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11. 发明授权

US06320065B1 Fatty acid partial esters of polyols 失效
标题翻译：多元醇的脂肪酸偏酯
公开(公告)号：US06320065B1
公开(公告)日：2001-11-20
申请号：US09306771
申请日：1999-05-07
申请人： Burghard Gruning , Geoffrey Hills
发明人： Burghard Gruning , Geoffrey Hills
IPC分类号： C07C5100
CPC分类号： C12P7/6436 , C07C69/33 , C11D1/66 , C12P7/62 , C12P7/6445 , C12P7/6454 , C12P7/6472
摘要： The invention relates to a process for the preparation of fatty acid partial esters of polyols, the fatty acid partial esters thus obtainable, and their use. The fatty acid partial esters (I) of polyols having at least 4 C atoms, at least one primary and at least one secondary alcohol group of the starting polyols are obtained in a process, where in a first process step the polyols are reacted with a fatty acid or a fatty acid derivative to give a fatty acid partial ester (II) and in a second process step the fatty acid partial esters (II) obtained are subjected to a selective enzymatic cleavage of primary ester groups.
摘要翻译：本发明涉及一种制备多元醇的脂肪酸偏酯的方法，由此得到的脂肪酸偏酯及其用途。具有至少4个C原子的多元醇的脂肪酸偏酯（I），至少一个伯并且在一个方法中获得起始多元醇的至少一个仲醇基团，其中在第一工艺步骤中，多元醇与脂肪酸或脂肪酸衍生物反应，得到脂肪酸偏酯（II）所获得的脂肪酸偏酯（II）进行主要酯基的选择性酶裂解。

12. 发明授权

US06287578B1 Condensation products containing polyether-modified monoesters and/or -amides of &agr;, &bgr;-unsaturated dicarboxylic acids, their preparation and use 失效
标题翻译：包含α，β-不饱和二羧酸的聚醚改性单酯和/或酰胺的缩合产物，其制备和用途
公开(公告)号：US06287578B1
公开(公告)日：2001-09-11
申请号：US09312221
申请日：1999-05-14
申请人： Michael Duetsch , Burghard Gruning , Jorg Simpelkamp , Christian Weitemeyer
发明人： Michael Duetsch , Burghard Gruning , Jorg Simpelkamp , Christian Weitemeyer
IPC分类号： A61K600
CPC分类号： A61Q19/10 , A61K8/06 , A61K8/85 , A61K8/88 , A61Q5/02 , A61Q11/00 , C08G69/10 , C08G73/1092 , C11D3/3719
摘要： The present invention describes condensation products of polyether-modified and optionally hydrophobically modified monoesters and/or -amides of &agr;, &bgr;-unsaturated dicarboxylic acids and ammonia, their preparation and use. The condensation products contain polyoxyalkylene chains bonded via ester and/or amide bonds and prepared from monoesters and/or monoamides of monoethylenically unsaturated dicarboxylic acids and ammonia or prepared from the ammonium salts of said acids, and the mixtures thereof, optionally in the presence of cocondensable compounds.
摘要翻译：本发明描述了聚醚改性和任选疏水改性的α，β-不饱和二羧酸和氨的酰胺的缩合产物及其制备和用途。缩合产物含有通过酯和/或酰胺键键合的聚氧化烯链并由单烯属不饱和二羧酸和氨的单酯和/或单酰胺制备，或由所述酸的铵盐及其混合物任选在共缩合化合物存在下制备。

13. 发明授权

US06268521B1 Process for preparing acrylic esters and/or methacrylic esters of polyoxyalkylenes and the use thereof 有权
标题翻译：制备聚氧化烯的丙烯酸酯和/或甲基丙烯酸酯的方法及其用途
公开(公告)号：US06268521B1
公开(公告)日：2001-07-31
申请号：US09431448
申请日：1999-11-01
申请人： Burghard Gruning , Geoffrey Hills , Wolfgang Josten , Dietmar Schaefer , Stefan Silber , Christian Weitemeyer
发明人： Burghard Gruning , Geoffrey Hills , Wolfgang Josten , Dietmar Schaefer , Stefan Silber , Christian Weitemeyer
IPC分类号： C08F6954
CPC分类号： C08G65/3322 , C12P7/62
摘要： The present invention provides a process for enzymatic preparation of acrylic esters and/or methacrylic esters of polyoxyalkylenes, and to the use thereof. The acryloyl and/or methacryloyl compounds of polyoxyalkylenes are obtainable by a process for esterifying or transesterifying acrylic and/or methacrylic acid or acrylic and/or methacrylic esters with a polyoxyalkylene of the general formula (I) wherein R1, R2, R3 and a-e are as defined in claim 1 and wherein at least one OH group is present per molecule and the sequence of the polyoxyalkylene segments (C2H4-aR2aO)b and (CcH2cO)d is arbitrary, in the presence of an enzyme which catalyzes the esterification or transesterification.
摘要翻译：本发明提供了一种用于酶制备聚氧化烯的丙烯酸酯和/或甲基丙烯酸酯的方法及其用途。聚氧化烯的丙烯酰基和/或甲基丙烯酰基化合物可通过丙烯酸和/或甲基丙烯酸或丙烯酸和/或甲基丙烯酸酯与通式（I）的聚氧化烯酯化或酯交换的方法获得，其中R1，R2，R3和ae为如在权利要求1中所定义的，并且其中每个分子存在至少一个OH基团，并且在催化酯化或酯交换的酶的存在下，聚氧化烯链段（C 2 H 4 -a R 2a）b和（C 1 H 8 C 10）d的序列是任意的。

