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    • 11. 发明授权
    • Method for preparing rare earth permanent magnet material
    • 稀土永磁材料的制备方法
    • US08420010B2
    • 2013-04-16
    • US11916498
    • 2007-03-28
    • Hajime NakamuraTakehisa MinowaKoichi Hirota
    • Hajime NakamuraTakehisa MinowaKoichi Hirota
    • B22F7/00
    • C23C10/30B22F3/24B22F2003/241B22F2003/242B22F2003/247B22F2003/248C21D6/00C22C38/005C22C2202/02C23C10/28C23C10/52C23C24/08H01F1/0577H01F41/0293
    • A method for preparing a rare earth permanent magnet material is characterized by comprising the steps of disposing a powder mixture on a surface of a sintered magnet body of R1—Fe—B composition wherein R1 is at least one element selected from rare earth elements inclusive of Sc and Y, the powder mixture comprising a powder containing at least 0.5% by weight of M which is at least one element selected from Al, Cu, and Zn and having an average particle size equal to or less than 300 μm and a powder containing at least 30% by weight of a fluoride of R2 which is at least one element selected from rare earth elements inclusive of Sc and Y and having an average particle size equal to or less than 100 μm, and heat treating the magnet body having the powder disposed on its surface at a temperature equal to or below the sintering temperature of the magnet body in vacuum or in an inert gas, for causing at least one of M and R2 in the powder mixture to be absorbed in the magnet body. The invention provides an R—Fe—B sintered magnet with high performance and a minimized amount of Tb or Dy used.
    • 一种制备稀土永磁材料的方法的特征在于包括以下步骤:在R1-Fe-B组合物的烧结磁体的表面上设置粉末混合物,其中R 1是选自稀土元素中的至少一种元素,包括 Sc和Y,所述粉末混合物包含含有至少0.5重量%M的至少一种选自Al,Cu和Zn的元素并且具有等于或小于300μm的平均粒度的粉末和包含 至少30重量%的R 2的氟化物,其为选自包括Sc和Y的稀土元素中的至少一种元素,并且具有等于或小于100μm的平均粒度,并且对具有粉末的磁体进行热处理 在真空中或在惰性气体中的等于或低于磁体的烧结温度的温度下,在粉末混合物中使M和R2中的至少一个吸收在磁体中。 本发明提供一种具有高性能和最小量的Tb或Dy的R-Fe-B烧结磁体。
    • 13. 发明授权
    • Method for preparing rare earth permanent magnet material
    • 稀土永磁材料的制备方法
    • US07955443B2
    • 2011-06-07
    • US11783639
    • 2007-04-11
    • Hajime NakamuraTakehisa MinowaKoichi Hirota
    • Hajime NakamuraTakehisa MinowaKoichi Hirota
    • H01F1/057
    • H01F41/0293H01F1/0577
    • A permanent magnet material is prepared by covering an anisotropic sintered magnet body of formula: R1x(Fe1-yCoy)100-x-z-aBzMa wherein R1 is a rare earth element, M is Al, Cu or the like, with a powder comprising an oxide of R2, a fluoride of R3 or an oxyfluoride of R4 wherein R2, R3, and R4 are rare earth elements, and having an average particle size up to 100 μm, heat treating the powder-covered magnet body in a hydrogen gas-containing atmosphere for inducing disproportionation reaction on R12Fe14B compound, and continuing heat treatment at a reduced hydrogen gas partial pressure for inducing recombination reaction to said compound, thereby finely dividing said compound phase to a crystal grain size up to 1 μm, and for effecting absorption treatment, thereby causing R2, R3 or R4 to be absorbed in the magnet body.
    • 通过覆盖式为:R1x(Fe1-yCoy)100-xz-aBzMa的各向异性烧结磁体,其中R1是稀土元素,M是Al,Cu等,并且包含氧化物 的R2,R3的氟化物或R4的氟氧化物,其中R2,R3和R4是稀土元素,平均粒径高达100μm,在含氢气体的气氛中对粉末包覆的磁体进行热处理 用于在R12Fe14B化合物上诱导歧化反应,并且在降低的氢气分压下继续热处理以诱导与所述化合物的复合反应,从而将所述化合物相细分至1μm以上的晶粒尺寸,从而进行吸收处理 导致R2,R3或R4被吸收在磁体中。