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11. 发明授权

US06815563B2 Method for producing bicyclic 1,3-diketones 失效
标题翻译：双环1,3-二酮的制备方法
公开(公告)号：US06815563B2
公开(公告)日：2004-11-09
申请号：US10332034
申请日：2003-01-06
申请人： Klaus Langemann , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Thorsten Volk , Guido Mayer
发明人： Klaus Langemann , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Thorsten Volk , Guido Mayer
IPC分类号： A01N4358
CPC分类号： C07C255/47 , C07C17/00 , C07C45/27 , C07C45/29 , C07C45/298 , C07C45/673 , C07C49/433 , C07C2602/44 , C07C23/30 , C07C49/693
摘要： A process for preparing bicyclic 1,3-diketones of the formula I where R1, R2, R3 and R4 are hydrogen, C1-C4-alkyl, C1-C4-alkoxy-carbonyl, halogen, cyano, nitro, C1-C4-alkylthio, C1-C4-alkylsulfenyl or C1-C4-alkylsulfonyl and Z is C1-C4-alkylene, O, S, N—R5 where R5 is C1-C4-alkyl or C1-C4-alkylcarbonyl, which comprises a) reacting a bicyclic olefin of the formula II with haloform in the presence of a base to give the ring-expanded product of the formula III where R1-R4 and Z are as defined above and X is halogen; b) hydrolyzing the allylic halogen of the compound of the formula III to the allyl alcohol of the formula IV c) oxidizing the allyl alcohol of the formula IV to the unsaturated ketone of the formula V d) reacting the ketone of the formula V with a nucleophilic ion Y− which stabilizes a negative charge to give the ketone of the formula VI e) hydrolyzing the ketone of the formula VI to the bicyclic 1,3-diketone of the formula I, novel intermediates and novel processes for preparing these intermediates are described.
摘要翻译：制备式I其中R 1，R 2，R 3和R 4的双环1,3-二酮的方法是氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基 - 羰基，卤素氰基，硝基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基硫基或C 1 -C 4 - 烷基磺酰基，Z是C 1 -C 4 - 亚烷基，O，S，NR 5，其中R 5是C 1 -C 4烷基或C 1 -C4 - 烷基羰基，其包括a）在碱存在下使式II的双环烯烃与卤代甲基反应，得到式III的环扩展产物，其中R 1 -R 4和Z如上所定义，X和X 将式III的化合物的烯丙基卤水解成式IVc的烯丙醇，将式Ⅳ的烯丙醇氧化为式ⅤⅤ的不饱和酮）使式Ⅴ的酮与使负电荷稳定以得到式VIe的酮）将式VI的酮水解成式I的双环1,3-二酮的新型中间体和新方法描述这些中间体。

12. 发明授权

US06713436B1 1-cycloalkylpyrazolyl-benzoyl derivatives 失效
标题翻译： 1-环烷基吡唑基 - 苯甲酰基衍生物
公开(公告)号：US06713436B1
公开(公告)日：2004-03-30
申请号：US10048949
申请日：2002-02-06
申请人： Ulf Neidlein , Norbert Götz , Ulf Misslitz , Roland Götz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Guido Mayer , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Ulf Neidlein , Norbert Götz , Ulf Misslitz , Roland Götz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Guido Mayer , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4380
CPC分类号： C07D413/10
摘要： The present invention relates to 1-cycloalkylpyrazolylbenzoyl derivatives of the formula I wherein all variables are as defined in the specification, their agriculturally useful salts, processes for their preparation, and for the use of these compounds or compositions comprising them, for controlling undesirable plants.
摘要翻译：本发明涉及式I的1-环烷基吡唑基苯甲酰基衍生物，其中所有变量如本说明书中所定义，其农业上有用的盐，其制备方法以及用于这些化合物或包含它们的组合物用于防治不期望的植物。

