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11. 发明授权

US5245082A Process for the production of di-(4-aminocyclohexyl)-methane containing 15 to 25% by weight of the trans-trans isomer 失效
标题翻译：制备含有15至25重量％反式异构体的二（4-氨基环己基）甲烷的方法
公开(公告)号：US5245082A
公开(公告)日：1993-09-14
申请号：US4382
申请日：1993-01-14
申请人： Otto Immel , Gerhard Darsow , Rudolf Braden , Hans-Helmut Schwarz , Helmut Waldmann
发明人： Otto Immel , Gerhard Darsow , Rudolf Braden , Hans-Helmut Schwarz , Helmut Waldmann
IPC分类号： B01J23/46 , C07C209/72
CPC分类号： B01J23/462 , C07C209/72 , C07C2101/14
摘要： Di-(4-aminocyclohexyl)-methane containing 15 to 25% by weight of the trans-trans isomer can be obtained by the catalytic hydrogenation of di-(4-aminophenyl)-methane at elevated temperature and elevated hydrogen pressure in the presence of a ruthenium-containing supported catalyst containing 0.05 to 5% by weight ruthenium on an Al.sub.2 O.sub.3 support which has been treated with compounds of rare earth metals and manganese.
摘要翻译：含有15-25％（重量）反式异构体的二 - （4-氨基环己基） - 甲烷可以通过二 - （4-氨基苯基） - 甲烷在升高的温度下催化氢化和升高氢气压力含有0.05〜5重量％钌的含钌载体的Al 2 O 3载体上已经用稀土金属和锰化合物处理。

12. 发明授权

US4745176A Catalytic process for preparing polycumylene from .alpha.-cumyl halide 失效
标题翻译：从α-枯基卤化物制备聚亚甲基的催化方法
公开(公告)号：US4745176A
公开(公告)日：1988-05-17
申请号：US678167
申请日：1984-12-04
申请人： Robert Becker , Ludwig Bottenbruch , Johann Grolig , Helmut Waldmann
发明人： Robert Becker , Ludwig Bottenbruch , Johann Grolig , Helmut Waldmann
IPC分类号： C08G61/00 , C08G61/02
CPC分类号： C08G61/02
摘要： Polycumylene of a relatively high degree of polymerization is obtained in a reasonable space-time yield by Friedel-Crafts alkylation of .alpha.-cumyl halide when catalyst composition, catalyst concentration and dilution ratio are selected within certain limits.
摘要翻译：当催化剂组成，催化剂浓度和稀释比选择在一定限度内时，通过Friedel-Crafts烷基化反应，以合适的时空产率获得较高聚合度的聚亚甲基。

13. 发明授权

US4341709A Preparation of .epsilon.-caprolactone 失效
标题翻译： ε-己内酯的制备
公开(公告)号：US4341709A
公开(公告)日：1982-07-27
申请号：US150260
申请日：1980-05-15
申请人： Willi Hofen , Herbert Klenk , Gerd Schreyer , Otto Weiberg , Helmut Waldmann , Hermann Seifert , Karl-Hermann Reissinger , Wolfgang Swodenk
发明人： Willi Hofen , Herbert Klenk , Gerd Schreyer , Otto Weiberg , Helmut Waldmann , Hermann Seifert , Karl-Hermann Reissinger , Wolfgang Swodenk
IPC分类号： C07D313/04 , C07D315/00 , C07D313/02
CPC分类号： C07D315/00
摘要： A process for the preparation of .epsilon.-caprolactone comprising:(a) reacting cyclohexanone with a solution of perpropionic acid in an organic solvent at a molar ratio of cyclohexanone;perpropionic acid of about 1.1-5:1 at a temperature of about 10.degree. to 80.degree. C. to form a reaction mixture consisting essentially of .epsilon.-caprolactone, propionic acid and organic solvent,(b) distilling the reaction mixture from (a) in a first distillation unit to obtain a distillate comprising the organic solvent and a distillation residue,(c) introducing the distillation residue from (b) at a point into a second distillation unit to obtain a distillate comprising propionic acid and unreacted cyclohexanone, removing from the second distillation unit, separately from one another and at a point below the point of introduction into the second distillation unit, .epsilon.-caprolactone and any high-boiling constituents, and,(d) distilling in a third distillation unit the distillate from (c) to obtain a distillate consisting essentially of propionic acid and a distillation residue comprising a mixture of propionic acid and cyclohexanone.
摘要翻译：一种制备ε-己内酯的方法，包括：（a）使环己酮与过丙酸在有机溶剂中的溶液以环己酮的摩尔比约1.1-5:1的约0.1〜5:1的摩尔比在约10℃〜形成基本上由ε-己内酯，丙酸和有机溶剂组成的反应混合物，（b）在第一蒸馏单元中将反应混合物从（a）中蒸馏，得到包含有机溶剂和蒸馏残余物的馏出物（c）在一点将来自（b）的蒸馏残余物引入第二蒸馏单元以获得包含丙酸和未反应的环己酮的馏出物，从第二蒸馏单元彼此分离并在低于引入第二蒸馏装置，ε-己内酯和任何高沸点组分，和（d）在第三蒸馏装置中蒸馏出馏出物（c）得到基本上由丙酸组成的馏出物和包含丙酸和环己酮的混合物的蒸馏残渣。

