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11. 发明申请

US20110160503A1 PROCESS FOR PREPARING A SUPPORTED CATALYST BASED ON Ni AND A METAL FROM GROUP IB, FOR THE SELECTIVE HYDROGENATION OF POLYUNSATURATED HYDROCARBONS 审中-公开
标题翻译：用于制备基于Ni和来自IB组的金属的支持催化剂的方法，用于选择性加氢聚合烃
公开(公告)号：US20110160503A1
公开(公告)日：2011-06-30
申请号：US12856932
申请日：2010-08-16
申请人： Lars FISCHER , Anne Claire Dubreuil , Cecile Thomazeau , Layane Deghedi , Jean Pierre Candy , Jean Marie Basset , Fabienne Le Peltier
发明人： Lars FISCHER , Anne Claire Dubreuil , Cecile Thomazeau , Layane Deghedi , Jean Pierre Candy , Jean Marie Basset , Fabienne Le Peltier
IPC分类号： C07C5/00 , B01J23/89 , B01J37/025 , B01J37/16 , B01J21/08 , B01J37/06
CPC分类号： C10G45/36 , B01J21/08 , B01J23/755 , B01J23/892 , B01J37/0203 , B01J37/0205 , B01J37/0213 , B01J37/18 , C07C5/05 , C07C2523/755 , C07C15/073
摘要： A process is described for preparing a catalyst comprising at least one porous support and at least one metallic phase containing nickel and at least one metal M from group IB in a proportion such that the molar ratio M/Ni is in the range 0.005 to 0.5, said process comprising at least the following steps in succession: a1) depositing nickel on at least said support in order to obtain a supported nickel-based monometallic catalyst; b1) depositing, in the presence of at least one reducing gas and in the absence of any aqueous solvent, at least one organometallic compound of at least said metal M onto said monometallic catalyst.
摘要翻译：描述了一种制备催化剂的方法，该催化剂包含至少一种多孔载体和至少一种含有镍和至少一种金属M的金属相，其比例使得M / Ni的摩尔比在0.005至0.5的范围内，所述方法至少包括以下步骤：a1）在至少所述载体上沉积镍以获得负载的镍基单金属催化剂; b1）在至少一种还原气体存在下，在不存在任何水性溶剂的情况下，将至少一种至少所述金属M的有机金属化合物沉积在所述单金属催化剂上。

12. 发明授权

US06315892B1 Catalytic hydroreforming process 失效
标题翻译：催化加氢成型工艺
公开(公告)号：US06315892B1
公开(公告)日：2001-11-13
申请号：US09688167
申请日：2000-10-16
申请人： Fabienne Le Peltier , Blaise Didillon , Patrick Sarrazin , Jean-Paul Boitiaux
发明人： Fabienne Le Peltier , Blaise Didillon , Patrick Sarrazin , Jean-Paul Boitiaux
IPC分类号： C10G35085
CPC分类号： B01J23/622 , B01J23/62 , B01J37/0205 , C10G35/09 , Y10S502/506 , Y10S502/513 , Y10S502/514
摘要： A process of hydroreforming in the presence of a catalyst containing at least one refractory inorganic carrier, platinum, possibly at least one metal from Group VIII (palladium, nickel, and ruthenium), a halogen or compound thereof, and at least one additional metal M selected from among germanium, tin, lead, gallium, indium, and thallium, process in which said metal M, in the form of at least one organic compound, is introduced in situ into the reactor where the hydrocarbon charge will then be treated or into a prereactor that is connected to said reactor.
摘要翻译：在含有至少一种难熔性无机载体的铂的催化剂存在下进行加氢反应的方法，铂，可能的至少一种来自第VIII族（钯，镍和钌）的金属，卤素或其化合物，以及至少一种另外的金属M 选自锗，锡，铅，镓，铟和铊的方法，其中将至少一种有机化合物形式的所述金属M原位引入反应器中，其中烃装料将被处理或进入连接到所述反应器的预反应器。

