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    • 13. 发明授权
    • Silicone rubber powder and method of manufacturing thereof
    • 硅橡胶粉及其制造方法
    • US08217122B2
    • 2012-07-10
    • US12675508
    • 2008-08-19
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • C08J3/24C08G77/12
    • C08K5/5435C08G77/12C08G77/16C08J3/24C08J3/26C08J2383/04C08K5/57C08L83/04C08L83/00
    • A silicone rubber powder obtained by curing a condensation-curable silicone rubber composition in a dispersed state in water, having an epoxy equivalent measured by a titration method equal to or lower than 3,000 and an average particle size in the range of 0.1 to 100 μm; and a method of manufacturing a silicone rubber powder comprising the steps of dispersing in water a silicone rubber composition comprising at least components (A) through (C) listed below; adding component (D); and curing the mixture: (A) a diorganopolysiloxane capped at both molecular terminals with silanol groups and having in one molecule 30 or less silicon atoms; (B) an organopolysiloxane having in one molecule at least two silicon-bonded hydrogen atoms; (C) an epoxy-containing alkoxysilane; and (D) a condensation-reaction catalyst. The silicone rubber powder has low epoxy equivalent and possesses excellent dispersibility in organic resins, and the method is efficient in manufacturing of the aforementioned powder.
    • 将分散状态的可缩合固化硅橡胶组合物在水中固化,通过滴定法测定的环氧当量为3000以下,平均粒径为0.1〜100μm的方法得到的硅橡胶粉末; 和一种制造硅橡胶粉末的方法,包括以下步骤:在水中分散包含至少包含以下列出的组分(A)至(C)的硅橡胶组合物; 添加组分(D); 并固化该混合物:(A)在两个分子末端用硅烷醇基封端并且在一个分子中具有30个或更少硅原子的二有机聚硅氧烷; (B)在一个分子中具有至少两个与硅键合的氢原子的有机聚硅氧烷; (C)含环氧基的烷氧基硅烷; 和(D)缩合反应催化剂。 硅橡胶粉末具有低环氧当量,并且在有机树脂中具有优异的分散性,并且该方法在制备上述粉末中是有效的。
    • 14. 发明申请
    • Silicone Rubber Powder And Method Of Manufacturing Thereof
    • 硅橡胶粉及其制造方法
    • US20100216952A1
    • 2010-08-26
    • US12675508
    • 2008-08-19
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • C08J3/24C08G77/12
    • C08K5/5435C08G77/12C08G77/16C08J3/24C08J3/26C08J2383/04C08K5/57C08L83/04C08L83/00
    • A silicone rubber powder obtained by curing a condensation-curable silicone rubber composition in a dispersed state in water, having an epoxy equivalent measured by a titration method equal to or lower than 3,000 and an average particle size in the range of 0.1 to 100 μm; and a method of manufacturing a silicone rubber powder comprising the steps of dispersing in water a silicone rubber composition comprising at least components (A) through (C) listed below; adding component (D); and curing the mixture: (A) a diorganopolysiloxane capped at both molecular terminals with silanol groups and having in one molecule 30 or less silicon atoms; (B) an organopolysiloxane having in one molecule at least two silicon-bonded hydrogen atoms; (C) an epoxy-containing alkoxysilane; and (D) a condensation-reaction catalyst. The silicone rubber powder has low epoxy equivalent and possesses excellent dispersibility in organic resins, and the method is efficient in manufacturing of the aforementioned powder.
    • 将分散状态的可缩合固化硅橡胶组合物在水中固化,通过滴定法测定的环氧当量为3000以下,平均粒径为0.1〜100μm的方法得到的硅橡胶粉末; 和一种制造硅橡胶粉末的方法,包括以下步骤:在水中分散包含至少包含以下列出的组分(A)至(C)的硅橡胶组合物; 添加组分(D); 并固化该混合物:(A)在两个分子末端用硅烷醇基封端并且在一个分子中具有30个或更少硅原子的二有机聚硅氧烷; (B)在一个分子中具有至少两个与硅键合的氢原子的有机聚硅氧烷; (C)含环氧基的烷氧基硅烷; 和(D)缩合反应催化剂。 硅橡胶粉末具有低环氧当量,并且在有机树脂中具有优异的分散性,并且该方法在制备上述粉末中是有效的。
    • 15. 发明申请
    • Aqueous emulsion comprising an organosilicon polymer, process for producing the same and cosmetic materials
    • 包含有机硅聚合物的水乳液,其制备方法和化妆品材料
    • US20060104929A1
    • 2006-05-18
    • US10526184
    • 2003-09-12
    • Yoshitsugu MoritaKazuo KobayashiMasaru OzakiYasue Mitzutani
    • Yoshitsugu MoritaKazuo KobayashiMasaru OzakiYasue Mitzutani
    • A61K8/89
    • A61K8/895A61K8/062A61K8/92A61Q5/00A61Q19/00
    • An aqueous emulsion comprises as the disperse phase obtained by emulsifying a mixture consisting of (A) a linear organosilicon polymer whose main chain is composed of diorganosiloxane units and alkylene units and (B) an oil that is liquid at room temperature. The emulsion can be produced by emulsifying a mixture of (a) a diorganopolysiloxane having silicon-bonded hydrogen atoms at the two ends of the molecular chain, (b) a diolefin or diorganopolysiloxane having silicon-bonded alkenyl groups at the two ends of the molecular chain, and (c) an oil that is liquid at room temperature and does not contain hydrosilation-reactive groups, in water, and, in this state, component (a) and component (b) are addition-polymerized using (d) a hydrosilation reaction catalyst. Cosmetic materials incorporating such aqueous emulsions possess excellent lubricating properties, good dispersibility, and adherence; a method of preparation of the emulsion; and skin and hair cosmetic materials prepared from the emulsion with excellent sensation of smoothness and moistness to the touch.
    • 水乳液包含通过乳化由(A)主链由二有机硅氧烷单元和亚烷基单元构成的直链有机硅聚合物和(B)在室温下为液体的油的混合物而获得的分散相。 乳液可以通过在(a)在分子链的两端具有与硅键合的氢原子的二有机聚硅氧烷的混合物(b)在分子的两端具有硅键合的烯基的二烯烃或二有机聚硅氧烷, 链和(c)在室温下为液体并且在水中不含硅氢化反应性基团的油,并且在该状态下,组分(a)和组分(b))使用(d)a 硅氢化反应催化剂。 掺入这种水性乳液的化妆品具有优异的润滑性能,良好的分散性和粘附性; 乳液的制备方法; 并且由乳液制备的皮肤和头发化妆品具有优异的光滑感和湿润感。