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11. 发明授权

US6051294A Heat-resistant hydroxy-functional polyethers as thermoplastic barrier resins 失效
标题翻译：耐热羟基官能聚醚作为热塑性阻隔树脂
公开(公告)号：US6051294A
公开(公告)日：2000-04-18
申请号：US21058
申请日：1998-02-09
申请人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
发明人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
IPC分类号： C08L71/00 , B65B55/00
CPC分类号： C08L71/00 , Y10T428/1352
摘要： Hydroxy-functional polyethers having a "cardo" diphenylene group in their backbones are prepared by contacting at least one dinucleophilic monomer with at least one dtglycidyl ether of a cardo bisphenol, such as bis(hydroxyphenyl)fluorene, phenolphthalein, or phenolphthalimidine or a substituted cardo bisphenol, such as a substituted bis(hydroxyphenyl)fluorene, a substituted phenolphthalein or a substituted phenolphthalimidine, under conditions sufficient to cause the nucleophillo moieties of the dinucleophilic monomer to react with epoxy moieties to form a polymer backbone containing pendant hydroxy moieties and ether, imino, amino, sulfonamido or ester linkages. These polyethers possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rate less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day to oxygen) and high heat resistance (i.e., Tg above 120.degree. C.). These polyethers are suitable for use in the manufacture of retort-sterilizable packaging materials exhibiting high barrier to oxygen.
摘要翻译：在其主链中具有“cardo”二亚苯基的羟基官能的聚醚通过使至少一种双亲性单体与双酚（如双（羟基苯基）芴，酚酞或苯酚苯并咪唑或取代的cardo双酚的至少一种dt缩水甘油醚双酚，例如取代的双（羟基苯基）芴，取代的酚酞或取代的苯酚苯酞，在足以使双亲单体的亲核部分与环氧部分反应形成含有侧羟基部分和醚的聚合物主链的条件下，亚氨基，氨基，亚磺酰氨基或酯键。这些聚醚具有高的透氧阻隔性（氧气透过率低于氧气的氧气渗透速度小于10.0立方厘米/ 100英寸/天）和高耐热性（即高于120℃的Tg）。这些聚醚适用于制造显示出高阻隔氧的蒸煮灭菌包装材料。

12. 发明授权

US5532331A Thiodiphenol copolycarbonates and their use as components of multilayered polymeric reflective bodies 失效
标题翻译：硫代二苯酚共聚碳酸酯及其作为多层聚合物反射体的组分的用途
公开(公告)号：US5532331A
公开(公告)日：1996-07-02
申请号：US351436
申请日：1994-12-14
申请人： Stephen E. Bales , Charles A. Langhoff , John A. Wheatley
发明人： Stephen E. Bales , Charles A. Langhoff , John A. Wheatley
IPC分类号： C08G64/08 , C08G64/00
CPC分类号： C08G64/081 , Y10T428/31507
摘要： This invention provides novel copolycarbonates that exhibit improvements in glass transition temperature, refractive index, and limiting oxygen index compared to prior art thiodiphenol/bisphenol A copolycarbonates. The copolycarbonates of this invention comprise the reaction products of 4,4'-thiodiphenol and compounds such as 9,9-bis (4-hydroxyphenyl) fluorene with phosgene. They are useful as components of multilayered polymeric reflective bodies.
摘要翻译： PCT No.PCT / US93 / 06074 Sec。 371日期1994年12月15日 102（e）1994年12月15日日期PCT提交1993年6月24日PCT公布。出版物WO94 / 02533 日本1994年2月3日。本发明提供与现有技术的硫代二酚/双酚A共聚碳酸酯相比，显示玻璃化转变温度，折射率和极限氧指数的改进的新型共聚碳酸酯。本发明的共聚碳酸酯包括4,4'-硫代二酚和诸如9,9-双（4-羟基苯基）芴和光气的化合物的反应产物。它们可用作多层聚合物反射体的组分。

