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    • 14. 发明授权
    • Basic azo dyestuffs of the 2,6-diamino-pyridine series
    • 2,6-二氨基 - 吡啶系列的碱性偶氮染料
    • US3899478A
    • 1975-08-12
    • US35660873
    • 1973-05-02
    • HOECHST AG
    • FLECKENSTEIN ERWINMOHR REINHARDHEINRICH ERNST
    • C07D213/74C07D213/80C07D213/82C07D213/85C09B29/42C09B44/00C09B44/08C09B44/10C09B29/36
    • C09B29/3639C09B44/08C09B44/105
    • A basic azo dyestuff of the formula

      WHEREIN A is an aromatic or heterocyclic diazo component, R1 and R2 each is primary, secondary or tertiary amino or hydrazino, R3 is cyano, carbo lower alkoxy, carbamoyl, lower alkyl carbamoyl, di lower alkyl carbamoyl, lower alkylsulfonyl or phenylsulfonyl, R4 is lower alkyl, substituted lower alkyl or phenyl, m is 1 or 2 and X is an anion and at least one of the groups A, R1, R2 and R4 contain a quaternary ammonium group of the formula

      wherein Y1 and Y2 are hydrogen, lower alkyl, benzyl or cyclohexyl, Y3 is hydrogen, lower alkyl, benzyl, cyclohexyl, lower alkoxy or amino or the nitrogen atom forms together with Y1 and Y2 or Y3 a heterocyclic ring. The novel dyestuffs are suitable for the preparation of writing and stamping inks or ball pen pastes and can be used for rubber printing. They are also suitable for the dyeing, printing or mass dyeing of tannined cellulose fibers, silk, hair, leather, coco fibers, jute, sisal or synthetic fibers, such as acetate silk, polyamide fibers or acid modified polyolefin, polyamide or polyester fibers, especially, however, of fibers containing polyacrylonitrile or polyvinylidene cyanide. The dyeings obtained on these fibers have, mostly, a high tinctorial strength and, in general, good fastnesses to light and to wet processing.
    • 式(Ⅰ)的碱性偶氮染料AN = N m X(I)m其中A是芳族或杂环重氮组分,R1和R2分别是伯,仲或叔氨基或肼基,R3是氰基 ,低级烷氧基,氨基甲酰基,低级烷基氨基甲酰基,二低级烷基氨基甲酰基,低级烷基磺酰基或苯基磺酰基,R4为低级烷基,取代的低级烷基或苯基,m为1或2,X为阴离子,基团A至 R1,R2和R4含有式Y1 | - + N-Y2 | Y3的季铵基,其中Y1和Y2为氢,低级烷基,苄基或环己基,Y3为氢,低级烷基,苄基,环己基, 低级烷氧基或氨基或氮原子与Y1和Y2或Y3一起形成杂环。
    • 15. 发明授权
    • Dihydroindolyl-,pyrimidonyl-,benzothiazolyl-,dihydroquinoxalyl-or dihydroquinazolylmethylene azo diphenylene oxide or carbazole dyestuffs
    • 二氢吲哚,吡咯烷酮,苯并二唑,二氢吲哚氧基或二氢吲哚并噻唑基亚氨基二氧化硫或氧杂环丁烷二异氰酸酯
    • US3840518A
    • 1974-10-08
    • US16983171
    • 1971-08-06
    • BAYER AG
    • SCHMITT ERAUE R
    • C09B26/04C09B44/10C09B69/06C09B29/36D06P3/24D06P3/70
    • C09B69/065C09B26/04C09B44/102
    • 1. HYDRAZONE DYESTUFF OF THE FORMULA

      (Y C=CH-N=N(-R1)-),(R2-)-1,2-PHENYLENE)-

      (R3-1,2-CYCLOHEX-1,2-YLENE(B))-))(+) A(-)

      WHEREIN B IS PHENYL, TETRAHYDROPHENYL OR HEXAHYDROPHENYL;

      =C
      IS DIHYDROINDOYL, PYRIMIDONYL, DIHYDROPYRIMIDONYL, BENZOTHIAZOLYL, DIHYDROQUINOXALYL, DIHYDROQUINOXALONYL, OR DIHYDROQUINAZOLYL; Y IS

      -O-, -S-, OR -N(-R)-

      WHERE R IS HYDROGEN, LOWER ALKYL, 2-CHLOROETHYL, 3-CHLOROPROPYL, BENZYL, B-PHENYLETHYL, Y-PHENYLPROPYL, PHENYLPROPYL-(2,2), 4-NITRONENZYL, PHENYL, LOWER ALKYLPHENYL, CHLOROPEHNYL, OR 4-AMINOPHENYL; R1 IS LOWER ALKYL, 2-CHLOROETHYL, 3-CHLOROPROPYL, LOWER ALKENYL, BENZYL, B-PHENYLETHYL, Y-PHENYLPROPYL, PHENYLPROPYL-(2,2), 4-NITROBENZYL, ETHOXYETHYL, OR ETHOXYCARBONYL-METHYL; R2 IS HYDROGEN, FLUORO, CHLORO, BROMO, LOWER ALKOXY, LOWER ALKYL, 2-CHLOROETHYL, 3-CHLOROPROPYL, HYDROXY, DIMETHYLAMINO, DIETHYLAMINO, DI-N-PROPYLAMINO, OR LOWER ALKANOYLAMINO; R3, WHEN RING B IS PHENYL, IS HYDROGEN, CHLORO, BROMO, LOWER ALKYL, 2-CHLOROETHYL, 3-CHLOROPROPYL, LOWER ALKOXY, HYDROXYL, DIEMTHYLAMINO, DIETHYLAMINO, DI-NPROPYLAMINO, OR LOWER ALKANOYLAMINO; R3, WHEN RING B IS TETRAHYDROPHENYL, OR HEXAHYDROPHENYL, IS HYDROGEN, CHLORO, OR LOWER ALKYL; R4 IS LOWER ALKYL, 2-CHLOROETHYL, 3-CHLOROPROPYL, CYCLOHEXYL, 4 - METHYLCYCLOHEXYL, BENZYL, B-PHENYLETHYL, Y-PHENYLPROPYL, PHENYLPROPYL-(2,2), 4-NITROBENZYL, PHENYL, LOWER ALKYLPHENYL, CHLOROPEHNYL, OR BROMOPHENYL; AND A- IS AN ANION.