14. 发明授权

US5837831A Method for separating alkyl glycosides 失效
标题翻译：分离烷基糖苷的方法
公开(公告)号：US5837831A
公开(公告)日：1998-11-17
申请号：US717950
申请日：1996-09-23
申请人： Burghard Gruning , Siegfried Peter , Eckhard Weidner , Zhengfeng Zhang
发明人： Burghard Gruning , Siegfried Peter , Eckhard Weidner , Zhengfeng Zhang
IPC分类号： C07H1/06 , C07B63/00 , C07H15/04 , C07G3/00
CPC分类号： C07H15/04 , Y02P20/544
摘要： The invention relates to a method for separating alkyl glycoside mixtures or alcohol-containing alkyl glycoside mixtures by extraction, which is characterized in that the extraction is carried out with an extraction agent, which is close to or below the critical point at a reduced temperature ranging from 0.9 to 1.2, and at pressures, which are selected so that the density of the extraction agent is at least 180 kg/m.sup.3.
摘要翻译：本发明涉及一种通过提取分离烷基糖苷混合物或含醇烷基糖苷混合物的方法，其特征在于用提取剂进行萃取，该提取剂在降低的温度范围内接近或低于临界点 0.9至1.2，并且在压力下，其选择使得提取剂的密度为至少180kg / m 3。

15. 发明授权

US4931362A Microcapsule and micromatrix bodies and method for their formation 失效
标题翻译：微胶囊和微阵体及其形成方法
公开(公告)号：US4931362A
公开(公告)日：1990-06-05
申请号：US233667
申请日：1988-08-18
申请人： Wilhelm Zsifkovits , Burghard Gruning , Hans-Joachim Kollmeier , Dietmar Schaefer , Christian Weitemeyer
发明人： Wilhelm Zsifkovits , Burghard Gruning , Hans-Joachim Kollmeier , Dietmar Schaefer , Christian Weitemeyer
IPC分类号： B01J13/18 , B41M5/165
CPC分类号： B01J13/18 , B01J13/185 , B41M5/165 , Y10S514/963 , Y10S514/965 , Y10T428/2985 , Y10T428/2987
摘要： An organic phase which comprises a water-insoluble material to be encapsulated, a capsule-forming or matrix-forming monomer or prepolymer and, should this be desirable, a solvent, is dispersed in droplet form in an aqueous phase. The capsule-forming or matrix-forming monomer or prepolymer forms a sheath around the material to be encapsulated. As a capsule-forming or matrix-forming monomer, an organosilicon compound of the general formula ##STR1## is used, wherein R.sup.1 is a linear or branched, saturated or unsaturated, n-functional hydrocarbon moiety, which may be interrupted by groups containing oxygen, nitrogen or sulfur; R.sup.2 and R.sup.3 are the same or different and represent a hydrocarbon moiety with 1 to 6 carbon atoms or X; X is a hydroxyl group or a hydrolyzable group and n is a whole number greater than or equal to 1, with the proviso that, when n=1, R.sup.1 has at least 12 carbon atoms and R.sup.2 and R.sup.3 represent X or a prepolymer hereof. The method can be carried out easily and requires only one compound to form the capsules or micromatrix bodies. In the implementation of the method, no foam occurs and the method results in end products with an acceptable shelf life.
摘要翻译：包含待包封的水不溶性材料，胶囊形成或基质形成单体或预聚物的有机相，并且如果这是期望的话，溶剂以水滴形式分散在水相中。胶囊形成或基质形成单体或预聚物在待包被材料周围形成鞘。作为胶囊形成或基质形成单体，使用通式“IMAGE”的有机硅化合物，其中R 1是直链或支链饱和或不饱和的正构官能烃部分，其可以被含氧的基团中断，氮或硫; R2和R3相同或不同，表示具有1至6个碳原子的烃部分或X; X是羟基或可水解基团，n是大于或等于1的整数，条件是当n = 1时，R 1具有至少12个碳原子，R 2和R 3表示X或其预聚物。该方法可以容易地进行，并且仅需要一种化合物来形成胶囊或微阵列体。在该方法的实施中，不发生泡沫，并且该方法导致最终产品具有可接受的保质期。