13. 发明授权

US5208299A Nonlinear optical arylhydrazones and nonlinear optical polymers thereof 失效
标题翻译：非线性光学芳基腙及其非线性光学聚合物
公开(公告)号：US5208299A
公开(公告)日：1993-05-04
申请号：US866400
申请日：1992-04-10
申请人： Stephen E. Bales , David J. Brennan , Robert J. Gulotty , Anthony P. Haag , Muthiah N. Inbasekaran
发明人： Stephen E. Bales , David J. Brennan , Robert J. Gulotty , Anthony P. Haag , Muthiah N. Inbasekaran
IPC分类号： G02F1/35 , C07C251/86 , C07C255/66 , C07C317/32 , C07C317/34 , C07C323/48 , C07D277/82 , C08G59/62 , C08G63/68 , C08G63/685 , C08G64/00 , C08G64/08 , C08G64/12 , C08G65/00 , C08G65/40 , C08G73/00 , C08J5/18 , C08L67/02 , C08L69/00 , C08L71/00 , C08L101/00 , D01F6/92 , G02F1/355 , G02F1/361
CPC分类号： C07C317/32 , C07C251/86 , C07C255/66 , C07C317/34 , C07C323/48 , C07D277/82 , C08G59/621 , C08G63/68 , C08G63/685 , C08G64/08 , C08G65/4006 , C08G65/4031 , G02F1/3611 , G02F1/3613 , G02F1/3614 , G02F1/3616
摘要： The present invention relates to nonlinear optical material comprising nonlinear optical dihydroxy arylhydrazones and to nonlinear optical materials comprising compositions containing at least one divalent moiety of nonlinear optical arylhydrazones. The present invention also relates to polyesters, polyestercarbonates, polycarbonates, polyethers, and poly(hydroxy ether) polymers, incorporating the dihydroxy arylhydrazone as recurring divalent moieties in the backbone of the polymer. The polymeric compositions of the present invention have high glass transition temperatures and exhibit stable nonlinear optical activity at high temperatures over a period of time.
摘要翻译：本发明涉及包含非线性光学二羟基芳基腙的非线性光学材料和包含含有非线性光学芳基腙的至少一个二价部分的组合物的非线性光学材料。本发明还涉及在聚合物主链中掺入二羟基芳基腙作为重复的二价部分的聚酯，聚酯碳酸酯，聚碳酸酯，聚醚和聚（羟基醚）聚合物。本发明的聚合物组合物具有高玻璃化转变温度，并且在一段时间内在高温下表现出稳定的非线性光学活性。

14. 发明授权

US5037935A Thermoplastic compositions with nonlinear optical activity 失效
标题翻译：具有非线性光学活性的热塑性组合物
公开(公告)号：US5037935A
公开(公告)日：1991-08-06
申请号：US535210
申请日：1990-06-08
申请人： Robert J. Gulotty , Stephen E. Bales
发明人： Robert J. Gulotty , Stephen E. Bales
IPC分类号： C08G63/64 , C08G64/08 , C08G64/12
CPC分类号： C08G64/08 , C08G63/64 , C08G64/12
摘要： This invention provides thermoplastic polymeric materials comprising polycarbonate and polyestercarbonate resins and oriented polymeric compositions thereof which exhibit nonlinear optical properties.
摘要翻译：本发明提供包含聚碳酸酯和聚酯碳酸酯树脂的热塑性聚合物材料及其取向的聚合物组合物，其显示非线性光学性质。

15. 发明授权

US4994533A Poly(aryl ether)-poly(aryl carbonate) block copolymers and their preparation 失效
标题翻译：聚（芳基醚） - 聚（芳基碳酸酯）嵌段共聚物及其制备方法
公开(公告)号：US4994533A
公开(公告)日：1991-02-19
申请号：US329802
申请日：1989-03-28
申请人： Michael J. Mullins , Steven P. Crain , Edmund P. Woo , Daniel J. Murray , Stephen E. Bales
发明人： Michael J. Mullins , Steven P. Crain , Edmund P. Woo , Daniel J. Murray , Stephen E. Bales
IPC分类号： C08G64/18 , C08G64/42
CPC分类号： C08G64/183 , C08G64/42
摘要： A method for preparing novel poly(aryl ether)-(poly aryl carbonate) block copolymers by the decarboxylation of copolycarbonates prepared by the condensation of two different aromatic dihydroxy compounds and a carbonate precursor such as phosgene. At least one of the aromatic diols must have at least one electron-withdrawing group located in a position ortho or para to at least one of its hydroxy groups and at least one of the diols must not have any electron-withdrawing groups in a position ortho or para to either of its hydroxy groups. The method is particularly effective in making crystalline block copolymers.
摘要翻译：通过使两种不同的芳族二羟基化合物和碳酸酯前体如光气缩合制备的共聚碳酸酯的脱羧来制备新的聚（芳基醚） - （聚芳基碳酸酯）嵌段共聚物的方法。至少一种芳族二醇必须具有位于至少一个羟基的邻位或对位的至少一个吸电子基团，并且至少一个二醇在邻位不能具有任何吸电子基团或对位于其任一羟基。该方法在制备结晶嵌段共聚物中特别有效。

