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11. 发明授权

US06900251B2 Dental materials based on acrylic-ester phosphonic acids 有权
标题翻译：基于丙烯酸酯膦酸的牙科材料
公开(公告)号：US06900251B2
公开(公告)日：2005-05-31
申请号：US10606142
申请日：2003-06-25
申请人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
发明人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
IPC分类号： A61C13/087 , A61K6/00 , A61K6/083 , C07F9/38 , C08F30/02 , C08F220/54 , C08F230/02 , C09J4/00 , C09J4/02 , C09J11/04 , C09J11/06 , A61K8/00 , C07F9/09 , C08F2/46
CPC分类号： A61K6/0023 , A61K6/083 , C07F9/3808 , C08F30/02 , C08L33/00 , C08L43/02 , C08L39/06
摘要： Acrylic ester phosphonic acids of general formula (I), stereoisomers thereof and mixtures of these, wherein n is 1 or 2, on the condition that for n=1 R1 has the meaning and for n=2 R1 has the meaning R2 is a C1 to C12 alkylene radical, C4-C8 cycloalkylene radical or C7 to C15 alkylene phenylene radical; R3 is hydrogen, a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical; and R4, R5, independently of each other, each stand for a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical.
摘要翻译：在通式（I）的丙烯酸酯膦酸，其立体异构体和它们的混合物，其中n为1或2，条件是对于n = 1的R 1具有含义，n = 2 R 1具有R 2是C 1至C 12亚烷基的C 1至C 4亚烷基，C 4 C 1 -C 8亚环烷基或C 7至C 15亚烷基亚苯基; R 3是氢，C 1至C 5烷基或C 1至C 6烷基， 5 O - 烷基; 和R 4，R 5，R 5彼此独立地代表C 1至C 5烷基自由基或C 1至C 5 - O-烷基。

12. 发明授权

US09138382B2 Use of polymerizable macrocyclic polyethers and macrocyclic heteroanalogous polyethers in dental materials 有权
标题翻译：在牙科材料中使用可聚合的大环聚醚和大环杂芳族聚醚
公开(公告)号：US09138382B2
公开(公告)日：2015-09-22
申请号：US12684308
申请日：2010-01-08
申请人： Norbert Moszner , Frank Zeuner , Urs Karl Fischer , Volker M. Rheinberger , Iris Lamparth
发明人： Norbert Moszner , Frank Zeuner , Urs Karl Fischer , Volker M. Rheinberger , Iris Lamparth
IPC分类号： A61K6/083 , A61K6/00 , A61K6/087 , C07D257/02 , C07D323/00 , C07D327/00 , C07D498/08
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0073 , A61K6/083 , A61K6/087 , C07D257/02 , C07D323/00 , C07D327/00 , C07D498/08 , C08L71/00
摘要： Radically polymerizable macrocyclic polyethers or macrocyclic heteroanalogous polyethers, preferably crown ethers, heteroanalogous crown ethers and cryptands for use in dental materials is disclosed.
摘要翻译：公开了可自由基聚合的大环聚醚或大环杂芳族聚醚，优选冠醚，杂芳族冠醚和用于牙科材料的穴状物。

13. 发明授权

US08829067B2 Polymerizable compositions with initiators containing several Ge atoms 有权
标题翻译：含有几个Ge原子的引发剂的可聚合组合物
公开(公告)号：US08829067B2
公开(公告)日：2014-09-09
申请号：US12276030
申请日：2008-11-21
申请人： Norbert Moszner , Frank Zeuner , Robert Liska , Volker M. Rheinberger , Iris Lamparth , Urs Karl Fischer
发明人： Norbert Moszner , Frank Zeuner , Robert Liska , Volker M. Rheinberger , Iris Lamparth , Urs Karl Fischer
IPC分类号： G03F7/029 , C08F4/44 , C07F7/00 , C08F4/16 , A61K6/00 , C08F4/72 , A61K6/083 , C08F2/50
CPC分类号： C08F2/50 , A61K6/0017 , A61K6/0023 , A61K6/0052 , A61K6/083 , C08F4/16 , C08F4/44 , C08F4/72 , C08L33/04 , C08L33/26
摘要： Composition with at least one polymerizable binder and one polymerization initiator, which contains at least one acylgermanium compound according to general Formula (I), and the use of acylgermanes of Formula (I) as initiators for radical polymerization or for the preparation of dental restorations.
摘要翻译：含有至少一种可聚合粘合剂和一种聚合引发剂的组合物，其含有至少一种根据通式（I）的酰基锗化合物，以及使用式（I）的酰基锗烷作为引发剂用于自由基聚合或用于制备牙齿修复体。

