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    • 16. 发明申请
    • PROCESS FOR PREPARING (METH)ACRYLIC ESTERS OF N,N-SUBSTITUTED AMINO ALCOHOLS
    • 制备N,N-取代氨基醇的(甲基)丙烯酸酯的方法
    • US20120077977A1
    • 2012-03-29
    • US13236893
    • 2011-09-20
    • Virginie BetteHermann BergmannJochen PetzoldtFrank Höfer
    • Virginie BetteHermann BergmannJochen PetzoldtFrank Höfer
    • C07C67/02C07D295/185C07D295/15
    • C07D295/088
    • The present invention relates to a process for preparing (meth)acrylic esters (F) of N,N-substituted amino alcohols, by transesterifying N,N-substituted amino alcohols (I) in which Y and Z are each independently C1-C20-alkyl, C3-C15-cycloalkyl, aryl, or Y and Z together with the nitrogen atom connecting them form a 5- to 9-membered saturated heterocyclic radical which optionally has oxygen, sulfur, nitrogen or C1-C4-alkyl-substituted nitrogen as a further heteroatom, and X is C2-C20-alkylene which may be interrupted by 1 to 10 nonadjacent oxy groups and/or unsubstituted or methoxy-substituted C1-C4-alkylimino groups, or a C3-C15-cycloalkylene, with at least one (meth)acrylic ester (D) in the presence of at least one heterogeneous catalyst (K), wherein the heterogeneous catalyst (K) is used without any further solvent and the content of polymerization inhibitors in the reaction mixture is
    • 本发明涉及一种制备N,N-取代氨基醇的(甲基)丙烯酸酯(F)的方法,其中N,N-取代的氨基醇(I),其中Y和Z各自独立地为C 1 -C 20 - 烷基,C 3 -C 15 - 环烷基,芳基或Y和Z与连接它们的氮原子一起形成5-至9-元饱和杂环基,其任选具有氧,硫,氮或C 1 -C 4 - 烷基取代的氮作为 另外的杂原子,X是可被1-10个不相邻的氧基和/或未被取代的或甲氧基取代的C 1 -C 4烷基亚氨基或C 3 -C 15 - 亚环烷基间隔的C 2 -C 20亚烷基,其中至少有一个 (甲基)丙烯酸酯(D)在至少一种非均相催化剂(K)的存在下使用,其中非均相催化剂(K)不使用任何其它溶剂而使用,反应混合物中的聚合抑制剂的含量<450ppm,和 涉及使用N,N-取代的氨基醇的(甲基)丙烯酸酯(F)。
    • 18. 发明申请
    • PROCESS FOR PREPARING (METH)ACRYLIC ESTERS OF N-HYDROXYALKYLATED IMIDAZOLES
    • 制备N-羟基甲基咪唑的(甲基)丙烯酸酯的方法
    • US20100004462A1
    • 2010-01-07
    • US12525686
    • 2008-02-11
    • Hermann Bergmann
    • Hermann Bergmann
    • C07D233/64
    • C07D233/60
    • A process for preparing (meth)acrylic esters (F) of N-hydroxyalkylated imidazoles, wherein N-hydroxyalkylated imidazoles (I), in which R1 and R2 may each independently be hydrogen or C1-C20-alkyl, R3, R4 and R5 are each independently hydrogen or C1-C20-alkyl, C1-C20-alkylcarbonyl, C2-C20-alkenyl, C2-C20-alkenylcarbonyl, C2-C20-alkynyl, C2-C20-alkynylcarbonyl, C3-C15-cycloalkyl, C3-C15-cycloalkylcarbonyl, aryl, arylcarbonyl, a heterocycle or a halogen atom, and m and n are each integers in the range of in each case from 0 to 20, where m and n cannot simultaneously be 0, and in which the particular units bracketed by the variables m and n are present in any sequence, and in which, in the case that m≧2, the R1 and R2 radicals are in each case independent in the particular units, in the presence of at least one catalyst (K), are esterified with (meth)acrylic acid (S) or transesterified with at least one (meth)acrylic ester (D).
