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1. 发明申请

US20060009571A1 Aqueous polymer dispersions containing alkyldiketenes, methods for the production thereof, and their use 失效
标题翻译：含有烷基恶臭酮的聚合物水分散体，其制备方法及其用途
公开(公告)号：US20060009571A1
公开(公告)日：2006-01-12
申请号：US10529782
申请日：2003-10-09
申请人： Rainer Dyllick-Brenzinger , Roland Ettl , Franca Tiarks , Ulrich Riebeling
发明人： Rainer Dyllick-Brenzinger , Roland Ettl , Franca Tiarks , Ulrich Riebeling
IPC分类号： C08G18/63
CPC分类号： D06M13/13 , C08F2/22 , C08F2/44 , C14C11/003 , D21H17/17 , D21H17/72
摘要： Alkyldiketene-containing aqueous polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkyldiketenes, processes for the preparation of such polymer dispersions and the use of the thus obtainable dispersions as sizes for paper or as water repellents for leather, natural and/or manmade fibers and textiles.
摘要翻译：含有烷基染料的含水聚合物分散体，其可通过疏水性单烯属不饱和单体在烷基二乙烯基酯的存在下的细乳液聚合得到，制备这种聚合物分散体的方法以及由此获得的分散体作为纸张的尺寸或用作皮革的防水剂，天然和/或人造纤维和纺织品。

2. 发明授权

US07709052B2 Aqueous polymer dispersions containing alkyldiketenes, methods for the production thereof, and their use 失效
标题翻译：含有烷基恶臭酮的聚合物水分散体，其制备方法及其用途
公开(公告)号：US07709052B2
公开(公告)日：2010-05-04
申请号：US10529782
申请日：2003-10-09
申请人： Rainer Dyllick-Brenzinger , Roland Ettl , Franca Tiarks , Ulrich Riebeling
发明人： Rainer Dyllick-Brenzinger , Roland Ettl , Franca Tiarks , Ulrich Riebeling
IPC分类号： C08F212/00 , C08J3/00 , C08F2/00
CPC分类号： D06M13/13 , C08F2/22 , C08F2/44 , C14C11/003 , D21H17/17 , D21H17/72
摘要： Alkyldiketene-containing aqueous polymer dispersions which are obtainable by miniemulsion polymerization of hydrophobic monoethylenically unsaturated monomers in the presence of alkyldiketenes, processes for the preparation of such polymer dispersions and the use of the thus obtainable dispersions as sizes for paper or as water repellents for leather, natural and/or manmade fibers and textiles.
摘要翻译：含有烷基染料的含水聚合物分散体，其可通过疏水性单烯属不饱和单体在烷基二乙烯基酯的存在下的细乳液聚合得到，制备这种聚合物分散体的方法以及由此获得的分散体作为纸张的尺寸或用作皮革的防水剂，天然和/或人造纤维和纺织品。

3. 发明授权

US5498648A Paper size mixtures 失效
标题翻译：纸张大小的混合物
公开(公告)号：US5498648A
公开(公告)日：1996-03-12
申请号：US393001
申请日：1995-03-01
申请人： Arnold de Clercq , Roland Ettl , Carlos A. Goncalves , Lothar Hoehr , Andreas Hohmann , Ulrich Riebeling
发明人： Arnold de Clercq , Roland Ettl , Carlos A. Goncalves , Lothar Hoehr , Andreas Hohmann , Ulrich Riebeling
IPC分类号： D21H17/17 , D21H17/29 , D21H21/16 , C08L3/00 , C08L89/00 , C09D4/00
CPC分类号： D21H21/16 , D21H17/17 , D21H17/29
摘要： Paper size mixtures which are prepared by mixing an aqueous suspension of a digested cationic starch with a finely divided, aqueous polymer dispersion which is the paper size and emulsifying the C.sub.14 -C.sub.22 -alkyldiketene in this mixture at not less than 70.degree. C. are used for engine and surface sizing of the paper.
摘要翻译： PCT No.PCT / EP93 / 02259 Sec。 371 1995年3月1日 102（e）1995年3月1日PCT 1993年8月23日PCT PCT。出版物WO94 / 05855 日期：1994年3月17日。通过将消化的阳离子淀粉的水性悬浮液与纸浆尺寸的细分散的水性聚合物分散体混合制备的纸浆尺寸混合物，并将该混合物中的C14-C22-烷基二乙烯基化乳化 70℃以上用于纸张的发动机和表面施胶。

