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    • 13. 发明授权
    • Spherical crosslinked organic particles suspensions and methods of preparing spherical crosslinked organic particles and suspensions
    • 球形交联有机颗粒悬浮液和制备球形交联有机颗粒和悬浮液的方法
    • US06531542B1
    • 2003-03-11
    • US09626135
    • 2000-07-26
    • Yoshitsugu MoritaKazuo KobayashiRyuji Tachibana
    • Yoshitsugu MoritaKazuo KobayashiRyuji Tachibana
    • C08L8304
    • A61K8/891A61K8/86A61K2800/594A61Q19/00C08J3/05C08J3/12C08J3/26C08J2383/10
    • Spherical crosslinked organic particles exhibit a good dispersibility in thermoplastic resins, thermosetting resins, paints, coatings, cosmetics, rubbers, and toners and carriers employed in electrostatic development. Highly efficient methods for preparing these crosslinked organic particles are provided. Suspensions of crosslinked organic particles have excellent handling properties, and are highly blendable with other components. Highly efficient methods for preparing these suspensions are also provided. The spherical crosslinked organic particles have an average particle size of 0.1-500 &mgr;m, and can be prepared by emulsifying in water using an emulsifying agent, a fluid composition containing (A) an organic compound that has at least 2 aliphatically unsaturated bonds in each molecule, (B) a silicon-containing organic compound that has at least 2 silicon-bonded hydrogen atoms in each molecule, (C) an hydrosilylation reaction catalyst, crosslinking the fluid composition by carrying out an hydrosilylation reaction, and thereafter removing water.
    • 球形交联的有机颗粒在用于静电显影的热塑性树脂,热固性树脂,油漆,涂料,化妆品,橡胶和调色剂和载体中表现出良好的分散性。 提供了制备这些交联的有机颗粒的高效方法。 交联有机颗粒的悬浮液具有优异的处理性能,并且与其它组分高度可混合。 还提供了制备这些悬浮液的高效方法。 球形交联有机颗粒的平均粒径为0.1-500μm,并且可以通过使用乳化剂在水中乳化,含有(A)在各分子中具有至少2个不饱和键的有机化合物的流体组合物 ,(B)在每个分子中具有至少2个与硅键合的氢原子的含硅有机化合物,(C)氢化硅烷化反应催化剂,通过进行氢化硅烷化反应使流体组合物交联,然后除去水。
    • 16. 发明授权
    • Method of treating hair or skin
    • 治疗头发或皮肤的方法
    • US06461597B1
    • 2002-10-08
    • US09707512
    • 2000-11-07
    • Yoshitsugu MoritaKazuo KobayashiOzaki Masaru
    • Yoshitsugu MoritaKazuo KobayashiOzaki Masaru
    • A61K706
    • A61K8/894A61K8/025A61K8/89A61K8/891A61K2800/412A61Q1/02A61Q1/08A61Q5/00A61Q5/02A61Q19/00Y10S424/02Y10S514/88Y10S514/951
    • A cosmetic consists of a cosmetic raw material in the form of an emulsion of silicone or organic oil containing crosslinked particles mixed with other cosmetic raw materials. Its touch on fingers and skin is good, spreading and feel during use are good, and it can also prevent unruly hair, stray hair, and tangling of hair, so hair can easily be arranged. It imparts a fresh, dry feeling without any stickiness. The cosmetic raw material consists of the silicone or organic oil emulsion containing crosslinked particles with a mean particle diameter of 0.05 to 100 &mgr;m. Crosslinking is obtained by an hydrosilylation of liquid crosslinkable compositions consisting of (A) organic compounds with at least two aliphatic unsaturated bonds per molecule, (B) silicon containing organic compounds with at least two hydrogen atoms bonded to silicon atoms in each molecule, and (C) hydrosilylation reaction catalysts. The resulting crosslinked particles are contained in the droplets of the silicone oil or the organic oil which have mean particle sizes of 0.1 to 500 &mgr;m, and which droplets are in turn dispersed in water.
    • 化妆品由含有与其他化妆品原料混合的交联颗粒的硅氧烷或有机油的乳液形式的化妆品原料组成。 它的手指和皮肤触感好,使用过程中的传播和感觉都很好,还可以防止头发不稳定,流淌毛发和头发缠结,所以头发很容易安排。 它赋予新鲜,干燥的感觉,没有任何粘性。 化妆品原料由含有平均粒径为0.05〜100μm的交联颗粒的有机硅乳液或有机油乳液组成。 通过由(A)每分子具有至少两个脂肪族不饱和键的有机化合物组成的液体可交联组合物的氢化硅烷化获得交联,(B)具有至少两个与每个分子中的硅原子键合的氢原子的含硅有机化合物和(B) C)氢化硅烷化反应催化剂。 所得到的交联颗粒包含在平均粒度为0.1-500μm的硅油或有机油的液滴中,并且这些液滴又分散在水中。
    • 18. 发明授权
    • Resin additive, curable resin composition, and cured resin
    • 树脂添加剂,可固化树脂组合物和固化树脂
    • US06239245B1
    • 2001-05-29
    • US09507867
    • 2000-02-22
    • Yoshitsugu MoritaKazuo KobayashiHiroshi UekiHaruhiko Furukawa
    • Yoshitsugu MoritaKazuo KobayashiHiroshi UekiHaruhiko Furukawa
    • C08G7708
    • C08J3/26C08J3/12C08J2383/04
    • There is provided (i) a resin additive able to impart superior thermal shock resistance even in the case of resins that have absorbed moisture, (ii) a curable resin composition capable of forming a cured resin that has superior thermal shock resistance even after absorbing moisture, and (iii) a cured resin that has superior thermal shock resistance even after absorbing moisture. The resin additive consists of a powder with a mean particle size of 0.1 to 100 &mgr;m of silicone rubber. It has a moisture absorption rate of 0.20 weight percent or less after being treated for 20 hours at a temperature of about 121° C., a pressure of two atmospheres, and a relative humidity of 100 percent. The curable resin composition contains the resin additive, and the cured resin is formed by curing the curable resin composition.
