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11. 发明申请

US20050258025A1 Method for purifying tetrahydrofuran by distillation 有权
标题翻译：通过蒸馏提纯四氢呋喃的方法
公开(公告)号：US20050258025A1
公开(公告)日：2005-11-24
申请号：US10505774
申请日：2003-02-28
申请人： Gunther Windecker , Alexander Weck , Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Michael Hesse , Stephan Schlitter , Holger Borchert
发明人： Gunther Windecker , Alexander Weck , Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Michael Hesse , Stephan Schlitter , Holger Borchert
IPC分类号： B01D3/14 , C07D307/08 , B01D3/38
CPC分类号： B01D3/146 , C07D307/08 , Y10S203/20
摘要： The present invention provides a process for distillatively purifying crude water-containing tetrahydrofuran by passing the crude tetrahydrofuran through three distillation columns, withdrawing water from the bottom of the first column, recycling water-containing tetrahydrofuran from the top of the second column into the first column, passing a sidestream of the first column into the second column, recycling the bottom product of the third column into the first column, and withdrawing a distillate at the top of the first column, which comprises passing a sidestream of the second column into the third column and recovering the pure tetrahydrofuran as the top product of the third column.
摘要翻译：本发明提供了一种通过将粗四氢呋喃通过三个蒸馏塔，从第一塔的底部排出水，将含水四氢呋喃从第二塔的顶部再循环到第一塔中来蒸馏精制含粗水的四氢呋喃的方法将第一塔的侧流通入第二塔，将第三塔的底部产物再循环到第一塔中，并且抽出第一塔顶部的馏出物，其包括将第二塔的侧流通入第三塔的第三塔并回收纯四氢呋喃作为第三列的顶级产物。

12. 发明申请

US20050119494A1 Method for the simultaneous production of tetrahydrofurans ad pyrrolidones 有权
标题翻译：同时生产四氢呋喃和吡咯烷酮的方法
公开(公告)号：US20050119494A1
公开(公告)日：2005-06-02
申请号：US10505706
申请日：2003-02-28
申请人： Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Alexander Weck , Gunther Windecker , Michael Hesse , Holger Borchert , Stephan Schlitter
发明人： Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Alexander Weck , Gunther Windecker , Michael Hesse , Holger Borchert , Stephan Schlitter
IPC分类号： B01J23/72 , B01J23/80 , C07B61/00 , C07D207/26 , C07D207/267 , C07D307/08 , C07D307/02
CPC分类号： C07D207/267 , C07D307/08
摘要： A process for coproducing alkyl-substituted or unsubstituted THF and pyrrolidones by catalytically hydrogenating C4-dicarboxylic acids and/or derivatives thereof in the gas phase in the presence of copper catalysts and reacting GBL with ammonia or primary amines to give pyrrolidones comprises a) hydrogenating C4-dicarboxylic acids and/or derivatives thereof in the gas phase at from 200 to 300° C., from 0.1 to 100 bar, catalyst hourly space velocities of from 0.01 to 1 kg of reactant/l of catalyst*hour and reactant/hydrogen molar ratios of from 20 to 800 in the presence of catalysts comprising copper, aluminum and/or zinc to give mixtures of THF and GBL, b) separating the hydrogenation effluent obtained by distillation into a THF/water mixture as the top product and a GBL-containing bottom product, c) separating the THF/water mixture from step b) in a distillation facility consisting of three columns by withdrawing water from the bottom of the first column, recycling water-containing THF from the second into the first column, passing a side stream of the first into the second column, recycling the bottom product of the third column into the first column and withdrawing a distillate at the top of the first column, wherein a side stream of the second column is passed into the third column and the pure THF is obtained as the top product of the third column, d) recovering GBL from the GBL-containing bottom product from step b) by distillation and e) reacting the GBL obtained with ammonia or amines to give corresponding pyrrolidones.
摘要翻译：在铜催化剂存在下，在气相中催化氢化C 4 - 二羧酸和/或其衍生物，共同生产烷基取代或未取代的THF和吡咯烷酮的方法，并使GBL与氨或伯胺得到吡咯烷酮包括：a）在200-300℃，0.1-100巴的气相中氢化C 4-14 - 二羧酸和/或其衍生物，催化剂小时空速为0.01 在包含铜，铝和/或锌的催化剂存在下，至1kg反应物/ l催化剂*小时和反应物/氢摩尔比为20至800，得到THF和GBL的混合物，b）分离所得氢化流出物通过蒸馏作为顶部产物的THF /水混合物和含有GBL的底部产物，c）通过从第一塔底部排出水分离由三塔组成的蒸馏设备中的步骤b）中的THF /水混合物，回收将含水THF从第二塔进入第一塔，将第一塔的侧流通入第二塔，将第三塔的底部产物再循环到第一塔中并抽出第一塔顶部的馏出物，其中将第二塔的侧流进入第三塔，得到纯THF作为第三塔的顶部产物，d）通过蒸馏从步骤b）的含GBL的底部产物中回收GBL，和e）使用氨或胺得到GBL，得到相应的吡咯烷酮。