16. 发明申请

US20090087399A1 POLYSILOXANE BLOCK COPOLYMERS 失效
标题翻译：聚硅氧烷嵌段共聚物
公开(公告)号：US20090087399A1
公开(公告)日：2009-04-02
申请号：US12238596
申请日：2008-09-26
申请人： Dirk KUPPERT , Burghard Gruning , Brain Yang , Sven Balk , Gerd Lohden
发明人： Dirk KUPPERT , Burghard Gruning , Brain Yang , Sven Balk , Gerd Lohden
IPC分类号： A61K8/89 , C08L83/10 , A61Q5/12 , C08L53/00
CPC分类号： A61K8/899 , A61Q5/06 , C08G77/385 , C08G77/442 , C08L83/10
摘要： The invention relates to polysiloxane block copolymers of the formula A[LB(S)Q]m, where A is a polysiloxane block, L is a divalent organic linker, B is a polymer block composed of radically polymerizable monomers, S is a sulfur atom and Q is a monovalent organic radical and m is an integer from 1 to 50, to a method for their production, and to their use in cosmetics or personal care.
摘要翻译：本发明涉及式A [LB（S）Q] m的聚硅氧烷嵌段共聚物，其中A是聚硅氧烷嵌段，L是二价有机连接基，B是由可自由基聚合的单体组成的聚合物嵌段，S是硫原子 Q为1价有机基团，m为1〜50的整数，其制造方法及其在化妆品或个人护理中的用途。

17. 发明授权

US07465438B2 Solubilizing agents/solvents for organic UV filters 失效
标题翻译：有机紫外线过滤器的增溶剂/溶剂
公开(公告)号：US07465438B2
公开(公告)日：2008-12-16
申请号：US11105837
申请日：2005-04-14
申请人： Christoph Schunicht , Burghard Gruning , Pawel Grzebyk , Klaus Jenni
发明人： Christoph Schunicht , Burghard Gruning , Pawel Grzebyk , Klaus Jenni
IPC分类号： A61K8/00 , A61K8/18 , A61K8/02 , A61K31/44 , A61Q17/04
CPC分类号： A61K8/37 , A61K8/33 , A61K8/39 , A61Q17/04
摘要： The invention relates to the use of compounds of the general formula (I) wherein R, R′=H, C1-5-hydrocarbon radical, —O—C1-5-oxyhydrocarbon radical and are identical or different, R1, R2, R3=H, C1-5-hydrocarbon radical and are identical or different, X, Y=—O—; —O—C(O)—; —(O)C—O— and are identical or different, A=Aα=—O—C(O)—O—; Aβ=R4—CH2C(CH2—)3, Aγ=—C(H)-isopropyl, R4=R4δ=—CH3; R4ε=—[CH2—CH(R1)]e—(Y)d—(CH2)c-Ph(R)a, a, b=1 to 5 and are identical or different, c, k=0 to 5 and are identical or different, d, h=0 or 1 and are identical or different, e, g=0 or 1 and are identical or different, f=0 or 1, m=1 to 3, n=0 or 1, as solubilizing agents/solvents for dissolving organic UV filters.
摘要翻译：本发明涉及通式（I）的化合物，其中R，R'= H，C 1-5 - 烃基，-O-C 1-5 - 羟基烃基和R 1，R 2，R 3 = H，C 1-5烃基，相同或不同，X，Y = -O-; -O-C（O） - ; - （O）C-O-并且相同或不同，A = Aalpha = -O-C（O）-O-; Abeta = R4-CH2C（CH2-）3，Agamma = -C（H） - 异丙基，R4 = R4delta = -CH3; R4 =（CH2）c-（Y）d-（CH2）c-Ph（R）a，a，b = 1〜5，相同或不同，c，k = 0〜5，相同或不同，d，h = 0或1并且相同或不同，e，g = 0或1，并且相同或不同，f = 0或1，m = 1至3，n = 0或1，用于溶解有机UV过滤器的增溶剂/溶剂。