    • 制备N-羟烷基化咪唑的(甲基)丙烯酸酯(F)的方法,其中R 1和R 2可各自独立地为氢或C 1 -C 20烷基,R 3,R 4和R 5为N-羟烷基化的咪唑(I) 各自独立地为氢或C 1 -C 20烷基,C 1 -C 20烷基羰基,C 2 -C 20 - 烯基,C 2 -C 20 - 烯基羰基,C 2 -C 20炔基,C 2 -C 20炔基羰基,C 3 -C 15 - 环烷基,C 3 -C 15 - 环烷基羰基,芳基,芳基羰基,杂环或卤素原子,m和n各自为0〜20的整数,m和n不能同时为0,其中由 变量m和n以任何顺序存在,并且在m> = 2的情况下,R1和R2基团在每种情况下在特定单元中独立,在至少一种催化剂(K)的存在下, 被(甲基)丙烯酸(S)酯化,或与至少一种(甲基)丙烯酸酯(D)酯交换。
    • 19. 发明申请
    • USE OF TRIARYLAMINE DERIVATIVES AS HOLE-CONDUCTING MATERIALS IN ORGANIC SOLAR CELLS AND ORGANIC SOLAR CELLS CONTAINING SAID TRIARYLAMINE DERIVATIVES
    • 在有机太阳能电池和含有三胺衍生物的有机太阳能电池中使用三胺衍生物作为导电材料
    • US20110297235A1
    • 2011-12-08
    • US13202878
    • 2010-02-15
    • Hermann Bergmann
    • Hermann Bergmann
    • H01L51/46C07D209/88C07D409/04C07C211/54
    • H01L51/006H01L51/0059H01L51/0061H01L51/0068H01L51/4226Y02E10/549
    • The present invention relates to the use of compounds of the general formula I in which A1, A2, A3 are each independently divalent organic units which may comprise one, two or three optionally substituted aromatic or heteroaromatic groups, where, in the case of two or three aromatic or heteroaromatic groups, two of these groups in each case are joined to one another by a chemical bond and/or via a divalent alkyl radical, R1, R2, R3 are each independently R, OR, NR2, A3-OR or A3-NR2 substituents, R is alkyl, aryl or a monovalent organic radical which may comprise one, two or three optionally substituted aromatic or heteroaromatic groups, where, in the case of two or three aromatic or heteroaromatic groups, two of these groups in each case are joined to one another by a chemical bond and/or via a divalent alkyl or NR′ radical, R′ is alkyl, aryl or a monovalent organic radical which may comprise one, two or three optionally substituted aromatic or heteroaromatic groups, where, in the case of two or three aromatic or heteroaromatic groups, two of these groups in each case are joined to one another by a chemical bond and/or via a divalent alkyl radical, and n at each instance in formula I is independently 0, 1, 2 or 3, with the proviso that the sum of the individual values n is at least 2 and at least two of the R1, R2 and R3 radicals are OR and/or NR2 substituents, as hole-conducting materials in organic solar cells. The present invention further relates to organic solar cells which comprise these compounds.
    • 本发明涉及通式I化合物的用途,其中A1,A2,A3各自独立地为可以包含一个,两个或三个任选取代的芳族或杂芳族基团的二价有机单元,其中在两个或两个 三种芳族或杂芳族基团,每种情况下这些基团中的两个通过化学键和/或经由二价烷基彼此连接,R1,R2,R3各自独立地为R,OR,NR2,A3-OR或A3 -NR2取代基,R是烷基,芳基或可以包含一个,两个或三个任选取代的芳族或杂芳族基团的单价有机基团,其中在两个或三个芳族或杂芳族基团的情况下,在每种情况下这些基团中有两个 通过化学键和/或通过二价烷基或NR'基团彼此连接,R'是烷基,芳基或可以包含一个,两个或三个任选取代的芳族或杂芳族基团的单价有机基团,其中, 的 两种或三种芳族或杂芳族基团的情况,每种情况下这些基团中的两个通过化学键和/或经由二价烷基彼此连接,式I中每一个实例中的n独立地为0,1,2 或3,条件是各个值n的总和至少为2,并且R 1,R 2和R 3基团中的至少两个为OR和/或NR 2取代基,作为有机太阳能电池中的空穴导电材料。 本发明还涉及包含这些化合物的有机太阳能电池。