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11. 发明授权

US06287696B1 Resin composition for a fiber reinforced composite, a prepreg and a fiber reinforced composite 失效
标题翻译：用于纤维增强复合材料，预浸料和纤维增强复合材料的树脂组合物
公开(公告)号：US06287696B1
公开(公告)日：2001-09-11
申请号：US09063453
申请日：1998-04-21
申请人： Shunsaku Noda , Hiroki Oosedo , Nobuaki Oki
发明人： Shunsaku Noda , Hiroki Oosedo , Nobuaki Oki
IPC分类号： B32B904
CPC分类号： C08L63/00 , C08J5/24 , C08L101/00 , Y10T428/2916 , Y10T428/2918 , Y10T428/30 , Y10T428/31504 , Y10T428/31511 , Y10T428/31551 , Y10T428/31743 , Y10T428/31765 , Y10T428/31797 , Y10T428/31862 , Y10T428/31873 , Y10T428/31877 , C08L2666/02 , C08L2666/04
摘要： The invention provides a resin composition for a fiber reinforced composite which can be used to produce a prepreg excellent in tackiness, drapability and windability around a mandrel, and also provides a prepreg in which reinforcing fibers are impregnated with a resin composition, and a fiber reinforced composite obtained from them. The resin composition includes a thermosetting resin and a thermoplastic resin with a weight average molecular weight of 200,000 to 5,000,000.
摘要翻译：本发明提供了一种用于纤维增强复合材料的树脂组合物，其可用于生产在心轴周围具有优异的粘合性，悬垂性和卷绕性优异的预浸料，并且还提供了预浸料，其中增强纤维被树脂组合物浸渍，并且增强了纤维从他们获得的复合材料。树脂组合物包括热固性树脂和重均分子量为200,000至5,000,000的热塑性树脂。

12. 发明授权

US06515081B2 Composition of epoxy resin, curing agent and reactive compound 失效
标题翻译：环氧树脂，固化剂和反应性化合物的组成
公开(公告)号：US06515081B2
公开(公告)日：2003-02-04
申请号：US09319902
申请日：1999-06-14
申请人： Hiroki Oosedo , Ryuji Sawaoka , Shunsaku Noda , Naomi Miyoshi
发明人： Hiroki Oosedo , Ryuji Sawaoka , Shunsaku Noda , Naomi Miyoshi
IPC分类号： B32B2704
CPC分类号： C08J5/24 , C08G59/40 , C08J2363/00 , C08L67/06 , Y10T428/24994 , Y10T428/249952
摘要： A thermosetting resin composition for carbon fiber reinforced composite materials of the present invention chiefly comprises (A)2 thermosetting resin such as epoxy resin and a curing agent, and (B)2 compound containing one functional group which can react with thermosetting resin (A) or its curing agent, and a moiety selected from the following formulae (1) to (4) Furthermore, the present invention also relates to a prepreg formed by impregnating reinforcing fiber with the aforesaid resin composition and to carbon fiber reinforced composite materials comprising reinforcing fiber and a cured aforesaid thermosetting resin composition.
摘要翻译：本发明的碳纤维增强复合材料用热固性树脂组合物主要包含（A）2种环氧树脂等热固性树脂和固化剂，（B）2种含有可与热固性树脂（A）反应的一种官能团的化合物，或其固化剂和选自下式（1）至（4）的部分。此外，本发明还涉及通过用上述树脂组合物浸渍增强纤维和由增强纤维制成的碳纤维增强复合材料形成的预浸料和上述固化的热固性树脂组合物。

