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11. 发明授权

US09499671B2 Hydrophilic polysiloxane compositions containing carbinol groups 有权
标题翻译：含有甲醇基团的亲水性聚硅氧烷组合物
公开(公告)号：US09499671B2
公开(公告)日：2016-11-22
申请号：US14514481
申请日：2014-10-15
申请人： Ramani Narayan , Daniel Graiver , Sudhanwa Dewasthale
发明人： Ramani Narayan , Daniel Graiver , Sudhanwa Dewasthale
IPC分类号： C08G77/388
CPC分类号： C08G77/388
摘要： Preparation and use of organopolysiloxanes having carbinol groups that are bonded to the silicon atom through carbamate-containing groups. These hydrophilic polysiloxanes can be made to completely dissolve in water or behave as amphoteric surfactants by controlling the concentration of the carbinol radicals and the molecular weight of the polysiloxane.
摘要翻译：具有通过含氨基甲酸酯基团与硅原子键合的甲醇基的有机聚硅氧烷的制备和用途。这些亲水性聚硅氧烷可以通过控制甲醇基团的浓度和聚硅氧烷的分子量而完全溶解在水中或表现为两性表面活性剂。

12. 发明申请

US20160108179A1 HYDROPHILIC POLYSILOXANE COMPOSITIONS CONTAINING CARBINOL GROUPS 有权
标题翻译：含有碳水化合物组合物的羟基聚硅氧烷组合物
公开(公告)号：US20160108179A1
公开(公告)日：2016-04-21
申请号：US14514481
申请日：2014-10-15
申请人： Ramani Narayan , Daniel Graiver , Sudhanwa Dewasthale
发明人： Ramani Narayan , Daniel Graiver , Sudhanwa Dewasthale
IPC分类号： C08G77/388
CPC分类号： C08G77/388
摘要： Preparation and use of organopolysiloxanes having carbinol groups that are bonded to the silicon atom through carbamate-containing groups. These hydrophilic polysiloxanes can be made to completely dissolve in water or behave as amphoteric surfactants by controlling the concentration of the carbinol radicals and the molecular weight of the polysiloxane.
摘要翻译：具有通过含氨基甲酸酯基团与硅原子键合的甲醇基的有机聚硅氧烷的制备和用途。这些亲水性聚硅氧烷可以通过控制甲醇基团的浓度和聚硅氧烷的分子量而完全溶解在水中或表现为两性表面活性剂。

13. 发明授权

US09273180B2 Polyols from biomass and polymeric products produced therefrom 有权
标题翻译：来自生物质的多元醇和由其生产的聚合物
公开(公告)号：US09273180B2
公开(公告)日：2016-03-01
申请号：US14034611
申请日：2013-09-24
申请人： Ramani Narayan , Daniel Graiver , Elodie Hablot , Vahid Sendijarevic , Siva Rama Krishna Chalasani
发明人： Ramani Narayan , Daniel Graiver , Elodie Hablot , Vahid Sendijarevic , Siva Rama Krishna Chalasani
IPC分类号： C08G63/685 , C08G18/38 , C08G4/00 , C08G18/48 , C08G18/66 , C08G18/76 , C08G71/04 , C07C277/08 , C08G18/60 , C07C269/00 , C07C269/04 , C08G18/64 , C08G101/00
CPC分类号： C08G63/6854 , C07C269/00 , C07C269/04 , C07C277/08 , C08G4/00 , C08G18/3831 , C08G18/4833 , C08G18/60 , C08G18/6446 , C08G18/6685 , C08G18/7664 , C08G71/04 , C08G2101/0025 , C08G2101/0083 , C07C279/14 , C07C279/24
摘要： Polyol compositions containing methane linkages derived from amino acids. The polyols are obtained from the reaction of the carbonate with the cadres in the amino acids. Individual amino acids or mixtures of amino acids that are prepared from the hydrolysis of the proteins can be used.
摘要翻译：含有衍生自氨基酸的甲烷键的多元醇组合物。多元醇是从碳酸盐与氨基酸中的干扰物的反应获得的。可以使用由蛋白质水解制备的单个氨基酸或氨基酸混合物。