4. 发明授权

US4770743A Engine size for paper, based on fatty alkyl diketenes and cationic polyacrylamides 失效
标题翻译：纸张的发动机尺寸，基于脂肪烷基二烯酮和阳离子聚丙烯酰胺
公开(公告)号：US4770743A
公开(公告)日：1988-09-13
申请号：US071772
申请日：1987-07-10
申请人： Volkmar Weberndoerfer , Enrique Freudenberg , Hans-Juergen Degen , Ulrich Riebeling
发明人： Volkmar Weberndoerfer , Enrique Freudenberg , Hans-Juergen Degen , Ulrich Riebeling
IPC分类号： C08L33/26 , C08F220/56 , C08L33/24 , D21H17/03 , D21H17/17 , D21H17/37 , D21H17/45 , D21H3/10
CPC分类号： D21H17/375 , C08F220/56 , D21H17/17 , D21H17/455
摘要： Engine sizes for paper are based on aqueous emulsions of C.sub.14 -C.sub.20 -alkyl diketenes and cationic copolymers of(a) from 40 to 99% by weight of acrylamide and/or methacrylamide,(b) from 1 to 40% by weight of an unsubstituted or substituted N-vinylimidazoline and(c) from 0 to 30% by weight of an unsubstituted or substituted N-vinylimidazole.
摘要翻译：纸的发动机尺寸基于C 14 -C 20烷基双烯酮的水乳液和（a）40-99重量％的丙烯酰胺和/或甲基丙烯酰胺的阳离子共聚物，（b）1至40重量％的未取代的或取代的N-乙烯基咪唑啉，和（c）0至30重量％的未取代或取代的N-乙烯基咪唑。

5. 发明申请

US20090139677A1 AQUEOUS ALKYLKETENE DIMER DISPERSIONS 有权
标题翻译：水性阿尔茨海默分散剂
公开(公告)号：US20090139677A1
公开(公告)日：2009-06-04
申请号：US12303253
申请日：2007-06-01
申请人： Christoph Hamers , Andreas Brockmeyer , Markus Schmid , Klaus Lorenz , Ulrich Riebeling
发明人： Christoph Hamers , Andreas Brockmeyer , Markus Schmid , Klaus Lorenz , Ulrich Riebeling
IPC分类号： D21H17/28 , C09K3/00
CPC分类号： D21H17/17 , D21H17/23 , D21H17/29 , D21H17/66 , D21H21/16 , D21H27/10
摘要： Aqueous alkyl ketene dimer dispersions which comprise at least 15% by weight of an alkyl ketene dimer and at least one water-soluble cationic starch, aluminum sulfate and at least one condensate of naphthalenesulfonic acid and formaldehyde or lignin sulfonic acid or in each case salts thereof, the dispersions comprising, based in each case on alkyl ketene dimer, from 2 to 50% by weight of aluminum sulfate, and in which the dispersions additionally comprise from 0.1 to 5% by weight of a saturated carboxylic acid having 1 to 10 carbon atoms, benzenesulfonic acid, p-toluenesulfonic acid and/or a mineral acid at an aluminum sulfate content of from 2 to 15% by weight, and the use of the dispersions as engine size and surface size for paper and paper products.
摘要翻译：包含烷基烯酮二聚体和至少一种水溶性阳离子淀粉，硫酸铝和至少一种萘磺酸和甲醛或木质素磺酸的缩合物的至少15重量％的烷基乙烯酮二聚物分散体，或者在其每种情况下都是其盐，基于烷基烯酮二聚体，基于烷基烯酮二聚体的分散体含有2-50重量％的硫酸铝，其中分散体另外包含0.1-5重量％的具有1-10个碳原子的饱和羧酸，苯磺酸，对甲苯磺酸和/或无机酸，硫酸铝含量为2〜15重量％，分散体用作纸和纸制品的发动机尺寸和表面尺寸。

6. 发明授权

US5266165A Paper sizing using copolymers of long-chain olefins and maleic anhydride in the form of the semiamides with morpholine 失效
标题翻译：使用长链烯烃和马来酸酐的共聚物以半自由基与吗啉的纸浆定型
公开(公告)号：US5266165A
公开(公告)日：1993-11-30
申请号：US955270
申请日：1992-10-01
申请人： Arnold DeClercq , Walter Denzinger , Norbert Greif , Heinrich Hartmann , Knut Oppenlaender , Ulrich Riebeling
发明人： Arnold DeClercq , Walter Denzinger , Norbert Greif , Heinrich Hartmann , Knut Oppenlaender , Ulrich Riebeling
IPC分类号： C08F8/32 , C08F8/44 , C08F10/00 , C08F210/00 , D21H17/16 , D21H19/16 , D21H17/45 , C08F8/30 , C08F222/06 , D21H21/16
CPC分类号： D21H17/16 , C08F8/44
摘要： Abstract of the Disclosure: Copolymers of (a) C.sub.12 - to C.sub.24 -monoolefins and (b) maleic anhydride or itaconic anhydride, having molecular weights of from 800 to 100,000 g/mol, in the form of partially or completely neutralized semiamides with morpholine, in aqueous solution or dispersion, can be used as sizes for paper.
摘要翻译：公开的摘要：（a）C12-至C24-单烯烃和（b）分子量为800至100,000g / mol的马来酸酐或衣康酸酐的共聚物为部分或完全中和的具有吗啉的半酰胺形式，在水溶液或分散体中，可用作纸张的尺寸。