13. 发明授权

US5543212A Prepregs comprising a reinforcing fiber layer, a knitted fabric of thermoplastic fibers and a matrix resin 失效
标题翻译：包含增强纤维层，热塑性纤维的针织物和基质树脂的预浸料
公开(公告)号：US5543212A
公开(公告)日：1996-08-06
申请号：US339599
申请日：1994-11-14
申请人： Hiroki Oosedo , Nobuyuki Odagiri
发明人： Hiroki Oosedo , Nobuyuki Odagiri
IPC分类号： B29B11/16 , B29C70/08 , B32B5/12 , B32B5/14 , B32B27/04 , C08J5/04 , C08J5/24 , D03D3/00 , B32B5/02 , B32B7/00
CPC分类号： C08J5/24 , B29C70/083 , B32B5/12 , C08J5/047 , B29K2101/10 , B29K2105/08 , B29K2105/0836 , B29K2301/12 , Y10S428/902 , Y10T442/494
摘要： The present invention relating to prepegs has the following constitution to achieve the above object. That is, a prepreg, comprising long reinforcing fibers [A], matrix resin [B] and a knitted fabric made from thermoplastic resin fibers [C], with the component [C] distributed near either or both of the surface layers. Moreover, the present invention relating to processes for production of prepregs has either of the following constitution to achieve the above object. That is, a process for preparing a prepreg, comprising the steps of impregnating long reinforcing fibers [A] with matrix resin [B], and bonding a knitted fabric made from thermoplastic resin fibers [C] onto one side or both sides of the intermediate product, or a process for preparing a prepreg, comprising the step of bonding matrix resin [B] formed as a film, a knitted fabric made from thermoplastic resin fibers [C] and long reinforcing fibers [A]. The prepregs of the present invention, therefore, are tacky and drapable, and the composite materials obtained by heating and forming the prepregs are high in heat resistance, and very high in impact resistance and inter-layer toughness. Furthermore, the prepregs are easy to produce and high in their latitude in availability of materials, this being industrially significant.
摘要翻译：涉及预制物的本发明具有以下结构以实现上述目的。也就是说，包含长增强纤维[A]，基质树脂[B]和由热塑性树脂纤维[C]制成的针织物的预浸料，其中组分[C]分布在表面层的一个或两个附近。此外，与制造预浸料坯的方法相关的本发明具有以下结构以实现上述目的。也就是说，制备预浸料的方法包括以下步骤：用基质树脂[B]浸渍长增强纤维[A]，并将由热塑性树脂纤维[C]制成的针织物粘合到中间体的一侧或两侧产品或制备预浸料的方法，包括将由热塑性树脂纤维[C]和长增强纤维[A]制成的针织物与作为膜形成的基质树脂[B]接合的步骤。因此，本发明的预浸料具有粘性和悬垂性，通过加热和形成预浸料获得的复合材料的耐热性高，耐冲击性和层间韧性非常高。此外，预浸料容易生产，在材料可用性方面的纬度高，这在工业上是显着的。

14. 发明申请

US20080160860A1 Epoxy Resin Composition for Fiber-Reinforced Composite Material, Prepreg, and Fiber-Reinforced Composite Material 审中-公开
标题翻译：纤维增强复合材料，预浸料和纤维增强复合材料的环氧树脂组合物
公开(公告)号：US20080160860A1
公开(公告)日：2008-07-03
申请号：US10591165
申请日：2005-03-02
申请人： Motohiro Kuroki , Nobuyuki Tomioka , Naomi Wadahara , Kenichi Yoshioka , Hiroaki Sakata , Eisuke Wadahara , Hiroki Oosedo
发明人： Motohiro Kuroki , Nobuyuki Tomioka , Naomi Wadahara , Kenichi Yoshioka , Hiroaki Sakata , Eisuke Wadahara , Hiroki Oosedo
IPC分类号： B32B5/24 , B32B27/12 , C08L63/00
CPC分类号： C08J5/24 , B29K2063/00 , B32B3/12 , B32B5/022 , B32B27/08 , B32B27/12 , B32B27/18 , B32B27/26 , B32B27/38 , B32B2264/0207 , B32B2307/31 , B32B2307/538 , B32B2307/5825 , B32B2605/08 , B32B2605/18 , C08G59/3227 , C08G59/3236 , C08J5/048 , C08J2363/00 , C08L63/00 , Y10T428/24994 , Y10T442/647 , C08L2666/04
摘要： The invention provides epoxy resin composition containing, as epoxy resin, the following epoxy resin (a) and epoxy resin (b), solid rubber at a ratio of 1 to 20 parts by weight to 100 parts by weight of the entire epoxy resins, and an aromatic amine as a curing agent and having a glass transition temperature of 160 to 220° C. in form of a cured material after heat curing at 180° C. for 2 hours: (a) an epoxy resin having oxazolidone rings and (b) a glycidylamine type epoxy resin.
摘要翻译：本发明提供环氧树脂组合物，作为环氧树脂包含以下环氧树脂（a）和环氧树脂（b），固体橡胶的比例为1至20重量份，相对于整个环氧树脂为100重量份，以及芳香胺作为固化剂，并且在180℃下热固化2小时后，固化物的玻璃化转变温度为160〜220℃。（a）具有恶唑烷酮环的环氧树脂和（b ）缩水甘油胺型环氧树脂。

