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11. 发明授权

US06242653B1 Process for the preparation of &agr;-diketones from ketols or ketals from ketols 失效
标题翻译：从酮基酮或酮缩酮制备α-二酮的方法
公开(公告)号：US06242653B1
公开(公告)日：2001-06-05
申请号：US09377732
申请日：1999-08-19
申请人： Werner Aquila , Jörg Botzem , Melanie Brunner , Hartwig Fuchs , Wolfgang Krause , Klaus Pandl , Ulrich Schäfer-Lüderssen
发明人： Werner Aquila , Jörg Botzem , Melanie Brunner , Hartwig Fuchs , Wolfgang Krause , Klaus Pandl , Ulrich Schäfer-Lüderssen
IPC分类号： C07C4529
CPC分类号： C07C45/39 , C07C45/515 , C07C49/12 , C07C49/175 , C07C49/517
摘要： The process for the preparation of carbonyl compounds of the formula I where R1 and R2 are a hydrocarbon radical, or R1 and R2 together are an unsubstituted or substituted alkylene group, and X is=O or two alkoxy groups, comprises oxidizing alcohols of the formula II where R1 to R2 and X are as defined above, with oxygen in the gaseous phase a) at temperatures of from 270 to 600° C. on silver coated catalysts which comprise an abrasion-resistant coating of metallic silver on a core of inert support material, or b) at temperatures of from 450 to 750° C. on silver crystals and/or copper crystals having a particle size of from 0.1 to 2.5 mm for a residence time of at most 0.1 second. Also claimed is an advantageous overall process for the preparation of &agr;-diketones, preferably diacetal, from the corresponding ketone, in particular methyl ethyl ketone, via the carbonyl compounds of the formula I where X is two alkoxy groups.
摘要翻译：制备式I的羰基化合物的方法，其中R 1和R 2是烃基，或者R 1和R 2一起是未取代或取代的亚烷基，并且X是= O或两个烷氧基，包括氧化式II的醇，其中R 1 在含有惰性载体材料芯上的金属银的耐磨涂层的银涂覆的催化剂上，在温度为270-600℃的温度下，R2和X如上定义，在气相中为氧）在450至750℃的温度下，在银晶体和/或具有0.1至2.5mm的粒度的铜晶体上，停留时间至多为0.1秒。还要求保护的是制备α 二酮，优选二缩醛，通过其中X是两个烷氧基的式I的羰基化合物从相应的酮，特别是甲基乙基酮中获得。

12. 发明授权

US5773635A Preparation of polyenecarbonyl compounds having a high content of the all-E isomer, and of their acetals or ketals 失效
标题翻译：具有全E异构体含量高的多烯羰基化合物及其缩醛或缩酮的制备
公开(公告)号：US5773635A
公开(公告)日：1998-06-30
申请号：US498840
申请日：1995-07-06
申请人： Walter Dobler , Wolfgang Krause , Joachim Paust , Otto Worz , Udo Rheude , Wolfram Burst , Gunter Dauwel , Armin Bertram , Bernhard Schulz , Gunter Wegner , Peter Munster , Hansgeorg Ernst , Arno Kochner , Heinz Etzrodt
发明人： Walter Dobler , Wolfgang Krause , Joachim Paust , Otto Worz , Udo Rheude , Wolfram Burst , Gunter Dauwel , Armin Bertram , Bernhard Schulz , Gunter Wegner , Peter Munster , Hansgeorg Ernst , Arno Kochner , Heinz Etzrodt
IPC分类号： C07C51/16 , C07C403/00 , C07C403/20
CPC分类号： C07C403/20 , C07C403/16 , C07B2200/09 , C07C2101/16
摘要： A process for preparing polyenecarbonyl compounds having a high all-E content and their acetals or ketals by aldol condensation or Horner-Emmons reaction comprises carrying out the reaction, for the purposes of the preferred formation of a double bond of E configuration and in order to maintain the E configuration of the double bonds in the stating compounds as completely as possible, in the presence of oxygen or an oxygen-inert gas mixture or nitric oxide or a nitric oxide-inert gas mixture and/or in the presence of specific stable radicals and/or in the presence of quinones or quinone derivatives.
摘要翻译：通过醛醇缩合或霍纳 - 埃蒙斯反应制备具有高全E含量的多元羰基化合物及其缩醛或缩酮的方法包括进行反应，为了优选形成E构型的双键，为了在氧气或氧惰性气体混合物或一氧化氮或一氧化氮惰性气体混合物的存在下和/或在特定的稳定基团的存在下，尽可能地完全地保持化合物中双键的E构型和/或在醌或醌衍生物的存在下。