13. 发明授权

US06187985B1 Process for dehydrogenating saturated aliphatic hydrocarbons to olefinic hydrocarbons 有权
标题翻译：将饱和脂肪烃脱氢成烯烃的方法
公开(公告)号：US06187985B1
公开(公告)日：2001-02-13
申请号：US09182660
申请日：1998-10-30
申请人： Fabienne Le Peltier , Blaise Didillon , Olivier Clause
发明人： Fabienne Le Peltier , Blaise Didillon , Olivier Clause
IPC分类号： C07C202
CPC分类号： C07C5/3335 , B01J23/622 , B01J37/0203 , C07C5/3337 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/62 , C07C11/02
摘要： A process for dehydrogenating C5-C22 aliphatic hydrocarbons to the corresponding olefinic hydrocarbons is carried out in the presence of a catalyst comprising at least one support, at least one metal from group VIII of the periodic table and at least one additional element M selected from the group formed by germanium, tin, lead, rhenium, gallium, indium, and thallium. The process is characterized in that the catalyst is prepared using a process in which said metal M is introduced in an aqueous solvent in the form of at least one organometallic compound comprising at least one carbon-M bond.
摘要翻译：将C5-C22脂族烃脱氢成相应的烯烃的方法是在催化剂存在下进行的，所述催化剂包含至少一种载体，至少一种来自元素周期表第VIII族的金属和至少一种选自由锗，锡，铅，铼，镓，铟和铊形成的组。该方法的特征在于，使用其中所述金属M以包含至少一个碳-M键的至少一种有机金属化合物的形式引入水性溶剂中的方法制备催化剂。

14. 发明授权

US5336829A Continuous process for the dehydrogenation of paraffinic to olefinic hydrocarbons 失效
标题翻译：链烷烃到烯烃脱氢的连续方法
公开(公告)号：US5336829A
公开(公告)日：1994-08-09
申请号：US37117
申请日：1993-03-25
申请人： Jean-Paul Boitiaux , Jean De Bonneville , Jean-Pierre Burzynski , Gerard Leger , Fabienne Le Peltier , Germain Martino
发明人： Jean-Paul Boitiaux , Jean De Bonneville , Jean-Pierre Burzynski , Gerard Leger , Fabienne Le Peltier , Germain Martino
IPC分类号： B01J23/90 , B01J29/90 , B01J38/44 , C07C5/333
CPC分类号： B01J38/44 , B01J23/90 , B01J29/90 , C07C5/3337 , C07C2523/04 , C07C2523/14 , C07C2523/40 , C07C2523/42 , C07C2529/06 , Y02P20/584
摘要： A continuous process for the dehydrogenation of paraffinic and olefinic hydrocarbons in the presence of a catalyst comprises circulating a charge containing said paraffinic hydrocarbons through at least two reactions zones of the moving bed type which are arranged in series, the catalyst flowing successively in each reaction zone. The catalyst which is drawn off from the last reaction zone is sent to a regeneration zone at the exit from which it is reintroduced close to the first reaction zone. The process comprises the injection of sulphur and/or at least one sulphur compound before or simultaneously to the introduction of the charge into the first reaction zone. In accordance with the process, the catalyst which is drawn off from the last reaction zone is sent into a stripping zone wherein the sulphur which it contains is removed before the catalyst is sent to the regeneration zone.
摘要翻译：在催化剂存在下，链烷烃和烯烃的脱氢的连续方法包括使包含所述链烷烃的进料通过串联排列的移动床型的至少两个反应区循环，催化剂在每个反应区中依次流动。从最后一个反应区抽出的催化剂被送到出口处的再生区，在该再生区再次引入靠近第一反应区的再生区。该方法包括在将电荷引入第一反应区之前或同时注入硫和/或至少一种硫化合物。根据该方法，将从最后反应区抽出的催化剂送入汽提区，其中在将催化剂送至再生区之前将其所含的硫除去。

