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    • 15. 发明授权
    • Crosslinking of polymers and foams thereof
    • 聚合物和泡沫的交联
    • US06325956B2
    • 2001-12-04
    • US09140004
    • 1998-08-26
    • Bharat I. ChaudharyThoi H. HoSeema V. KarandeChe-I. KaoRobert H. TerbrueggenDavid A. BabbClark H. CumminsMichael J. MullinsH. Craig Silvis
    • Bharat I. ChaudharyThoi H. HoSeema V. KarandeChe-I. KaoRobert H. TerbrueggenDavid A. BabbClark H. CumminsMichael J. MullinsH. Craig Silvis
    • B29C4402
    • The invention includes a process comprising (a) forming a polymeric admixture including at least one polyolefin which has been prepared using a single site catalyst and at least a crosslinking amount of at least one poly(sulfonyl azide) crosslinking agent; (b) shaping the resulting admixture; and (c) heating the resulting shaped admixture to a temperature at least the decomposition temperature of the crosslinking agent. The steps take place in any sequence and optionally include substeps. The single site catalyst is preferably a constrained geometry or metallocene catalyst, but optionally another transition metal catalyst which is not a traditional Ziegler Natta Ti/MgCl2 catalyst such as a vanadium catalyst. The invention further includes all compositions obtainable by the process of the invention as well as all articles formed from these compositions. The articles are preferably thermoformed, compression molded, injection molded, extruded, cast, blow molded, blown, profile extruded, spun, foamed or molded of any composition of the invention. The invention includes a use of any composition of the invention in any process of thermoforming, injection molding, extrusion, casting, blow molding, spinning, blowing, profile extrusion, foaming, compression molding or a combination thereof.
    • 本发明包括一种方法,其包括(a)形成包含至少一种聚烯烃的聚合物混合物,所述聚合物混合物已经使用单中心催化剂和至少交联量的至少一种聚(磺酰基叠氮化物)交联剂制备; (b)成型所得混合物; 和(c)将所得成形的混合物加热至至少交联剂的分解温度的温度。 步骤以任何顺序进行,并且可选地包括子步骤。 单中心催化剂优选为约束几何形状或茂金属催化剂,但可选地为不是传统的齐格勒 - 纳塔Ti / MgCl 2催化剂如钒催化剂的另一种过渡金属催化剂。 本发明还包括通过本发明的方法获得的所有组合物以及由这些组合物形成的所有制品。 制品优选是由本发明的任何组合物进行热成型,压塑,注射成型,挤出,铸造,吹塑,吹塑,型材挤出,纺丝,发泡或模制的。 本发明包括在热成型,注射成型,挤出,铸造,吹塑,纺丝,吹塑,型材挤出,发泡,压缩成型或其组合的任何方法中使用本发明的任何组合物。
    • 19. 发明授权
    • Paintable olefinic interpolymer compositions
    • 可涂漆烯烃互聚物组合物
    • US5883188A
    • 1999-03-16
    • US926760
    • 1997-09-10
    • Yuh-Chin HwangStephen R. BetsoThomas J. McKeand, Jr.H. Craig SilvisDeepak R. ParikhDon J. GermanoSeema V. Karande
    • Yuh-Chin HwangStephen R. BetsoThomas J. McKeand, Jr.H. Craig SilvisDeepak R. ParikhDon J. GermanoSeema V. Karande
    • C08L51/06C08L51/00
    • C08L51/06Y10T428/31938
    • Paintable thermoplastic polyolefin compositions are disclosed which comprise (i) about 20 to about 70 wt % of at least one graft-modified polypropylene, (ii) about 10 to about 40 wt % of at least one nongrafted or graft-modified homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, styrene block copolymer, or a combination thereof and (iii) about 5 to about 50 wt % of an interpolymer of ethylene and an .alpha.,.beta.-unsaturated carbonyl copolymer, e.g. a copolymer of ethylene and acrylic acid. The polypropylene and, optionally the homogeneously branched linear ethylene polymer, ethylene-propylene monomer rubber, ethylene-propylene-diene monomer rubber, heterogeneously branched linear ethylene polymer, and styrene block copolymer are grafted with an unsaturated organic compound containing at least one site of ethylenic unsaturation and at least one carbonyl group, e.g. maleic anhydride. The compositions exhibit excellent paintability with conventional paints without prior application of a primer or surface treatment, good heat resistance, good low temperature impact resistance, and they can be recycled by melt blending the compositions with thermoplastic materials, e.g., in an extruder.
    • 公开了可涂覆的热塑性聚烯烃组合物,其包含(i)约20至约70重量%的至少一种接枝改性聚丙烯,(ii)约10至约40重量%的至少一种未接枝或接枝改性的均匀支化的线型乙烯 聚合物,乙烯 - 丙烯单体橡胶,乙烯 - 丙烯 - 二烯单体橡胶,非均匀支化的线性乙烯聚合物,苯乙烯嵌段共聚物或其组合,和(iii)约5-约50wt%的乙烯和α的互聚物, β-不饱和羰基共聚物,例如 乙烯和丙烯酸的共聚物。 聚丙烯和任选的均匀支化的线性乙烯聚合物,乙烯 - 丙烯单体橡胶,乙烯 - 丙烯 - 二烯单体橡胶,非均匀支化的线性乙烯聚合物和苯乙烯嵌段共聚物用含有至少一个烯属的位点的不饱和有机化合物 不饱和键和至少一个羰基,例如 马来酸酐。 组合物在常规涂料中表现出优异的可涂色性,而无需预先施用底漆或表面处理,良好的耐热性,良好的低温耐冲击性,并且它们可以通过将组合物与热塑性材料(例如在挤出机中)熔融共混来再循环。