13. 发明申请

US20060030743A1 Catalyst and method for producing alcohol by hydrogenation on said catalyst 审中-公开
标题翻译：在所述催化剂上通过氢化制备醇的催化剂和方法
公开(公告)号：US20060030743A1
公开(公告)日：2006-02-09
申请号：US10534457
申请日：2003-11-06
申请人： Markus Schubert , Sylvia Huber-Dirr , Michael Hesse , Jochen Pfeifer , Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Alexander Weck , Gunther Windecker , Gunnar Heydrich
发明人： Markus Schubert , Sylvia Huber-Dirr , Michael Hesse , Jochen Pfeifer , Rolf-Hartmuth Fischer , Markus Rosch , Nils Bottke , Alexander Weck , Gunther Windecker , Gunnar Heydrich
IPC分类号： B01J23/656 , C07C29/14 , C07C29/136
CPC分类号： C07C29/149 , B01J23/6567 , B01J37/0205 , C07B41/02 , C07C29/177 , C07C31/207 , C07C31/20
摘要： The invention relates to a catalyst containing from 0.1 to 20 mass % rhenium and 0.05 to 10 mass % platinum in relation to the total mass thereof. The inventive method for producing a support for said catalyst consists in a) treating a support which can be eventually pre-treated with the aid of a solution of rhenium compound, b) drying and annealing said support at a temperature ranging from 80 to 600° C., and c) impregnating the support with a solution of platinum compound and in drying it. The inventive method for producing alcohol by catalytic hydrogenation of carbonyl compound on said catalyst is also disclosed.
摘要翻译：本发明涉及相对于其总质量含有0.1〜20质量％铼和0.05〜10质量％铂的催化剂。用于制备所述催化剂载体的本发明方法在于：a）处理可以最终借助铼化合物溶液预处理的载体，b）在80至600℃的温度下干燥和退火所述载体 C.和c）用铂化合物溶液浸渍载体并干燥。还公开了通过催化氢化羰基化合物在所述催化剂上生产醇的本发明方法。

