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    • 11. 发明授权
    • Photographic element, dispersion, compound and process
    • 摄影元素,分散体,复合物和工艺
    • US06190851B1
    • 2001-02-20
    • US09473790
    • 1999-12-28
    • John W. HarderJames S. HonanAlbert J. Mura
    • John W. HarderJames S. HonanAlbert J. Mura
    • G03C108
    • G03C7/346G03C7/3885
    • Disclosed is a photographic element complising a light sensitive silver halide emulsion layer having associated therewith a cyan dye forming coupler having Formula (I): wherein R1 and R3 independently represent hydrogen or an alkyl group; R2 represents a carbocyclic or heterocyclic aromatic group; n represents 1, 2, or 3; each X is an independently selected substituent where at least one X located at a position of the phenyl ring meta or para to the sulfonyl group and is either an alkoxy group having a branched carbon or an aiyloxy group; and Z represents hydrogen or a group that can be split off by the reaction of the coupler with an oxidized color-developing compound; provided that the substituents of the compound of formula (I) are selected so that the compound has a melting point of 160° C. or less. The element provides improved phase stability during manufacturing while exhibiting satisfactory hue and dye light stability.
    • 公开了一种照相元件,其与具有式(I)的蓝色染料形成成色剂相关联的感光卤化银乳剂层:其中R1和R3独立地表示氢或烷基; R2表示碳环或杂环芳族基团; n表示1 ,2或3;每个X是独立选择的取代基,其中至少一个X位于苯环的位置上位于磺酰基的间位或对位,并且是具有支链碳或芳氧基的烷氧基; 并且Z表示氢或可通过偶合剂与氧化显色化合物的反应而分离的基团;条件是选择式(I)化合物的取代基使化合物的熔点为160℃ C.或更少。该元件在制造过程中提供改善的相稳定性,同时具有令人满意的色调和染料光稳定性。
    • 12. 发明授权
    • Photographic element having improved magenta dye light stability and
process for its use
    • 具有改善的品红染料光稳定性的照相元件及其使用方法
    • US5925503A
    • 1999-07-20
    • US784851
    • 1997-01-15
    • John W. HarderPaul A. BurnsPaul P. Spara
    • John W. HarderPaul A. BurnsPaul P. Spara
    • G03C7/38G03C7/46
    • G03C7/3835
    • The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: ##STR1## wherein X is hydrogen or a coupling-off group; andR' is a tertiary alkyl group and R" represents the group ##STR2## in which R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2, and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent; andW is a substituent selected from the group consisting of --C(O)R.sup.5, --SO.sub.2 R.sup.5, and --P(O)(OR.sup.6).sub.2 in which R.sup.5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R.sup.6 is selected from the group consisting of alkyl and aryl groups.The element exhibits improved magenta dye light stability.
    • 本发明提供了一种照相元件,其包含卤化银乳剂层,其具有与式I化合物形成的染料形成成色剂:其中X为氢或偶合离去基团; 并且R'是叔烷基,R“表示其中R 1,R 2和R 3是独立选择的烷基的基团,条件是R 1,R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基,条件是当R 4为取代基时,R 3和R 4可以连接形成环; 并且W是选自-C(O)R 5,-SO 2 R 5和-P(O)(OR 6)2的取代基,其中R 5选自烷基,芳基,烷氧基,芳氧基,烷基氨基 和芳基氨基,R 6选自烷基和芳基。 该元件表现出改善的品红染料光稳定性。