15. 发明授权

US5985431A Prepreg, and a fiber reinforced composite material 失效
标题翻译：预浸料和纤维增强复合材料
公开(公告)号：US5985431A
公开(公告)日：1999-11-16
申请号：US682761
申请日：1996-12-10
申请人： Hiroki Oosedo , Atsushi Ozaki , Hideo Nagata
发明人： Hiroki Oosedo , Atsushi Ozaki , Hideo Nagata
IPC分类号： C08G59/20 , C08G59/32 , C08G59/38 , C08G59/50 , C08J5/24 , C08L63/00 , B32B27/04 , B32B5/16 , B32B27/38
CPC分类号： C08J5/24 , C08G59/20 , C08G59/3227 , C08G59/38 , C08G59/5033 , C08L63/00 , C08J2363/00 , Y10T428/24994 , Y10T428/25 , Y10T428/254 , Y10T428/31511 , Y10T428/31721 , Y10T428/31725 , Y10T428/31728 , Y10T428/31786 , Y10T428/31942
摘要： A prepreg comprising (a) reinforcing fibers and (b) a matrix resin which comprises specific epoxy resin composition, a curing agent with a specific structure and a highly heat resistant thermoplastic resin, the cured product of which has a low water absorption. An interlayer toughened prepreg containing reinforcing fibers and a matrix resin comprising a specific epoxy resin composition, a hardening agent with a specific structure and a highly heat resistant thermoplastic resin is also provided. In addition, a cured product can be obtained by curing any of the above prepregs, which product satisfies both impact resistance (residual compressive strength after impact) and heat and wet property (compressive strength of notched coupon at high temperature and high humidity) at high levels, even though these properties have been in contradictory relation in the conventional techniques.
摘要翻译： PCT No.PCT / JP95 / 02474。 371日期1996年12月10日第 102（e）日期1996年12月10日PCT 1995年12月4日PCT PCT。公开号WO96 / 日期：1996年6月6日一种预浸料，其包含（a）增强纤维和（b）包含特定环氧树脂组合物的基质树脂，具有特定结构的固化剂和高耐热性热塑性树脂，其固化产物具有低吸水。还提供了含有增强纤维的层间增韧预浸料和包含特定环氧树脂组合物的基质树脂，具有特定结构的硬化剂和高耐热性热塑性树脂。此外，通过固化上述预浸料，可以获得固化产物，该产品满足耐冲击性（冲击后的残余压缩强度）和高和湿性（高温高湿下的缺口试样的抗压强度）高水平，即使这些性质在常规技术中是相互矛盾的关系。

