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    • 11. 发明授权
    • Process for producing amorphous alloy material
    • 生产非晶合金材料的方法
    • US5296059A
    • 1994-03-22
    • US943703
    • 1992-09-11
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • Tsuyoshi MasumotoAkihisa InoueJunichi NagahoraKazuhiko Kita
    • C22C45/00B22F3/00C22C1/00C22C45/08C22F1/00C22F1/04C22F1/06C22F1/18
    • C22F1/186B22F3/006C22C1/00C22F1/00C22F1/04C22F1/06C22F1/18C21D2201/03
    • A process for producing an amorphous alloy material characterized by imparting ductility to an amorphous alloy having a supercooled liquid region by giving a prescribed amount of strain at a prescribed strain rate to the alloy in the glass transition temperature region of the alloy. The amorphous alloy may be in the form of spherical or irregular-shaped powders or thin ribbons or in the form of primary consolidated shapes thereof or an amorphous alloy casting. The amount of strain and strain rate are preferably 50% or greater and 2.times.10.sup.-2 /sec or higher, respectively, and the worked amorphous alloy material is preferably allowed to cool in a furnace or spontaneously. Suitable examples of the amorphous alloy to be employed include Al-TM-Ln, Mg-TM-Ln, Zr-TM-Al and Hf-TM-Al alloys, wherein TM is a transition metal element and Ln is a rare earth metal element. The thus obtained amorphous alloy is greatly improved in the prevention of embrittlement in hot working peculiar to the alloy.
    • 一种非晶态合金材料的制造方法,其特征在于,在合金的玻璃化转变温度区域中,通过以规定的应变速率向合金赋予规定量的应变率,赋予具有过冷液体区域的非晶质合金的延展性。 非晶合金可以是球形或不规则形状的粉末或薄带的形式,或者是其主要固结形状或非晶态合金铸件的形式。 应变量和应变速率分别优选为50%以上且2×10 -2 /秒以上,加工后的非晶态合金材料优选在炉内自发冷却。 所使用的非晶合金的合适实例包括Al-TM-Ln,Mg-TM-Ln,Zr-TM-Al和Hf-TM-Al合金,其中TM是过渡金属元素,Ln是稀土金属元素 。 由此获得的非晶态合金在防止合金特有的热加工中脆化方面大大提高。
    • 12. 发明授权
    • Aluminum alloy powders for coating materials, and coating materials
containing the alloy powders
    • 用于涂料的铝合金粉末和含有合金粉末的涂料
    • US5198042A
    • 1993-03-30
    • US791572
    • 1991-11-12
    • Tsuyoshi MasumotoAkihisa InoueKazuhiko KitaYoshio HarakawaMasahiro Oguchi
    • Tsuyoshi MasumotoAkihisa InoueKazuhiko KitaYoshio HarakawaMasahiro Oguchi
    • B22F1/00B22F9/00B22F9/10C09C1/62C09C1/64C22C1/04C22C45/08C23C4/04C23C4/12
    • C22C1/0416B22F9/008B22F9/10C09C1/62C09C1/622C23C4/04C23C4/123B22F2009/084C01P2002/02C01P2002/70C01P2004/03C01P2004/54C01P2004/61C01P2004/62C01P2006/11C01P2006/22C01P2006/60C01P2006/90Y10T428/256
    • An aluminum alloy powder for coating materials and a coating material containing the aluminum alloy powder. The aluminum alloy powder comprises an amorphous aluminum alloy consisting essentially of from 83 to 91% of Al, from 0.5 to 5% of Ca and from 8 to 12% of Ni, all in atom %, and comprising a leaf-shaped particle having a thickness of 0.3 to 3 .mu.m, a minor axis of from 10 to 150 .mu.m, a ratio of the minor axis to a major axis of from 1 to 3, and an aspect ratio which is the ratio of the minor axis to the thickness of from 3 to 100, wherein the aluminum alloy powder is contained in an amount of from 5 to 25 parts by weight based on 100 parts by weight of the total weight of (i) the coating material resin component and (ii) aluminum alloy powder, and the coating material resin component is selected from the group consisting of a water-based synthetic latex and a water-soluble resin. The aluminum alloy powder has a superior dispersibility in a resin in a coating material. When added to a coating material and then coated, the aluminum alloy powder can bring about leafing in a desirable state, so that the coating surface can be effectively covered with the powder. The aluminum alloy powder can impart better hiding power and reflecting properties, even when added in a smaller quantity than conventional powders. Since the aluminum alloy powder is comprised of an amorphous alloy, it does not cause deterioration of reflecting properties, even when used in coating materials containing water-soluble solvents.
