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    • 13. 发明申请
    • Aqueous cross-linkable binder composition and its use in the production of lacquer coatings
    • 水性交联粘合剂组合物及其在漆涂料生产中的应用
    • US20020040093A1
    • 2002-04-04
    • US09928616
    • 2001-08-13
    • Klaus HobelJosephus Christiaan Van OorschotKeimpe Jan Van Den Berg
    • C08K003/00
    • C08G18/83C08G18/0823C08G18/2815C08G18/6625C08G18/725C08G18/84C09D175/04
    • The aqueous-based cross-linkable binder composition comprising (A) an aqueous dispersion of an aldehyde-functional polyurethane having a number average molecular weight of more than 1,000 and an average aldehyde functionality ofnull2, which polyurethane comprises ionic and/or non-ionic dispersing groups, and (B) a low-molecular weight aldehyde-reactive cross-linker selected from the group of low-molecular weight polyamines and low-molecular weight compounds comprising at least one group of one of the formulae E1nullCHR1nullE2 and HnullCnull(E1E2E3), wherein nullE1, nullE2 and nullE3 are independently chosen from electron-withdrawing groups such as nullP(nullO)nullOnull, nullCOnull, nullCN, nullSO2null, nullNO2 and wherein R1 has the meaning of hydrogen or a hydrocarbon radical having 1 to 10 carbon atoms. Preference is given to a coating composition wherein the ionic dispersing group is an anionic dispersing group selected from the group of carboxylate, sulphonate and/or phosph(on)ate salt groups, and/or wherein for the nonionic dispersing group use is made of a C1-C4 alkoxy poly C2-C3 alkylene-oxide group in an amount between 2.5 and 20 wt. %, based on the polyurethane.
    • 所述水性可交联粘合剂组合物包含(A)数均分子量大于1000且平均醛官能度> = 2的醛官能聚氨酯的水分散体,所述聚氨酯包含离子和/或非 - - (B)低分子量醛反应性交联剂,其选自低分子量多胺和低分子量化合物,所述低分子量化合物包含至少一个下式之一:E1-CHR1- E2和HC-(E1E2E3),其中-E1,-E2和-E3独立地选自吸电子基团,例如-P(= O)-O-,-CO-,-CN,-SO 2 - , - NO 2 并且其中R 1具有氢或具有1至10个碳原子的烃基的含义。 优选一种涂料组合物,其中离子分散基团是选自羧酸盐,磺酸盐和/或磷酸盐基团的阴离子分散基团,和/或其中对于非离子分散基团使用的是由 量为2.5至20重量%的C 1 -C 4烷氧基聚C 2 -C 3亚烷基氧基。 %,基于聚氨酯。
    • 18. 发明授权
    • Process for the preparation of aqueous dispersions or solutions of
isocyanate polyaddition products
    • 制备水分散体或异氰酸酯加成产物溶液的方法
    • US4240942A
    • 1980-12-23
    • US925674
    • 1978-07-18
    • Wolfgang WenzelWalter MeckelJosef Pedain
    • Wolfgang WenzelWalter MeckelJosef Pedain
    • C08G18/00C08G18/08C08G18/10C08G18/12C08G18/83C08G18/84C09D175/04C08J3/08C08L75/04
    • C08G18/12C08G18/0804C08G18/10C08G18/831C08G18/84C09D175/04
    • The present invention relates to a process for the preparation of aqueous dispersions or solutions of isocyanate polyaddition products characterized in that oligourethanes(a) which have an average molecular weight of less than about 15,000,(b) which contain from about 0 to 120 milliequivalents, per 100 g of solid content, of built-in ionic groups and/or from about 0 to 25% by weight, based on the total weight of the oligourethane, of built-in ethylene oxide units --CH.sub.2 --CH.sub.2 --O-- present within a polyether chain and/or from about 0 to 30% by weight, based on the total weight of the oligourethane, of external emulsifiers which are not chemically fixed, the total quantity of the aforesaid hydrophilic groups or external emulsifiers being sufficient to ensure the dispersibility or solubility of the oligourethanes in water, and(c) which contain primary or secondary amino end groups or semicarbazide end groups with at least one NH end groupare reacted in the aqueous phase with a chain lengthening agent which is at least difunctional and which undergoes an addition reaction or condensation reaction with the amino end groups or semicarbazide end groups to effect chain lengthening of the oligourethanes. The present invention also relates to the dispersions or solutions obtainable by this process and to their use for the production of films and coatings.
    • 本发明涉及一种制备异氰酸酯加成产物的水性分散体或溶液的方法,其特征在于平均分子量小于约15,000的低聚氨酯(a),(b)含有约0至120毫当量的 每100克固体含量的内置离子基团和/或约0至25重量%,基于低聚氨酯的总重量,内置的环氧乙烷单元-CH2-CH2-O-存在于 聚醚链和/或约0至30重量%,基于寡聚氨酯的总重量,未化学固定的外部乳化剂,上述亲水基团或外部乳化剂的总量足以确保分散性 或寡氨基甲酸酯在水中的溶解度,和(c)含有具有至少一个NH端基的伯或仲氨基端基或氨基脲端基在水相中与链长反应 该化合物至少是双官能的,并且与氨基端基或氨基脲端基进行加成反应或缩合反应,以实现低聚氨酯的链延长。 本发明还涉及通过该方法获得的分散体或溶液及其用于生产膜和涂料的用途。