14. 发明申请

US20080058443A1 Dental materials having low polymerization shrinkage 审中-公开
标题翻译：具有低聚合收缩率的牙科材料
公开(公告)号：US20080058443A1
公开(公告)日：2008-03-06
申请号：US11897228
申请日：2007-08-29
申请人： Norbert Moszner , Helmut Ritter , Urs-Karl Fischer , Monir Tabatabai , Matthias Schaub , Andreas Utterodt
发明人： Norbert Moszner , Helmut Ritter , Urs-Karl Fischer , Monir Tabatabai , Matthias Schaub , Andreas Utterodt
IPC分类号： A61K6/08
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/083 , A61K6/087 , C08F222/1006 , C08L61/14 , C08L33/04
摘要： The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.
摘要翻译：本发明涉及由杯形[n]芳烃组成的牙科用材料，以及其在牙科领域中用于粘合剂，复合材料，粘合剂和涂层材料的用途。这些材料包括：（a）0.5至90重量％的至少一种根据式（I）的可聚合杯[n]芳烃，（b）0.01至5重量％的引发剂，（c）0至90重量％的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合，（d）0至85重量％的填料，（e）0.01至5重量％的添加剂和（f）0〜70重量％的溶剂。

15. 发明授权

US06653375B2 Urethane di(meth)acrylate derivatives of 1,3-bis(1-isocyanato-1-methylethyl)benzene 有权
标题翻译：苯乙烯的聚氨酯二（甲基）丙烯酸酯衍生物，1,3-双（1-异氰酸基-1-甲基乙基）苯
公开(公告)号：US06653375B2
公开(公告)日：2003-11-25
申请号：US09236787
申请日：1999-01-25
申请人： Norbert Moszner , Volker Rheinberger , Thomas Völkel , Urs Karl Fischer
发明人： Norbert Moszner , Volker Rheinberger , Thomas Völkel , Urs Karl Fischer
IPC分类号： A61K6083
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/09 , C07C271/20 , C08L75/16
摘要： The invention relates to urethane di(meth)acrylate derivatives of 1-3-bis(1-isocyanato-1-methylethyl)benzene according to Formula (I) in which R is hydrogen or a straight-chained C1-C8 alkyl radical; X and Y independently of each other stand for R1 being a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; R2 hydrogen, a C1- to C5-alkyl or a substituted or unsubstituted C6- to C12-aryl radical; R3 hydrogen or a methyl radical; R4 a C1- to C8-alkylene radical which can be broken by oxygen atoms, or a phenylene radical; R5 hydrogen or a methyl radical; R6 a substituted or unsubstituted C6- to C12-aryl or C7- to C16-alkyl aryl radical; Z being —CO— or a chemical bond and W standing for oxygen, sulphur or NR7, R7 being hydrogen or a straight-chained C1- to C6-alkyl radical. The substances are suitable in particular for the production of dental materials.
摘要翻译：本发明涉及式（I）的1,3-双（1-异氰酸基-1-甲基乙基）苯的氨基甲酸酯二（甲基）丙烯酸酯衍生物，其中R为氢或直链C1-C8烷基; X和Y彼此独立地代表R 1是取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; R 2为氢，C 1至C 5 - 烷基或取代或未取代的C 6至C 12 - 芳基; R 3氢或甲基; R 4可以被氧原子断裂的C1-至C8-亚烷基或亚苯基; R 5氢或甲基; R 6取代或未取代的C 6 -C 12 - 芳基或C 7 -C 16烷基芳基; Z是-CO-或化学键，W代表氧，硫或NR 7，R 7是氢或直链C 1至C 6烷基。这些物质特别适用于生产牙科材料。

16. 发明授权

US06353039B1 Polymerizable composite material 有权
标题翻译：可聚合复合材料
公开(公告)号：US06353039B1
公开(公告)日：2002-03-05
申请号：US09209905
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/0276 , A61K6/083 , A61K6/09 , C08F2/44 , C08K3/40 , C08K9/08 , C08L33/00 , C08L75/16
摘要： A composite material is described which contains polymerizable monomers plus a special transparent glass having high release of calcium ions and fluorine ions and, because of this release property and in particular of its optical properties, can be used as a restoration material in dentistry.
摘要翻译：描述了一种复合材料，其包含可聚合单体加上具有高释放的钙离子和氟离子的特殊透明玻璃，并且由于该释放性质，特别是其光学性质，可用作牙科中的修复材料。