14. 发明申请

US20140171535A1 POLYOLS FROM BIOMASS AND POLYMERIC PRODUCTS PRODUCED THEREFROM 有权
标题翻译：生物质的聚合物和生产的聚合物
公开(公告)号：US20140171535A1
公开(公告)日：2014-06-19
申请号：US14034611
申请日：2013-09-24
申请人： Ramani Narayan , Daniel Graiver , Elodie Hablot , Vahid Sendijarevic , Siva Rama Krishna Chalasani
发明人： Ramani Narayan , Daniel Graiver , Elodie Hablot , Vahid Sendijarevic , Siva Rama Krishna Chalasani
IPC分类号： C07C271/20 , C08G4/00 , C08G63/685 , C07C269/04 , C08G18/38
CPC分类号： C08G63/6854 , C07C269/00 , C07C269/04 , C07C277/08 , C08G4/00 , C08G18/3831 , C08G18/4833 , C08G18/60 , C08G18/6446 , C08G18/6685 , C08G18/7664 , C08G71/04 , C08G2101/0025 , C08G2101/0083 , C07C279/14 , C07C279/24
摘要： Polyol compositions containing methane linkages derived from amino acids. The polyols are obtained from the reaction of the carbonate with the cadres in the amino acids. Individual amino acids or mixtures of amino acids that are prepared from the hydrolysis of the proteins can be used.
摘要翻译：含有衍生自氨基酸的甲烷键的多元醇组合物。多元醇是从碳酸盐与氨基酸中的干扰物的反应获得的。可以使用由蛋白质水解制备的单个氨基酸或氨基酸混合物。

15. 发明申请

US20060194975A1 Biodiesel additive and method of preparation thereof 失效
标题翻译：生物柴油添加剂及其制备方法
公开(公告)号：US20060194975A1
公开(公告)日：2006-08-31
申请号：US11363193
申请日：2006-02-27
申请人： Ramani Narayan , Daniel Graiver , Kenneth Farminer
发明人： Ramani Narayan , Daniel Graiver , Kenneth Farminer
IPC分类号： C07C51/43
CPC分类号： C07C67/39 , C07C69/38 , C07C69/48 , C07C69/24
摘要： Fuel oxygenates comprised of fatty acid or fatty acid ester derivatives which have been reacted with ozone; a base; and a lower alkanol (1 to 8 carbon atoms) are described. The oxygenates comprise ester groups at a point of cleavage by the ozone which provide oxygen in the oxygenate.
摘要翻译：由与臭氧反应的脂肪酸或脂肪酸酯衍生物组成的燃料含氧化合物; 一个基地和低级链烷醇（1〜8个碳原子）。含氧化合物在通过在氧合物中提供氧的臭氧裂解的点处包含酯基。

16. 发明申请

US20060194974A1 Novel triglycerides and method of preparation thereof 失效
标题翻译：新型甘油三酯及其制备方法
公开(公告)号：US20060194974A1
公开(公告)日：2006-08-31
申请号：US11363101
申请日：2006-02-27
申请人： Ramani Narayan , Daniel Graiver , Kenneth Farminer , Phuong Tran
发明人： Ramani Narayan , Daniel Graiver , Kenneth Farminer , Phuong Tran
IPC分类号： C07C51/34
CPC分类号： C11C3/006 , C08G18/36 , C08G63/12 , C11C3/08
摘要： A process for the preparation of new polyols from a natural oil is described. The process involves ozone cleavage of double bonds in the fatty acid chains of the oils along with coupling of a di or polyol to the cleaved ends of the molecules resulting from the cleavage with a base. The resulting polyols are as intermediates for polymers.
摘要翻译：描述了从天然油制备新的多元醇的方法。该方法包括在油的脂肪酸链中双键的臭氧裂解以及二元或多元醇与由碱裂解产生的分子的切割末端的偶联。所得多元醇作为聚合物的中间体。

17. 发明申请

US20060035794A1 Triglyceride based lubricant 失效
公开(公告)号：US20060035794A1
公开(公告)日：2006-02-16
申请号：US10915749
申请日：2004-08-11
申请人： Daniel Graiver , Kenneth Farminer , Ramani Narayan , Phuong Tran
发明人： Daniel Graiver , Kenneth Farminer , Ramani Narayan , Phuong Tran
IPC分类号： C10M169/04
CPC分类号： C10M105/38 , C10M111/02 , C10M2201/02 , C10M2203/10 , C10M2207/28 , C10M2207/401 , C10N2220/023 , C10N2220/025 , C10N2220/026 , C10N2230/06 , C10N2230/10 , C10N2240/102 , C10N2240/104 , C10N2240/105
摘要： A method for lubrication by supplying a liquid lubricant to moving metal parts, more than fifty percent by weight of the liquid lubricant being a triglyceride vegetable oil having a saturated fatty acid content of less than nine percent by weight of the triglyceride vegetable oil and a polyunsaturated fatty acid content of more than seventy percent by weight of the triglyceride vegetable oil, the triglyceride vegetable oil having an American Petroleum Institute Thermo-Oxidation Engine Oil Simulation Test rod residue weight of less than thirty five milligrams and a pour point of less than minus twenty degrees Celsius.

