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    • 14. 发明授权
    • Photographic silver halide elements containing infrared filter dyes
    • 含有红外线滤光染料的摄影卤化银元素
    • US4871656A
    • 1989-10-03
    • US166134
    • 1988-03-10
    • Richard L. PartonANthony D. GingelloDavid J. CollettDavid A. StegmanANthony Adin
    • Richard L. PartonANthony D. GingelloDavid J. CollettDavid A. StegmanANthony Adin
    • C09B23/01C09B23/08G03C1/83
    • C09B23/0066C09B23/086G03C1/832
    • A dye useful for absorbing infrared radiation in photographic elements, having the structure: ##STR1## is disclosed. In this formula, R.sub.1 and R.sub.2 each independently represents sulfoalkyl, carboxyalkyl, or sulfatoalkyl, from 2 to 4 carbon atoms, having 2 carbon atoms in the alkyl chain linking the nitrogen atom of each Z ring and the sulfo or sulfato group, and 1 carbon atom in the alkyl chain linking the nitrogen atom of each Z ring and the carboxy group.R.sub.3 and R.sub.5 are each hydrogen or together represent the atoms necessary to complete a 5- or 6-membered carbocyclic ring, and R.sub.4 represents hydrogen, alkyl of 1 to 4 carbon atoms, halogen, cyano, or ##STR2## where R.sub.6 and R.sub.7 each independently represents alkyl of from 1 to 6 carbon atoms or aryl or together represent the non-metallic atoms necessary to form a 5- or 6-membered heterocyclic ring.X.sup..sym. represents a cation.Z.sub.1 and Z.sub.2 each independently represent the atoms needed to complete an indole, naphthindole or benzindole nucleus.
    • 公开了一种用于吸收照相元件中的红外辐射的染料,具有以下结构:。 在该式中,R 1和R 2各自独立地表示在连接每个Z环的氮原子和磺基或硫酸根的烷基链中具有2个碳原子的2至4个碳原子的磺基烷基,羧基烷基或硫酸酯基烷基,以及1个碳 连接每个Z环的氮原子和羧基的烷基链中的原子。 R 3和R 5各自为氢或一起表示完成5-或6-元碳环所必需的原子,R 4表示氢,1-4个碳原子的烷基,卤素,氰基或者其中R 6和R 7各自 独立地表示1至6个碳原子的烷基或芳基或一起表示形成5或6元杂环所必需的非金属原子。 X(+)表示阳离子。 Z1和Z2各自独立地表示完成吲哚,萘啶或萘吲哚核所需的原子。
    • 17. 发明授权
    • Photographic material having enhanced light absorption
    • 具有增强的光吸收的照相材料
    • US06361932B1
    • 2002-03-26
    • US09151916
    • 1998-09-11
    • Richard L. PartonThomas L. PennerWilliam J. HarrisonMargaret J. Helber
    • Richard L. PartonThomas L. PennerWilliam J. HarrisonMargaret J. Helber
    • G03C112
    • G03C1/29
    • This invention comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dye layers comprising (a) an inner dye layer adjacent to the silver halide grain and comprising at least one dye, Dye 1, that is capable of spectrally sensitizing silver halide and (b) an outer dye layer adjacent to the inner dye layer and comprising at least one dye, Dye 2, wherein Dye 2 is other than a cyanine dye, wherein the dye layers are held together by non-covalent forces; the outer dye layer adsorbs light at equal or higher energy than the inner dye layer; and the energy emission wavelength of the outer dye layer overlaps with the energy absorption wavelength of the inner dye layer. This invention also comprises a silver halide photographic material comprising at least one silver halide emulsion comprising silver halide grains having associated therewith at least one dye having at least one anionic substituent and at least one dye having at least one cationic substituent, with the proviso that one of the dyes is other than a cyanine dye.
    • 本发明包括卤化银照相材料,其包含至少一种包含卤化银颗粒的卤化银乳剂,所述卤化银颗粒具有至少两个染料层,所述染料层包含(a)与卤化银颗粒相邻的内部染料层,并且包含至少一种染料染料1 能够对卤化银进行光谱增感和(b)与内部染料层相邻的外部染料层,并且包括至少一种染料染料2,其中染料2不是花青染料,其中染料层保持在一起 非共同力量; 外染料层以等于或高于内染料层的能量吸收光; 并且外部染料层的能量发射波长与内部染料层的能量吸收波长重叠。本发明还包括卤化银照相材料,其包含至少一种卤化银乳剂,其包含与其相关联的至少一种染料, 至少一个阴离子取代基和至少一种具有至少一个阳离子取代基的染料,条件是染料之一不是花青染料。
    • 19. 发明授权
    • Photographic material having improved color reproduction
    • 具有改进的色彩再现的照相材料
    • US06140036A
    • 2000-10-31
    • US259992
    • 1999-03-01
    • Richard L. PartonSteven G. LinkJoan C. PotenzaLois A. Buitano
    • Richard L. PartonSteven G. LinkJoan C. PotenzaLois A. Buitano
    • G03C1/14G03C1/16G03C1/18
    • G03C1/16G03C1/18G03C1/14
    • This invention relates to a silver halide photographic material comprising at least one silver halide emulsion having associated therewith at least one dye of Formula I ##STR1## wherein: W and W' represent independently an O atom, a S atom, a Se atom or a NR' group wherein R' is a substituted or unsubstituted alkyl group,Z.sub.1 represents a substituted or unsubstituted aromatic group,Z.sub.1 ' independently represents a fused aromatic group or a substituted or unsubstituted aromatic group which may be appended directly to the dye or Z.sub.1 ' represents LZ.sub.2 where L represents a linking group and Z.sub.2 represents a substituted or unsubstituted aromatic group or substituted or unsubstituted alkyl group,L.sub.1, L.sub.2, and L.sub.3 independently represent methine groups bearing a hydrogen, substituted or unsubstituted alkyl group, or a halogen atom,n represents 0 or 1,the benzene rings shown can be further substituted or unsubstituted,R.sub.1 and R.sub.2 are both substituted or unsubstituted alkyl groups,R.sub.3 is hydrogen or a substituted or unsubstituted alkyl group,X is one or more ions as needed to balance the charge on the molecule.
    • 本发明涉及一种卤化银照相材料,其包含至少一种卤化银乳剂,其具有至少一种式I的染料,其中:W和W'独立地表示O原子,S原子,Se原子或NR'基团 其中R'为取代或未取代的烷基,Z1表示取代或未取代的芳基,Z1'独立地表示可以直接与染料偶联的稠合芳基或取代或未取代的芳基,或者Z1'表示LZ2,其中L 表示连接基团,Z 2表示取代或未取代的芳基或取代或未取代的烷基,L 1,L 2和L 3独立地表示带有氢,取代或未取代的烷基或卤素原子的次甲基,n表示0或1 所示的苯环可以被进一步取代或未取代,R 1和R 2都是取代或未取代的烷基,R 3是氢或取代基 有机或未取代的烷基,X是平衡分子上的电荷所需的一种或多种离子。