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11. 发明授权

US5648585A Process for isomerizing linear olefins to isoolefins 失效
标题翻译：将线性烯烃异构化成异烯烃的方法
公开(公告)号：US5648585A
公开(公告)日：1997-07-15
申请号：US175010
申请日：1993-12-29
申请人： Brendan Dermot Murray , Bruce Herman Charles Winquist , Donald Henry Powers , Jon Barin Wise , Richard Brian Halsey
发明人： Brendan Dermot Murray , Bruce Herman Charles Winquist , Donald Henry Powers , Jon Barin Wise , Richard Brian Halsey
IPC分类号： B01J29/67 , A61K8/02 , A61K8/19 , A61K8/23 , A61K8/30 , A61K8/365 , A61K8/41 , A61K8/42 , A61K8/55 , A61K8/60 , A61K8/64 , A61K8/72 , A61K8/73 , A61K8/88 , A61K8/89 , A61K8/92 , A61K8/97 , A61K8/98 , A61K31/715 , A61P17/02 , A61Q5/02 , A61Q5/12 , A61Q19/00 , A61Q19/08 , A61Q19/10 , B01J29/66 , B01J29/90 , C07C5/27 , C07C11/02 , C07C11/08 , C08B37/08 , C07C5/22
CPC分类号： A61K8/736 , A61Q19/00 , B01J29/90 , C07C5/2775 , C08B37/003 , A61K2800/5426 , A61Q19/08 , Y02P20/584
摘要： This invention relates to a process in which a linear olefin is converted under isomerizing conditions to its corresponding methyl branched isoolefin by contact at a temperature of from 200.degree. C. to 650.degree. C. with an isomerizing catalyst comprising (i) at least one zeolite having only in one dimension a pore structure having a pore size small enough to retard by-product dimerization and coke formation and large enough to permit entry of the linear olefin and allow formation of the methyl branched isoolefin, (ii) an alumina binder and (iii) up to about 15% by weight of coke oxidation-promoting metal. After a period of operation, when sufficient coke has deposited on the catalyst in an amount to significantly reduce the activity of the catalyst, the catalyst is stripped of hydrocarbon and then contacted at elevated temperature with an oxygen-containing gas for a sufficient time to burn off the coke, i.e., to regenerate the catalyst at a temperature of less than about 565.degree. C. After regeneration, the isomerization process is continued. The use of palladium and/or platinum as the coke oxidation-promoting metal is particularly desirable.
摘要翻译：本发明涉及一种方法，其中线性烯烃在异构化条件下通过在200℃至650℃的温度下与异构化催化剂接触而转化成相应的甲基支链异烯烃，所述异构化催化剂包含（i）至少一种沸石仅在一个维度上具有孔径足够小以阻止副产物二聚和焦炭形成并且足够大以允许线性烯烃进入并允许形成甲基支链异烯烃的孔结构，（ii）氧化铝粘合剂和（ iii）高达约15重量％的焦炭氧化促进金属。经过一段时间的操作后，当催化剂上沉积足够的焦炭以显着降低催化剂活性的量时，将催化剂汽提出烃，然后在高温下与含氧气体接触足够的时间燃烧即，在低于约565℃的温度下再生催化剂。再生后，继续进行异构化处理。使用钯和/或铂作为焦炭氧化促进金属是特别理想的。

12. 发明授权

US08753425B2 Method of making a gas separation molecular sieve membrane 失效
标题翻译：制造气体分离分子筛膜的方法
公开(公告)号：US08753425B2
公开(公告)日：2014-06-17
申请号：US13322733
申请日：2010-05-27
申请人： Brendan Dermot Murray , Paul Jason Williams
发明人： Brendan Dermot Murray , Paul Jason Williams
IPC分类号： B01D71/02 , B01D53/22 , B05D1/36
CPC分类号： B01D53/228 , B01D67/0051 , B01D69/04 , B01D71/028 , B01D2323/12
摘要： A method of preparing a supported gas separation membrane, comprising: preparing crystalline seeds from a synthesis mixture comprising an aluminum source, a phosphorous source, a silicon source, at least one organic templating agent and water; applying the seeds to a porous support to produce a seeded porous support; contacting the seeded porous support with a synthesis gel under hydrothermal synthesis conditions to produce a coated porous support; and calcining the coated porous support is described. A supported gas separation membrane made by this method is also described.
摘要翻译：一种制备负载气体分离膜的方法，包括：从包含铝源，磷源，硅源，至少一种有机模板剂和水的合成混合物制备晶体种子; 将种子施加到多孔载体上以产生接种的多孔载体; 在水热合成条件下使接种的多孔载体与合成凝胶接触以产生涂覆的多孔载体; 并描述了涂覆的多孔载体的煅烧。还描述了通过该方法制备的支撑气体分离膜。

