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11. 发明授权

US08455698B2 Hydroxy- and aldehyde functional compounds 失效
标题翻译：羟基和醛官能化合物
公开(公告)号：US08455698B2
公开(公告)日：2013-06-04
申请号：US13124600
申请日：2009-12-30
申请人： Michael A. R. Meier , Anastasiya Rybak , Dominik Geisker
发明人： Michael A. R. Meier , Anastasiya Rybak , Dominik Geisker
IPC分类号： C07C45/00 , C07C27/00 , C07C249/00 , C07B43/00
CPC分类号： C07C51/367 , C07C45/512 , C07C51/373 , C07C67/333 , C07C47/02 , C07C59/42 , C07C59/147 , C07C69/732 , C07C69/716
摘要： The invention relates to a method for producing a mixture containing hydroxy- and aldehyde functional compounds by a cross-metathesis reaction of at least one at least monounsaturated fatty acid or at least one at least monounsaturated fatty acid derivative with an olefinic compound having at least one hydroxy group and at least one C—C double bond, in the presence of a metathesis catalyst at a maximum temperature of 180° C.
摘要翻译：本发明涉及通过至少一种至少一不饱和脂肪酸或至少一种至少一不饱和脂肪酸衍生物与至少一种至少一种不饱和脂肪酸衍生物的烯烃化合物的交叉复分解反应来生产含有羟基和醛官能化合物的混合物的方法羟基和至少一个CC双键，在复分解催化剂存在下，最高温度为180℃。

12. 发明授权

US08450509B2 Method for synthesising 9-aminononanoic acid or the esters thereof from natural unsaturated fatty acids 有权
标题翻译：从天然不饱和脂肪酸合成9-氨基壬酸或其酯的方法
公开(公告)号：US08450509B2
公开(公告)日：2013-05-28
申请号：US13001659
申请日：2009-07-09
申请人： Jean-Luc Dubois
发明人： Jean-Luc Dubois
IPC分类号： C07C227/00 , C07C229/00
CPC分类号： C07C229/08 , C07C51/353 , C07C51/373 , C07C67/333 , C07C67/475 , C07C227/08 , C07C227/28 , C08G69/08 , C07C57/03 , C07C59/147 , C07C69/533 , C07C69/738 , C07C69/73
摘要： The invention relates to a method for synthesizing 9-aminononanoic acid or the esters thereof from natural unsaturated fatty acids, comprising at least one step of metathesis of the natural fatty acid and an oxidation step by oxidative cleaving. Said synthetic method uses widely available renewable starting materials and hence economical.
摘要翻译：本发明涉及从天然不饱和脂肪酸合成9-氨基壬酸或其酯的方法，其包括至少一步天然脂肪酸的复分解和通过氧化裂解的氧化步骤。所述合成方法使用广泛可用的可再生原料，因此是经济的。

13. 发明申请

US20090076302A1 PROCESS FOR PREPARING a-KETO ACIDS AND DERIVATIVES THEREOF 有权
标题翻译：制备α-酮酸及其衍生物的方法
公开(公告)号：US20090076302A1
公开(公告)日：2009-03-19
申请号：US12169683
申请日：2008-07-09
申请人： Christoph Kobler , Martin Hateley , Philipp Roth , Barbara Jaeger , Christoph Weckbecker , Klaus Huthmacher
发明人： Christoph Kobler , Martin Hateley , Philipp Roth , Barbara Jaeger , Christoph Weckbecker , Klaus Huthmacher
IPC分类号： C07C319/12 , C07C47/02 , C07C381/00
CPC分类号： C07C319/20 , C07B41/06 , C07B41/08 , C07C51/373 , C07C67/313 , C07C319/14 , C07C323/52 , C07D317/32 , C07D493/08 , C07C62/18 , C07C69/716 , C07C321/14
摘要： A method for preparing α-keto acids, especially α-ketomethionine, and/or derivatives thereof, whereby an aldehyde is reacted with thiols to give a corresponding dithioacetal, the dithioacetal formed, is reacted with an electrophile in the presence of a strong base, and the resulting α,α-(dithio)carboxylic acid is solvolyzed with acid-catalysis to release thiol and give the α-keto acid or a derivative thereof. Umpolung of aliphatic or aromatic aldehydes is effected by reaction with thiols.
摘要翻译：一种制备α-酮酸，特别是α-酮基甲硫氨酸和/或其衍生物的方法，其中醛与硫醇反应，得到相应的二硫缩醛，形成的二硫缩醛与亲电子试剂在强碱存在下反应，并且所得的α，α-（二硫代）羧酸用酸催化溶剂分解以释放硫醇并得到α-酮酸或其衍生物。通过与硫醇反应来实现脂族或芳族醛的沸腾。