13. 发明授权

US5584802A Elastic knee-joint bandage 失效
标题翻译：弹性膝关节绷带
公开(公告)号：US5584802A
公开(公告)日：1996-12-17
申请号：US532841
申请日：1995-10-06
申请人： Heinrich Hess , Wolfgang Krause , Hans B. Bauerfeind
发明人： Heinrich Hess , Wolfgang Krause , Hans B. Bauerfeind
IPC分类号： A63B71/08 , A61F13/06 , A61F5/00
CPC分类号： A61F13/061
摘要： An elastic knee support is designed as a flexible tube (5) with an elastic profiled insert (6) in the area of the hollow of the knee. The profiled insert extends across the axis of the leg, covering the sinews (11,12) of the hollow of the knee. Recesses (7,8) which receive each one sinew of the hollow of the knee interrupt on both sides of the sinews of the hollow of the knee supporting zones of the profiled insert which exercise a pressure on the hollow of the knee.
摘要翻译： PCT No.PCT / EP94 / 00979 Sec。 371日期1995年10月6日 102（e）日期1995年10月6日PCT 1994年3月28日PCT公布。出版物WO94 / 22404 日期1994年10月13日弹性膝盖支撑设计为柔性管（5），在膝盖中空区域具有弹性异型插入件（6）。异形刀片横跨腿部的轴线延伸，覆盖膝盖中空部分的筋骨（11,12）。接收膝盖中空部分的每个凹槽的凹槽（7,8）在对膝盖的中空部分施加压力的异型插入件的膝盖支撑区域的中空部分的中心的两侧中断。

14. 发明授权

US5295460A Hydraulic valve play equalization element 失效
标题翻译：液压阀打均衡元件
公开(公告)号：US5295460A
公开(公告)日：1994-03-22
申请号：US012687
申请日：1993-02-03
申请人： Klaus Dohring , Wolfgang Krause
发明人： Klaus Dohring , Wolfgang Krause
IPC分类号： F01L1/24 , F01L1/25
CPC分类号： F01L1/25 , Y10T74/2107
摘要： A hydraulic valve play equalization element for the valve drive of an internal combustion engine is disclosed. The equalization element comprises an inner tappet and an outer tappet arranged to move relative to one another in the axial direction. The outside tappet is formed by an essentially cup-shaped housing with a level bottom and the inside tappet and the outside tappet delimit an oil-filled storage space which is sealed towards the outside and which can change in volume. A displacement element to equalize volume changes is enclosed in the storage space. The outside tappet is formed by an essentially tube-shaped mantle of thermoplastic material, which has slide surfaces radially inside and outside. The mantle is closed off with a fluid seal, by a disk structured as an expeller, in the direction of a cam shaft that is used. The inside slide surface encloses the inside tappet, resting against its circumference, and forming a fluid seal.
摘要翻译：公开了一种用于内燃机的阀驱动的液压阀游隙均衡元件。均衡元件包括内部挺杆和外部挺杆，其布置成在轴向方向上相对于彼此移动。外部挺杆由基本上具有水平底部的杯形壳体形成，并且内部挺杆和外部挺杆限定了向外部密封并且可能改变体积的充满油的储存空间。用于均衡音量变化的位移元件包含在存储空间中。外部挺杆由基本上管状的热塑性材料罩形成，其具有径向内部和外部的滑动表面。通过使用的凸轮轴的方向，通过作为推进器构成的盘形的流体密封封闭地幔。内部滑动表面包围内部挺杆，靠在其周边上，并形成流体密封。

15. 发明申请

US20130230476A1 Fragrance Compositions Comprising Special Mixtures of Diastereomers of 2-Isobutyl-4-Methyl-Tetrahydro-2H-Pyran-4-OL 审中-公开
标题翻译：包含2-异丁基-4-甲基 - 四氢-2H-吡喃-4-醇的非对映异构体的特殊混合物的香料组合物
公开(公告)号：US20130230476A1
公开(公告)日：2013-09-05
申请号：US13884503
申请日：2011-11-08
申请人： Ralf Pelzer , Wolfgang Krause , Karl Beck , Francis Bocris
发明人： Ralf Pelzer , Wolfgang Krause , Karl Beck , Francis Bocris
IPC分类号： C11B9/00
CPC分类号： C11B9/008
摘要： The present invention relates to a fragrance composition comprising a mixture of diastereomers of 2-isobutyl-4-methyl-tetrahydro-2H-pyran-4-ol, which comprises more than 95 wt. % of the optically inactive cis-racemate and less than 5 wt. % of the optically inactive trans-racemate. The present invention further relates to a method for producing a perfumed product or article as well as perfumed or aromatized articles comprising the fragrance compositions of the present invention.
摘要翻译：本发明涉及包含2-异丁基-4-甲基 - 四氢-2H-吡喃-4-醇的非对映异构体的混合物的香料组合物，其包含大于95wt。％的光学活性的顺式外消旋物和小于5wt。％的光学无活性反式外消旋物。本发明还涉及一种用于生产加香产品或制品的方法，以及包含本发明的香料组合物的加香或芳香化制品。