7. 发明授权

US4908240A Printability of paper 失效
标题翻译：纸的印刷性
公开(公告)号：US4908240A
公开(公告)日：1990-03-13
申请号：US244679
申请日：1988-09-15
申请人： Werner Auhorn , Hans-Juergen Degen , Lothar Hoehr , Ulrich Riebeling
发明人： Werner Auhorn , Hans-Juergen Degen , Lothar Hoehr , Ulrich Riebeling
IPC分类号： D21H19/36 , D21H19/44 , D21H19/54
CPC分类号： D21H19/44 , Y10T428/31899 , Y10T428/31902 , Y10T428/31906
摘要： The printability of paper is improved by applying an aqueous coating agent consisting of(a) 100 parts by weight of a finely divided pigment,(b) from 5 to 70 parts by weight, based on solids, of a cationic aqueous polymer dispersion of a paper size and(c) from 0.01 to 10 parts by weight of a surfactant which interferes with the formation of the surface size and/or of a polymeric dispersantin an amount of from 0.5 to 4 g/m.sup.2 to one or both surfaces of the paper and drying the coated paper.
摘要翻译：通过使用由（a）100重量份的细分散颜料组成的水性涂布剂，（b）5至70重量份的基于固体的阳离子水性聚合物分散体纸张尺寸和（c）0.01至10重量份的干扰表面尺寸形成的表面活性剂和/或聚合物分散剂的量为0.5至4g / m 2，纸和干燥涂层纸。

8. 发明授权

US4835212A Sizing agents for paper based on finely divided aqueous dispersions 失效
标题翻译：基于细分散水分散体的纸张上浆剂
公开(公告)号：US4835212A
公开(公告)日：1989-05-30
申请号：US146193
申请日：1988-01-20
申请人： Hans-Juergen Degen , Fritz Reichel , Ulrich Riebeling , Lothar Hoehr
发明人： Hans-Juergen Degen , Fritz Reichel , Ulrich Riebeling , Lothar Hoehr
IPC分类号： C08F2/22 , C08F2/44 , C08F4/28 , C08F20/52 , C08F220/10 , C08F220/12 , C08F220/18 , C08F220/42 , C08F220/56 , C08F251/00 , D21H17/28 , D21H17/37 , D21H19/20 , D21H21/16
CPC分类号： D21H17/28 , C08F220/18 , D21H17/37 , D21H21/16
摘要： Sizing agents for paper are based on finely divided aqueous dispersions of copolymers obtainable by copolymerizing from 40 to 140 parts by weight of a monomer mixture of(a) from 20 to 65% by weight of (meth)acrylonitrile,(b) from 35 to 80% by weight of one or more acrylates of monohydric saturated C.sub.3 -C.sub.8 -alcohols and(c) from 0 to 10% by weight of other ethylenically unsaturated copolymerizable monomers,the weight percentages (a), (b) and (c) always adding up to 100, in the manner of an emulsion polymerization in 100 parts by weight of an aqueous solution containing in solution from 2.7 to 15% by weight of a degraded starch having a viscosity n.sub.i from 0.04 to less than 0.12 dl/g at from 40.degree. to 100.degree. C. in the presence of a peroxide initiator.
摘要翻译：用于纸张的上浆剂是基于通过共聚合40至140重量份的（a）20至65重量％的（甲基）丙烯腈，（b）从35至 80重量％的一种或多种一元饱和C 3 -C 8醇的丙烯酸酯和（c）0至10重量％的其它烯属不饱和可共聚单体，重量百分比（a），（b）和（c）总是以100重量份的含有2.7至15重量％的粘度为0.04至小于0.12dl / g的降解淀粉的溶液为100重量份的水溶液，以100重量份的浓度加入至100，在过氧化物引发剂的存在下，在40℃至100℃。