14. 发明申请

US20040242828A1 Method of modifying components present in cashew nut shell liquid 失效
标题翻译：修改腰果壳液中存在的成分的方法
公开(公告)号：US20040242828A1
公开(公告)日：2004-12-02
申请号：US10798684
申请日：2004-03-11
发明人： Mohammed Lokman Khan , Jeremy Tomkinson , Richard James Salisbury
IPC分类号： C08G083/00 , C10M101/00
CPC分类号： C09J161/06 , C07C45/40 , C07C51/373 , C07C65/30 , C08G8/04 , C08G8/24 , C08L61/06
摘要： Disclosed is a process for modifying cashew nut shell liquid (CNSL) which involves the steps of subjecting the CNSL to ozonolysis to form ozonolysis reaction products, followed by reduction of the ozonolysis reaction products to give a mixture of phenolic components and aldehydes. In a preferred embodiment, the process involves reacting CNSL with ozone to form a mixture containing ozonolysis reaction products, and then treating the mixture under reducing conditions to form a further mixture containing phenolic components with an eight carbon chain having a terminal nullCHO group and alkyl components of varying lengths with either one or two terminal nullCHO groups. The resulting CNSL aldehydes may be used to form adhesives for use in the manufacture of composites such as wood particle board.
摘要翻译：本发明公开了一种改性腰果壳液（CNSL）的方法，该方法涉及以下步骤：使CNSL进行臭氧分解以形成臭氧分解反应产物，然后还原臭氧分解反应产物，得到酚类组分和醛的混合物。在优选的实施方案中，该方法包括使CNSL与臭氧反应以形成含有臭氧分解反应产物的混合物，然后在还原条件下处理该混合物以形成含有具有末端-CHO基团的八个碳链的酚类组分和烷基具有一个或两个末端-CHO基团的不同长度的组分。所得到的CNSL醛可用于形成用于制造复合材料如木材刨花板的粘合剂。

15. 发明授权

US06403817B1 Method for preparing prostaglandin E-type compound 失效
标题翻译：前列腺素E型化合物的制备方法
公开(公告)号：US06403817B1
公开(公告)日：2002-06-11
申请号：US09791711
申请日：2001-02-26
申请人： Chi-Hsiang Yao , Rung-Tian Suen , Yu-Liang Liu
发明人： Chi-Hsiang Yao , Rung-Tian Suen , Yu-Liang Liu
IPC分类号： C07C5116
CPC分类号： C07C51/373 , C07C51/09 , C07C51/377 , C07C59/90
摘要： The present invention discloses a method for preparing a prostaglandin E-type compound, in which prostaglandin F-type compound is used as an initiator to generate novel derivative of prostaglandin F-type compound through a silylation reaction, and eventually a prostaglandin E-type compound is obtained through an oxidation and a desilylation reaction.
摘要翻译：本发明公开了一种前列腺素E型化合物的制备方法，其中使用前列腺素F型化合物作为引发剂，通过甲硅烷基化反应产生前列腺素F型化合物的新型衍生物，最终得到前列腺素E型化合物通过氧化和脱甲硅烷基化反应获得。