13. 发明授权

US06667333B2 Herbicidal 3-(4,5 dihydroisoxazole- 3 yl) substituted benzoycyclohexenone derivatives 失效
标题翻译：除草剂3-（4,5二氢异恶唑-3-基）取代的苯并环己烯酮衍生物
公开(公告)号：US06667333B2
公开(公告)日：2003-12-23
申请号：US10130021
申请日：2002-05-13
申请人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
发明人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A10N4380
CPC分类号： A01N43/80 , C07D261/20
摘要： 3-(4,5-Dihydroisoxazol-3-yl)-substituted benzoylcyclohexenone derivatives of the formula I in which the substituents A and R1 to R12 are as defined in the description and their agriculturally useful salts are described. The compounds have herbicidal action.
摘要翻译：描述了取代基A和R 1至R 12的3-（4,5-二氢异恶唑-3-基） - 取代的苯甲酰基环己烯酮衍生物如说明书中所定义的及其农业上有用的盐。该化合物具有除草作用。

14. 发明授权

US06645919B1 3-(4,5-Dihydroisoxazol-5-yl)benzoylcyclohexenones and the use thereof as herbicides 失效
标题翻译： 3-（4,5-二氢异恶唑-5-基）苯甲酰基环己烯酮及其作为除草剂的用途
公开(公告)号：US06645919B1
公开(公告)日：2003-11-11
申请号：US10276225
申请日：2002-11-14
申请人： Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Helmut Walter , Cyrill Zagar , Matthias Witschel
发明人： Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Helmut Walter , Cyrill Zagar , Matthias Witschel
IPC分类号： A01N4380
CPC分类号： A01N43/80 , C07D261/04 , C07D261/20
摘要： 3-(4,5-Dihydroisoxazol-5-yl)benzoylcyclohexenones of the formula I in which the variables have the following meanings: R1, R2 are hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl or C1-C6-haloalkylsulfonyl; R3 is hydrogen, halogen or alkyl; R4 is hydrogen or alkyl; R5, R6 are hydrogen, halogen, cyano, nitro, alkyl, alkoxy, alkylthio, dialkylamino, phenyl, benzyl or carbonyl, it being possible for the 7 last-mentioned radicals to be substituted; R11 is unsubstituted or substituted cyclohexenone which is linked in position 2 and has attached to it in position 1 a hydroxyl radical or derivatives thereof; and their agriculturally useful salts, processes for the preparation of the 3-(4,5-dihydroisoxazol-5-yl)benzoylcyclohexenones, compositions comprising them, and the use of these derivatives or of compositions comprising them for controlling undesired plants.
摘要翻译：式Iin的3-（4,5-二氢异恶唑-5-基）苯甲酰基环己烯酮，其变量具有以下含义：R 1，R 2为氢，硝基，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷基亚磺酰基，烷基磺酰基或C 1 -C 6卤代烷基磺酰基; R 3是氢，卤素或烷基; R 4是氢或烷基; R 5，R 6是氢，卤素，氰基，硝基，烷基，烷氧基，烷硫基，二烷基氨基，苯基，苄基或羰基，可以将7个最后提到的基团取代; R 11是未取代的或取代的环己烯酮，已经在位置1附着了羟基或其衍生物;及其农业上有用的盐，制备3-（4,5-二氢异恶唑-5-基）苯甲酰基环己烯酮的方法，包含它们的组合物，以及这些衍生物或包含它们的组合物以控制不期望的植物。

15. 发明授权

US06903221B2 Method for producing β-ketoenol esters 失效
标题翻译：生产β-酮戊二醇酯的方法
公开(公告)号：US06903221B2
公开(公告)日：2005-06-07
申请号：US10362056
申请日：2001-08-21
申请人： Steffen Kudis , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann
发明人： Steffen Kudis , Ulf Misslitz , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann
IPC分类号： C07B61/00 , C07C45/54 , C07C67/36 , C07C69/78 , C07C69/83 , C07D261/04 , C07D275/06
CPC分类号： C07D275/06 , C07C45/54 , C07C67/36 , C07D261/04 , C07C69/76
摘要： The invention relates to a method for producing β-ketoenol esters of the general formula (Ia) or (Ib), wherein Ar, Ra and Rb are defined as in claim 1. The inventive method is characterized by reacting an arylhalogenide of the general formula (II) with a 1,3-diketone of the general formula (III) or the tautomers thereof in a carbon monoxide atmosphere in the presence of an alkali and a catalyst that contains at least one transition metal of group VIII of the periodic system
摘要翻译：本发明涉及一种制备通式（Ia）或（Ib）的β-酮戊二醇酯的方法，其中Ar，R a和R b定义如权利要求1。本发明的方法的特征在于使通式（II）的芳基卤化物与通式（III）的1,3-二酮或其互变异构体在一氧化碳气氛中在碱和催化剂存在下反应，所述催化剂含有周期系的第VIII族的至少一种过渡金属