9. 发明授权

US08097124B2 Aqueous alkylketene dimer dispersions 有权
标题翻译：水性烷基烯酮二聚体分散体
公开(公告)号：US08097124B2
公开(公告)日：2012-01-17
申请号：US12303253
申请日：2007-06-01
申请人： Christoph Hamers , Andreas Brockmeyer , Markus Schmid , Klaus Lorenz , Ulrich Riebeling
发明人： Christoph Hamers , Andreas Brockmeyer , Markus Schmid , Klaus Lorenz , Ulrich Riebeling
IPC分类号： D21F11/00
CPC分类号： D21H17/17 , D21H17/23 , D21H17/29 , D21H17/66 , D21H21/16 , D21H27/10
摘要： Aqueous alkyl ketene dimer dispersions which comprise at least 15% by weight of an alkyl ketene dimer and at least one water-soluble cationic starch, aluminum sulfate and at least one condensate of naphthalenesulfonic acid and formaldehyde or lignin sulfonic acid or in each case salts thereof, the dispersions comprising, based in each case on alkyl ketene dimer, from 2 to 50% by weight of aluminum sulfate, and in which the dispersions additionally comprise from 0.1 to 5% by weight of a saturated carboxylic acid having 1 to 10 carbon atoms, benzenesulfonic acid, p-toluenesulfonic acid and/or a mineral acid at an aluminum sulfate content of from 2 to 15% by weight, and the use of the dispersions as engine size and surface size for paper and paper products.
摘要翻译：包含烷基烯酮二聚体和至少一种水溶性阳离子淀粉，硫酸铝和至少一种萘磺酸和甲醛或木质素磺酸的缩合物的至少15重量％的烷基乙烯酮二聚物分散体，或者在其每种情况下都是其盐，基于烷基烯酮二聚体，基于烷基烯酮二聚体的分散体含有2-50重量％的硫酸铝，其中分散体另外包含0.1-5重量％的具有1-10个碳原子的饱和羧酸，苯磺酸，对甲苯磺酸和/或无机酸，硫酸铝含量为2〜15重量％，分散体用作纸和纸制品的发动机尺寸和表面尺寸。

10. 发明授权

US5672392A Preparation of recording materials for inkjet printers 失效
标题翻译：喷墨打印机的记录材料的制备
公开(公告)号：US5672392A
公开(公告)日：1997-09-30
申请号：US635973
申请日：1996-05-08
申请人： Arnold De Clercq , Lothar Hohr , Ulrich Riebeling
发明人： Arnold De Clercq , Lothar Hohr , Ulrich Riebeling
IPC分类号： B41M5/00 , B32B27/00 , B41M5/50 , B41M5/52 , C09D133/02 , C09D133/04 , C09D133/06 , C09D133/20 , D21H19/10 , D21H19/20 , D21H19/34 , D21H19/54 , D21H19/58 , D21H27/00 , B05D3/00
CPC分类号： D21H19/34 , B41M5/52 , B41M5/5245 , D21H19/20 , B41M5/5236 , B41M5/5254
摘要： A process for the preparation of recording materials for inkjet printers by applying aqueous coating compositions to one or both sides of a sheet of paper which has been treated with size, where the coating compositions contain from 20 to 200 g/l of starch and from 1 to 50 g/l of a copolymer which is obtainable by emulsion copolymerization of 100 parts by weight of a monomer mixture comprising (a) from 10 to 65 parts by weight of styrene, .alpha.-methylstyrene, acrylonitrile and/or methacrylonitrile, (b) from 30 to 85 parts by weight of acrylic and/or methacrylic esters of alcohols having 1 to 18 carbon atoms, (c) from 5 to 25 parts by weight of monomers containing tertiary and/or quaternary amino groups, and (d) from 0 to 20 parts by weight of other monoethylenically unsaturated monomers in an aqueous medium in the presence of from 12 to 300% by weight, based on the monomers, of at least one natural or synthetic protective colloid.
摘要翻译： PCT No.PCT / EP94 / 03584 371日期：1996年5月8日 102（e）日期1996年5月8日PCT 1994年10月31日PCT公布。公开号WO95 / 13194 日期1995年5月18日一种通过将水性涂料组合物涂布在已经经过尺寸处理的纸张的一面或两面上来制备用于喷墨打印机的记录材料的方法，其中涂料组合物含有20至200g / l的淀粉和1至50g / l共聚物，其通过100重量份的单体混合物的乳液共聚获得，所述单体混合物包含（a）10至65重量份的苯乙烯，α-甲基苯乙烯，丙烯腈和/或甲基丙烯腈，（b）30至85重量份的具有1至18个碳原子的醇的丙烯酸和/或甲基丙烯酸酯，（c）5至25重量份的含有叔和/或季氨基的单体和（ d）0至20重量份的其它单烯键式不饱和单体在水性介质中以基于单体的12至300重量％存在至少一种天然或合成的保护胶体。

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