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    • 11. 发明授权
    • Inorganic/organic dispersant and application thereof
    • 无机/有机分散剂及其应用
    • US08653147B2
    • 2014-02-18
    • US13300585
    • 2011-11-20
    • Jiang-Jen LinYen-Chi HsuMing-Li ChiangChien-Chia Chu
    • Jiang-Jen LinYen-Chi HsuMing-Li ChiangChien-Chia Chu
    • B01F3/12C01B33/44B01J31/26
    • B01F17/0007B01F17/005
    • The present invention discloses an inorganic/organic mixed component (I/O) dispersant and applications thereof, which is primarily applied to dispersing nanoparticles of metal oxides. The I/O dispersant of the present invention can be a composite of inorganic clay and an organic surfactant, a composite of inorganic clay and polyoxyalkylene-amine, or a composite of inorganic clay, polyisobutylene succinic anhydride (PIB-SA) and hydrochloric acid salt or tetraalkyl quaternary salt of polyoxyalkylene-amine, or fatty amines. By mixing with the I/O dispersant of the present invention, nanoparticles of a metal oxide can be uniformly dispersed without aggregation particularly at high solid content. The dispersion has a lower viscosity and is relatively stable in storage even at high temperature.
    • 本发明公开了一种主要用于分散金属氧化物纳米颗粒的无机/有机混合组分(I / O)分散剂及其应用。 本发明的I / O分散剂可以是无机粘土和有机表面活性剂的复合物,无机粘土和聚氧化烯胺的复合物,或无机粘土,聚异丁烯琥珀酸酐(PIB-SA)和盐酸盐 或聚氧化烯 - 胺的四烷基季盐,或脂肪胺。 通过与本发明的I / O分散剂混合,金属氧化物的纳米颗粒可以均匀地分散而不聚集,特别是在高固体含量下。 分散体具有较低的粘度,即使在高温下也具有相对稳定的储存性。
    • 13. 发明申请
    • INORGANIC/ORGANIC DISPERSANT AND APPLICATION THEREOF
    • 无机/有机分散剂及其应用
    • US20090146107A1
    • 2009-06-11
    • US12146449
    • 2008-06-26
    • Jiang-Jen LinYen-Chi HsuMing-Li ChiangChien-Chia Chu
    • Jiang-Jen LinYen-Chi HsuMing-Li ChiangChien-Chia Chu
    • B01F3/18
    • B01F17/0007B01F17/005
    • The present invention discloses an inorganic/organic mixed component (I/O) dispersant and applications thereof, which is primarily applied to dispersing nanoparticles of metal oxides. The I/O dispersant of the present invention can be a composite of inorganic clay and an organic surfactant, a composite of inorganic clay and polyoxyalkylene-amine, or a composite of inorganic clay, polyisobutylene succinic anhydride (PIB-SA) and hydrochloric acid salt or tetraalkyl quaternary salt of polyoxyalkylene-amine, or fatty amines. By mixing with the I/O dispersant of the present invention, nanoparticles of a metal oxide can be uniformly dispersed without aggregation particularly at high solid content. The dispersion has a lower viscosity and is relatively stable in storage even at high temperature.