16. 发明授权

US4818254A Semi-permeable membranes consisting predominantly of polycarbonates derived from tetrahalobisphenols 失效
标题翻译：半透膜主要由衍生自四卤双酚的聚碳酸酯组成
公开(公告)号：US4818254A
公开(公告)日：1989-04-04
申请号：US141878
申请日：1988-01-06
申请人： Joginder N. Anand , Darrell C. Feay , Stephen E. Bales , Thomas O. Jeanes
发明人： Joginder N. Anand , Darrell C. Feay , Stephen E. Bales , Thomas O. Jeanes
IPC分类号： B01D71/50 , C01B13/02 , C01B21/04 , C01B32/50 , C07C7/144 , C08G64/10 , B01D53/22
CPC分类号： C08G64/10 , B01D71/50 , C01B13/0255 , C01B21/0444 , C01B31/20 , C07C7/144 , C01B2210/0045 , C01B2210/0046
摘要： The invention is an improved gas separation membrane comprising a thin, discriminating layer consisting predominantly of a carbonate polymer derived from a bisphenol corresponding to Formula I ##STR1## wherein R at each occurrence is independently H, Cl, Br, or C.sub.1 -C.sub.4 alkyl and R.sup.1 is ##STR2## --S--, --SO.sub.2 --, --O--, or a C.sub.1 -C.sub.6 divalent hydrocarbon or a C.sub.1 -C.sub.6 divalent fluorocarbon radical or inertly substituted hydrocarbon radical, with the proviso that at least 25 weight percent of the moieties derived from the bisphenol of Formula I present in the discriminating layer bear R groups which are exclusively Br or Cl, the gas separation membrane exhibiting a separation factor for oxygen and nitrogen at 24.degree. C. of at least 6.1. In another aspect this invention relates to a process for separating oxygen from nitrogen, or a nitrogen-containing gas.
摘要翻译：本发明是一种改进的气体分离膜，其包括主要由衍生自对应于式I的双酚的碳酸酯聚合物组成的薄的鉴别层，其中R在每次出现时独立地为H，Cl，Br或C 1 -C 4烷基， R 1是-S-，-SO 2 - ， - O-或C 1 -C 6二价烃或C 1 -C 6二价氟代烃基或惰性取代的烃基，条件是至少25重量％的部分衍生自鉴别层中存在的式I的双酚的R基团仅具有Br或Cl，气相分离膜在24℃下表现出氧和氮的分离因子至少为6.1。另一方面，本发明涉及从氮气或含氮气体中分离氧气的方法。

