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    • 11. 发明授权
    • Anisotropic liquid phase photochemical etch
    • 各向异性液相光化学蚀刻
    • US5460687A
    • 1995-10-24
    • US246388
    • 1994-05-20
    • Monte A. Douglas
    • Monte A. Douglas
    • C23F1/02C23F4/02H01L21/306H01L21/3065H01L21/3213B44C1/22
    • C23F1/02H01L21/30655H01L21/32134
    • An anisotropic liquid phase photochemical etch is performed by submersing a substrate 30 (e.g. copper) in a liquid 34 containing an etchant (e.g. hydrochloric acid) and a passivant (e.g. iodine), the passivant forming an insoluble passivation layer 36 (e.g. Cul) on the surface, preventing the etchant from etching the surface. The passivant and its concentration are chosen such that the passivation layer 36 has a solubility which is substantially increased when it is illuminated with radiation 38 (e.g. visible/ultraviolet light). Portions of the surface are then illuminated with radiation 38, whereby the passivation layer 36 is removed from those illuminated portions of the surface, allowing the etch to proceed there. Portions of the surface not illuminated are not etched, resulting in an anisotropic etch. Preferably, an etch mask 32 is used to create the unilluminated areas. This etch mask 32 may be formed on the surface or it may be interposed between the surface and the radiation source.
    • 通过将衬底30(例如铜)浸没在含有蚀刻剂(例如盐酸)和钝化剂(例如碘))的液体34中来进行各向异性液相光化学蚀刻,钝化剂形成不溶性钝化层36(例如Cul) 表面,防止蚀刻剂蚀刻表面。 选择钝化剂及其浓度使得钝化层36具有当用辐射38(例如可见/紫外光)照射时基本上增加的溶解度。 然后用辐射38照射表面的部分,由此钝化层36从表面的那些照射部分移除,允许蚀刻在那里进行。 未被照射的表面的部分没有蚀刻,导致各向异性蚀刻。 优选地,使用蚀刻掩模32来产生未发光的区域。 该蚀刻掩模32可以形成在表面上,或者它可以插入在表面和辐射源之间。
    • 14. 发明授权
    • Method for forming local interconnects using selective anisotropy
    • 使用选择性各向异性形成局部互连的方法
    • US4957590A
    • 1990-09-18
    • US402944
    • 1989-09-05
    • Monte A. Douglas
    • Monte A. Douglas
    • C01B23/00H01L21/302H01L21/3065H01L21/311H01L21/3213H01L21/768H01L23/532
    • H01L21/31116H01L21/32136H01L21/32137H01L21/32139H01L21/76895H01L23/53257H01L2924/0002
    • A method for etching titanium nitride local interconnects is disclosed. A layer of titaniun nitride is either formed as a by-product of the formation of titanium silicide by direct reaction or by deposition. The location of the interconnects is defined by patterning photoresist at the desired locations. A plasma etch using a chlorine-bearing agent such as CCl.sub.4 as the etchant etches the titanium nitride anisotropically at those locations covered by photoresist, and isotropically elsewhere, so that filaments of the titanium nitride are removed without undercutting the photoresist mask. The etch is selective relative to the underlying material, such as a refractory metal silicide, refractory metals, or silicon, due to the passivation of the underlying material by the carbon atoms of the CCl.sub.4. The selectivity, together with the selective anisotropy, even allows significant overetch of the material to remove the filaments without undercutting the masked interconnect material.