16. 发明申请

US20020004576A1 Method of modifying components present in cashew nut shell liquid 失效
标题翻译：修改腰果壳液中存在的成分的方法
公开(公告)号：US20020004576A1
公开(公告)日：2002-01-10
申请号：US09866451
申请日：2001-05-25
发明人： Mohammed Lokman Khan , Jeremy Tomkinson , Richard James Salisbury
IPC分类号： C08G075/00
CPC分类号： C09J161/06 , C07C45/40 , C07C51/373 , C07C65/30 , C08G8/04 , C08G8/24 , C08L61/06
摘要： Disclosed is a process for modifying cashew nut shell liquid (CNSL) which involves the steps of subjecting the CNSL to ozonolysis to form ozonolysis reaction products, followed by reduction of the ozonolysis reaction products to give a mixture of phenolic components and aldehydes. In a preferred embodiment, the process involves reacting CNSL with ozone to form a mixture containing ozonolysis reaction products, and then treating the mixture under reducing conditions to form a further mixture containing phenolic components with an eight carbon chain having a terminal nullCHO group and alkyl components of varying lengths with either one or two terminal nullCHO groups. The resulting CNSL aldehydes may be used to form adhesives for use in the manufacture of composites such as wood particle board.
摘要翻译：本发明公开了一种改性腰果壳液（CNSL）的方法，该方法涉及以下步骤：使CNSL进行臭氧分解以形成臭氧分解反应产物，然后还原臭氧分解反应产物，得到酚类组分和醛的混合物。在优选的实施方案中，该方法包括使CNSL与臭氧反应以形成含有臭氧分解反应产物的混合物，然后在还原条件下处理该混合物以形成含有具有末端-CHO基团的八个碳链的酚类组分和烷基具有一个或两个末端-CHO基团的不同长度的组分。所得到的CNSL醛可用于形成用于制造复合材料如木材刨花板的粘合剂。

17. 发明授权

US06242057B1 Photoreactor composition and applications therefor 失效
标题翻译：光反应器组成及应用
公开(公告)号：US06242057B1
公开(公告)日：2001-06-05
申请号：US09070126
申请日：1998-04-29
申请人： Ronald Sinclair Nohr , John Gavin MacDonald
发明人： Ronald Sinclair Nohr , John Gavin MacDonald
IPC分类号： C08F250
CPC分类号： G03F7/0295 , C07C51/373 , C07C69/76 , C08F2/50 , G03F7/028 , G03F7/029 , G03F7/031 , Y10T428/2938 , Y10T442/2738 , Y10T442/2861 , C07C65/38
摘要： A method of generating reactive species which includes exposing a wavelength specific photoreactor composition to radiation, in which the wavelength specific photoreactor composition comprises one or more wavelength-specific sensitizers associated with one or more reactive species-generating photoinitiators. Also described are methods of polymerizing unsaturated monomers, methods of curing an unsaturated oligomer/monomer mixture, and methods of laminating.
摘要翻译：一种产生反应物种的方法，其包括将波长特异性光反应器组合物暴露于辐射，其中波长特异性光反应器组合物包含一种或多种与一种或多种产生活性物质的光引发剂相关的波长特异性敏化剂。还描述了聚合不饱和单体的方法，固化不饱和低聚物/单体混合物的方法和层压方法。

18. 发明授权

US5739175A Photoreactor composition containing an arylketoalkene wavelength-specific sensitizer 失效
标题翻译：含有芳基酮酸波长特异性敏化剂的光反应器组合物
公开(公告)号：US5739175A
公开(公告)日：1998-04-14
申请号：US463188
申请日：1995-06-05
申请人： Ronald Sinclair Nohr , John Gavin MacDonald
发明人： Ronald Sinclair Nohr , John Gavin MacDonald
IPC分类号： C07C51/373 , C07C69/76 , G03F7/028 , G03F7/031 , C07C49/794 , C08F2/50
CPC分类号： G03F7/031 , C07C51/373 , C07C69/76 , G03F7/028
摘要： A method of generating reactive species which includes exposing a photoreactor composition to radiation, in which the photoreactor composition comprises a wavelength-specific sensitizer associated with a reactive species-generating photoinitiator. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.
摘要翻译：一种产生反应物种的方法，其包括将光反应器组合物暴露于辐射，其中所述光反应器组合物包含与产生活性物质的光引发剂相关的波长特异性敏化剂。还描述了使不饱和单体聚合并固化不饱和低聚物/单体混合物的方法。