17. 发明授权

US5814373A Heat-resistant hydroxy-functional polyethers as thermoplastic barrier resins 失效
标题翻译：耐热羟基官能聚醚作为热塑性阻隔树脂
公开(公告)号：US5814373A
公开(公告)日：1998-09-29
申请号：US131110
申请日：1993-10-01
申请人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
发明人： Jerry E. White , H. Craig Silvis , Stephen E. Bales , Michael N. Mang , Muthiah N. Inbasekaran
IPC分类号： C08G59/06 , C08G59/62 , C08L71/00 , B65B55/00
CPC分类号： C08G59/066 , C08G59/621 , C08L71/00 , Y10T428/1307 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383
摘要： Hydroxy-functional polyethers having a "cardo" diphenylene group in their backbones are prepared by contacting at least one dinucleophilic monomer with at least one diglycidyl ether of a cardo bisphenol, such as bis(hydroxyphenyl)fluorene, phenolphthalein, or phenolphthalimidine or a substituted cardo bisphenol, such as a substituted bis(hydroxyphenyl)fluorene, a substituted phenolphthalein or a substituted phenolphthalimidine, under conditions sufficient to cause the nucleophilic moieties of the dinucleophilic monomer to react with epoxy moieties to form a polymer backbone containing pendant hydroxy moieties and ether, imino, amino, sulfonamido or ester linkages. These polyethers possess a combination of high barrier to oxygen transmission (i.e., oxygen transmission rate less than 10.0 cm.sup.3 -mil/100 in.sup.2 -atm-day to oxygen) and high heat resistance (i.e., Tg above 120.degree. C.). These polyethers are suitable for use in the manufacture of retort-sterilizable packaging materials exhibiting high barrier to oxygen.
摘要翻译：在其主链中具有“cardo”二亚苯基的羟基官能聚醚通过使至少一种亲核性单体与双酚（如双（羟基苯基）芴，酚酞或苯酚苯并咪唑或取代的cardo双酚的至少一种二缩水甘油醚双酚，例如取代的双（羟基苯基）芴，取代的酚酞或取代的苯酚苯酞，在足以使亲核单体的亲核部分与环氧部分反应形成含有侧羟基部分和醚的聚合物主链的条件下，亚氨基，氨基，亚磺酰氨基或酯键。这些聚醚具有高的透氧阻隔性（氧气透过率低于氧气的氧气渗透速度小于10.0立方厘米/ 100英寸/天）和高耐热性（即高于120℃的Tg）。这些聚醚适用于制造显示出高阻隔氧的蒸煮灭菌包装材料。

18. 发明授权

US5614599A Stilbene-based polyester and polycarbonate compositions 失效
标题翻译：二苯乙烯基聚酯和聚碳酸酯组合物
公开(公告)号：US5614599A
公开(公告)日：1997-03-25
申请号：US542489
申请日：1995-10-13
申请人： Stephen E. Bales , Robert E. Hefner, Jr. , Rina Singh
发明人： Stephen E. Bales , Robert E. Hefner, Jr. , Rina Singh
IPC分类号： C08L67/03 , C08G63/547 , C08G63/64 , C08G64/04 , C08L67/06 , C08L69/00 , C08L101/00 , C08F283/00
CPC分类号： C08G63/547 , C08G63/64 , C08G64/045
摘要： Described is a polycarbonate, polyester, or polyestercarbonate composition prepared from a reaction mixture comprising at least one diol and at least one carbonate precursor or ester precursor, wherein at least about 95 mole percent of the diol present in the reaction mixture consists of one or more aromatic diols, at least about 10 mole percent of which consists of one or more stilbene diols. The composition of the invention advantageously has a relatively high thermal resistance, melting temperature, tensile and flexural properties, and/or resistance to thermal embrittlement. Moreover, the polymers of the invention which are thermotropic liquid crystalline also advantageously possess a broad temperature range for liquid crystallinity, good melt processibility, a low coefficient of thermal expansion, a high ignition resistance, high solvent resistance, and/or good barrier properties.
摘要翻译：描述了由包含至少一种二醇和至少一种碳酸酯前体或酯前体的反应混合物制备的聚碳酸酯，聚酯或聚酯碳酸酯组合物，其中存在于反应混合物中的至少约95摩尔％的二醇由一种或多种芳族二醇，其至少约10摩尔％由一种或多种二苯乙烯二醇组成。本发明的组合物有利地具有相对高的耐热性，熔融温度，拉伸和弯曲性能和/或耐热脆性。此外，作为热致液晶的本发明的聚合物还有利地具有液晶的宽温度范围，良好的熔融加工性，低热膨胀系数，高耐点火性，高耐溶剂性和/或良好的阻隔性能。