16. 发明授权

US08337442B2 Ankle joint orthosis 有权
标题翻译：踝关节矫形器
公开(公告)号：US08337442B2
公开(公告)日：2012-12-25
申请号：US12439982
申请日：2007-09-05
申请人： Heinrich Hess , Rainer Scheuermann , Wolfgang Krause
发明人： Heinrich Hess , Rainer Scheuermann , Wolfgang Krause
IPC分类号： A61F5/00
CPC分类号： A61F5/0111
摘要： The invention relates to an ankle orthosis comprising a U-shaped support stirrup made of a flexible material, the sides of which stirrup converge beneath the foot in a web projecting as a tab toward the metatarsus, extend past the bones, and are held together at their end regions by a fastening strap wrapping around the leg. The tab has a convexity, which presses against the cuboid bone of the foot due to a preloading of the tab.
摘要翻译：本发明涉及一种踝关节矫形器，其包括由柔性材料制成的U形支撑箍，其两侧的镫骨在脚下方会聚在以朝向跖骨的突出部突出的腹板中延伸超过骨骼，并且保持在一起它们的端部区域通过围绕腿部的紧固带缠绕。突片具有凸起，其由于突片的预加载而压靠脚的长方体骨。

17. 发明授权

US07608742B2 Diarylphenoxy aluminum compounds 有权
标题翻译：二芳基苯氧基铝化合物
公开(公告)号：US07608742B2
公开(公告)日：2009-10-27
申请号：US11817468
申请日：2006-03-03
申请人： Marko Friedrich , Klaus Ebel , Norbert Götz , Wolfgang Krause , Christian Zahm
发明人： Marko Friedrich , Klaus Ebel , Norbert Götz , Wolfgang Krause , Christian Zahm
IPC分类号： C07C35/08 , C07F5/06
CPC分类号： C07F5/069
摘要： The present invention relates to diarylphenoxyaluminum compounds which are obtainable by reacting a bis(diarylphenol) ligand of the formula (I) with an alkylaluminum compound and/or a complex aluminum hydride. The invention moreover relates to the use of such diarylphenoxyaluminum compounds as catalysts.Moreover, the invention relates to a method of producing isopulegol by cyclization of citronellal in the presence of diarylphenoxyaluminum compounds as catalysts.The invention also relates to a method of producing menthol by cyclization of citronellal in the presence of diarylphenoxyaluminum compounds as catalysts and subsequent hydrogenation.
摘要翻译：本发明涉及通过使式（I）的双（二芳基苯酚）配体与烷基铝化合物和/或络合氢化铝反应得到的二芳基苯氧基铝化合物。本发明还涉及这种二芳基苯氧基铝化合物作为催化剂的用途。此外，本发明涉及通过在二芳基苯氧基铝化合物作为催化剂的存在下环绕香茅醛来生产异ule醇的方法。本发明还涉及在二芳基苯氧基铝化合物作为催化剂和随后的氢化存在下，通过香茅醛环化生产薄荷醇的方法。

18. 发明申请

US20080177100A1 Method For Producing Saturated Nitriles 有权
标题翻译：生产饱和腈的方法
公开(公告)号：US20080177100A1
公开(公告)日：2008-07-24
申请号：US11910295
申请日：2006-04-07
申请人： Jan Eberhardt , Wolfgang Krause
发明人： Jan Eberhardt , Wolfgang Krause
IPC分类号： C07C253/30
CPC分类号： C07C253/30 , C07C255/03
摘要： The present invention relates to a process for the preparation of saturated nitrites by catalytic hydrogenation of the corresponding olefinically unsaturated compounds in the presence of a supported transition metal catalyst at a pressure of from 1 to 95 bar. Specifically, the invention relates to a process for the preparation of tetrahydrogeranonitrile (3,7-dimethyloctanenitrile) by catalytic hydrogenation of geranonitrile.
摘要翻译：本发明涉及一种在负载过渡金属催化剂存在下，在1-95巴的压力下，通过催化氢化相应的烯属不饱和化合物来制备饱和亚硝酸盐的方法。具体地说，本发明涉及通过γ-葡聚糖的催化氢化制备四氢呋喃腈（3,7-二甲基辛腈）的方法。