16. 发明授权

US06627581B1 Cyclopropyl-anellated 3-(4,5-dihydroisoxazol-3-yl)-substituted benzoylpyrazoles 失效
标题翻译：环丙基 - 苯甲酰基3-（4,5-二氢异恶唑-3-基） - 取代的苯甲酰基吡唑
公开(公告)号：US06627581B1
公开(公告)日：2003-09-30
申请号：US10130849
申请日：2002-05-23
申请人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
发明人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4380
CPC分类号： C07D413/10 , A01N43/80 , C07D261/20
摘要： Cyclopropyl-fused 3-(4,5-dihydroisoxazol-3-yl)-substituted benzoylpyrazoles of the formula I in which the variables are as defined in the description, and their agriculturally useful salts are described. The compounds have herbicidal action.
摘要翻译：描述了变体如说明书中定义的式Iin的环丙基稠合的3-（4,5-二氢异恶唑-3-基） - 取代的苯甲酰基吡唑及其农业上有用的盐。该化合物具有除草作用。

17. 发明授权

US06613719B1 3-(4,5-dihydroisoxazol-3-yl)-substituted benzoylpyrazoles 失效
标题翻译： 3-（4,5-二氢异恶唑-3-基） - 取代的苯甲酰基吡唑
公开(公告)号：US06613719B1
公开(公告)日：2003-09-02
申请号：US10130848
申请日：2002-05-23
申请人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
发明人： Steffen Kudis , Ernst Baumann , Wolfgang von Deyn , Klaus Langemann , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4380
CPC分类号： C07D413/10 , A01N43/80 , C07D261/04
摘要： 3-(4,5-Dihydroisoxazol-3-yl)-substituted benzoylpyrazoles of the formula I in which R4 is C1-C4-haloalkyl and R1 to R3 and R5 to R10 are as defined in the description are described. The compounds have herbicidal activity.
摘要翻译：描述了式Iin的3-（4,5-二氢异恶唑-3-基） - 取代的苯甲酰基吡唑，其中R 4为C 1 -C 4 - 卤代烷基且R 1至R 3和R 5至R 10如说明书中所定义。该化合物具有除草活性。

18. 发明授权

US06352959B1 Thiochromanoylpyrazolone derivatives 失效
标题翻译：硫代色酰基吡唑啉酮衍生物
公开(公告)号：US06352959B1
公开(公告)日：2002-03-05
申请号：US09857053
申请日：2001-05-31
申请人： Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Norbert Götz , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Klaus Langemann , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Guido Mayer , Ulf Misslitz , Ulf Neidlein , Matthias Witschel , Norbert Götz , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4384
CPC分类号： C07D409/06 , C07D409/14
摘要： Thiochromanoylpyrazolone derivatives of the formula I where: A is an unsubstituted or substituted, saturated or unsaturated alkyl chain; R1 is cyano, thiocyanato, nitro, OR4, SR5, SOR6, S02R6, ONR6NR7, ON═CR6R8, NR9R10, P(O)R11R12, P(S)R11R12, COR, CO2R6, unsubstituted or substituted phenyl or heterocyclyl; R2 is alkyl, haloalkyl, alkoxy or haloalkoxy; R3 is hydrogen, alkyl or halogen; X is oxygen, sulfur, S═O, S(═O)2, CR13R14, C═O or C═NR15; m is 0, 1 or 2; n is 0, 1, 2, 3 or 4; R16 is substituted pyrazol-4-yl-carbonyl or substituted (4,5-dihydro-5-oxo-pyrazol-4-yl)methylidene; and their agriculturally useful salts; Processes for preparing the thiochromanoylpyrazolone derivatives, compositions comprising them, and the use of these derivatives or of the compositions comprising them for controlling undesirable plants are described.
摘要翻译：其中：A为未取代或取代的饱和或不饱和烷基链; R1为氰基，氰硫基，硝基，OR4，SR5，SOR6，SO2R6，ONR6NR7，ON = CR6R8，NR9R10，P（O）R11R12， P（S）R 11 R 12，COR，CO 2 R 6，未取代或取代的苯基或杂环基; R 2是烷基，卤代烷基，烷氧基或卤代烷氧基; R 3是氢，烷基或卤素; X是氧，硫，S = O，S（= O） 2，CR 13 R 14，C = O或C = NR 15; m为0,1或2; n为0,1,2,3或4; R 16为取代的吡唑-4-基 - 羰基或取代的（4,5-二氢描述了制备硫代色满酰基吡唑啉酮衍生物的方法，包含它们的组合物，以及这些衍生物或包含它们的组合物用于防治不期望的植物的用途。

