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    • 16. 发明授权
    • Fluorine-containing elastomeric copolymers, process for preparing the
same and composition containing the same
    • 含氟弹性体共聚物,其制备方法和含有该共聚物的组合物
    • US4141874A
    • 1979-02-27
    • US740772
    • 1976-11-10
    • Masahiko OkaSingo TanigawaTakesi SuzukiMasayasu TomodaYutaka Ueta
    • Masahiko OkaSingo TanigawaTakesi SuzukiMasayasu TomodaYutaka Ueta
    • C08F2/16C08F259/08C08L27/16
    • C08F259/08
    • Elastomeric copolymer of vinylidene fluoride and at least one other fluorine-containing monomer containing 28 to 92% by mole of the vinylidene fluoride unit and having an intrinsic viscosity of 0.4 to 1.3 at 35.degree. C. in methyl ethyl ketone, which is prepared by a two-stage polymerization process of vinylidene fluoride monomer and at least one other fluorine-containing monomer wherein monomers are copolymerized in an aqueous medium in the presence of a water-soluble radical polymerization initiator at a first stage to give a first stage-copolymer having an intrinsic viscosity of 0.01 to 3.0 at 35.degree. C. in methyl ethyl ketone and then copolymerized in an aqueous medium in the presence of the first stage-copolymer and an oil-soluble radical polymerization initiator at a second stage to give a second stage-copolymer, said elastomeric copolymer comprising 1 to 80% by weight of the first stage-copolymer and 20 to 99% by weight of the second stage-copolymer, process for preparing the same and composition containing the same. The elastomeric copolymer can be cured at satisfactory cure rate to give cured rubber having low compression set and high elongation.
    • 偏二氟乙烯与至少一种含有28-92%(摩尔)偏二氟乙烯单元的其它含氟单体的弹性共聚物,在35℃下在甲基乙基酮中的特性粘度为0.4〜1.3,其由 偏二氟乙烯单体和至少一种其它含氟单体的两阶段聚合方法,其中单体在第一阶段在水溶性自由基聚合引发剂存在下在水性介质中共聚,得到第一阶段共聚物,其具有 在35℃下在甲基乙基酮中的特性粘度为0.01〜3.0,然后在第一阶段共聚物和油溶性自由基聚合引发剂的存在下,在含水介质中共聚,得到第二级共聚物 ,所述弹性体共聚物包含1至80重量%的第一阶段共聚物和20至99重量%的第二阶段共聚物,其制备方法 nd组合物。 弹性体共聚物可以以令人满意的固化速率固化,得到具有低压缩永久变形和高伸长率的固化橡胶。