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    • 16. 发明授权
    • Photographic element containing dispersions of high dye-yield couplers
having improved photographic activity
    • 包含具有改善的摄影活性的高染料收率成色剂的分散体的照相元件
    • US5830632A
    • 1998-11-03
    • US741886
    • 1996-10-31
    • Krishnan ChariDavid Thomas SouthbyDavid Hoke
    • Krishnan ChariDavid Thomas SouthbyDavid Hoke
    • G03C7/305G03C7/388G03C1/08G03C7/26G03C7/32
    • G03C7/388G03C7/30576Y10S430/136Y10S430/156
    • Photographic element are described comprising a support bearing a photographic silver halide emulsion layer having associated therewith a micro-precipitated dispersion of a high dye-yield coupler having the formula: COUP--(T).sub.m --L--DYE where COUP is the coupler moiety of the coupler capable of reacting at the coupling position with oxidized color developer to form a first dye, T is one or more timing groups with m=0, 1 or 2, L is a linking group selected from the group consisting of --OC(O)--, --OC(S)--, --SC(O)--, --SC(S)--, or --OC(.dbd.NSO.sub.2 R)--, where R is a substituted or unsubstituted alkyl or aryl group, and DYE is a second dye or precursor thereof comprising an electrically neutral chromophore. The invention also provides a photographic coupler dispersion, a photographic silver halide emulsion, and a process for forming an image in a photographic element in accordance with the invention. The photographic element, coupler dispersion, silver halide emulsion, and imaging process provide improved reactivity and photographic properties.
    • 描述的照相元件包括具有照相卤化银乳剂层的载体,其具有与其相连的具有下式的高染料收率成色剂的微沉淀分散体:COUP-(T)mL-DYE,其中COUP是成色剂的成色剂部分 能够在偶联位置与氧化的显色剂反应形成第一种染料,T是一个或多个m = 0,1或2的时基,L是选自-OC(O) - ,-OC(S) - , - SC(O) - , - SC(S) - 或-OC(= NSO 2 R) - ,其中R是取代或未取代的烷基或芳基,DYE是第二种染料或 其前体包含电中性发色团。 本发明还提供了照相成色剂分散体,照相卤化银乳剂,以及根据本发明在照相材料中形成图像的方法。 照相元件,成色剂分散体,卤化银乳剂和成像方法提供改善的反应性和照相性能。
    • 17. 发明授权
    • High activity photographic dispersions with ultra low levels of
permanent solvent
    • 具有超低水平永久溶剂的高活性照相分散体
    • US5770352A
    • 1998-06-23
    • US634491
    • 1996-04-18
    • Krishnan Chari
    • Krishnan Chari
    • G03C7/388G03C7/392G03C7/25
    • G03C7/388G03C7/3885G03C7/39288Y10S430/136
    • The invention is accomplished by providing an aqueous dispersion of a photographic coupler by precipitation from a solvent solution by solvent and/or pH shift. A second aqueous dispersion of an activating permanent solvent for the photographic coupler is also provided. The dispersion of activating permanent solvent and photographic coupler are combined to form a combined dispersion with relatively low amounts of coupler solvent which may be then mixed with a gelatin dispersion of silver halide particles to form a photographic emulsion coating composition suitable for casting as a photographic element layer. The coupler is selected to have a logP greater than or equal to about 10 and the activating solvent is selected to have a logP greater than or equal to about 8 and a Tg less than or equal to about -80.degree. C. to provide stable, small size photographically active coupler dispersions without the need for nonionic water soluble polymers and with minimal amount of added solvent. Use of a weight ratio of permanent solvent to coupler within the range of from 0.01:1 to 0.3:1 in accordance with the invention enables thin photographic layers to be coated with good photographic activity.
    • 通过用溶剂和/或pH漂移从溶剂溶液中沉淀提供照相成色剂的水分散体来实现本发明。 还提供了用于照相偶联剂的活化永久性溶剂的第二水性分散体。 将活化永久性溶剂和照相成色剂的分散体结合形成具有相对少量成色剂溶剂的组合分散体,然后可将其与卤化银颗粒的明胶分散体混合以形成适合于作为照相元件浇铸的照相乳剂涂料组合物 层。 选择成色剂的logP大于或等于约10,活化溶剂选择为logP大于或等于约8,Tg小于或等于约-80℃,以提供稳定的, 小尺寸的照相活性成色剂分散体,而不需要非离子水溶性聚合物和最少量的添加溶剂。 根据本发明,使用永久性溶剂与偶联剂的重量比在0.01:1至0.3:1的范围内可使薄照相层具有良好的照相活性。
    • 18. 发明授权
    • Dispersions of epoxy scavengers exhibiting improved raw stock keeping
    • 环氧清除剂的分散体表现出改善的原料保存
    • US5620632A
    • 1997-04-15
    • US427763
    • 1995-04-25
    • Krishnan Chari
    • Krishnan Chari
    • C07D303/16C07D303/22C07D303/34C07D303/42C07D303/46C07D405/12C07F5/02C07F9/655G03C1/005G03C7/392B01J13/00C08K5/524C09K15/26
    • C07D303/22C07D303/16C07D303/34C07D303/42C07D303/46C07D405/12C07F5/025C07F9/65502G03C1/005G03C7/39268G03C7/39296Y10S516/928
    • A process for preparing a solid particle dispersion of an epoxy compound of the formula SI, ##STR1## wherein R is H, an alkyl group, or an aryl group; L.sub.1 is an alkylene group or an arylene group; L.sub.2 is --O--, --CO--, --S--, --SO.sub.2 --, --PO.sub.2 --, --CO.sub.2 --, --NHCO-- or --NHSO.sub.2 --, wherein L.sub.2 may be orientated in either direction; L.sub.3 is an alkylene group; m is 0 or 1; p is 0 or 1; and X is ##STR2## wherein R' is H or an alkyl or aryl group, with the proviso that where L.sub.2 comprises an ionizable group, X may also be an alkyl group or an aryl group is disclosed. The process comprising the steps of: (a) forming a coarse aqueous slurry of solid particles of said compound; and (b) milling said slurry in the presence of a hydrophobic, photographically inert, liquid second component which has a logP.sub.(calc) greater than about 6.0 for time sufficient to provide particles of the desired average particle size. Solid particle dispersions of the invention exhibit improved raw stock keeping under conditions of elevated temperatures when incorporated in a photographic element.
    • 一种制备式SI的环氧化合物的固体颗粒分散体的方法,其中R是H,烷基或芳基; L1是亚烷基或亚芳基; L 2是-O-,-CO-,-S-,-SO 2 - , - O 2 - , - CO 2 - , - NHCO-或-NHSO 2 - ,其中L2可以沿任一方向取向; L3是亚烷基; m为0或1; p为0或1; 并且X是,其中R'是H或烷基或芳基,条件是其中L2包含可离子化基团,X也可以是烷基或芳基。 该方法包括以下步骤:(a)形成所述化合物的固体颗粒的粗制含水浆料; 和(b)在疏水的,照相惰性的液体第二组分的存在下研磨所述浆料,其中logP(calc)大于约6.0,足以提供所需平均粒径的颗粒。 当结合到照相元件中时,本发明的固体颗粒分散体显示改善的原料保持在高温条件下。