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    • 18. 发明授权
    • Process for producing amines from olefins on zeolites of types SSZ-33,
CIT-1 or mixtures thereof
    • 在SSZ-33,CIT-1型沸石及其混合物上由烯烃生产胺的方法
    • US5886226A
    • 1999-03-23
    • US406
    • 1998-01-29
    • Karsten EllerRudolf KummerPeter Stops
    • Karsten EllerRudolf KummerPeter Stops
    • C07D295/02B01J29/70C07B61/00C07C209/60C07C211/07C07D207/323
    • C07C209/60
    • A process for preparing amines of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.2 -C.sub.20 -alkynyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.20 -alkylcycloalkyl, C.sub.4 -C.sub.20 -cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 -alkylaryl or C.sub.7 -C.sub.20 -aralkyl,R.sup.1 and R.sup.2 are together a saturated or unsaturated C.sub.3 -C.sub.9 -alkylene dichain, andR.sup.3 or R.sup.5 are each C.sub.21 -C.sub.200 -alkyl or C.sub.21 -C.sub.200 -alkenyl or together a C.sub.2 -C.sub.12 -alkylene dichain by reacting olefins of the general formula II ##STR2## where R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each as defined above, with ammonia or primary or secondary amines of the general formula III ##STR3## where R.sup.1 and R.sup.2 are each as defined above, at temperatures from 200.degree. to 350.degree. C. and pressures from 100 to 300 bar in the presence of a heterogeneous catalyst, comprises using a heterogeneous catalyst comprising zeolites of the type SSZ-26, SSZ-33, CIT-1 or mixtures thereof.
    • PCT No.PCT / EP96 / 05406 Sec。 371日期1998年1月29日 102(e)1998年1月29日PCT PCT 1996年12月4日PCT公布。 公开号WO97 / 21661 日期:1996年6月19日制备通式I(I)的胺的方法,其中R 1,R 2,R 3,R 4,R 5和R 6各自为氢,C 1 -C 20 - 烷基,C 2 -C 20 - 烯基,C 2 C 20 - 炔基,C 3 -C 20 - 环烷基,C 4 -C 20 - 烷基环烷基,C 4 -C 20 - 环烷基烷基,芳基,C 7 -C 20 - 烷基芳基或C 7 -C 20 - 芳烷基,R 1和R 2一起是饱和或不饱和的C 3 -C 9 - 亚烷基二烯和R3或R5各自为C 21 -C 200 - 烷基或C 21 -C 200-链烯基或通过使上述定义的通式II的烯烃与C 2 -C 12 - 亚烷基二醇的氨或仲胺或仲胺 在非均相催化剂的存在下,在200℃至350℃的温度和100至300巴的压力下,通式III“IMAGE”包括使用包含SSZ-26型,SSZ-33型沸石, CIT-1或其混合物。
    • 20. 发明授权
    • Preparation of amines from olefins over zeolites of the type SSZ-37
    • 通过SSZ-37型沸石从烯烃制备胺
    • US5739405A
    • 1998-04-14
    • US760296
    • 1996-12-04
    • Karsten EllerRudolf KummerPeter Stops
    • Karsten EllerRudolf KummerPeter Stops
    • B01J29/06C07B61/00C07C209/60C07C211/03C07C211/07C07C211/17C07C211/21C07C211/25C07C211/26C07C211/35C07C211/40C07C211/45
    • C07C209/60Y02P20/582
    • A process for the preparation of amines of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 denote hydrogen, C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.3 -C.sub.20 cycloalkyl, C.sub.4 -C.sub.20 alkylcycloalkyl, C.sub.4 -C.sub.20 cycloalkylalkyl, aryl, C.sub.7 -C.sub.20 alkylaryl, or C.sub.7 -C.sub.20 aralkyl, R.sup.1 and R.sup.2 together denote a saturated or unsaturated C.sub.3 -C.sub.9 alkylene dichain and R.sup.3 or R.sup.5 denotes C.sub.21 -C.sub.200 alkyl, C.sub.21 -C.sub.200 alkenyl or they together form a C.sub.2 -C.sub.12 alkylene dichain, by the reaction of olefins of the general formula II ##STR2## in which R.sup.3, R.sup.4, R.sup.5, and R.sup.6 have the above meanings, with ammonia or primary or secondary amines of the general formula III ##STR3## in which R.sup.1 and R.sup.2 have the above meanings, at temperatures ranging from 200.degree. to 350.degree. C. and pressures ranging from 100 to 300 bar in the presence of a heterogeneous catalyst, wherein the heterogeneous catalyst used is a zeolite of the type SSZ-37.
    • 制备通式I(I)的胺的方法,其中R 1,R 2,R 3,R 4,R 5,R 6表示氢,C 1 -C 20烷基,C 2 -C 20烯基,C 2 -C 20炔基,C 3 -C 20环烷基,C 4 -C 20烷基环烷基,C 4 -C 20环烷基烷基,芳基,C 7 -C 20烷基芳基或C 7 -C 20芳烷基,R 1和R 2一起表示饱和或不饱和的C 3 -C 9亚烷基二
      烯基,R 3或R 5表示C 21 -C 200烷基 C21 -C200烯基或它们一起形成C 2 -C 12亚烷基二酮,通过其中R3,R4,R5和R6具有上述含义的通式II(II)的烯烃与氨或 在其中R1和R2具有上述含义的通式III(III)的伯或仲胺中,在200-350℃的温度和100-300巴的压力范围内,在异质的存在下 催化剂,其中所用的非均相催化剂是SSZ-37型沸石。