    • 用于涂料的铝合金粉末和含有铝合金粉末的涂料。 所述铝合金粉末包含非晶态铝合金,其基本上由Al:83〜91%,0.5〜5%的Ca和8〜12%的Ni组成,全部为原子%,并且包含具有 厚度为0.3〜3μm,短轴为10〜150μm,短轴与长轴的比例为1〜3,纵轴比与纵轴的长径比 为3〜100,其中,相对于(i)涂料树脂成分和(ii)铝合金粉末的总重量的100重量份,铝合金粉末的含量为5〜25重量份 涂料树脂成分选自水性合成胶乳和水溶性树脂。 铝合金粉末在涂料中的树脂中具有优异的分散性。 当添加到涂料中然后涂覆时,铝合金粉末可以在期望的状态下带来漂浮,从而可以用粉末有效地覆盖涂层表面。 铝合金粉末即使加入比常规粉末更少的量,也能赋予更好的遮盖力和反射性能。 由于铝合金粉末是由非晶合金组成的,所以即使在含有水溶性溶剂的涂料中使用也不会引起反射性能的劣化。
    • 14. 发明授权
    • High strength and high rigidity aluminum-based alloy
    • 高强度高刚性铝基合金
    • US06017403A
    • 2000-01-25
    • US601949
    • 1996-02-15
    • Tsuyoshi MasumotoAkihisa InoueYuma Horio
    • Tsuyoshi MasumotoAkihisa InoueYuma Horio
    • C22C21/00
    • C22C21/00
    • An aluminum-based alloy having the general formula Al.sub.x L.sub.y M.sub.z (wherein L is Mn or Cr; M is Ni, Co, and/or Cu; and x, y, and z, representing a composition ratio in atomic percentages, satisfy the relationships x+y+z=100, 75.ltoreq.x.ltoreq.95, 2.ltoreq.y.ltoreq.15, and 0.5.ltoreq.z.ltoreq.10) having a metallographic structure comprising a quasi-crystalline phase possesses high strength and high rigidity. In order to enhance the ductility and toughness of the aluminum-based alloy, the atomic percentage of M may be further limited to 0.5.ltoreq.z.ltoreq.4, and more preferably to 0.5.ltoreq.z.ltoreq.3. The aluminum-based alloy is useful as a structural material for aircraft, vehicles and ships, and for engine parts; as material for sashes, roofing materials, and exterior materials for use in construction; or as materials for use in marine equipment, nuclear reactors, and the like.
    • 具有通式AlxLyMz(其中L是Mn或Cr; M是Ni,Co和/或Cu;和表示原子百分比的组成比的x,y和z)的铝基合金满足关系x + 具有包含准结晶相的金相组织的y + z = 100,75,或者= x,y = x,z = 100,75
    • 19. 发明授权
    • Sacrificial electrode material for corrosion prevention
    • 用于防腐的牺牲电极材料
    • US5423969A
    • 1995-06-13
    • US217009
    • 1994-03-23
    • Tsuyoshi MasumotoAkihisa InoueTakashi SakumaToshisuke Shibata
    • Tsuyoshi MasumotoAkihisa InoueTakashi SakumaToshisuke Shibata
    • C22C23/00C22C45/00C23F13/00C23F13/14C25B11/04
    • C23F13/14
    • The present invention provides a sacrificial electrode material which consists of a single phase amorphous structure or a structure consisting of an amorphous phase and a crystalline solid solution phase and provides electrochemical corrosion protection to metallic articles exposed to an aqueous electrolytic solution. The electrode material is prepared by rapidly quenching a magnesium-based alloy material from the liquid phase or vapor phase thereof, the magnesium-based alloy material consisting the general formula: Mg.sub.bal X1.sub.a X2.sub.b or Mg.sub.bal X1.sub.a, wherein X1 is at least one element selected from the group consisting of Al, Zn, Ga, Ca and In; X2 is at least one element selected from the group consisting of Mm (misch metal), Y and rare earth metal elements; a and b are, in atomic percentages, 5.0.ltoreq.a.ltoreq.35.0 and 3.0.ltoreq.b.ltoreq.25.0, respectively. The magnesium-based alloy material may further contain one or more transition metal elements in their total contents not exceeding 1.0 atomic %.
    • 本发明提供一种牺牲电极材料,其由单相无定形结构或由非晶相和结晶固溶体相组成的结构组成,并且对暴露于水性电解液的金属制品提供电化学腐蚀保护。 通过从其液相或气相快速淬火镁基合金材料制备电极材料,镁基合金材料由以下通式组成:MgbalX1aX2b或MgbalX1a,其中X1是选自以下的至少一种元素: 的Al,Zn,Ga,Ca和In; X2是选自由Mm(混合稀土金属),Y和稀土金属元素组成的组中的至少一种元素; a和b分别为原子百分比为5.0