    • 本发明公开了一种主要用于分散金属氧化物纳米颗粒的无机/有机混合组分(I / O)分散剂及其应用。 本发明的I / O分散剂可以是无机粘土和有机表面活性剂的复合物,无机粘土和聚氧化烯胺的复合物,或无机粘土,聚异丁烯琥珀酸酐(PIB-SA)和盐酸盐 或聚氧化烯 - 胺的四烷基季盐,或脂肪胺。 通过与本发明的I / O分散剂混合,金属氧化物的纳米颗粒可以均匀地分散而不聚集,特别是在高固体含量下。 分散体具有较低的粘度,即使在高温下也具有相对稳定的储存性。
    • 15. 发明授权
    • Polymeric polyamines and method for stabilizing silver nanoparticle by employing the same
    • 聚合多胺及其使用方法稳定银纳米颗粒
    • US08013048B2
    • 2011-09-06
    • US12140507
    • 2008-06-17
    • Jiang-Jen LinWei-Cheng TsaiYen-Chi HsuWen-Hsin Chang
    • Jiang-Jen LinWei-Cheng TsaiYen-Chi HsuWen-Hsin Chang
    • C08K3/08C08K5/3415C08K5/20C08K5/107C08K5/05C08F26/00
    • C08F26/00
    • The present invention discloses a polymeric polyamine which can be produced by polymerizing polyoxyalkylene-amine and a linker. The linker can be anhydride, carboxylic acid, epoxy, isocyanate or poly(styrene-co-maleic anhydride) copolymers (SMA). The present invention also discloses a method for stabilizing the Ag nanoparticles with polymeric polyamine. The polymeric polyamine serving as a stabilizer or dispersant is mixed with a water solution of silver salt and then a reducer is provided to reduce the silver ions and form an organic or a water solution of Ag nanoparticles. Water or solvent of this solution can be further removed through a heating, freezing or decompression process, and thus solid content of the solution can be increased. The concentrated solution also can be diluted to obtain a stable dispersion without aggregation.
    • 本发明公开了一种聚合多胺,其可通过聚合聚氧亚烷基 - 胺和连接体而制备。 接头可以是酐,羧酸,环氧,异氰酸酯或聚(苯乙烯 - 共 - 马来酸酐)共聚物(SMA)。 本发明还公开了一种用聚合多胺稳定Ag纳米颗粒的方法。 用作稳定剂或分散剂的聚合多胺与银盐水溶液混合,然后提供还原剂以还原银离子并形成Ag纳米颗粒的有机或水溶液。 该溶液的水或溶剂可以通过加热,冷冻或减压方法进一步除去,从而可以提高溶液的固体含量。 浓缩溶液也可以稀释以获得稳定的分散体而不凝聚。
    • 20. 发明授权
    • Exfoliative clay and derivative thereof and method for producing the same
    • 剥离性粘土及其衍生物及其制造方法
    • US07022299B2
    • 2006-04-04
    • US10270209
    • 2002-10-15
    • Jiang-Jen LinChin-Cheng ChouTzong-Yuan Juang
    • Jiang-Jen LinChin-Cheng ChouTzong-Yuan Juang
    • C01B33/12
    • C01B33/44
    • The present invention discloses an exfoliative clay and a derivative thereof and a method for producing the same. The exfoliative clay is formed by emulsion exfoliating an inorganic layered silicate clay with an amphibious intercalating agent by powerfully stirring at 60–180° C. and not less than 14.7 psig. The amphibious intercalating agent is obtained by copolymerizing polyoxyalkylene amine having molecular weight over 1,800 and polypropylene-grafting-maleic anhydride (PP-g-MA). Before emulsion exfoliation, the intercalating agent is acidified with an inorganic acid. The acidification is the key step for obtaining nanoscale of emulsifying particles less than 100 nm for the exfoliation. The exfoliative clay can be further extracted with a hydroxide or a chloride of alkali metal or alkaline-earth metal to obtain a derivative in the form of nanosilica plates which is free of organic portions.
    • 本发明公开了一种剥离性粘土及其衍生物及其制造方法。 通过在60-180℃和不低于14.7psig的强力搅拌下将无机层状硅酸盐粘土与两栖嵌入剂乳化成剥离形成剥离性粘土。 通过共聚分子量超过1800的聚氧亚烷基胺和聚丙烯接枝 - 马来酸酐(PP-g-MA)获得两栖嵌入剂。 在乳液脱落之前,插入剂用无机酸酸化。 酸化是获得纳米级乳化颗粒小于100nm的剥落的关键步骤。 剥离性粘土可以用碱金属或碱土金属的氢氧化物或氯化物进一步提取,得到无机部分的纳米二氧化硅板形式的衍生物。