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    • 14. 发明申请
    • METHOD FOR PRODUCING AQUEOUS POLYMER DISPERSIONS CONTAINING AT LEAST ONE LIPOPHILIC ACTIVE SUBSTANCE AND THE USE THEREOF
    • 生产含有至少一种活性物质的水性聚合物分散体的方法及其用途
    • US20090178773A1
    • 2009-07-16
    • US12305976
    • 2007-06-05
    • Andreas BrockmeyerRoland EttlRainer Dyllick-Brenzinger
    • Andreas BrockmeyerRoland EttlRainer Dyllick-Brenzinger
    • D21H21/16C08K5/1539C08K5/04C08K5/42C08K5/07C08L89/00C08L3/00
    • C08F2/24C08F2/44
    • A process for the preparation of aqueous polymer dispersions comprising at least one lipophilic active substance by emulsion polymerization of ethylenically unsaturated monomers in an aqueous medium in the presence of at least one lipophilic active substance, wherein (i) at least one lipophilic active substance which has a water solubility of not more than 5 g/l (determined at 25° C. and 1013 mbar) and a melting point below 130° C. is emulsified in an aqueous solution which comprises at least one dispersion stabilizer with formation of an aqueous dispersion of the active substance having a mean particle size of not more than 1000 nm and (ii) a monomer composition which comprises at least 80% by weight of a neutral, monoethylenically unsaturated monomer emulsifiable in water is subjected to an emulsion polymerization in the aqueous dispersion of the active substance which is obtained according to (i), and use of the dispersions thus obtainable as sizes for paper, board and cardboard, for the treatment and for the stabilization of thermoplastic polymers, for material protection and for crop protection.
    • 一种制备包含至少一种亲脂性活性物质的含水聚合物分散体的方法,其通过在至少一种亲脂性活性物质存在下,在含水介质中的烯属不饱和单体的乳液聚合反应,其中(i)至少一种亲脂性活性物质,其具有 将水溶解度不超过5g / l(在25℃和1013毫巴下测定)和低于130℃的熔点在含有至少一种分散稳定剂的水溶液中乳化,形成水分散体 的平均粒径不大于1000nm的活性物质和(ii)包含至少80重量%的在水中可乳化的中性单烯属不饱和单体的单体组合物在水分散体中进行乳液聚合 根据(i)获得的活性物质的使用,以及由此获得的分散体作为纸,纸板和纸板的尺寸, 用于热塑性聚合物的处理和稳定化,用于材料保护和作物保护。
    • 15. 发明申请
    • Fine-Particled Polymer Dispersions Containing Starch
    • 包含淀粉的细颗粒聚合物分散体
    • US20090139675A1
    • 2009-06-04
    • US11993919
    • 2006-06-23
    • Hildegard SteinRoland Ettl
    • Hildegard SteinRoland Ettl
    • D21H21/16C08L67/00D21H17/46
    • D21H17/35C08F2/26C08F2/44D21H17/29D21H17/37
    • Finely divided, starch-containing polymer dispersions obtainable by emulsion copolymerization, with redox initiators, of ethylenically unsaturated monomers from the group consisting of (a) from 45 to 55% by weight of at least one optionally substituted styrene, methyl methacrylate, acrylonitrile and/or methacrylonitrile, (b) from 15 to 29% by weight of at least one C1-C12-alkyl acrylate and/or one C2-C12-alkyl methacrylate and (c) from 0 to 10% by weight of at least one other ethylenically unsaturated copolymerizable monomer in an aqueous medium in the presence of (d) from 15 to 35% by weight of a degraded cationized starch which has a molar mass Mw of from 1000 to 65 000, the sum (a)+(b)+(c)+(d) being 100% and being based on the total solids content, processes for the preparation of such polymer dispersions by emulsion polymerization of the monomers (a), (b) and (c) in an aqueous medium with redox initiators in the presence of (d) cationic starch, and use of the starch-containing polymer dispersions as size for paper, board and cardboard.
