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    • 12. 发明授权
    • Optical glass, glass material for press molding, optical element blank, optical element and manufacturing method thereof
    • 光学玻璃,压模用玻璃材料,光学元件坯料,光学元件及其制造方法
    • US08431499B2
    • 2013-04-30
    • US13492224
    • 2012-06-08
    • Mikio Ikenishi
    • Mikio Ikenishi
    • C03C3/247C03B11/00
    • C03C3/247C03B2215/12C03B2215/24G02B1/02Y02P40/57
    • A fluorophosphate glass containing: P5+ in an amount of 20 to 45 cationic %; Al3+ in an amount of 15 to 35 cationic %; Ba2+ in an amount of 20 to 50 cationic %; B3+ in an amount of 0 to 5 cationic %; F− in an amount of 20 to 50 anionic %; and O2− in an amount of 50 to 80 anionic %. A molar ratio of O2−/P5+ is greater than or equal to 3.5. In addition, a molar ratio of Al3+/P5+ is less than or equal to 1. In addition, the Abrasion FA is less than or equal to 600, or the Knoop hardness number is greater than or equal to 300 MPa. Furthermore, the Abbe number (νd) of the glass is larger than or equal to 66. Moreover, a refractive index (nd) of the glass satisfies an expression (1): nd≧2.0614−0.0071×νd. Finally, the fluorophosphate glass does not contain Cu in an amount by which Cu serves as a coloring agent.
    • 含有磷酸酯玻璃,其含量为20〜45阳离子%的P5 + 含量为15〜35阳离子%的Al3 + Ba2 +的量为20〜50阳离子%; B3 +为0〜5阳离子%; F-含量为20〜50%阴离子%; 和O 2 - 的量为50至80阴离子%。 O2- / P5 +的摩尔比大于或等于3.5。 此外,Al3 + / P5 +的摩尔比小于或等于1.另外,磨损FA小于或等于600,或者诺普硬度大于或等于300MPa。 此外,玻璃的阿贝数(nud)大于或等于66.此外,玻璃的折射率(nd)满足式(1):nd> = 2.0614-0.0071×nud。 最后,氟磷酸盐玻璃不含有以Cu作为着色剂的量的Cu。
    • 13. 发明授权
    • Optical glass, preform for press forming, optical element, and processes for producing these
    • 光学玻璃,压制成形用预成型体,光学元件及其制造方法
    • US08354352B2
    • 2013-01-15
    • US12528189
    • 2008-02-27
    • Mikio Ikenishi
    • Mikio Ikenishi
    • C03C3/23C03C3/247C03C3/16C03B5/26C03B5/28C03B17/00
    • C03C3/247C03B11/12G02B5/226
    • Provided is a low-dispersion optical glass that is formed of a fluorophosphate glass in which the molar ratio of the content of O2− to the content of P5+, O2−/P5+, is 3.5 or more and that has an Abbe's number (νd) of over 70 or has an F− content of 65 anionic % or more, and the optical glass enables the suppression of the volatilization of a glass component when an optical glass formed of a fluorophosphate glass is produced or when an obtained glass in a molten state is caused to flow out to shape it into a glass shaped material, so that the variation of properties such as a refractive index, etc., involved in the fluctuations of a glass composition and the variation of quality such as the occurrence of striae can be suppressed.
    • 本发明提供一种低分散型光学玻璃,其由O 2 - 与P 5+,O 2 - / P 5+的含量的摩尔比为3.5以上且具有阿贝数(&ngr; d)超过70或具有65阴离子%以上的F含量,并且当由氟磷酸盐玻璃形成的光学玻璃制造时,或者当获得的玻璃成分为玻璃成分时,光学玻璃能够抑制玻璃成分的挥发 导致熔融状态流出以将其成形为玻璃形状的材料,使得涉及玻璃组合物的波动等的性能如折射率等的变化以及诸如条纹的发生的质量的变化 可以抑制。
    • 15. 发明授权
    • Optical glass, press-molding preform, process for the production thereof, optical element and process for the production thereof
    • 光学玻璃,压制成型预成型件,其制造方法,光学元件及其制造方法
    • US07595272B2
    • 2009-09-29
    • US11389532
    • 2006-03-27
    • Mikio IkenishiXuelu Zou
    • Mikio IkenishiXuelu Zou
    • C03C3/17C03C3/19C03C3/16C03C3/12C03C3/247
    • C03C3/17C03C3/247
    • A low-dispersion optical glass suitable for producing a quality preform from a molten glass and suitable for precision press-molding, which is a fluorophosphate glass containing, as essential cationic components, P5+, Al3+, at least two members selected from Mg2+, Ca2+, Sr2+ and Ba2+ as divalent cationic components (R2+) and Li+ and containing, by cationic %, 10 to 45% of P5+, 5 to 30% of Al3+, 0 to 20% of Mg2+, 0 to 25% of Ca2+, 0 to 30% of Sr2+, 0 to 33% of Ba2+, 1 to 30% of Li+, 0 to 10% of Na+, 0 to 10% of K+, 0 to 5% of Y3+, and 0 to 15% of B3+, the molar ratio of the content of F− to the total content of F− and O2−, F−/(F−+O2−), being 0.25 to 0.85, the optical glass having a refractive index (Nd) of 1.40 to 1.58 and an Abbe's number (νd) of 67 to 90.
    • 一种低分散型光学玻璃,适用于从熔融玻璃制造优质预成型体,适用于精密加压成型,其为含有作为必需阳离子成分的P5 +,Al3 +,至少两种选自Mg2 ​​+,Ca2 +, Sr 2+和Ba 2+作为二价阳离子成分(R2 +)和Li +,阳离子%含有10〜45%的P5 +,5〜30%的Al3 +,0〜20%的Mg2 +,0〜25%的Ca2 +,0〜30 的Sr2 +,0〜33%的Ba2 +,1〜30%的Li +,0〜10%的Na +,0〜10%的K +,0〜5%的Y3 +,0〜15%的B3 + 的F-和O 2 - ,F - /(F- + O 2 - )的总含量为0.25至0.85的光学玻璃的折射率(Nd)为1.40至1.58的光学玻璃和阿贝氏 number(nud)为67〜90。