16. 发明授权

US5629127A Positive electron beam resist composition containing cresolnovolak resin, select additive and methyl gallate/1,2-naphthoquinonediazido-4-sulfonyl chloride reaction product 失效
标题翻译：含有甲酚新酚树脂的正电子束抗蚀剂组合物，选择的添加剂和没食子酸甲酯/ 1,2-萘醌二叠氮基-4-磺酰氯反应产物
公开(公告)号：US5629127A
公开(公告)日：1997-05-13
申请号：US360806
申请日：1995-05-25
申请人： Hiroki Oosedo , Mutsuo Kataoka, deceased , Mayumi Kataoka, legal representative , Shigeyoshi Kanetsuki , Kazutaka Tamura , Masaya Asano
发明人： Hiroki Oosedo , Mutsuo Kataoka, deceased , Mayumi Kataoka, legal representative , Shigeyoshi Kanetsuki , Kazutaka Tamura , Masaya Asano
IPC分类号： G03F7/022 , G03F7/20 , G03F7/32 , G03F7/023 , G03C1/61
CPC分类号： G03F7/322 , G03F7/022 , G03F7/0226 , G03F7/32 , Y10S430/143
摘要： The present invention relates to a positive electron beam resist composition containing a cresolnovolak resin, a lower molecular additive with a specific structure and a quinonediazide compound with a specific structure, and a developer for the positive electron beam resist, containing specific amounts of alkali metal ions, weak acid radical ions and a water soluble organic compound. The present invention can provide a positive electron beam resist composition with a novolak and a quinonediazide as main ingredients, excellent in dry etching resistance and resolution, and it if is used, a fine pattern can be obtained at high sensitivity especially when the developer of the present invention is used.
摘要翻译： PCT No.PCT / JP94 / 00720 Sec。 371日期：1995年5月25日 102（e）日期1995年5月25日PCT 1994年4月28日PCT PCT。第WO94 / 25904号公报日期：1994年11月10日本发明涉及一种正电子束抗蚀剂组合物，其含有甲酚新戊酸树脂，具有特定结构的低分子添加剂和具有特定结构的醌二叠氮化合物，以及用于正电子束抗蚀剂的显影剂，碱金属离子，弱酸根离子和水溶性有机化合物的量。本发明可以提供一种具有酚醛清漆和醌二叠氮化物的正电子束抗蚀剂组合物作为主要成分，具有优异的耐干蚀刻性和分辨率，并且如果使用，可以以高灵敏度获得精细图案，特别是当使用本发明。

17. 发明授权

US6063839A Prepreg of reinforcing fibers, epoxy resins, crosslinked rubber particles and curing agent 失效
标题翻译：增强纤维预浸料，环氧树脂，交联橡胶颗粒和固化剂
公开(公告)号：US6063839A
公开(公告)日：2000-05-16
申请号：US644025
申请日：1996-05-09
申请人： Hiroki Oosedo , Shunsaku Noda
发明人： Hiroki Oosedo , Shunsaku Noda
IPC分类号： B32B5/14 , C08G59/44 , C08J5/24 , C08K7/02 , C08L63/00 , B32B27/04 , C08L63/02 , C08L63/04
CPC分类号： C08J5/24 , C08L63/00 , C08J2363/00 , Y10T428/24994
摘要： Disclosed are epoxy resin compositions for fiber-reinforced composite materials, comprising an epoxy resin containing 70 parts by weight or more, per 100 parts by weight of the epoxy resin, of a bi-functional epoxy resin, fine particles comprising a rubber phase and substantially insoluble in epoxy resins and a curing agent. Also disclosed are prepregs and fiber-reinforced composite materials comprising the composition.
摘要翻译：公开了用于纤维增强复合材料的环氧树脂组合物，其包含每100重量份环氧树脂包含70重量份以上的环氧树脂，双功能环氧树脂，包含橡胶相的细颗粒和基本上不溶于环氧树脂和固化剂。还公开了包含该组合物的预浸料和纤维增强复合材料。

18. 发明授权

US06399199B1 Prepeg and carbon fiber reinforced composite materials 有权
标题翻译： Prepeg和碳纤维增强复合材料
公开(公告)号：US06399199B1
公开(公告)日：2002-06-04
申请号：US09536290
申请日：2000-03-27
申请人： Mutsuko Fujino , Shunsaku Noda , Hiroki Oosedo , Hideki Okita
发明人： Mutsuko Fujino , Shunsaku Noda , Hiroki Oosedo , Hideki Okita
IPC分类号： D02G300
CPC分类号： C08J5/24 , C08J2363/00 , C08L63/00 , Y10T428/249928 , Y10T428/2933 , Y10T428/2971
摘要： The invention provides a prepreg, formed by impregnating carbon fiber with an epoxy resin composition comprising an epoxy resin (A) and a curing agent (B) wherein the matrix resin content Wr (wt %) of the prepreg, the 0° tensile modulus E (GPa) of the carbon fiber, and the in-plane shear strength of S (MPa) of the carbon fiber reinforced composition material obtained by heating and curing the prepreg satisfy the following formulae (i) and (ii): S≧205×LOG(E)+610 (i) 15≦Wr≦40 (ii) The prepreg has a high in-plane shear strength, a high mode I interlayer fracture toughness GIC, an excellent CFRP tube in torsion al strength, a high radial compressive strength and a high impact strength and a light weight.
摘要翻译：本发明提供一种预浸料坯，其通过用包含环氧树脂（A）和固化剂（B）的环氧树脂组合物浸渍碳纤维而形成，其中预浸料坯的基质树脂含量Wr（wt％），0°拉伸模量E （GPa），通过加热固化预浸料获得的碳纤维增强组合物材料的S（MPa）的面内剪切强度满足下式（i）和（ii）：预浸料坯具有高平面剪切强度，高模量I层间断裂韧性GIC，扭转强度优异的CFRP管，高径向抗压强度和高冲击强度和重量轻。