19. 发明授权

US07314948B2 Method for producing alkyl nitrites and alkyl dinitrites 有权
标题翻译：亚硝酸烷基酯和二硝基烷基酯的制备方法
公开(公告)号：US07314948B2
公开(公告)日：2008-01-01
申请号：US10485209
申请日：2002-08-02
申请人： Steffen Kudis , Rene Lochtman , Manfred Ehresmann , Michael Keil , Joachim Gebhardt , Michael Rack , Ralf Schimetzek
发明人： Steffen Kudis , Rene Lochtman , Manfred Ehresmann , Michael Keil , Joachim Gebhardt , Michael Rack , Ralf Schimetzek
IPC分类号： C07C23/02
CPC分类号： C07C201/04 , C07C203/00
摘要： In a continuous process for the preparation of alkyl nitrites and dinitrites, an alkanol or dialkanol is first mixed with an aqueous mineral acid, the reaction mixture obtained is then reacted with an inorganic nitrite and the product obtained can then be isolated immediately.
摘要翻译：在制备亚硝酸烷基酯和二硝酸烷基酯的连续方法中，首先将烷醇或二烷醇与无机酸水溶液混合，然后将得到的反应混合物与无机亚硝酸盐反应，然后立即分离得到的产物。

20. 发明授权

US06831039B1 3-(heterocyclyl)-substituted benzolpyrazols 失效
标题翻译： 3-（杂环基）取代的苯并吡唑
公开(公告)号：US06831039B1
公开(公告)日：2004-12-14
申请号：US09857067
申请日：2001-05-21
申请人： Ulf Neidlein , Norbert Götz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Guido Mayer , Ulf Misslitz , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
发明人： Ulf Neidlein , Norbert Götz , Ernst Baumann , Wolfgang von Deyn , Steffen Kudis , Klaus Langemann , Guido Mayer , Ulf Misslitz , Matthias Witschel , Martina Otten , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N4356
CPC分类号： C07D413/10 , C07D231/20
摘要： The invention relates to 3-(heterocyclyl)-substituted benzoylpyrazois of formula (I), wherein the variables have the following meanings: X is O, NH or N-alkyl; R1 is alkyl; R2, R3, R4, R5 are hydrogen, alkyl or alkyl halide; R6 is halogen, nitro, alkyl halide, alkoxy, halogenalkoxy, alkylthio, halogenalkylthio, alkylsulfonyl or halogenalkylsulfonyl; R7 is hydroxy, alkoxy, alkenyloxy, alkylsulfonyloxy, alkylcarboyloxy, alkylthiocarbonyloxy, phenylsulfonyloxy or phenylcarbonyloxy, and the phenyl radical can be substituted; R8, R9 are alkyl; R10 is hydrogen or alkyl; and R11 is hydrogen or alkyl; and to their agriculturally useable salts. The invention also relates to intermediate products and methods for producing the inventive compounds and to the use of these compounds or products containing them for combating undesirable plants.
摘要翻译：本发明涉及式（I）的3-（杂环基）取代的苯甲酰基吡啶，其中变量具有以下含义：X是O，NH或N-烷基; R 1是烷基; R 2，R 3，R 4，R 5是氢，烷基或烷基卤; R 6是卤素，硝基，烷基卤，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基磺酰基或卤代烷基磺酰基; R 7是羟基，烷氧基，烯氧基，烷基磺酰氧基，烷基羰氧基，烷硫基羰基氧基，苯基磺酰氧基或苯基羰基氧基，苯基可以被取代; R 8，R 9是烷基; R 10是氢或烷基; 和R 11是氢或烷基; 以及其农业上可用的盐类。本发明还涉及用于生产本发明化合物的中间产物和方法以及含有它们的这些化合物或产品用于对抗不期望的植物的用途。

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