17. 发明授权

US08921450B2 Dental materials based on dimer acid derivatives with ring opening polymerizable groups 有权
标题翻译：基于具有开环聚合基团的二聚酸衍生物的牙科材料
公开(公告)号：US08921450B2
公开(公告)日：2014-12-30
申请号：US13175988
申请日：2011-07-05
申请人： Norbert Moszner , Jörg Angermann , Urs Karl Fischer , Volker Rheinberger
发明人： Norbert Moszner , Jörg Angermann , Urs Karl Fischer , Volker Rheinberger
IPC分类号： A61K6/08 , A61K6/083 , C07D339/00 , A61K6/00
CPC分类号： C07D339/00 , A61K6/0023 , A61K6/083 , C08L33/08 , C08L33/10 , C08L65/00
摘要： The invention relates to a radically polymerizable monomer of formula (I) wherein W1 and W2 in each case independently represent H or X—R—Y—PG, wherein at least one of W1 and W2 represents X—R—Y—PG, X in each case independently is missing or represents an ether, ester, amide, urethane or urea group, Y in each case independently is missing or represents an ether, ester, amide, urethane or urea group, R in each case independently is missing or represents a C1-C16 alkylene radical which can be interrupted by one or more O atoms, wherein R can be missing only if X and/or Y is simultaneously also missing, and PG in each case independently represents a cyclic, ring-opening polymerizable group, a, b, c and d independently of each other can take the values 3 to 10. The invention also relates to polymerizable compositions which comprise the monomers according to the invention, as well as their use as dental materials and for the preparation of dental materials, in particular composites, cements, adhesives or coatings.
摘要翻译：本发明涉及式（I）的自由基聚合性单体，其中W1和W2各自独立地表示H或X-R-Y-PG，其中W1和W2中的至少一个表示X-R-Y-PG，X 在每种情况下都独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，Y在每种情况下独立地缺失或表示醚，酯，酰胺，氨基甲酸酯或脲基，R各自独立地缺失或表示可以被一个或多个O原子中断的C1-C16亚烷基，其中只有当X和/或Y同时缺失时，R只能缺失，并且每种情况下PG都独立地表示环状的开环聚合基团， a，b，c和d可以取值为3至10.本发明还涉及包含根据本发明的单体的可聚合组合物，以及它们作为牙科材料和用于制备牙科材料的用途，特别是composi 水泥，粘合剂或涂料。

18. 发明申请

US20100311863A1 PROCESS FOR PREPARING DENTAL MATERIALS HAVING LOW POLYMERIZATION SHRINKAGE 有权
标题翻译：用于制备具有低聚合收缩的牙科材料的方法
公开(公告)号：US20100311863A1
公开(公告)日：2010-12-09
申请号：US12859052
申请日：2010-08-18
申请人： Norbert Moszner , Helmut Ritter , Urs-Karl Fischer , Monir Tabatabai , Matthias Schaub , Andreas Utterodt
发明人： Norbert Moszner , Helmut Ritter , Urs-Karl Fischer , Monir Tabatabai , Matthias Schaub , Andreas Utterodt
IPC分类号： A61K6/08
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/083 , A61K6/087 , C08F222/1006 , C08L61/14 , C08L33/04
摘要： The present invention relates to dental materials composed of calix[n]arenes and also to the use thereof for cements, composites, adhesives and coating materials in the dental field. The materials include (a) 0.5 to 90% by weight of at least one polymerizable calix[n]arene according to formula (I), (b) 0.01 to 5% by weight of initiator, (c) 0 to 90% by weight of at least one additional monomer which can polymerize under cationic and/or radical conditions and/or which can polymerize by ring opening, (d) 0 to 85% by weight of filler, (e) 0.01 to 5% by weight of additive and (f) 0 to 70% by weight of solvent.
摘要翻译：本发明涉及由杯形[n]芳烃组成的牙科用材料，以及其在牙科领域中用于粘合剂，复合材料，粘合剂和涂层材料的用途。这些材料包括：（a）0.5至90重量％的至少一种根据式（I）的可聚合杯[n]芳烃，（b）0.01至5重量％的引发剂，（c）0至90重量％的至少一种可在阳离子和/或自由基条件下聚合的另外的单体和/或可以通过开环聚合，（d）0至85重量％的填料，（e）0.01至5重量％的添加剂和（f）0〜70重量％的溶剂。