19. 发明授权

US5627247A Organometallic fluorenyl compounds and use thereof in olefin polymerization 失效
标题翻译：有机金属芴基化合物和在烯烃聚合中使用它们的
公开(公告)号：US5627247A
公开(公告)日：1997-05-06
申请号：US408468
申请日：1995-03-22
申请人： Helmut G. Alt , Gil R. Hawley , Paul D. Smith , Syriac J. Palackal , Michael Schmid , M. Bruce Welch , Konstantinos Patsidis , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel
发明人： Helmut G. Alt , Gil R. Hawley , Paul D. Smith , Syriac J. Palackal , Michael Schmid , M. Bruce Welch , Konstantinos Patsidis , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel
IPC分类号： B01J31/22 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/08 , C07F17/00 , C08F4/639 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F10/04
CPC分类号： B01J31/143 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F17/00 , C07F7/0809 , C07F7/0818 , C08F10/00 , C08F210/16 , B01J2531/40 , B01J2531/48 , B01J2531/49 , C07C2101/10 , C07C2101/14 , C07C2101/16 , C07C2103/18 , C08F110/02 , C08F110/06 , C08F4/63912 , C08F4/65912 , C08F4/65925 , Y10S526/943
摘要： Unbridged fluorenyl containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
摘要翻译：含有金属茂桥连芴与用于制备金属茂的方法沿着所公开的。还公开了使用金属茂作为聚合催化剂的方法。此外，从这种聚合得到的聚合物中公开。

20. 发明授权

US5571880A Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process 失效
标题翻译：有机金属芴基化合物及其在α-烯烃聚合方法中的应用
公开(公告)号：US5571880A
公开(公告)日：1996-11-05
申请号：US192223
申请日：1994-02-03
申请人： Helmut G. Alt , Syriac J. Palackal , Roland Zenk , M. Bruce Welch , Michael Schmid
发明人： Helmut G. Alt , Syriac J. Palackal , Roland Zenk , M. Bruce Welch , Michael Schmid
IPC分类号： B01J31/24 , B01J31/22 , C07B61/00 , C07C1/26 , C07C1/32 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F7/00 , C07F7/08 , C07F17/00 , C08F4/60 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16
CPC分类号： C08F210/16 , B01J31/143 , B01J31/2295 , C07C13/567 , C07C22/04 , C07C49/747 , C07C51/31 , C07C51/373 , C07C51/377 , C07C63/331 , C07C63/49 , C07C65/36 , C07F17/00 , C07F7/006 , C07F7/0809 , C07F7/0818 , C08F10/00 , C08F110/06 , C08F4/65927 , B01J2531/40 , B01J2531/48 , B01J2531/49 , B01J2531/50 , B01J2531/60 , C07C2101/10 , C07C2101/14 , C07C2101/16 , C07C2103/18 , C08F110/02 , C08F4/63912 , C08F4/63922 , C08F4/65912 , C08F4/65922 , Y10S526/943
摘要： Fluorenyl-containing metallocenes are disclosed along with methods for making the metallocenes. Also disclosed are methods for using the metallocenes as polymerization catalysts. In addition, polymers resulting from such polymerizations are disclosed.
摘要翻译：公开了含芴基金属茂以及制备金属茂的方法。还公开了使用金属茂作为聚合催化剂的方法。此外，公开了由这种聚合产生的聚合物。

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