    • 通过与氧化还原引发剂通过乳液共聚获得的烯键式不饱和单体可分散的含淀粉的聚合物分散体由(a)45至55重量%的至少一种任选取代的苯乙烯,甲基丙烯酸甲酯,丙烯腈和/ 或甲基丙烯腈,(b)15至29重量%的至少一种丙烯酸C 1 -C 12烷基酯和/或一种C 2 -C 12烷基甲基丙烯酸酯,和(c)0至10重量%的至少一种其它烯属 在(d)15至35重量%的摩尔质量分数为1000至65000的降解的阳离子化淀粉的存在下,(a)+(b)+( c)+(d)为100%,基于总固体含量,通过单体(a),(b)和(c)在具有氧化还原引发剂的水性介质中的乳液聚合制备这种聚合物分散体的方法 在(d)阳离子淀粉的存在下,并使用含淀粉的聚合物 聚合物分散体作为纸张,纸板和纸板的尺寸。
    • 16. 发明申请
    • Fine-Particled Amphoteric Aqueous Polymer Dispersion Method for Production and Use Thereof
    • 用于生产和使用的细颗粒两性水性聚合物分散体方法
    • US20080039598A1
    • 2008-02-14
    • US11569912
    • 2005-06-03
    • Hildegard KukulaRoland EttlRainer Dyllick-BrenzingerBernhard Sturm
    • Hildegard KukulaRoland EttlRainer Dyllick-BrenzingerBernhard Sturm
    • C08F2/22
    • D21H21/16C08F212/08C08F212/10C08F257/02C14C11/003D21H11/14D21H17/37D21H17/375D21H17/45C08F2/18C08F220/18
    • Finely divided, amphoteric, aqueous polymer dispersions which are obtainable by a two-stage polymerization, a prepolymer being prepared in the first polymerization stage from a monomer mixture comprising (a) from 15 to 40% by weight of at least one (meth)acrylate and/or (meth)acrylamide having in each case a free amino group, protonated amino group and/or quaternized amino group, (b) from 40 to 70% by weight of at least one optionally substituted styrene, (c) from 0 to 25% by weight of acrylonitrile and/or methacrylonitrile, (d) from 0.5 to 5% by weight of at least one ethylenically unsaturated monomer comprising acid groups and (e) from 0 to 30% by weight of at least one nonionic, ethylenically unsaturated monomer differing from (b) and (c), the sum of (a)+(b)+(c)+(d)+(e) being 100% by weight, in a solution polymerization in a solvent partly to completely miscible with water, water then being added to the solution/dispersion of the prepolymer and then at least one nonionic, ethylenically unsaturated monomer being subjected to an emulsion polymerization in the aqueous solution of the prepolymer in a second polymerization stage, processes for the preparation of the polymer dispersions by two-stage polymerization and use of the polymer dispersions as sizes for paper, board and cardboard.
    • 通过两阶段聚合可得到的细分两性聚合物水分散体,预聚物在第一聚合阶段由单体混合物制备,所述单体混合物包含(a)15-40%重量的至少一种(甲基)丙烯酸酯 和/或(甲基)丙烯酰胺,其各自为游离氨基,质子化氨基和/或季铵化氨基,(b)40至70重量%的至少一种任选取代的苯乙烯,(c)0至 25重量%的丙烯腈和/或甲基丙烯腈,(d)0.5至5重量%的至少一种包含酸基的烯属不饱和单体和(e)0至30重量%的至少一种非离子,烯属不饱和单体 与(b)和(c)不同的单体,在溶剂中的溶液聚合中部分地完全混溶的(a)+(b)+(c)+(d)+(e)的总和为100重量% 用水,然后将水加入到预聚物的溶液/分散体中,然后加入至少一种非离子的乙烯 lly不饱和单体在第二聚合阶段在预聚物的水溶液中进行乳液聚合,通过两步聚合制备聚合物分散体的方法和使用聚合物分散体作为纸,纸板和纸板的尺寸。
    • 18. 发明申请
    • Packaging material consisting of an at least double-layered composite material for producing containers for packing liquids
    • 包装材料由用于生产用于包装液体的容器的至少双层复合材料组成
    • US20070010386A1
    • 2007-01-11
    • US10556471
    • 2004-05-06
    • Simon ChampRoland Ettl
    • Simon ChampRoland Ettl
    • D21H23/00
    • B32B29/00B32B7/12B32B27/10B32B2307/7265B32B2553/00D21H19/04D21H19/20D21H19/22D21H19/30D21H19/78D21H19/84D21H21/16D21H27/10
    • Packaging material comprises an at least two-layer laminate of a paper engine-sized in each case with a polymer size or sized cardboard and at least one water-impermeable film or foil for producing containers for packaging liquids, and paper products which are obtainable in each case by (i) engine sizing of a paper stock comprising an aqueous slurry of cellulose fibers with at least one polymer size or with a polymer size and an aqueous dispersion of an alkylketene dimer or a mixture thereof in the presence of a retention aid and, if appropriate, of a water-soluble aluminum compound and, if appropriate, at least one cationic polymer, (ii) drainage of the paper stock on the wire of a paper machine, (iii) drying of the paper product and (iv) lamination of the paper product on one or both sides with a plastics film or metal foil are used for producing containers for packaging liquids, in particular beverages.
    • 包装材料包括至少两层的纸引擎尺寸,每种情况下具有聚合物尺寸或尺寸的纸板和用于生产用于包装液体的容器的至少一个不透水膜或箔,以及可以在 每种情况通过以下步骤:(i)在保留助剂和存在助留剂的存在下,包含具有至少一种聚合物尺寸或聚合物尺寸的纤维素纤维的水性浆料和烷基烯酮二聚体或其混合物的水分散体的纸料原料的发动机尺寸, 如果合适,可以使用水溶性铝化合物和(如果合适的话)至少一种阳离子聚合物,(ii)在造纸机的丝线上排出纸料,(iii)干燥纸制品和(iv) 使用塑料膜或金属箔将纸制品在一侧或两侧层压,用于生产用于包装液体,特别是饮料的容器。