15. 发明授权

US5112591A Process for preparing precursors of catalysts containing copper, aluminum and zinc, usable for the synthesis and the decomposition of methanol 失效
标题翻译：用于合成和分解甲醇的铜，铝和锌的催化剂前体的制备方法
公开(公告)号：US5112591A
公开(公告)日：1992-05-12
申请号：US656892
申请日：1991-02-19
申请人： Patrick Chaumette , Fabienne Le Peltier , Raymond F. Szymanski , Philippe Courty , Catherine Verdon
发明人： Patrick Chaumette , Fabienne Le Peltier , Raymond F. Szymanski , Philippe Courty , Catherine Verdon
IPC分类号： C01B3/32 , B01J23/80 , B01J37/03 , C07C29/153 , C07C29/154 , C07C31/02
CPC分类号： C07C29/154 , B01J23/80 , B01J37/03 , Y02P20/52
摘要： The present invention relates to a process for preparing a precursor of a catalyst containing copper, aluminum and zinc.This precursor is formed by the mixing of two ternary precursors, at different stages of their manufacturing, these two ternary precursors being different from one another in their metallic stoichiometry (atomic ratios between Cu, Zn and Al), in their crystallographic structure and in their elemental morphology.The catalyst obtained from this precursor can be used in particular for the synthesis of methanol.

16. 发明授权

US5019547A Process for preparing precursors of catalysts containing copper, aluminum and zinc, usable for the synthesis and the decomposition of methanol and catalysts obtained from the precursors 失效
标题翻译：制备含有铜，铝和锌的催化剂前体的方法，可用于甲醇的合成和分解以及从前体获得的催化剂
公开(公告)号：US5019547A
公开(公告)日：1991-05-28
申请号：US514059
申请日：1990-04-24
申请人： Patrick Chaumette , Fabienne Le Peltier , Raymond Szymanski , Philippe Courty , Catherine Verdon
发明人： Patrick Chaumette , Fabienne Le Peltier , Raymond Szymanski , Philippe Courty , Catherine Verdon
IPC分类号： C01B3/32 , B01J23/80 , B01J37/03 , C07C29/153 , C07C29/154 , C07C31/02
CPC分类号： C07C29/154 , B01J23/80 , B01J37/03 , Y02P20/52
摘要： The present invention relates to a process for preparing a precursor of a catalyst containing copper, aluminum and zinc.This precursor is formed by the mixing of two ternary precursors, at different stages of their manufacturing, these two ternary precursors being different from one another in their metallic stoichiometry (atomic ratios between Cu, Zn and Al), in their crystalographic structure and in their elemental morphology.The catalyst obtained from this precursor can be used in particular for the synthesis of methanol.
摘要翻译：本发明涉及一种制备含有铜，铝和锌的催化剂前体的方法。这种前体是通过混合两种三元前体在其制造的不同阶段形成的，这两种三元前体在其金属化学计量学（Cu，Zn和Al之间的原子比），它们的晶体结构和它们的结构中彼此不同元素形态。从该前体获得的催化剂可特别用于合成甲醇。