    • 公开了一种用于蚀刻氮化钛局部互连的方法。 一层氮化钛是通过直接反应或通过沉积形成硅化钛的副产物形成的。 互连的位置通过在期望的位置处图案化光刻胶来限定。 使用含氯试剂如CCl4作为蚀刻剂的等离子体蚀刻在各种各向异性地蚀刻氮化钛,在由光致抗蚀剂覆盖的位置处各向异性地蚀刻氮化钛,从而去除氮化钛的细丝而不使光刻胶掩模下切。 由于CCl4的碳原子钝化下面的材料,蚀刻相对于下面的材料是可选择的,例如难熔金属硅化物,难熔金属或硅。 选择性以及选择性各向异性甚至允许材料的显着过蚀刻去除长丝,而不会掩盖掩蔽的互连材料。
    • 18. 发明授权
    • Photo-stimulated etching of CaF2
    • 光激发蚀刻CaF2
    • US06177358B1
    • 2001-01-23
    • US08175865
    • 1993-12-30
    • Monte A. Douglas
    • Monte A. Douglas
    • H01L21302
    • H01L21/31111
    • Generally, and in one form of the invention, a method is presented for the photo-stimulated etching of a CaF2 surface 12, comprising the steps of exposing the CaF2 surface 12 to an ambient species 16, exciting the CaF2 surface 12 and/or the ambient species 16 by photo-stimulation sufficiently to allow reaction of the CaF2 surface 12 with the ambient species 16 to form CaF2 ambient species products, and removing the ambient species 16 and the CaF2 ambient species products from the CaF2 surface 12. Other devices, systems and methods are also disclosed.
    • 通常,在本发明的一种形式中,提出了用于CaF2表面12的光刺激蚀刻的方法,包括以下步骤:将CaF 2表面12暴露于环境物质16,激发CaF 2表面12和/或 环境物质16通过光刺激足以允许CaF 2表面12与环境物质16反应以形成CaF 2环境物质产物,以及从CaF 2表面12除去环境物质16和CaF 2环境物质产物。其它装置,系统 并且还公开了方法。
    • 20. 发明授权
    • Electrostatic particle removal and characterization
    • 静电除尘和表征
    • US5584938A
    • 1996-12-17
    • US166321
    • 1993-12-10
    • Monte A. Douglas
    • Monte A. Douglas
    • B08B6/00H01L21/00A47L13/40
    • H01L21/67028B08B6/00Y10S422/906Y10T436/25375
    • An electrostatic decontamination method and decontamination device (10) is disclosed for decontaminating the surface of a semiconductor substrate. The decontamination device (10) includes particle ionizing device (24) that charges contaminating particles (26) on the surface of semiconductor substrate (16) thereby creating ionized particles. Decontamination device (10) also includes substrate biasing device (12) for creating a charge accumulation layer (14) at the top of semiconductor substrate (16) so that the charge accumulation layer (14) has the same charge sign as the ionized particles. In addition, the invention analytically characterizes particles using contaminating particle isolator (44) which contains a particle ionizing device (24) that charges contaminating particles (26) on the surface of semiconductor substrate (16) thereby creating ionized particles. Contaminating particle isolator (44) includes substrate biasing device (12) operable to create charge accumulation layer (14) at the top of semiconductor substrate (16) so that the charge accumulation layer (14) has the same charge sign as the ionized particles. Contaminating particle isolator (44) also includes particle collector (46) that collects the ionized particles. This permits characterizing the particles to determine their chemical composition.
    • 公开了一种用于对半导体衬底的表面进行净化的静电去污方法和去污设备(10)。 净化装置(10)包括对半导体衬底(16)的表面上的污染颗粒(26)进行充电的颗粒电离装置(24),由此产生电离颗粒。 去污设备(10)还包括用于在半导体衬底(16)的顶部产生电荷累积层(14)的衬底偏压器件(12),使得电荷累积层(14)具有与电离粒子相同的电荷符号。 此外,本发明使用污染粒子隔离器(44)分析地表征粒子,其包含对半导体衬底(16)的表面上的污染颗粒(26)进行电荷的粒子离子化装置(24),由此产生电离粒子。 污染粒子隔离器(44)包括可操作以在半导体衬底(16)的顶部产生电荷累积层(14)的衬底偏置器件(12),使得电荷累积层(14)具有与电离粒子相同的电荷符号。 污染粒子隔离器(44)还包括收集离子化颗粒的颗粒收集器(46)。 这允许表征颗粒以确定其化学组成。