14. 发明授权

US4324925A Process for the preparation of polyhydric phenols 失效
标题翻译：多元酚的制备方法
公开(公告)号：US4324925A
公开(公告)日：1982-04-13
申请号：US164444
申请日：1980-06-30
申请人： Christoph Jupe , Helmut Waldmann , Hermann Seifert
发明人： Christoph Jupe , Helmut Waldmann , Hermann Seifert
IPC分类号： C07C27/00 , C07C37/60 , C07C37/82 , C07C39/08 , C07C51/00 , C07C59/52 , C07C65/01 , C07C67/00 , C07C201/00 , C07C205/23 , C07C213/00 , C07C215/74 , C07C253/00 , C07C255/53 , C07C39/12 , C07C79/24 , C07C91/30 , C07C149/36
CPC分类号： C07C37/60 , C07C37/82
摘要： An improved process for the preparation of a polyhydric phenol by hydroxylation of a phenol with a peroxidic hydroxylating agent, is disclosed. The improvement resides in that before the hydroxylation, all or some of the mixture to be hydroxylated is treated with a cation exchanger.
摘要翻译：公开了通过用过氧羟基化剂羟基化苯酚制备多元酚的改进方法。改进之处在于在羟基化之前，用阳离子交换剂处理待羟基化的所有或一些混合物。

15. 发明授权

US4013709A Production of .omega.-formyl carboxylic acid esters 失效
标题翻译：生产“7-甲酰基羧酸酯”
公开(公告)号：US4013709A
公开(公告)日：1977-03-22
申请号：US651989
申请日：1976-01-23
申请人： Helmut Waldmann , Wulf Schwerdtel , Wolfgang Swodenk
发明人： Helmut Waldmann , Wulf Schwerdtel , Wolfgang Swodenk
IPC分类号： C07C69/67 , C07C67/00
CPC分类号： C07C69/67
摘要： A process for the production of an .omega.-formyl carboxylic acid ester, comprising reacting an enol ether of a cyclic ketone with hydrogen peroxide in the presence of at least one catalyst selected from the group consisting of a compound of boron or of a metal of the Fifth or Sixth Secondary Group of the Periodic Table. Advantageously the enol ether has the formula ##STR1## wherein R.sub.1 is alkyl of 1 to about 3 carbon atoms, cycloalkyl of 5 or 6 carbon atoms or phenyl optionally substituted by fluorine, chlorine, alkoxy of 1 to about 3 carbon atoms, cyano or phenyl,n is an integer of about 3 to 10, andR.sub.2 each independently is hydrogen, fluorine, chlorine, cyano, alkoxy of 1 to about 4 carbon atoms, alkyl of 1 to about 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms or phenyl optionally substituted by fluorine, chlorine, cyano, alkoxy of 1 to about 4 carbon atoms or alkyl of 1 to about 6 carbon atoms,And the catalyst comprises about 15 to 25 mole % based on the hydrogen peroxide of a boron oxide, a boric acid, a salt of a boric acid, a boron halogen compound, a complex boron compound or a boric acid ester of the formula ##STR2## wherein R.sub.4, R.sub.5 and R.sub.6 each independently is alkyl of 1 to about 6 carbon atoms optionally substituted by hydroxyl, fluorine, chlorine, alkoxy of 1 to about 3 carbon atoms or phenyl, cycloalkyl of 5 to 7 carbon atoms or phenyl optionally substituted by fluorine, chlorine or alkyl of 1 to about 3 carbon atoms,Or about 0.01 to 1 mole % of at least one acetate, benzoate, acetylacetonate or naphthenate of a metal of the Fifth or Sixth Group of the Periodic table.