19. 发明申请

US20080076847A1 Polymerizable compositions with acylgermanes as initiatiors 审中-公开
标题翻译：具有酰基作为起始物的可聚合组合物
公开(公告)号：US20080076847A1
公开(公告)日：2008-03-27
申请号：US11730533
申请日：2007-04-02
申请人： Norbert Moszner , Ulrich Salz , Urs Karl Fischer , Robert Liska , Heinrich Gruber , Beate Ganster
发明人： Norbert Moszner , Ulrich Salz , Urs Karl Fischer , Robert Liska , Heinrich Gruber , Beate Ganster
IPC分类号： C08F2/50 , A61K6/08 , C08J3/28 , C08F2/46
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/0052 , A61K6/083 , C08F2/50 , C08F4/72 , C08F222/1006 , C08F230/10 , C08L33/00
摘要： Composition with at least one polymerizable binder and a polymerization initiator, which contains at least one acylgermane according to general Formula (I), in which R0 is a substituted or unsubstituted C1-18-alkyl radical or an acyl group; R1 and R2 are H, an acyl group or have one of the meanings given for R3; R3 is a branched or linear C1-18-alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH3)2Si—[OSi(CH3)2]r−, (CH3)3Si—[OSi(CH3)2]r—, —COOH, —COO—R10, —CO—NR11R12, —CO-vinyl, —CO-phenyl, phenyl-C1-4-alkyl, phenyl, naphthyl or biphenyl, C5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; and the use of acyl germanes of Formula (I) for example as initiator for radical polymerization.
摘要翻译：含有至少一种可聚合粘合剂和聚合引发剂的组合物，其含有至少一种根据通式（I）的酰基锗烷，其中R 0是取代或未取代的C 1-18烷基， /烷基或酰基; R 1和R 2均为H，酰基或具有R 3给出的含义之一; R 3是支链或直链C 1-18 - 烷基，其可以是未取代的或被-O - ， - NH-，-NR- ，-S-或被其它基团中断，三甲基甲硅烷基，卤代（CH 3）2 Si- [OSi（CH 3）3）（CH 3）3 Si- [OSi（CH 3）3） -COOH，-COO-R 10，-CO-NR， - ， - SO 2 - ， - 11- 12，-CO-乙烯基，-CO-苯基，苯基-C 1-4 - 烷基，苯基，萘基或联苯基，C

20. 发明授权

US07078446B2 (Meth) acrylate-substituted iminooxidiazine dione derivatives 有权
标题翻译：（甲基）丙烯酸酯取代的亚氨氧亚氨基二酮衍生物
公开(公告)号：US07078446B2
公开(公告)日：2006-07-18
申请号：US10361961
申请日：2003-02-10
申请人： Norbert Moszner , Thomas Völkel , Urs Karl Fischer , Volker Rheinberger
发明人： Norbert Moszner , Thomas Völkel , Urs Karl Fischer , Volker Rheinberger
IPC分类号： A61K6/083 , A61C5/00 , C08G18/04
CPC分类号： A61K6/083 , A61K6/0023 , C07D273/04 , C08L33/00
摘要： The invention relates to iminooxadiazine dione derivatives with the formula (I) in which X, Y and Z represent a (meth)acrylic acid radical of the formula (II) in which R1 is hydrogen, an aliphatic hydrocarbon radical with 1 to 14 carbon atoms, which can be interrupted by oxygen atoms, or an aromatic hydrocarbon radical with to 16 carbon atoms; R2 is hydrogen, an aliphatic hydrocarbon radical with 1 to 5 carbon atoms or an aromatic hydrocarbon radical with 6 carbon atoms, n is 1 or 2; where the (meth)acrylic acid radical of formula (II) is bound to the radical of formula (I) by R1 or R2 and the binding point remaining at R2 or R1 is saturated by hydrogen and X, Y and Z can be the same or different; the individual radicals R being able to be the same or different and selected from alicyclic or aromatic hydrocarbon radicals with 5 to 10 or aliphatic hydrocarbon radicals with 1 to 10 carbon atoms.
摘要翻译：本发明涉及式（I）的亚氨基恶二嗪二酮衍生物，其中X，Y和Z表示式（II）的（甲基）丙烯酸基，其中R 1是氢，脂族可以被氧原子中断的具有1至14个碳原子的烃基或具有16个碳原子的芳族烃基; R 2是氢，具有1至5个碳原子的脂族烃基或具有6个碳原子的芳族烃基，n是1或2; 其中式（II）的（甲基）丙烯酸基团通过R 1或R 2 2与式（I）的基团结合，并且R H 2和R 1可以被氢饱和，X，Y和Z可以相同或不同; 各个基团R能够相同或不同，并且选自具有5-10个碳原子的脂族或芳族烃基或具有1-10个碳原子的脂族烃基。

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