17. 发明申请

US20110045596A1 PROCESS AND INSTALLATION FOR TESTING CATALYSTS 有权
标题翻译：过程和安装测试催化剂
公开(公告)号：US20110045596A1
公开(公告)日：2011-02-24
申请号：US12668992
申请日：2008-06-24
申请人： Olivier Ducreux , Fabienne Le Peltier , Cyril Collado
发明人： Olivier Ducreux , Fabienne Le Peltier , Cyril Collado
IPC分类号： G01N31/10
CPC分类号： B01J8/0285 , B01J8/008 , B01J8/0453 , B01J35/00 , B01J2208/00061 , B01J2208/00407 , B01J2208/00814 , B01J2208/00964 , B01J2208/00973 , B01J2219/00286 , B01J2219/00495 , B01J2219/00585 , B01J2219/00747 , G01N31/10
摘要： The invention relates to a process for testing performance levels and/or changes over time of at least one catalyst CAT for a fixed-bed reactor comprising at least the following stages: A device for a CT test, comprising at least one hollow metal cartridge MC that contains in particular the catalyst CAT, is connected at a point A of an industrial chemical installation that uses a reaction feedstock that is suitable for testing the catalyst CAT, At point A, a liquid stream that consists of a fraction that is less than or equal to 1% of the preheated reagents circulating in the industrial chemical installation that is circulated in the cartridge MC through the catalyst CAT is sampled at a reaction temperature for a period T, At least a fraction of the effluent of the cartridge MC is sampled for chemical analysis, Optionally, the device for the CT test of the industrial chemical installation is isolated without stopping its operation, and at least a fraction of the catalyst CAT is sampled for physical and/or chemical analysis. The invention also relates to an industrial chemical installation that comprises the device for the CT bypass test.
摘要翻译：本发明涉及一种用于测试至少一种用于固定床反应器的至少一种催化剂CAT的性能水平和/或随时间变化的方法，该固定床反应器至少包括以下阶段：用于CT测试的装置，包括至少一个中空金属盒MC 其特别包含催化剂CAT在工业化学设备的A点处连接，工业化学设备使用适合于测试催化剂CAT的反应原料。在A点，由低于或等于相当于在通过催化剂CAT循环在筒MC中的工业化学设备中循环的预热试剂的1％在反应温度下进行一段时间T的采样，对盒式MC的至少一部分流出物进行取样化学分析，任选地，用于工业化学设备的CT测试的装置被隔离而不停止其操作，并且至少一部分催化剂CAT被采样用于物理和/或化学分析。本发明还涉及一种工业化学设备，其包括用于CT旁路测试的装置。

18. 发明申请

US20110016950A1 METHOD AND APPARATUS FOR DETECTING AND QUANTIFYING A CHEMICAL COMPOUND IN A FLUID FLOW 有权
标题翻译：检测和定量流体化学化合物的方法和装置
公开(公告)号：US20110016950A1
公开(公告)日：2011-01-27
申请号：US12669227
申请日：2008-06-24
申请人： Olivier Ducreux , Fabienne Le Peltier , Cyril Collado
发明人： Olivier Ducreux , Fabienne Le Peltier , Cyril Collado
IPC分类号： G01N30/02 , G01N21/33 , G01N21/35 , H01J49/26 , G01R33/44 , G01N25/00 , G01J3/46
CPC分类号： G01N1/4005 , G01N1/2214 , G01N1/2247 , G01N2001/4011
摘要： The invention concerns a method for capturing a chemical compound, typically an impurity, and for accumulating said chemical compound on a capture mass CAPT included in at least one removable adsorbant cartridge MC over a long period exceeding 2 days, with a view to the external chemical analysis thereof.The invention also concerns an apparatus ST suitable for capturing at least one chemical compound in a fluid flow for its detection and/or quantification comprising, downstream of said cartridge or cartridges, at least one means for measuring the cumulative flow which has traversed said cartridge or cartridges over a set time period. In a preferred variation of the invention, the capture mass CAPT is fragmented into a plurality of elementary masses CAPTi which allowing the spread of an irreversible adsorption front or the displacement of a chromatographic zone to be determined.
摘要翻译：本发明涉及一种用于捕获化合物（通常为杂质）的方法，并且用于在长时间超过2天的时间内将包含在至少一个可移除吸附剂盒MC中的捕获质量CAPT积聚在所述化学化合物上，分析。本发明还涉及适于捕获流体流中的至少一种化学化合物用于其检测和/或定量的装置ST，其包括在所述药筒或药筒的下游，至少一种用于测量已经穿过所述药筒的累积流量的装置墨盒在一段时间内。在本发明的优选变型中，捕获质量CAPT被分段成多个基本质量CAPTi，其允许确定不可逆吸附前沿的扩散或色谱区的位移。

