • 20. 发明授权
    • Platinum plating process
    • 铂电镀工艺
    • US3865697A
    • 1975-02-11
    • US36383473
    • 1973-05-25
    • SUGGS ROBERT
    • SUGGS ROBERT
    • C25D3/50C25D5/06C23B5/48B23P1/02C23B5/24
    • C25D3/50C25D5/06
    • The commutator segments of a rotatably supported assembled armature are shorted to the negative side of a DC voltage source and a platinum anode connected to the positive side of the voltage source is wet with an aqueous solution of chloroplatinic acid and an alkali metal compound such as sodium carbonate, the anode wet with solution being wiped across the shorted segments until a platinum layer builds up over the surface thereof. The proportions of chloroplatinic acid and sodium carbonate in the solution are such that platinum build up other than on the commutator segments remains sparse and isolated by the carbonate residue so that there is no shorting of the segments across the insulators.
    • 可旋转支撑的组装电枢的换向片段与直流电压源的负极短路,与电压源正极连接的铂阳极用氯铂酸和碱金属化合物如钠的水溶液润湿 碳酸盐,用溶液润湿的阳极被擦过短路段,直到铂层在其表面上积聚。 溶液中氯铂酸和碳酸钠的比例使得除了在换向片上形成的铂不断地被碳酸盐残留物稀释并分离,使得跨越绝缘体的片段不会短路。