13. 发明授权

US08617291B2 Method of making a gas separation molecular sieve membrane 失效
标题翻译：制造气体分离分子筛膜的方法
公开(公告)号：US08617291B2
公开(公告)日：2013-12-31
申请号：US13321298
申请日：2010-05-27
申请人： Brendan Dermot Murray , Paul Jason Williams
发明人： Brendan Dermot Murray , Paul Jason Williams
IPC分类号： B01D53/22
CPC分类号： B01J29/85 , B01D53/228 , B01D67/0051 , B01D69/10 , B01D71/028 , B01D2323/12
摘要： A method of preparing a supported gas separation membrane, comprising: preparing crystalline seeds from a synthesis mixture comprising an aluminum source, a phosphorous source, a silicon source, at least one organic templating agent and water; applying the seeds to a porous support to produce a seeded porous support; contacting the seeded porous support with a synthesis gel under hydrothermal synthesis conditions to produce a coated porous support; and calcining the coated porous support is described. A supported gas separation membrane made by this method is also described.
摘要翻译：一种制备负载气体分离膜的方法，包括：从包含铝源，磷源，硅源，至少一种有机模板剂和水的合成混合物制备晶体种子; 将种子施加到多孔载体上以产生接种的多孔载体; 在水热合成条件下使接种的多孔载体与合成凝胶接触以产生涂覆的多孔载体; 并描述了涂覆的多孔载体的煅烧。还描述了通过该方法制备的支撑气体分离膜。

14. 发明申请

US20120028794A1 CATALYSTS FOR THE PRODUCTION OF HYDROGEN 审中-公开
标题翻译：用于生产氢的催化剂
公开(公告)号：US20120028794A1
公开(公告)日：2012-02-02
申请号：US13141248
申请日：2009-12-17
申请人： Khiet Thanh Lam , Brendan Dermot Murray , Narayana Mysore , Scott Lee Wellington
发明人： Khiet Thanh Lam , Brendan Dermot Murray , Narayana Mysore , Scott Lee Wellington
IPC分类号： B01J23/00 , B01J37/00 , B01J23/755 , B01J37/08 , B01J35/02 , B01J23/10
CPC分类号： C01B3/326 , B01J23/50 , B01J23/78 , B01J23/83 , B01J35/008 , B01J35/065 , B01J35/1019 , B01J37/0225 , C01B3/40 , C01B2203/0233 , C01B2203/1041 , C01B2203/1058 , C01B2203/1082 , C01B2203/1094 , C01B2203/1205 , C01B2203/1229 , C01B2203/86 , Y02P20/52 , Y02P30/30
摘要： The invention provides a bio-based feedstock steam reforming catalyst comprising: a modified support; a metal component; and a promoter. The process also provides a method of preparing a bio-based feedstock steam reforming catalyst comprising: providing a support material comprising a transition metal oxide; providing a modifier comprising an alkaline earth element; contacting the support material with the modifier to form a modified support; providing a metal component comprising a Group VIII transition metal; contacting the support material, the modified support or combinations thereof with the metal component to form the steam reforming catalyst; and contacting the modified support, the metal component, the steam reforming catalyst or combinations thereof with a promoter.
摘要翻译：本发明提供一种基于生物的原料蒸汽重整催化剂，其包含：改性载体; 金属成分; 和启动子。该方法还提供了一种制备基于生物的原料蒸汽重整催化剂的方法，包括：提供包含过渡金属氧化物的载体材料; 提供包含碱土元素的改性剂; 使支撑材料与改性剂接触以形成改性的载体; 提供包含第VIII族过渡金属的金属组分; 使所述载体材料，所述改性载体或其组合与所述金属组分接触以形成所述蒸汽重整催化剂; 并将改性载体，金属组分，蒸汽重整催化剂或其组合与促进剂接触。