14. 发明申请

US20050215800A1 Method for producing gamma-butyrolactone 审中-公开
标题翻译： γ-丁内酯的制造方法
公开(公告)号：US20050215800A1
公开(公告)日：2005-09-29
申请号：US10513040
申请日：2003-04-25
申请人： Rolf Pinkos , Rolf-Hatmuth Fischer , Markus Rosch , Nils Bottke , Stephan Schlitter , Michael Hesse , Alexander Weck , Gunther Windecker , Gunnar Heydrich
发明人： Rolf Pinkos , Rolf-Hatmuth Fischer , Markus Rosch , Nils Bottke , Stephan Schlitter , Michael Hesse , Alexander Weck , Gunther Windecker , Gunnar Heydrich
IPC分类号： C07D307/33 , B01J21/08 , B01J23/72 , C07B61/00 , C07D307/20 , C07D307/26
CPC分类号： C07D307/20 , B01J21/08 , B01J23/72
摘要： The present invention relates to a process for preparing unsubstituted or C1-C4-alkyl-substituted gamma-butyrolactone by catalytic hydrogenation of maleic acid and/or its derivatives in the presence of chromium-free catalyst comprising from 10 to 80% by weight of copper oxide and from 10 to 90% by weight of at least one catalyst support selected from the group consisting of silicon dioxide, titanium dioxide, hafnium dioxide, magnesium silicate, activated carbon, silicon carbide, zirconium dioxide and alpha-aluminum oxide.
摘要翻译：本发明涉及通过马来酸和/或其衍生物的催化氢化制备未取代的或C 1 -C 4 - 烷基取代的γ-丁内酯的方法存在包含10至80重量％的氧化铜和10至90重量％的至少一种催化剂载体的无铬催化剂，所述催化剂载体选自二氧化硅，二氧化钛，二氧化铪，硅酸镁，活化的碳，碳化硅，二氧化锆和α-氧化铝。

15. 发明授权

US07230141B2 Method for producing toluol derivatives 失效
标题翻译：甲苯衍生物的制备方法
公开(公告)号：US07230141B2
公开(公告)日：2007-06-12
申请号：US10500718
申请日：2003-01-20
申请人： Nils Bottke , Rolf-Hartmuth Fischer , Thomas Nöbel , Markus Rösch
发明人： Nils Bottke , Rolf-Hartmuth Fischer , Thomas Nöbel , Markus Rösch
IPC分类号： C07C41/18 , C07C43/205
CPC分类号： B01J23/8892 , B01J23/002 , B01J23/72 , B01J23/755 , B01J23/885 , B01J23/8898 , B01J2523/00 , C07C2523/72 , C07C2523/75 , C07C2523/755 , B01J2523/17 , B01J2523/31 , B01J2523/68 , B01J2523/847 , B01J2523/12 , B01J2523/51 , B01J2523/72 , B01J2523/845 , B01J2523/41 , B01J2523/48
摘要： A process for preparing toluene derivatives of the formula I, where R1, R2 and R3 independently of one another are hydrogen, halogen, C1–C6-alkyl, hydroxyl or C1–C6-alkoxy, by hydrogenating benzaldehydes and/or benzyl alcohols of the formula II, with hydrogen in the presence of a catalyst, which is described in more detail in the description.
摘要翻译：制备式I的甲苯衍生物的方法，其中R 1，R 2和R 3彼此独立地为氢，卤素， C 1 -C 6 - 烷基，羟基或C 1 -C 6 - 烷氧基，通过氢化苯甲醛和 /或式II的苄醇与催化剂存在下的氢反应，这在描述中有更详细的描述。

16. 发明申请

US20060116521A1 Method for the production of optically active 2-amino 2-chloro, 2 hydroxy or 2-alkoxy-1-alcohols 有权
标题翻译：用于制备光学活性2-氨基2-氯，2-羟基或2-烷氧基-1-醇的方法
公开(公告)号：US20060116521A1
公开(公告)日：2006-06-01
申请号：US10524850
申请日：2003-08-28
申请人： Rolf-Hartmuth Fischer , Nils Bottke
发明人： Rolf-Hartmuth Fischer , Nils Bottke
IPC分类号： C07D207/12 , C07C213/00
CPC分类号： C07C29/149 , C07B2200/07 , C07C213/00 , C07C31/205 , C07C31/22
摘要： The invention relates to a process for preparing optically active 2-amino-, 2-chloro-, 2-hydroxy- or 2-alkoxy-1-alcohols by catalytically hydrogenating appropriate optically active 2-amino-, 2-chloro-, 2-hydroxy- and 2-alkoxycarboxylic acids or their acid derivatives in the presence of catalysts comprising palladium and rhenium or platinum and rhenium.
摘要翻译：本发明涉及通过催化氢化合适的光学活性2-氨基 - ，2-氯 - ，2-氯 - ，2-羟基 - 羟基和2-烷氧基羧酸或其酸衍生物在包含钯和铼或铂和铼的催化剂存在下进行。