19. 发明申请

US20080167504A1 Diarylphenoxy Aluminum Compounds 有权
标题翻译：二芳基苯氧基铝化合物
公开(公告)号：US20080167504A1
公开(公告)日：2008-07-10
申请号：US11817468
申请日：2006-03-03
申请人： Marko Friedrich , Klaus Ebel , Norbert Gotz , Wolfgang Krause , Christian Zahm
发明人： Marko Friedrich , Klaus Ebel , Norbert Gotz , Wolfgang Krause , Christian Zahm
IPC分类号： C07C39/04 , C07C35/12
CPC分类号： C07F5/069
摘要： The present invention relates to diarylphenoxyaluminum compounds which are obtainable by reacting a bis(diarylphenol) ligand of the formula (I) with an alkylaluminum compound and/or a complex aluminum hydride.The invention moreover relates to the use of such diarylphenoxyaluminum compounds as catalysts.Moreover, the invention relates to a method of producing isopulegol by cyclization of citronellal in the presence of diarylphenoxyaluminum compounds as catalysts.The invention also relates to a method of producing menthol by cyclization of citronellal in the presence of diarylphenoxyaluminum compounds as catalysts and subsequent hydrogenation.
摘要翻译：本发明涉及通过使式（I）的双（二芳基苯酚）配体与烷基铝化合物和/或络合氢化铝反应得到的二芳基苯氧基铝化合物。本发明还涉及这种二芳基苯氧基铝化合物作为催化剂的用途。此外，本发明涉及通过在二芳基苯氧基铝化合物作为催化剂的存在下环绕香茅醛来生产异ule醇的方法。本发明还涉及在二芳基苯氧基铝化合物作为催化剂和随后的氢化存在下，通过香茅醛环化生产薄荷醇的方法。

20. 发明授权

US5717128A Preparation of alkylesters of 0,0-dialkyl-4-phosphono-2-methyl-2-butenoic acid and alkyl esters of 4-halo-2-methyl-2-butenoic acid containing a high percentage of E isomers 失效
标题翻译：制备0-0-二烷基-4-膦酰基-2-甲基-2-丁烯酸的烷基酯和含有高百分比的E异构体的4-卤代-2-甲基-2-丁烯酸的烷基酯
公开(公告)号：US5717128A
公开(公告)日：1998-02-10
申请号：US535637
申请日：1995-09-28
申请人： Wolfgang Krause , Hansgeorg Ernst , Joachim Paust , Udo Rheude , Walter Dobler
发明人： Wolfgang Krause , Hansgeorg Ernst , Joachim Paust , Udo Rheude , Walter Dobler
IPC分类号： C07C67/307 , C07F9/40 , C07C69/65
CPC分类号： C07F9/4015 , C07C67/307
摘要： A process for the preparation of alkyl esters of 0,0-dialkyl-4-phosphono-2-methyl-2-butenoic acid containing a high percentage of E isomers, wherein the corresponding alkyl esters of 2-hydroxy-2-methyl-3-butenoic acid are caused to react with PBr.sub.3 or PCl.sub.3 at temperatures ranging from 0.degree. to 80.degree. C. in the absence of pyridine and, if desired, the resulting mixture comprising predominantly alkyl esters of 4-halo-2-methyl-2-butenoic acid is caused to react with trialkyl esters of phosphorous acid at temperatures ranging from 70.degree. to 140.degree. C. The end products are desirable C.sub.5 building blocks for polyene syntheses or preceding stages.
摘要翻译：一种制备含有高百分比的E异构体的0-二烷基-4-膦酰基-2-甲基-2-丁烯酸的烷基酯的方法，其中相应的2-羟基-2-甲基-3 在不存在吡啶的情况下，在0℃至80℃的温度范围内引发 - 丁烯酸与PBr 3或PCl 3反应，如果需要，所得混合物主要包含4-卤代-2-甲基-2- 使丁烯酸在70℃至140℃的温度范围内与亚磷酸三烷基酯反应。最终产物是用于多烯合成或先前阶段的所需C5构建块。

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