18. 发明授权

US6103848A Method of rendering substrates water repellent using hyperbranched polymers containing silicon atoms 失效
标题翻译：使用含有硅原子的超支化聚合物使底物防水的方法
公开(公告)号：US6103848A
公开(公告)日：2000-08-15
申请号：US334902
申请日：1999-06-17
申请人： Gary Thomas Decker , Daniel Graiver , Arthur James Tselepis , Dwight Edward Williams
发明人： Gary Thomas Decker , Daniel Graiver , Arthur James Tselepis , Dwight Edward Williams
IPC分类号： B27K3/15 , C08G77/54 , C08G83/00 , C09D183/14 , C09D201/00 , C08G77/06
CPC分类号： C09D201/005 , C08G77/54 , C08G83/005 , C08L97/02 , C09D183/14 , B27K3/15 , C08K5/3445 , C08L83/04
摘要： Substrates are rendered water repellent by applying to the substrate a hyperbranched polymer containing a silicon atom made by polymerizing a derivatized aminofunctional organosilicon monomer which is the reaction product of an amine functional silane monomer precursor or an amine functional polysiloxane monomer precursor and a derivative of carbonic acid or a cyclic lactone.
摘要翻译：通过向基材施加含有通过聚合作为胺官能的硅烷单体前体或胺官能的聚硅氧烷单体前体与碳酸的衍生物的反应产物的衍生的氨基官能的有机硅单体而制备的硅原子的超支化聚合物，或环状内酯。

19. 发明授权

US5789516A Method of making silicone-organic block copolymers 失效
标题翻译：硅酮有机嵌段共聚物的制备方法
公开(公告)号：US5789516A
公开(公告)日：1998-08-04
申请号：US826716
申请日：1997-04-07
申请人： Daniel Graiver , Aaron Quoc Khieu , Binh Thanh Nguyen
发明人： Daniel Graiver , Aaron Quoc Khieu , Binh Thanh Nguyen
IPC分类号： C08L83/10 , C08F4/40 , C08F4/44 , C08F293/00 , C08G77/442 , C08G77/06
CPC分类号： C08G77/442 , C08F4/40
摘要： A method of manufacturing block copolymers containing a polyorganosiloxane segment, by dual polymerization involving (i) polycondensation of a silicone block followed by (ii) the free radical polymerization of a monomer that can be polymerized by free radical polymerization, such as a vinyl containing organic monomer. Initiation of free radical polymerization in step (ii) is carried out with a carbonyl functional group attached to the silicone polymer block. The carbonyl functional silicone polymer, preferably an aldehyde functional silicone polymer, is included as one component of a copper-based Redox initiating system. The method ensures no free homopolymerization, complete reactivity, and various polymer architectures are possible, including for example, polymeric structures such as AB, ABA, (AB).sub.n, brush, and radiant types. The method is fast, effective, convenient, and easier to control than typical ionic polymerization techniques. The silicone-organic block copolymers obtained by the process have utility as polymeric surfactants or as solubility modifiers.
摘要翻译：通过双重聚合制造含有聚有机硅氧烷链段的嵌段共聚物的方法，包括（i）硅氧烷嵌段的缩聚，随后（ii）可通过自由基聚合反应的单体的自由基聚合，例如含乙烯基的有机物单体。在步骤（ii）中开始自由基聚合是用与硅氧烷聚合物嵌段连接的羰基官能团进行的。羰基官能硅氧烷聚合物，优选醛官能的硅氧烷聚合物，作为铜基氧化还原引发体系的一个组分被包括在内。该方法确保没有游离的均聚，完全的反应性，并且各种聚合物结构是可能的，包括例如聚合物结构如AB，ABA，（AB）n，刷和辐射型。该方法比典型的离子聚合技术快速，有效，方便，易于控制。通过该方法获得的硅氧烷 - 有机嵌段共聚物可用作聚合物表面活性剂或溶解度调节剂。

20. 发明授权

US5708115A Polymerization of vinyl monomers from silanes and siloxanes 失效
公开(公告)号：US5708115A
公开(公告)日：1998-01-13
申请号：US798990
申请日：1997-02-11
申请人： Daniel Graiver , Aaron Quoc Khieu , Binh Thanh Nguyen
发明人： Daniel Graiver , Aaron Quoc Khieu , Binh Thanh Nguyen
IPC分类号： C07F7/08 , C07F7/12 , C07F7/18 , C08F4/16 , C08F4/42 , C08F283/12 , C08G77/38 , C08G77/14
CPC分类号： C08G77/38 , C07F7/12 , C07F7/1836 , C08F4/42
摘要： A method in which radical polymerization of a vinyl monomer is initiated by an ozonide group attached to a silane or a siloxane polymer. The method is particularly useful for preparing organic polymers having a silicone chain end, or for preparing wide ranges of silicone/organic polymers and copolymers with varied architecture, i.e., ABA block copolymers, comb polymers, star polymers, and hyper-branched polymers. In one embodiment, the method is carried out by simply heating a vinyl monomer in the presence of a silane containing ozonide functionality. The ozonide silane is obtained by exposing silanes or siloxanes having an alkyl group containing a double bond to ozone. Surprisingly, an ozonide attached to an organosilicon compound was found to be stable, and capable of initiating vinyl polymerization upon heating to moderate temperatures, i.e., about 70.degree. C.

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