17. 发明申请

US20050032627A1 Method for producing toluol derivatives 失效
标题翻译：甲苯衍生物的制备方法
公开(公告)号：US20050032627A1
公开(公告)日：2005-02-10
申请号：US10500718
申请日：2003-01-20
申请人： Nils Bottke , Rolf-Hartmuth Fischer , Thomas Nobel , Markus Rosch
发明人： Nils Bottke , Rolf-Hartmuth Fischer , Thomas Nobel , Markus Rosch
IPC分类号： C07C41/18 , B01J23/00 , B01J23/72 , B01J23/755 , B01J23/885 , B01J23/889 , C07B61/00 , C07C43/205 , B01J29/04
CPC分类号： B01J23/8892 , B01J23/002 , B01J23/72 , B01J23/755 , B01J23/885 , B01J23/8898 , B01J2523/00 , C07C2523/72 , C07C2523/75 , C07C2523/755 , B01J2523/17 , B01J2523/31 , B01J2523/68 , B01J2523/847 , B01J2523/12 , B01J2523/51 , B01J2523/72 , B01J2523/845 , B01J2523/41 , B01J2523/48
摘要： A process for preparing toluene derivatives of the formula I, where R1, R2 and R3 independently of one another are hydrogen, halogen, C1-C6-alkyl, hydroxyl or C1-C6-alkoxy, by hydrogenating benzaldehydes and/or benzyl alcohols of the formula II, with hydrogen in the presence of a catalyst, which is described in more detail in the description.
摘要翻译：制备式I的甲苯衍生物的方法，其中R 1，R 2和R 3彼此独立地是氢，卤素，C 1 -C 6 - 烷基，羟基或C 1 -C 6 - 烷氧基，由在催化剂存在下用氢气将式II的苯甲醛和/或苄醇氢化，这在描述中更详细地描述。

18. 发明授权

US07217847B2 Method for the production of optically active 2-amino 2-chloro, 2 hydroxy or 2-alkoxy-1-alcohols 有权
标题翻译：用于制备光学活性2-氨基2-氯，2-羟基或2-烷氧基-1-醇的方法
公开(公告)号：US07217847B2
公开(公告)日：2007-05-15
申请号：US10524850
申请日：2003-08-28
申请人： Rolf-Hartmuth Fischer , Nils Bottke
发明人： Rolf-Hartmuth Fischer , Nils Bottke
IPC分类号： C07C29/156 , C07C27/04 , C07C213/00 , C07C209/78
CPC分类号： C07C29/149 , C07B2200/07 , C07C213/00 , C07C31/205 , C07C31/22
摘要： The invention relates to a process for preparing optically active 2-amino-, 2-chloro-, 2-hydroxy- or 2-alkoxy-1-alcohols by catalytically hydrogenating appropriate optically active 2-amino-, 2-chloro-, 2-hydroxy- and 2-alkoxycarboxylic acids or their acid derivatives in the presence of catalysts comprising palladium and rhenium or platinum and rhenium.
摘要翻译：本发明涉及通过催化氢化合适的光学活性2-氨基 - ，2-氯 - ，2-氯 - ，2-羟基 - 羟基和2-烷氧基羧酸或其酸衍生物在包含钯和铼或铂和铼的催化剂存在下进行。