    • 提供(i)即使在吸收了水分的树脂的情况下也能赋予优异的耐热冲击性的树脂添加剂,(ii)能够形成具有优异的耐热冲击性的固化树脂的固化性树脂组合物,即使在吸收水分后 ,和(iii)即使在吸收水分后也具有优异的耐热冲击性的固化树脂。 树脂添加剂由平均粒径为0.1〜100μm的硅橡胶的粉末构成。 在约121℃,两个大气压,相对湿度为100%的温度下处理20小时后,其吸湿率为0.20重量%以下。 固化性树脂组合物含有树脂添加剂,固化树脂通过使固化性树脂组合物固化而形成。
    • 19. 发明授权
    • Silicone rubber powder and method of manufacturing thereof
    • 硅橡胶粉及其制造方法
    • US08217122B2
    • 2012-07-10
    • US12675508
    • 2008-08-19
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • C08J3/24C08G77/12
    • C08K5/5435C08G77/12C08G77/16C08J3/24C08J3/26C08J2383/04C08K5/57C08L83/04C08L83/00
    • A silicone rubber powder obtained by curing a condensation-curable silicone rubber composition in a dispersed state in water, having an epoxy equivalent measured by a titration method equal to or lower than 3,000 and an average particle size in the range of 0.1 to 100 μm; and a method of manufacturing a silicone rubber powder comprising the steps of dispersing in water a silicone rubber composition comprising at least components (A) through (C) listed below; adding component (D); and curing the mixture: (A) a diorganopolysiloxane capped at both molecular terminals with silanol groups and having in one molecule 30 or less silicon atoms; (B) an organopolysiloxane having in one molecule at least two silicon-bonded hydrogen atoms; (C) an epoxy-containing alkoxysilane; and (D) a condensation-reaction catalyst. The silicone rubber powder has low epoxy equivalent and possesses excellent dispersibility in organic resins, and the method is efficient in manufacturing of the aforementioned powder.
    • 将分散状态的可缩合固化硅橡胶组合物在水中固化,通过滴定法测定的环氧当量为3000以下,平均粒径为0.1〜100μm的方法得到的硅橡胶粉末; 和一种制造硅橡胶粉末的方法,包括以下步骤:在水中分散包含至少包含以下列出的组分(A)至(C)的硅橡胶组合物; 添加组分(D); 并固化该混合物:(A)在两个分子末端用硅烷醇基封端并且在一个分子中具有30个或更少硅原子的二有机聚硅氧烷; (B)在一个分子中具有至少两个与硅键合的氢原子的有机聚硅氧烷; (C)含环氧基的烷氧基硅烷; 和(D)缩合反应催化剂。 硅橡胶粉末具有低环氧当量,并且在有机树脂中具有优异的分散性,并且该方法在制备上述粉末中是有效的。
    • 20. 发明申请
    • Silicone Rubber Powder And Method Of Manufacturing Thereof
    • 硅橡胶粉及其制造方法
    • US20100216952A1
    • 2010-08-26
    • US12675508
    • 2008-08-19
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • Yoshitsugu MoritaKazuo KobayashiKen Tanaka
    • C08J3/24C08G77/12
    • C08K5/5435C08G77/12C08G77/16C08J3/24C08J3/26C08J2383/04C08K5/57C08L83/04C08L83/00
    • A silicone rubber powder obtained by curing a condensation-curable silicone rubber composition in a dispersed state in water, having an epoxy equivalent measured by a titration method equal to or lower than 3,000 and an average particle size in the range of 0.1 to 100 μm; and a method of manufacturing a silicone rubber powder comprising the steps of dispersing in water a silicone rubber composition comprising at least components (A) through (C) listed below; adding component (D); and curing the mixture: (A) a diorganopolysiloxane capped at both molecular terminals with silanol groups and having in one molecule 30 or less silicon atoms; (B) an organopolysiloxane having in one molecule at least two silicon-bonded hydrogen atoms; (C) an epoxy-containing alkoxysilane; and (D) a condensation-reaction catalyst. The silicone rubber powder has low epoxy equivalent and possesses excellent dispersibility in organic resins, and the method is efficient in manufacturing of the aforementioned powder.
    • 将分散状态的可缩合固化硅橡胶组合物在水中固化,通过滴定法测定的环氧当量为3000以下,平均粒径为0.1〜100μm的方法得到的硅橡胶粉末; 和一种制造硅橡胶粉末的方法,包括以下步骤:在水中分散包含至少包含以下列出的组分(A)至(C)的硅橡胶组合物; 添加组分(D); 并固化该混合物:(A)在两个分子末端用硅烷醇基封端并且在一个分子中具有30个或更少硅原子的二有机聚硅氧烷; (B)在一个分子中具有至少两个与硅键合的氢原子的有机聚硅氧烷; (C)含环氧基的烷氧基硅烷; 和(D)缩合反应催化剂。 硅橡胶粉末具有低环氧当量,并且在有机树脂中具有优异的分散性,并且该方法在制备上述粉末中是有效的。