19. 发明授权

US6046257A Composition for prepreg comprising epoxy resin, polyamide block copolymer and curing agent 失效
标题翻译：包含环氧树脂，聚酰胺嵌段共聚物和固化剂的预浸料组合物
公开(公告)号：US6046257A
公开(公告)日：2000-04-04
申请号：US615996
申请日：1996-03-18
申请人： Hiroki Oosedo , Shunsaku Noda
发明人： Hiroki Oosedo , Shunsaku Noda
IPC分类号： C08K9/08 , C08L63/00 , C08K7/06 , C08K7/08 , C08K7/10 , C08K7/14
CPC分类号： C08K9/08 , C08J5/24 , C08L63/00 , C08J2363/00 , C08J2467/00 , C08J2477/00
摘要： A composition is useful as a prepreg containing reinforcing fibers comprises an epoxy resin, a thermoplastic elastomer of a polyamide and/or polyester block copolymer, a curing agent such as dicyandiamide, and optionally a thermoplastic resin such as a polyvinyl formal resin.
摘要翻译：组合物可用作包含增强纤维的预浸料，其包含环氧树脂，聚酰胺和/或聚酯嵌段共聚物的热塑性弹性体，双氰胺等固化剂，以及任选的热塑性树脂如聚乙烯醇缩甲醛树脂。

20. 发明授权

US6027794A Prepregs, processes for their production, and composite laminates 失效
标题翻译：预浸料，生产工艺和复合层压板
公开(公告)号：US6027794A
公开(公告)日：2000-02-22
申请号：US999931
申请日：1997-08-08
申请人： Atsushi Ozaki , Hajime Kishi , Nobuyuki Odagiri , Hiroki Oosedo , Hiroaki Hinomiya
发明人： Atsushi Ozaki , Hajime Kishi , Nobuyuki Odagiri , Hiroki Oosedo , Hiroaki Hinomiya
IPC分类号： C08J5/24 , B32B27/04
CPC分类号： C08J5/24 , B29K2301/12 , Y10T428/249927 , Y10T428/249933 , Y10T428/249934 , Y10T428/24994 , Y10T428/249941 , Y10T428/249942 , Y10T428/249949 , Y10T428/24995 , Y10T442/2877 , Y10T442/2885 , Y10T442/2893 , Y10T442/291 , Y10T442/2918 , Y10T442/2951 , Y10T442/659
摘要： Prepregs, comprising the following components [A], [B] and [C], with the component [C] distributed near either or both of the surface layers without being regularly arranged.[A]: Long reinforcing fibers[B]: A matrix resin[C]: Long thermoplastic resin fibersThe prepregs of the present invention are tacky and drapable, and the composite materials obtained by heating and forming the prepregs are high in heat resistance, and very high in impact resistance and inter-layer toughness. Furthermore, the prepregs are easy to produce and high in their latitude in availability of materials.
摘要翻译：包含以下组分[A]，[B]和[C]的预浸料，组分[C]分布在任何一个或两个表面层附近，而不经常排列。 [A]：长增强纤维[B]：基体树脂[C]：长的热塑性树脂纤维本发明的预浸料是粘性和可悬挂性的，通过加热和形成预浸料获得的复合材料的耐热性高，并且耐冲击性和层间韧性非常高。此外，预浸料容易生产，并且在材料可用性方面的纬度高。

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