19. 发明授权

US07601861B2 Method for producing alkylaryl compounds and alkylaryl sulphonates 失效
标题翻译：烷基芳基化合物和烷基芳基磺酸盐的制备方法
公开(公告)号：US07601861B2
公开(公告)日：2009-10-13
申请号：US10577321
申请日：2004-10-29
申请人： Nils Bottke , Regina Benfer , Marco Bosch , Thomas Narbeshuber , Ulrich Steinbrenner , Juergen Stephan
发明人： Nils Bottke , Regina Benfer , Marco Bosch , Thomas Narbeshuber , Ulrich Steinbrenner , Juergen Stephan
IPC分类号： C07C309/31
CPC分类号： C11D1/22 , C07C2/66 , C07C2529/18 , C07C2529/70 , C07C15/107
摘要： In a process for preparing alkylaryl compounds by reacting a C10-14-monoolefin mixture with an aromatic hydrocarbon in the presence of an alkylation catalyst to form alkyl aromatic compounds and if appropriate subsequently sulfonating and neutralizing the resulting alkylaryl compounds, in the C10-14-monoolefins, on average, more than 0% and up to 100% of methyl branches are present in the longest carbon chain and fewer than 50% of the methyl branches are in the 2-, 3- and 4-position, calculated starting from the chain ends of the longest carbon chain.
摘要翻译：在烷基芳基化合物存在下，通过使C10-14-单烯烃混合物与芳族烃反应制备烷基芳基化合物的方法形成烷基芳香族化合物，如果合适，则随后磺化和中和得到的烷基芳基化合物，在C10-14- 平均来说，最长碳链中存在大于0％和高达100％的甲基支链的单烯烃，并且少于50％的甲基支链位于2-，3-和4-位，从最长碳链的链端。

20. 发明申请

US20080110763A1 Method For Producing Alkoxylated 2,5-Dihydrofuran But-2-Ene Derivatives Or Tetra-1,1,4,4-Alkoxylated But-2-Ene Derivatives 审中-公开
标题翻译：生产烷氧基化2,5-二氢呋喃丁-2-烯衍生物或四 - 1,1,4,4-烷氧基化丁-2-烯衍生物的方法
公开(公告)号：US20080110763A1
公开(公告)日：2008-05-15
申请号：US11908506
申请日：2006-03-23
申请人： Ingo Richter , Hermann Putter , Ulrich Griesbach , Nils Bottke
发明人： Ingo Richter , Hermann Putter , Ulrich Griesbach , Nils Bottke
IPC分类号： C25D3/62 , C07D307/02
CPC分类号： C07D307/32 , C07D307/88 , C07D307/89 , C25B3/02
摘要： A process for the preparation of 2,5-dihydrofuran derivatives substituted in the 3- or 4-position, which in the 2- or in the 5-position or at both positions each carry a C1- to C6-alkoxy radical (DHF-alkoxy derivatives 1), or 1,1,4,4-tetraalkoxy-but-2-ene derivatives substituted in the 3- or 4-position, from 2-butene-1 ,4-diol derivatives of the general formula (I) in which the radicals R1 and R2 independently of one another are hydrogen, C1- to C6-alkyl, C6- to C12-aryl or C5- to C12-cycloalkylene orR1 and R2, together with the double bond to which they are bonded, form a C6- to C12-aryl radical or a mono- or polyunsaturated C5- to C12-cycloalkyl radical,orfrom their mixture with 2,5-dihydrofuran derivatives substituted in the 3- position or 4-position, which in the 2- or in the 5-position carry a C1- to C6-alkoxy radical, by electro-chemical oxidation in the presence of a C1- to C6-monoalkyl alcohol.
摘要翻译：制备在3-或4-位取代的2,5-二氢呋喃衍生物的方法，其中2-或5-位或两个位置各自携带C 1 - 至C 6 - 烷氧基（DHF-烷氧基衍生物1）或在3-或4-位取代的1,1,4,4-四烷氧基 - 丁-2-烯衍生物，2 其中基团R 1和R 2彼此独立的通式（I）的1-丁烯-1,4-二醇衍生物是氢，C 1 -C 6烷基， 1〜C 6 - 烷基，C 6 - 至C 12 - 芳基或C 5〜 > - > C 12 - 亚环烷基或R 1和R 2与它们所键合的双键一起形成C < C 6 -C 12 - C 12 - 芳基或单不饱和C 5〜C 12 - 环烷基，或它们与3-或4-位取代的2,5-二氢呋喃衍生物的混合物，其在2-或5-位上携带C 1 H 通过在C 1 -C 6 - C 6 - 单烷基醇存在下的电化学氧化反应生成C 6〜C 6 - 烷氧基。

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