15. 发明授权

US07888307B2 Highly branched primary alcohol compositions, and biodegradable detergents made therefrom 有权
标题翻译：高分支伯醇组合物和由其制成的可生物降解的洗涤剂
公开(公告)号：US07888307B2
公开(公告)日：2011-02-15
申请号：US12119422
申请日：2008-05-12
申请人： David M. Singleton , Louis Kravetz , Brendan Dermot Murray
发明人： David M. Singleton , Louis Kravetz , Brendan Dermot Murray
IPC分类号： C11D17/00
CPC分类号： C11D1/72 , C11D1/146
摘要： There is provided a new branched primary alcohol composition and the sulfates thereof exhibiting good cold water detergency and biodegradability. The branched primary alcohol composition has an average number of branches per chain of at least 0.7, having at least 8 carbon atoms and containing both methyl and ethyl branches. The primary alcohol composition may also contain less than 0.5 atom % of quaternary carbon atoms, and a significant number ethyl branches, terminal isopropyl branches, and branching at the C3 position relative to the hydroxyl carbon. The process for its manufacture is by skeletally isomerizing an olefin feed having at least 7 carbon atoms followed by conversion to an alcohol, as by way of hydroformylation, and ultimately, sulfation to obtain a detergent surfactant. Useful catalysts include the zeolites having at least one channel with a crystallographic free diameter along the x and/or y planes of the [001] view ranging from greater than 4.2 Å and less than 7 Å, but allows one to skeletally isomerize the olefin to produce a variety of branches, while retaining ready biodegradability and good cold water detergency.
摘要翻译：提供了一种新的支链伯醇组合物，其硫酸盐具有良好的冷水去污力和生物降解性。支链伯醇组合物具有至少0.7个链的平均支链数，至少具有8个碳原子并含有甲基和乙基支链。伯醇组合物还可以含有小于0.5原子％的季碳原子，相对于羟基碳，在C3位上有大量的乙基支链，末端异丙基支链和支链。其制造方法是通过骨架异构化具有至少7个碳原子的烯烃原料，然后转化为醇，通过加氢甲酰化，最终硫酸化得到洗涤剂表面活性剂。有用的催化剂包括具有沿[001]视图的x和/或y平面的至少一个通道具有至少一个具有晶体自由直径的沸石的沸石，其范围从大于4.2且小于7，但允许将骨架异构化烯烃至生产各种分支，同时保持即时的生物降解性和良好的冷水去污力。

16. 发明申请

US20090032437A1 Catalytic Distillation Process for Primary Haloalkanes 失效
标题翻译：主要卤代烷烃的催化蒸馏工艺
公开(公告)号：US20090032437A1
公开(公告)日：2009-02-05
申请号：US11887195
申请日：2006-03-24
申请人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
发明人： Howard Lam-Ho Fong , Brendan Dermot Murray , Thomas Carl Semple
IPC分类号： C10G65/02 , C07C19/075
CPC分类号： C07C17/23 , A61K8/20 , A61Q17/04 , C07C17/10 , C07C17/358 , C07C17/383 , C07C41/16 , C11D1/72 , C11D11/0082 , Y02P20/127 , C07C19/075 , C07C43/04
摘要： A process for making primary haloalkanes by catalytic distillation of internal haloalkanes which comprises a) introducing an internal haloalkane feed into a catalytic distillation column; b) isomerizing at least a portion of the internal haloalkane feed in the presence of an internal haloalkane isomerization catalyst at a temperature at or above the boiling point of the internal haloalkanes and below the temperature and pressure at which hydrogen halide is formed to form primary haloalkanes; and removing the primary haloalkanes from the catalytic distillation column.
摘要翻译：通过内部卤代烷烃的催化蒸馏制备主要卤代烷烃的方法，其包括：a）将内部卤代烷烃进料引入催化蒸馏塔; b）在内部卤代烷烃异构化催化剂的存在下，在内部卤代烷烃的沸点或高于内部卤代烷的沸点的温度和低于形成卤化氢的温度和压力下形成主要的卤代烷烃，异构化内部卤代烷烃进料的至少一部分 ; 并从催化蒸馏塔中除去主卤代烷烃。