16. 发明授权

US5801285A Process for the preparation of 2-methyl-2,4-diaminopentane 失效
标题翻译： 2-甲基-2,4-二氨基戊烷的制备方法
公开(公告)号：US5801285A
公开(公告)日：1998-09-01
申请号：US961675
申请日：1997-10-31
申请人： Helmut Waldmann , Jurgen Dahmer , Anatoly Bazanov , Alexandre Timofeev , Natalja Zubritskaya , Gennady Terechtchenko
发明人： Helmut Waldmann , Jurgen Dahmer , Anatoly Bazanov , Alexandre Timofeev , Natalja Zubritskaya , Gennady Terechtchenko
IPC分类号： C07C209/26 , C07C209/62 , C07C211/09 , C07C211/11 , C07D239/06
CPC分类号： C07D239/06 , C07C209/62
摘要： The present invention relates to a process for preparing 2-methyl-2,4-diaminopentane by introducing acetone, ammonia and hydrogen into a two-zone reactor at a temperature of 20.degree. to 130.degree. C. and a pressure of 30 to 250 bar, wherein the first zone contains a cationic exchange resin containing NH.sub.4.sup..sym. groups or an aluminum oxide and/or silicon oxide catalyst and the second zone contains a hydrogenation catalyst containing nickel.
摘要翻译：本发明涉及一种通过将丙酮，氨和氢气在20℃至130℃的温度和30至250巴的压力下引入双区反应器中制备2-甲基-2,4-二氨基戊烷的方法，其中所述第一区含有含有NH 4（+）基团的阳离子交换树脂或氧化铝和/或氧化硅催化剂，所述第二区含有含镍的氢化催化剂。

17. 发明授权

US5552549A Process for the dechlorination of chlorinated aromatic compounds 失效
标题翻译：氯化芳烃化合物脱氯工艺
公开(公告)号：US5552549A
公开(公告)日：1996-09-03
申请号：US315001
申请日：1994-09-29
申请人： Christian Rasp , Helmut Waldmann , Hans-Joachim Traenckner
发明人： Christian Rasp , Helmut Waldmann , Hans-Joachim Traenckner
IPC分类号： A62D3/32 , A62D101/22 , C07B35/06 , C07B61/00 , C07C1/26 , C07C15/04 , C07C17/23 , C07C25/02 , C07D213/06 , C07D213/61 , C07D215/18 , C07D217/22 , C07D319/24 , C07D217/00 , C07C1/20 , C07C22/00 , C07D309/00
CPC分类号： A62D3/32 , A62D2101/22
摘要： Chlorinated aromatic compounds are dechlorinated in a simple and inexpensive manner by heating them to 300.degree. to 450.degree. C. in a salt melt in the presence of water and/or water vapor and carbon.
摘要翻译：氯化芳族化合物以简单且便宜的方式通过在水和/或水蒸气和碳的存在下在盐熔体中加热至300-450℃进行脱氯。

18. 发明授权

US5434310A Process for the preparation of acylbenzenes 失效
标题翻译：酰基苯的制备方法
公开(公告)号：US5434310A
公开(公告)日：1995-07-18
申请号：US180516
申请日：1994-01-12
申请人： Helmut Waldmann , Manfred Hajek , Otto Immel , Lothar Puppe , Rudolf Braden
发明人： Helmut Waldmann , Manfred Hajek , Otto Immel , Lothar Puppe , Rudolf Braden
IPC分类号： B01J29/76 , B01J29/70 , B01J29/78 , B01J29/86 , B01J29/87 , B01J29/88 , C07B61/00 , C07C45/46 , C07C49/76 , C07C49/78 , C07C49/786 , C07C45/45
CPC分类号： C07C45/46
摘要： Acylbenzenes of the formula ##STR1## can be prepared by reaction of benzene with carboxylic acids of the formulaHOOC--R.sup.1 (II)where R.sup.1 has the meaning given in the text, using a molar ratio of benzene:carboxylic acid=1-50:1 at a temperature of 200.degree.-400.degree. C., a zeolite of the Pentasil type having an SiO.sub.2 /M.sup.2 O.sub.2 ratio of 15-500:1 being used as acid catalyst; in the latter formula, M.sup.2 is one element or more from the group comprising Al, B, Ga, In, Fe, Cr, V, As and Sb.
摘要翻译：式（I）的酰基苯可以通过苯与式HOOC-R1（II）的羧酸反应来制备，其中R 1具有本文给出的含义，使用苯：羧酸的摩尔比= 1 -50：1，温度为200-400℃，使用SiO 2 / M 2 O 2比为15-500:1的Pentasil型沸石作为酸催化剂; 在后一公式中，M2是由Al，B，Ga，In，Fe，Cr，V，As和Sb组成的组中的一种以上。