18. 发明申请

US20050261484A1 Process for preparing alkylglycosides 失效
标题翻译：制备烷基糖苷类的方法
公开(公告)号：US20050261484A1
公开(公告)日：2005-11-24
申请号：US11113750
申请日：2005-04-25
申请人： Matthias Pascaly , Burghard Gruning , Dietrich Maass , Christian Weitemeyer
发明人： Matthias Pascaly , Burghard Gruning , Dietrich Maass , Christian Weitemeyer
IPC分类号： C07H1/00 , C07H15/04 , C07H15/06 , C07H15/10
CPC分类号： C07H15/06 , C07H15/04 , C07H15/10 , Y02P20/544
摘要： The invention relates to a process for preparing alkylpolyglycosides from monomeric glycosides, oligo- or polyglycosides and alcohols according to the general scheme (Glyc-O)zH+R1—OH→(Glyc-O)z′R1 where z≧1 z′≦z, preferably from 1 to 10, (Glyc-O)— is a glycoside radical, R1 is a hydrocarbon radical which optionally contains multiple bonds and/or heteroatoms, which comprises carrying out the reaction under supercritical conditions with regard to the alcohol, preferably at pressures and temperatures which are at least 5% above the critical parameters, the alcohols serving both as the solvent and as reactants.
摘要翻译：本发明涉及根据通用方案<？in-line-formula description =“In-line Formulas”end =“lead”→（Glyc-O）的单体糖苷，寡糖或多糖苷和醇制备烷基多糖苷的方法）H 1 H + R 1 -OH - （Glyc-O）z' 1 -line-formula description =“In-line Formulas”end =“tail”？>其中z> = 1 z'<= z，优选为1〜10，（Glyc-O） - 为糖苷基，R为 > 1是烃基，其任选地包含多个键和/或杂原子，其包括在超临界条件下相对于醇进行反应，优选在高于关键参数的至少5％的压力和温度下，既用作溶剂又用作反应物的醇。

19. 发明授权

US6150543A Enzymatic preparation of regioselective fatty acid esters of ascorbic acid 失效
标题翻译：抗坏血酸区域选择性脂肪酸酯的酶制剂
公开(公告)号：US6150543A
公开(公告)日：2000-11-21
申请号：US211182
申请日：1998-12-14
申请人： Burghard Gruning , Geoffrey Hills
发明人： Burghard Gruning , Geoffrey Hills
IPC分类号： C07D307/62 , C12P17/04 , C07C59/00 , C07D305/12
CPC分类号： C07D307/62 , C12P17/04
摘要： The invention relates to a process for the enzymatic preparation of regioselective fatty acid esters of ascorbic acid and selected fatty acid alkyl esters.Ascorbic acid and fatty acid alkyl esters are reacted in a solvent or suspending agent at reduced pressure in relation to the atmosphere and temperatures above the boiling point of the resulting alcohol of reaction.
摘要翻译：本发明涉及一种酶制备抗坏血酸和选择性脂肪酸烷基酯的区域选择性脂肪酸酯的方法。抗坏血酸和脂肪酸烷基酯在溶剂或悬浮剂中相对于气氛和低于所得反应醇沸点的温度在减压下反应。

20. 发明授权

US5994415A Compound antifoams for defoaming polymer dispersions and aqueous coating systems 失效
标题翻译：用于消泡聚合物分散体和水性涂料体系的复合消泡剂
公开(公告)号：US5994415A
公开(公告)日：1999-11-30
申请号：US78958
申请日：1998-05-14
申请人： Burghard Gruning , Petra Hinrichs , Michael Keup , Frank Konig , Stefan Silber , Roland Sucker , Ellen Wallhorn
发明人： Burghard Gruning , Petra Hinrichs , Michael Keup , Frank Konig , Stefan Silber , Roland Sucker , Ellen Wallhorn
IPC分类号： B01D19/04 , C09K3/00
CPC分类号： B01D19/0404
摘要： The invention relates to compound antifoams comprising alkoxylated partial esters--using from 3 to 60 mol of propylene oxide with or without from 1 to 10 mol of styrene oxide and/or from 1 to 10 mol of butylene oxide--of oligoglycerols, obtainable by condensation of 2 to 20 glycerol molecules, with C.sub.8 to C.sub.22 fatty acids and inorganic or organic solids for defoaming polymer dispersions and aqueous coating systems.
摘要翻译：本发明涉及包含烷氧基化偏酯的化合物消泡剂 - 使用3至60摩尔环氧丙烷，具有或不具有1-10摩尔氧化苯乙烯和/或1-10摩尔环氧丁烷的低聚甘油，其可通过 2至20个甘油分子，具有C8至C22脂肪酸和无机或有机固体，用于消泡聚合物分散体和水性涂料体系。

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