17. 发明授权

US06455712B1 Preparation of oxirane compounds 有权
标题翻译：环氧乙烷化合物的制备
公开(公告)号：US06455712B1
公开(公告)日：2002-09-24
申请号：US09736522
申请日：2000-12-13
申请人： Garo Garbis Vaporciyan , Brendan Dermot Murray
发明人： Garo Garbis Vaporciyan , Brendan Dermot Murray
IPC分类号： C07D30119
CPC分类号： C07D301/19
摘要： A process for preparing oxirane compounds, which process comprises: (i) oxidizing an alkylaryl to obtain a stream comprising alkylaryl hydroperoxide, (ii) contacting at least a part of the alkylaryl hydroperoxide obtained in step (i) with an olefin in the presence of a catalyst to obtain a product stream comprising an oxirane compound and alkylaryl hydroxyl, (iii) optionally reacting part of the alkylaryl hydroperoxide obtained in step (i) to obtain a mixture comprising (a) phenol, and (b) a ketone and/or aldehyde, and (c) optionally by-products, (iv) separating oxirane compound from the product stream of step (ii) to obtain (a) a residual product stream and (b) oxirane, and (v) contacting at least a part of the residual product stream with hydrogen to obtain alkylaryl, wherein at least a part of said alkylaryl is recycled to step (i).
摘要翻译：一种制备环氧乙烷化合物的方法，该方法包括：（i）氧化烷基芳基以获得包含烷基芳基氢过氧化物的流，（ii）使步骤（i）中获得的烷基芳基氢过氧化物的至少一部分与烯烃在获得包含环氧乙烷化合物和烷基芳基羟基的产物流的催化剂，（iii）任选地使步骤（i）中获得的烷基芳基氢过氧化物的一部分反应以获得包含（a）苯酚和（b）酮和/或醛，和（c）任选的副产物，（iv）从步骤（ii）的产物流中分离环氧乙烷化合物以获得（a）残余产物流和（b）环氧乙烷，和（v）使至少一部分的剩余产物流与氢气反应以获得烷基芳基，其中至少一部分所述烷基芳基被再循环到步骤（i）。

18. 发明授权

US06307095B1 Process for the preparation of vinylesters 失效
标题翻译：制备乙烯基酯的方法
公开(公告)号：US06307095B1
公开(公告)日：2001-10-23
申请号：US08950427
申请日：1997-10-15
申请人： Johannes Jacobus Keijsper , Jean-Paul Lange , Brendan Dermot Murray
发明人： Johannes Jacobus Keijsper , Jean-Paul Lange , Brendan Dermot Murray
IPC分类号： C07C6704
CPC分类号： C07C67/04 , C07C69/01 , C07C69/24
摘要： A process for the catalytic conversion of carboxylic acids with acetylene to vinylesters. At least one, preferably saturated, secondary carboxylic ester and/or at least one, preferably tertiary carboxylic acid is (are) passed in the gas phase together with acetylene at an elevated temperature, preferably in the range of from 150 to 400° C., over a catalyst comprising zinc and a solid inert oxidic carrier, preferably alumina. The carboxylic acids have advantageously the following formula: in which R1 is H or an alkyl group and R2 and R3 are alkyl groups, the total number of C-atoms of R1+R2+R3 being in the range of from 3 to 18. These vinylesters have a good stability and are particularly useful components in emulsion paints and as modifiers in alkyd and epoxy resin.
摘要翻译：将羧酸与乙炔催化转化成乙烯基酯的方法。在高温下，将至少一种优选饱和的仲羧酸酯和/或至少一种优选叔羧酸与乙炔一起通入气相中温度，优选在150-400℃的范围内，在包含锌和固体惰性氧化载体的催化剂，优选氧化铝中。羧酸有利地具有下式：其中R 1是H或烷基，R 2 并且R 3是烷基，R 1 + R 2 + R 3的C原子总数在3至18的范围内。这些乙烯基酯具有良好的稳定性，并且在乳液漆中和作为醇酸树脂和环氧树脂中的改性剂是特别有用的组分树脂。