19. 发明授权

US5369947A Process for converting plastic waste into power 失效
标题翻译：将塑料废物转化为电力的过程
公开(公告)号：US5369947A
公开(公告)日：1994-12-06
申请号：US120630
申请日：1993-09-13
申请人： Hans-Ulrich Dummersdorf , Helmut Waldmann
发明人： Hans-Ulrich Dummersdorf , Helmut Waldmann
IPC分类号： B01D53/34 , C08J11/12 , C10B53/00 , C10B53/07 , C10J3/46 , F01K23/10 , F01K27/02 , F02C3/20 , F02C3/28 , F02C6/18 , F23G5/027 , H02K44/28 , H02N11/00 , F02C3/26
CPC分类号： F02C6/18 , C10B53/07 , C10J3/482 , F02C3/28 , C10J2200/12 , C10J2200/158 , C10J2300/1238 , C10J2300/165 , C10J2300/1675 , Y02E20/12 , Y02E20/14 , Y02E20/16 , Y02E50/11 , Y02E50/12 , Y02P20/123 , Y02P20/124 , Y02P20/129 , Y02P20/143
摘要： The plastic waste is reacted in a plasma reactor 3 under reducing conditions in a plasma containing substoichiometric oxygen at temperatures above 1200.degree. C. to form a plasma pyrolysis gas consisting of low molecular weight carbon fragments which is then cooled to temperatures below 1500.degree. C. The cooled plasma pyrolysis gas is then delivered in compressed form as a fuel of high calorific value and high temperature to a gas turbine 10 for generating power. The waste heat of this gas turbine is used to generate steam which is fed into a steam turbine 12 for generating more power. The process is suitable for plastic waste of any composition and leads to complete conversion into a gas of high calorific value so that a high exergetic efficiency level is achieved.
摘要翻译：塑料废料在等离子体反应器3中在还原条件下在含有亚化学计量氧的等离子体中在高于1200℃的温度下反应，以形成由低分子量碳片段组成的等离子体热解气体，然后冷却至低于1500℃的温度。然后将冷却的等离子体热解气体作为高热值和高温的燃料以压缩形式输送到用于发电的燃气轮机10。该燃气轮机的废热用于产生蒸汽，其被馈送到蒸汽涡轮机12中以产生更多的功率。该方法适用于任何组合物的塑料废料，并导致完全转化为高热值气体，从而达到高的高效率水平。

20. 发明授权

US5233072A Process for the preparation of dialkyl carbonates 失效
标题翻译：制备碳酸二甲酯的方法
公开(公告)号：US5233072A
公开(公告)日：1993-08-03
申请号：US976627
申请日：1992-11-16
申请人： Zoltan Kricsfalussy , Helmut Waldmann , Hans-Joachim Traenckner , Marko Zlokarnik , Reinhard Schomacker
发明人： Zoltan Kricsfalussy , Helmut Waldmann , Hans-Joachim Traenckner , Marko Zlokarnik , Reinhard Schomacker
IPC分类号： C07B61/00 , C07C68/00 , C07C69/96
CPC分类号： C07C68/005
摘要： To prepare C.sub.1 -C.sub.4 -dialkyl carbonates, C.sub.1 -C.sub.4 -alkanols are reacted with CO and O.sub.2 at a relatively high temperature in a salt melt containing Cu salts.
摘要翻译：为了制备C1-C4二烷基碳酸酯，C1-C4-链烷醇在含有Cu盐的盐熔体中在相当高的温度下与CO和O 2反应。

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