19. 发明授权

US5486577A Blends of diaryl fluorene carbonate polymers with bisphenol A carbonate polymers 失效
标题翻译：二芳基芴碳酸酯聚合物与双酚A碳酸酯聚合物的共混物
公开(公告)号：US5486577A
公开(公告)日：1996-01-23
申请号：US407930
申请日：1995-03-21
申请人： Hani Farah , Stephen E. Bales
发明人： Hani Farah , Stephen E. Bales
IPC分类号： C08L69/00
CPC分类号： C08L69/00
摘要： Carbonate polymer compositions are prepared comprising a first diaryl fluorene carbonate polymer component and a second bisphenol A carbonate polymer component, the blend composition preferably comprising from about 1 to about 99 weight percent diaryl fluorene carbonate polymer component based on weight of first and second components. Preferably the first diaryl fluorene carbonate polymer component is a copolymer comprising (a) from about 1 up to and including about 99 mole percent dihydroxyaryl fluorene moiety based on the weight of dihydroxyaryl fluorene compound and additional multihydric monomer compound and (b) moieties of at least one additional condensation copolymerizable multihydric monomer compound remnant. In another embodiment, the invention is an improved process for preparing heat resistant diaryl fluorene carbonate polymer composition comprising the step of combining a first diaryl fluorene carbonate polymer component and a second bisphenol A carbonate polymer component, different from the diaryl fluorene carbonate polymer component. These blends can be prepared by known means such as by solution blending or melt blending. It has surprisingly been found that these blend compositions are miscible and transparent across a range of weight ratios and diaryl fluorene contents.
摘要翻译：制备碳酸酯聚合物组合物，其包含第一二芳基芴碳酸酯聚合物组分和第二双酚A碳酸酯聚合物组分，所述共混组合物优选包含基于第一组分和第二组分重量的约1至约99重量％的二芳基芴碳酸酯聚合物组分。优选地，第一二芳基芴碳酸酯聚合物组分是包含（a）基于二羟基芳基芴化合物和另外的多羟基单体化合物的重量的约1至约99摩尔％的二羟基芳基芴部分的共聚物，和（b）至少一种另外的可共聚的多羟基单体化合物残余物。在另一个实施方案中，本发明是制备耐热二芳基芴碳酸酯聚合物组合物的改进方法，其包括将不同于二芳基芴碳酸酯聚合物组分的第一二芳基芴碳酸酯聚合物组分和第二双酚A碳酸酯聚合物组分组合的步骤。这些共混物可以通过已知的方法制备，例如通过溶液共混或熔融共混。惊奇地发现，这些共混组合物在重量比和二芳基芴含量范围内是可混溶和透明的。

20. 发明授权

US5466397A Nonlinear optically active pyrazolines and polymeric compositions containing moieties derived therefrom 失效
标题翻译：非线性光学活性吡唑啉和含有衍生自其的部分的聚合物组合物
公开(公告)号：US5466397A
公开(公告)日：1995-11-14
申请号：US159010
申请日：1993-11-29
申请人： Stephen E. Bales , David J. Brennan , Robert J. Gulotty, Jr. , Muthiah N. Inbasekaran , Michael N. Mang , Mark D. Newsham
发明人： Stephen E. Bales , David J. Brennan , Robert J. Gulotty, Jr. , Muthiah N. Inbasekaran , Michael N. Mang , Mark D. Newsham
IPC分类号： C07D231/06 , C07D303/22 , C07D405/14 , C08G59/06 , C08G59/26 , C08G59/62 , C08G64/12 , G02F1/361 , F21V9/00 , C08F2/46
CPC分类号： C07D231/06 , C07D303/22 , C07D405/14 , C08G59/066 , C08G59/26 , C08G59/621 , C08G64/12 , G02F1/3612 , G02F1/3616
摘要： Disclosed are compounds containing substituted pyrazoline which exhibit nonlinear optical activity on orientation and to oriented polymeric compositions comprising moieties derived therefrom in the backbone of the polymer. Also disclosed are the processes for making the oriented polymeric composition of the invention.
摘要翻译：公开了含有取代的吡唑啉的化合物，其在取向上表现出非线性光学活性，并且包含在聚合物的主链中由其衍生的部分的定向聚合物组合物。还公开了制备本发明的取向聚合物组合物的方法。

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