19. 发明授权

US07781390B2 Highly branched primary alcohol compositions, and biodegradable detergents made therefrom 有权
标题翻译：高分支伯醇组合物和由其制成的可生物降解的洗涤剂
公开(公告)号：US07781390B2
公开(公告)日：2010-08-24
申请号：US11748976
申请日：2007-05-15
申请人： David M. Singleton , Louis Kravetz , Brendan Dermot Murray
发明人： David M. Singleton , Louis Kravetz , Brendan Dermot Murray
IPC分类号： C11D17/00
CPC分类号： C11D1/72 , C11D1/146
摘要： There is provided a new branched primary alcohol composition and the sulfates thereof exhibiting good cold water detergency and biodegradability. The branched primary alcohol composition has an average number of branches per chain of at least 0.7, having at least 8 carbon atoms and containing both methyl and ethyl branches. The primary alcohol composition may also contain less than 0.5 atom % of quaternary carbon atoms, and a significant number ethyl branches, terminal isopropyl branches, and branching at the C3 position relative to the hydroxyl carbon. The process for its manufacture is by skeletally isomerizing an olefin feed having at least 7 carbon atoms followed by conversion to an alcohol, as by way of hydroformylation, and ultimately, sulfation to obtain a detergent surfactant. Useful catalysts include the zeolites having at least one channel with a crystallographic free diameter along the x and/or y planes of the [001] view ranging from greater than 4.2 Å and less than 7 Å but allows one to skeletally isomerize the olefin to produce a variety of branches, while retaining ready biodegradability and good cold water detergency.
摘要翻译：提供了一种新的支链伯醇组合物，其硫酸盐具有良好的冷水去污力和生物降解性。支链伯醇组合物具有至少0.7个链的平均支链数，至少具有8个碳原子并含有甲基和乙基支链。伯醇组合物还可以含有小于0.5原子％的季碳原子，相对于羟基碳，在C3位上有大量的乙基支链，末端异丙基支链和支链。其制造方法是通过骨架异构化具有至少7个碳原子的烯烃原料，然后转化为醇，通过加氢甲酰化，最终硫酸化得到洗涤剂表面活性剂。有用的催化剂包括沿[001]视图的x和/或y平面具有至少一个具有至少一个具有结晶自由直径的通道的沸石，范围从大于4.2和小于7，但允许一个骨架异构化烯烃以产生各种分支，同时保持即时的生物降解性和良好的冷水去污力。

20. 发明申请

US20090025935A1 System and methods for producing oil and/or gas 有权
公开(公告)号：US20090025935A1
公开(公告)日：2009-01-29
申请号：US11918839
申请日：2006-04-19
申请人： Johan Jacobus Van Dorp , Michael Zvi Golombok , Michiel Jan Groeneveld , Douglas Charlton McCammon , Thomas Mikus , Alexander Michiel Mollinger , Brendan Dermot Murray , Eric Johannes Puik , Raul Valdez , Willem Van Vark , Dean Chien Wang
发明人： Johan Jacobus Van Dorp , Michael Zvi Golombok , Michiel Jan Groeneveld , Douglas Charlton McCammon , Thomas Mikus , Alexander Michiel Mollinger , Brendan Dermot Murray , Eric Johannes Puik , Raul Valdez , Willem Van Vark , Dean Chien Wang
IPC分类号： E21B43/40 , E21B43/16 , C01B31/26
CPC分类号： E21B43/40 , C01B32/72 , C01B32/75 , E21B43/16
摘要： A system including a mechanism for recovering oil and/or gas from an underground formation, the oil and/or gas comprising one or more sulfur compounds; a mechanism for converting at least a portion of the sulfur compounds from the recovered oil and/or gas into a carbon disulfide formulation; and a mechanism for releasing at least a portion of the carbon disulfide formulation into a formation.

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