19. 发明申请

US20100168493A1 PROCESS FOR DEHYDROGENATION IN THE PRESENCE OF A BIMETALLIC OR MULTI-METALLIC CATALYST THAT HAS AN OPTIMIZED BIMETALLICITY INDEX AND AN OPTIMIZED HYDROGEN ADSORPTION CAPACITY 有权
标题翻译：双金属或多金属催化剂存在下的脱氢方法，其具有优化的二元指数和优化的氢吸附能力
公开(公告)号：US20100168493A1
公开(公告)日：2010-07-01
申请号：US12520445
申请日：2007-12-07
申请人： Fabienne Le Peltier , Sylvie Lacombe , Christophe Chau , Stephane Morin , Lars Fischer , Renaud Revel
发明人： Fabienne Le Peltier , Sylvie Lacombe , Christophe Chau , Stephane Morin , Lars Fischer , Renaud Revel
IPC分类号： C07C5/333
CPC分类号： B01J23/626 , B01J21/04 , B01J23/62 , B01J35/1019 , B01J35/1042 , B01J37/0063 , B01J37/0207 , B01J37/06 , C07C5/3337 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/42 , C10G35/09 , C07C11/02
摘要： The invention relates to a process for dehydrogenation of a hydrocarbon feedstock in the presence of a catalyst that comprises a noble metal M that is selected from the group that consists of platinum, palladium, rhodium, and iridium, at least one promoter X1 that is selected from the group that consists of tin, germanium, and lead, and optionally a promoter X2 that is selected from the group that consists of gallium, indium and thallium, an alkaline or alkaline-earth compound and a porous substrate, in which the atomic ratio X1/M and optionally X2/M is between 0.3 and 8, the Hir/M ratio that is measured by hydrogen adsorption is greater than 0.40, and the bimetallicity index BMI that is measured by hydrogen/oxygen titration is greater than 108.
摘要翻译：本发明涉及一种在催化剂存在下烃原料脱氢的方法，所述催化剂包含贵金属M，所述贵金属M选自由铂，钯，铑和铱组成的组，所述催化剂选自至少一个选自来自由锡，锗和铅组成的组，以及任选的选自由镓，铟和铊，碱金属或碱土金属化合物和多孔基材组成的组的启动子X2，其中原子比 X1 / M和任选的X2 / M在0.3和8之间，通过氢吸附测量的Hir / M比大于0.40，并且通过氢/氧滴定测量的双金属指数BMI大于108。

20. 发明授权

US06294696B1 Process for hydrogenating organic functions 有权
标题翻译：氢化有机功能的工艺
公开(公告)号：US06294696B1
公开(公告)日：2001-09-25
申请号：US09182635
申请日：1998-10-30
申请人： Blaise Didillon , Fabienne Le Peltier
发明人： Blaise Didillon , Fabienne Le Peltier
IPC分类号： C07C20900
CPC分类号： C07C209/36 , B01J23/62 , B01J23/626 , B01J37/0203 , B01J37/086 , C07B31/00 , C07C29/141 , C07C211/46 , C07C33/02
摘要： A process for hydrogenating organic compounds containing at least one function selected from aldehyde, ketone, ester, acid and nitro functions and/or containing an aromatic group is carried out in the presence of a catalyst comprising at least one support, at least one metal from group VIII of the periodic table and at least one additional element M selected from the group formed by germanium, tin, lead, rhenium, gallium, indium, gold, silver and thallium. The process is characterized in that the catalyst is prepared using a process in which said metal M is introduced in an aqueous solvent, in the form of at least one organometallic compound comprising at least one carbon-M bond.
摘要翻译：用于氢化含有至少一种选自醛，酮，酯，酸和硝基官能团和/或含有芳族基团的官能团的官能团的有机化合物的方法是在催化剂存在下进行的，所述催化剂包括至少一种载体，元素周期表VIII族和选自锗，锡，铅，铼，镓，铟，金，银和铊中的至少一种另外的元素M. 该方法的特征在于，使用其中所述金属M以包含至少一个碳-M键的至少一种有机金属化合物的形式引入水性溶剂的方法制备催化剂。

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